• Title/Summary/Keyword: Additive Material

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Effect of Vinyl Ethylene Carbonate on Electrochemical Characteristics for Activated Carbon/Li4Ti5O12 Capacitors (활성탄/리튬티탄산화물 커패시터의 전기화학적 특성에 미치는 비닐에틸렌카보네이트의 영향)

  • Kwon, Yong-Kab;Choi, Ho-Suk;Lee, Joong-Kee
    • Journal of the Korean Electrochemical Society
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    • v.15 no.3
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    • pp.190-197
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    • 2012
  • We employed the vinyl ethylene carbonate (VEC) as an electrolyte additive and investigated the effect of the electrolyte additive on the electrochemical performance in hybrid capacitor. The activated carbon was adopted as cathode material, and the $Li_4Ti_5O_{12}$ oxide was used as anode material. The electrolyte was prepared with the $LiPF_6$ salt in the mixed solvent of ethylene carbonate (EC), dimethyl carbonate (DMC), and ethyl methyl carbonate(EMC). We evaluated the electrochemical performance of the hybrid capacitor with increasing the amount of the VEC electrolyte additive, which is known as the remover of oxygen functional group and the stabilizer of the electrode by reducing the surface of electrode, and obtained the superior performance data especially at the addition of the VEC electrolyte additive of around 0.7 vol%. On the contrary, the addition of the VEC more than 0.7 vol% in the electrolyte leads to the degradation in electrochemical performance of hybrid capacitor, suggesting the increase of the side reaction from the excessive VEC additive. X-ray photoelectron spectroscopy (XPS) revealed that the addition of the VEC suppressed the formation of LiF component, which is known as the insulator, on the surface of electrode. The optimized addition of VEC exhibited the improved capacity retention around 82.7% whereas the bare capacitors without VEC additive showed the 43.2% of capacity retention after 2500 cycling test.

The Microstructure and Electrical Characteristics of Pr-Based ZnO Variators with $La_2O_3$Additives ($La_2O_3$가 첨가된 Pr계 ZnO 바리스터의 미세구조와 전기적 특성)

  • 남춘우;박춘현
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.11
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    • pp.969-974
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    • 1998
  • The effects of $La_2O_3$on the microstructure and electrical characteristics of Pr-based ZnO varistors were investigated. The average grain size increased in the range of 21.9~56.3$\mu$ m with increasing $La_2O_3$additive content(0.0~2.0 mol%). La was, of course grain boundary, largely segregated at the nodal point. As $La_2O_3$additive content increases, threshold voltage and nonlinear coefficient decreased and leakage current increased. In particular, 2.0 mol% $La_2O_3$-added varistor exhibited low threshold voltage 17.0V/mm and nonlinear coefficient of about 6. Based on these results, this varistor can be said to be used as low-voltage varistor, if nonlinear coefficient is somewhat improved forward.

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Recovery Characteristics of a Flux-lock Type HTSC Fault Current Limiter after Fault Removal (자속구속형 고온초전도 사고전류 제한기의 사고제거 후 회복특성)

  • Lim, Sung-Hun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.9
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    • pp.812-815
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    • 2007
  • To apply the superconducting fault current limiter(SFCL) into a power system, the analysis for its recovery characteristics as well as the consideration for its cooperation with other protecting machine such as a circuit breaker is required. The recovery characteristics of the flux-lock type SFCL like its current limiting characteristics are dependent on the winding direction of two coils. In this paper, the experiments of the current limiting and the recovery characteristics of the flux-lock type SFCL with YBCO thin film were performed. From the analysis on the experimental results due to the winding direction of two coils, the limited fault current in case of the additive polarity winding was observed to be lower than that for the case of the subtractive polarity winding. In addition, the recovery time was found to be faster in case of the additive polarity winding compared to the subtractive polarity winding.

The Piezoelectric Characteristics Depending on the GrainSize of the PT-PZ-PNN Ceramics (압전변압기용 PT-PZ-PNN 세라믹스의 그레인 크기에 따른 압전특성)

  • 박정호;김철수;김성곤;이상렬
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.10
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    • pp.815-820
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    • 2001
  • The piezoelectric properties of the PT-PZ-PNN system ceramics were investigated depending on the variati on of the grain size. The grain size was varied by sintering temperature, and additive. The effect of the grain size on the electrical, dielectric, and piezoelectric properties was studied with respect to the feasibility of the application for the piezoelectric transformer. Grain size increased as the PMW contents increased. The smaller the particle size used, the smaller the grain size obtained. Specimens are densily sintered. Dielectric and piezoelectric properties are not always improved in proportion to the grain sizes. When he particle size are fine and the grain size are increased properly with the optimum additives, the piezoelectric preperties have good values. the specimen sintered at 1200$\^{C}$ with PMW 2 mol% and MnO$\_$2/ 0.5wt% contents exhibited good piezoelectric properties for a piezoelectric transformer.

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The Physicochemical properties and Antioxidation Effect of Samul Chol-Pyon (사물절편의 이화학적 품질특성 및 항산화 효과)

  • 김윤선;임영희;왕수경;윤숙자;박춘란
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.28 no.5
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    • pp.990-996
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    • 1999
  • In physicochemical property, increasing the raw materials of Samul Chol Pyon, the content of moisture decreased, somewhat in total sugar, crude lipid, ash was increased. The pH of raw material for Samul Chol Pyon was shown at 5.70~5.80, in the mild acidity. Total saturated fatty acid of 50% added to the sample was shown to be four times higher than that of rice powder. The raw materials of Samul Chol Pyon were shown to possess 16 kinds of total amino acids. The content of minerals, K, P, Zn, Mn, Fe, Mg, Ca increased its additive raw material of Samul Chol Pyon. Especially, Na decreased, while K increased its additive raw materials of Samul Chol Pyon. In a limited Na diet, Samul Chol Pyon should be used in the future.

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Effect of Filler and Additive on Performance of Cycloaliphatic Epoxy used for Outdoor Insulators (싸이클로알리파틱 에폭시 절연재료의 옥외 성능에 미치는 층전재 및 첨가물의 영향)

  • 허창수;연복희;서유진;이기택;김남렬;황명근;김완태
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.431-434
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    • 2002
  • This paper reports on the evaluation of weathering resistance, tracking test and salt-fog of various kinds of cycloaliphatic epoxy systems. It was found that UV irradiation induced the loss of hydrophobic level due to the chain scission attack at the surface. It could be seen that samples containing an UV absorbent/antioxidant and a silicone oil additive knave a good performance in weathering ageing, whereas ATH filled ones have high resistance against tracking failure than others. Under salt-fog test, specimens mixed with silicone oil could suppress leakage current development. It was thought that silicone oil mixed into cycloaliphatic epoxy system could lead to lower the surface energy and to retain hydrophobic properties for a long time, which are desirable for outdoor performances.

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The Influence of Re2O3(RDy, Er) on the Electromagnetic Properties of Mn-Zn Ferrite (Re2O3(RDy, Er)가 Mn-Zn ferrite의 전자기적 특성에 미치는 영향)

  • 백승철;최우성
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.2
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    • pp.178-183
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    • 2002
  • The effects of Dy$_2$O$_3$and Er$_2$O$_3$addition on the electromagnetic properties of Mn-Zn ferrite were investigated in the doping concentration range from 0.05 wt% to 0.25 wt%. All samples were prepared by standard fabrication of ferrite ceramics. The XRD patterns of sample were observed spinel and secondary phase. The densities of sample were showed nearly constant values. As the increased additive, electrical resistivity, initial permeability and real component of the series complex permeability increased with setting limits each other. Excess doped with Dy$_2$O$_3$ and Er$_2$O$_3$, those values decreased. The maximum electrical resistivity was observed with 0.15 we% and initial permeability was observed with 0.05 wt%. Magnetic loss decreased with additive and then increased in proportion to increased.

The effect of B-Bi-Zn on properties of NZCF (NCZF의 특성에 미치는 B-Bi-Zn의 영향)

  • 김태원;전석택;김성수;최우성
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.4
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    • pp.343-348
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    • 2000
  • NCZF ferrites doped with B-Bi-Zn(35-25-40) glass ceramics were prepared to investigate the magnetic properties. The XRD peaks of all of samples were observed only spinel phase. As the additive increased at sintering temperature 750$^{\circ}C$ and 850$^{\circ}C$ for 3 hours, the density and shrinkage of the samples increased until 5.28 g/cm$^3$ and 20% respectively. And other samples showed constant trends having the density about 5.4g/cm$^3$. According to SEM images the growth of grain progressed rapidly at sintering temperature of 850$^{\circ}C$ for 3 hours. Increasing the additive initial permeability and complex permeability decreased. The high values of complex permeability as a function of frequency showed that NCZF doped with 3 wt%, 5wt%, samples at sintered temperature of 850$^{\circ}C$/3h and 900$^{\circ}C$/3h.

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A study on insulation Characteristics of XLPE by various additives (다양한 첨가제에 따른 가교폴리에틸렌의 절연특성 분석)

  • Song, Sang-Min;Kim, Gyu-Sik;Son, Won-Keun;Ryu, Boo-Hyung;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.193-196
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    • 2001
  • XLPE is occasionally happened to deteriorate cable insulation characteristics. It is happened to do a breakdown state by the degradation of electrical characteristic and electrical breakdown strength. I prepared TR-XLPE (Tree-Retardant XLPE) as adding various additives to prevent its states. Various additives are treeing retardants, anti-oxidants. Treeing retardants three kinds of aromatic compounds as adding each additive. Anti-oxidants use quinone compound and cresol compound as adding each additive. In order to observe each electrical characteristics, I measured breakdown strength, relative dielectric constant$({\varepsilon}_r)$, dielectric loss tangent$(tan{\delta})$. TR-XLPE specimens as adding treeing retardants and anti-oxidants enhance breakdown strength, ${\varepsilon}_r$, $tan{\delta}$ than pure XLPE.

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A Study on the Cooling Characteristics and Subcooling Improvement of TMA-Water Clathrate Compound (TMA-물계 포접화합물의 냉각특성과 과냉각 개선에 대한 연구)

  • Park, Seul-Hyun;Kim, Chang-Oh
    • Journal of the Korean Solar Energy Society
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    • v.34 no.6
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    • pp.85-92
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    • 2014
  • This study carried out experimental on the cooling characteristics of clathrate compound including TMA(Tri-Methyl-Amine ; $(CH_3)_3N$) as a low temperature latent heat storage material. And additive was used for subcooling improvement of TMA-water clathrate compound. The conclusion of above study is as following ; TMA 25wt%-water clathrate compound is shown stable phase change and low subcooling degree. The subcooling was improved in the case ethanol($CH_3CH_2OH$) 0.5wt% is added to TMA 25wt%-water clathrate compound.