• Elastomers and Composites
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• 제54권4호
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• pp.335-344
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• 2019

In this work, styrene butadiene rubber (SBR) and styrene butadiene styrene (SBS) were used to modify asphalt, resulting in SBR- and SBS-modified asphalt, respectively. The two modified asphalts were emulsified with a nonionic emulsifier (Span 60) and cationic emulsifiers (ID, DDA) and their phase stabilization was investigated via particle size, Zeta potential, and flow behavior analysis. With increasing amount of the mixed emulsifier, the particle size decreased, leading to an increase in viscosity. The shear thinning behaviors and Zeta potential values ranging from 35-65 mV were determined and remained considerably stable. In addition, the adhesion strength and compression strength of the SBR-and SBS-modified asphalt emulsion were evaluated via surface free energy examination. The remarkable adhesion and compression strengths were estimated when 5 phr ID and 6 phr DDA were added to the emulsified asphalt modified with SBR and SBS. Therefore ID and DDA, the two cationic surfactants, played significant roles in improving the dispersion and interfacial adhesion strength, resulting in the improved adhesion and compression strength of the emulsified asphalts modified with SBR and SBS.

• Transactions on Electrical and Electronic Materials
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• 제1권3호
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• pp.23-28
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• 2000

A block-oxide layer was formed on the surface of Cu-based leadframe by chamical oxidation method in order to enhance the adhesion strength between Cu-based leadframe and epoxy molding compound (EMC) Using sandwiched double cantilever beam (SDCB) specimens, the adesion strength was measured in terms of interfacial fracture toughness, G$\sub$IC//Results showed that the black-oxide layer was composed of two kinds of layers: pebble-like Cu$_2$O layer and acicular CuO layer, At the initial stage of oxidation the Cu$_2$O layer was preferentially formed and thickened up to around 200 nm whithin 1 minute of the oxidation time. Then the CuO layer started to from atop of the Cu$_2$O layer and thickened up to around 1300 nm until 20 minutes. As soon as the CuO layer formed, the thickness of Cu$_2$O layer began to reduce and finally reached to around 150 nm. The pre-cleaned and the Cu$_2$O coated leadframes showed almost no adhesion of EMC, however, as the CuO precipitates appeared and became continuous, G$\sub$IC/ increased up to around 80 J/㎡. Further oxidation raised G$\sub$IC/ up. to around 100 J/㎡.

• Corrosion Science and Technology
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• 제13권5호
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• pp.186-194
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• 2014

Establishment of adhesion strength measurement procedure for marine epoxy coatings was conducted in order to ensure reliability of the test results. It was found that (1) the increase in thickness of the substrates would induce increase of pull-off strength. Especially, the increase in adhesion strength with the substrate thickness increment was attributed to the transition of stress mode to the pure tensile mode excluding bending effect. (2) The longer curing time, the higher pull-off strength. It may be due to higher cross-linking density of the coating (3) The pull-off strength increases as coating thickness increases due to the diminishment of bending effect (4) The longer drying time after water immersion, the higher pull-off strength. It may be due to the evaporation of water molecule at the coating-substrate interface.

• 폴리머
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• 제25권3호
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• pp.435-440
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• 2001

본 연구에서는 일방향 탄소/탄소 복합재료에 산화억제제로 사용된 $MoSi_2$의 첨가량에 따른 복합재료의 부착력, 파괴인성 그리고 충격강도와의 관계를 고찰하였다. 산화억제제로 사용한 이규화 몰리브덴 (MoSi$_2$)은 복합재료의 내산화 특성을 향상시키기 위하여 각각 4, 12, 20wt%의 중량비로 페놀수지에 함침시켰다. 본 연구에 있어서 복합재료의 부착력은 접촉각 측정에 의한 Wilhelmy 방정식을 사용하여 계산하였다. 파괴인성과 충격강도는 임계 세기인자 측정을 위한 3점 굴곡 시험 방법과 Izod 충격시험에 의해 각각 측정하였다. 그 결과, $MoSi_2$가 첨가된 탄소/탄소 복합재료의 파괴인성과 충격강도는 증가하였다. 특허 l2wt%의 $MoSi_2$가 첨가된 복합재료가 London dispersive 요소($W_A\;^L$)의 증가에 의한 가장 큰 부착력을 나타내었으며, 이는 복합재료의 각 구성요소간의 계면결합력 증가에 따른 결과라 사료된다.

• Restorative Dentistry and Endodontics
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• 제19권1호
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• pp.64-72
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• 1994

Zinc Phosphate Cement hand been used for about more than 100 years in luting of cast gold inlay. But many scientists had been trying to develop the new form of luting agent because the ZPC hand shown the lack of adhesiveness on the tooth structure and the toxicity to the pulp tissue. Recently many researches about the surface treatment of the cast body are being done to increase the adhesion of cement to it. The conventional Class I gold inlays were fabricated in the 20 permanent molars. After the internal surface of the cast body was sandblasted with $Al_2O_3$ particles and was tin-plated, the inlays were cemented with adhesive cement [G I cement and resin cement(Super-Bond & $Panavia_{EX}$)] and the evaluation on the adhesion pattern, adhesive strength and the fracture pattern of the adhesive cast gold inlay was compared to that of the cast gold inlay cemented conventionally with ZPC. The results were as follows : 1. The surface roughness of the cast body was increased significantly after sandblasting with the $Al_2O_3$ particles and the tin oxide layer, which was consisted of round particles, came into being. 2. The bond strength was in the order of Super-Bond, ZPC, Fuji I, $Panavia_{EX}$ group. The group cemented with Super-Bond showed statistically greater strength than the other groups(p<0.05). 3. The group cemented with ZPC was fallen apart by principal adhesion failure and that with Fuji I was by complete adhesion failure. But the group with Super-Bond showed pricncipal cohesive failure pattern and in the group with $Panavia_{EX}$, complete cohesive fracture pattern was shown and small protion of tooth structure was fractured out with cast body and the fractured surface showed the figure just as the enamel prism. 4. Various gaps were shown at the pulpal side regardless of little gap at the side walls of the cavity in all groups. Only the Super-Bond was attached to the tooth structure and the other cements were detached from both the tooth and the cast body.

• 접착 및 계면
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• 제23권4호
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• pp.101-107
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• 2022

Adhesive joints have many advantages such as weight savings, corrosion and fatigue resistance and now developed even withstand of high impact and dynamic loads. However, an adhesion has cumbersome and complicated surface preparation processes. The surface preparation step is critical in adhesive joint manufacturing in order to obtain the prescribed strength for adhesive joints. In this study, it was attempted to simplify and reduce the number of surface preparation steps, and abrasion and rapid adhesive application (ARAA) process is developed for an alternative solution. The abrasion processes are performed only for creating surface roughness in standard procedures (SP), although the abrasion processes cause surface activation itself. The results showed that there is no need the long procedures in laboratory or chemical agents for adhesion. After the abrasion process, the attracted and highly reactive fresh surface layer obtained, and its effect on bonding success is observed and analyzed in this research, in light of the essential physic and adhesion theories. Al 6061 aluminum adherends and epoxy-based adhesives were chosen for bonding processes, which is mostly used in light vehicle parts. The adherends were cleaned, treated and activated only with abrasion, and after the adhesive application the specimens were tested under quasi-static loading. The satisfied ARAA results were compared with that of the specimens fabricated by the standard procedure (SP) of adhesion processes of high impact loads.

• 접착 및 계면
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• 제8권3호
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• pp.16-23
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• 2007

폴리에스테르 편 직물들을 전류세기 5, 10, 15, 20 A로, 공급속도 5, 10, 15 m/min로 코로나 처리하였다. 이들의 표면변화를 주사전자현미경(SEM)과 X-ray 광전자분석기(XPS)로 확인하였다. 또한 물리적 성질의 변화를 인장강도, 건조 시와 습윤 시의 접착강도를 통하여 측정하였다. 접착에 사용된 접착제는 열경화성 반응형 폴리우레탄 핫 멜트 접착제이다. 대기압에서 코로나 방전처리에 의해 폴리에스테르 편 직물에 관능기들이 도입되어졌고, 표면에 요철이 발생하여 그 결과 접착력은 향상되었다. 건조 시 및 습윤 시의 접착강도를 모두 고려할 때, PET 직물의 코로나 처리에 있어 적절한 조건은 공급 속도 10 m/min, 전류 세기 15 A라 생각되며, mesh형 PET knit는 공급 속도 10 m/min, 10 A 이상의 전류세기라 생각된다.

• Journal of the Korean Wood Science and Technology
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• 제32권5호
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• pp.59-65
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• 2004

물고기의 공기 주머니인 부레를 말려 두었다가 물에 넣어 끓여서 만든 어교는 전통적인 방법으로 사용되고 있다. 어교의 경화시간에 따른 접착력과 접착력을 향상시키기 위한 방법으로 최적의 개방퇴적시간을 조사하여 어교의 접착특성을 연구하였다. TGA, DSC, FT-IR을 이용하여 경화 전과 후의 휘발성 물질(수분)의 변화량에 따른 어교의 경화특성과 어교의 반응성을 측정하였으며 자작나무 시편을 이용한 lap shear strength를 측정하여 경화시간과 개방퇴적시간에 따른 접착특성을 평가 하였다. 본 실험 결과 어교는 경화온도 22±1℃, 상대습도 43±2%에서 경화시간에 따른 접착력은 48시간에서 최대 강도를 나타냈으며 개방퇴적시간과 경화시간에 따른 접착력은 개방퇴적시간을 15분을 유지하고 6시간의 경화시간을 유지할 때 가장 높은 접착력을 나타냈다.

• 산업경영시스템학회지
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• 제23권54호
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• pp.137-144
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• 2000

The chloroprene adhesive for ladies' shoe-making applied by the cementing method in KS G 3116 has been evaluated.. For the quality test of adhesive for pump whole cut vamp using chloroprene adhesive, general property and adhesion strength were measured and duration for environmental exposure was tested. Also, a list of experiments for field application was prepared. In case of adhesion-strength measurement,, the KS G 3116 method of peel strength at end of toe was found to be reasonable by measurement through a whole length, toe to heel seat on feather edge.

• 접착 및 계면
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• 제10권2호
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• pp.84-89
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• 2009

The objective of this research was to investigate the curing behavior and adhesion performance of urea-melamine-formaldehyde (UMF) resin for the four types of UMF-1, UMF-2, UMF-3, and UMF-4 which synthesized by the staged addition of melamine. Also, various network structures of these resin types were discussed based on their different curing behavior and adhesion performance. The curing behavior was evaluated by DMTA and thermal stability was checked by TGA. Adhesion performance was evaluated by dry and wet shear strengths and the pH value of each cured resin was checked to see its effect on the adhesion performance. The results indicated that the UMF-1 resin type by the addition of melamine initially with the urea and formaldehyde at the same F/(U+M) rate showed the lowest thermal stability, rigidity (${\Delta}E^{\prime}$), temperature of tan ${\delta}$ maximum ($T_{tan}\;_{\delta}$), and wet shear strength, and pH value of cured resin. In wet shear strength, however, the UMF-4 resin type appears to be slightly higher than UMF-1 resin type.