• Title/Summary/Keyword: Additive Material

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Effects of the Mixing of an Active Material and a Conductive Additive on the Electric Double Layer Capacitor Performance in Organic Electrolyte

  • Yang, Inchan;Kwon, Soon Hyung;Kim, Bum-Soo;Kim, Sang-Gil;Lee, Byung-Jun;Kim, Myung-Soo;Jung, Ji Chul
    • Korean Journal of Materials Research
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    • v.25 no.3
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    • pp.132-137
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    • 2015
  • The effects of the mixing of an active material and a conductive additive on the electrochemical performance of an electric double layer capacitor (EDLC) electrode were investigated. Coin-type EDLC cells with an organic electrolyte were fabricated using the electrode samples with different ball-milling times for the mixing of an active material and a conductive additive. The ball-milling time had a strong influence on the electrochemical performance of the EDLC electrode. The homogeneous mixing of the active material and the conductive additive by ball-milling was very important to obtain an efficient EDLC electrode. However, an EDLC electrode with an excessive ball-milling time displayed low electrical conductivity due to the characteristic change of a conductive additive, leading to poor electrochemical performance. The mixing of an active material and a conductive additive played a crucial role in determining the electrochemical performance of EDLC electrode. The optimal ball-milling time contributed to a homogeneous mixing of an active material and a conductive additive, leading to good electrochemical performance of the EDLC electrode.

Investigation to Metal 3D Printing Additive Manufacturing (AM) Process Simulation Technology (II) (금속 3D 프린팅 적층제조(AM) 공정 시뮬레이션 기술에 관한 고찰(II))

  • Kim, Yong Seok;Choi, Seong Woong;Yang, Soon Yong
    • Journal of Drive and Control
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    • v.16 no.3
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    • pp.51-58
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    • 2019
  • The objective of this study was to investigate a simulation technology for the AM field based on ANSYS Inc.. The introduction of metal 3D printing AM process, and the examining of the present status of AM process simulation software, and the AM process simulation processor were done in the previous study (part 1). This present study (part 2) examined the use of the AM process simulation processor, presented in Part 1, through direct execution of Topology Optimization, Ansys Workbench, Additive Print and Additive Science. Topology Optimization can optimize additive geometry to reduce mass while maintaining strength for AM products. This can reduce the amount of material required for additive and significantly reduce additive build time. Ansys Workbench and Additive Print simulate the build process in the AM process and optimize various process variables (printing parameters and supporter composition), which will enable the AM to predict the problems that may occur during the build process, and can also be used to predict and correct deformations in geometry. Additive Science can simulate the material to find the material characteristic before the AM process simulation or build-up. This can be done by combining specimen preparation, measurement, and simulation for material measurements to find the exact material characteristics. This study will enable the understanding of the general process of AM simulation more easily. Furthermore, it will be of great help to a reader who wants to experience and appreciate AM simulation for the first time.

The Effect of Grain Refiner on Ni-Fe-P Alloy Electrodeposition (Ni-Fe-P 합금전착에 미치는 Grain Refiner의 영향)

  • 서무홍;김동진;김정수
    • Journal of the Korean institute of surface engineering
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    • v.36 no.6
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    • pp.437-443
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    • 2003
  • The effects of additive(grain refiner, GR) on process efficiency of the Ni-Fe-P alloy electrodeposition and the material properties of the deposit were investigated. Electrochemical properties of the deposits were investigated using polarization and electrochemical impedance techniques, and the material properties of the deposits were characterized through inductively coupled plasma(ICP), spiral contractometer, XRD, SEM and TEM. When the additive was added into the electrodeposition bath, current efficiency, Ni content and corrosion resistance of the deposit increased, whereas residual stress, surface roughness and grain size of the deposit decreased.

Review of Recent Trends and Technology for Additive Manufacturing (적층제조기술 응용사례 및 최신기술동향)

  • Lee, Jaehyang;Park, Sung-Jun
    • Journal of Institute of Convergence Technology
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    • v.6 no.1
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    • pp.1-5
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    • 2016
  • Additive manufacturing is converting a digitally designed object into a tangible three dimensional solid using an additive process where materials are applied in successive layers with no or very limited material waste. It can be distinguished form traditional manufacturing which begins with a fixed amount of raw material and removes excess to arrive at the final product. Generally there are five stages to the additive manufacturing supply chain, namely materials, systems, software, application design and production. In this paper, recent market trends and technology about additive manufacturing based on supply chain are analyzed and reviewed.

Effect of Conductive Additive Amount on Electrochemical Performances of Organic Supercapacitors (유기계 슈퍼커패시터에서 도전재의 양이 전기화학적 특성에 미치는 영향)

  • Yang, Inchan;Lee, Gihoon;Jung, Ji Chul
    • Korean Journal of Materials Research
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    • v.26 no.12
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    • pp.696-703
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    • 2016
  • In this study, we intensively investigated the effect of conductive additive amount on electrochemical performance of organic supercapacitors. For this purpose, we assembled coin-type organic supercapacitor cells with a variation of conductive additive(carbon black) amount; carbon aerogel and polyvinylidene fluoride were employed as active material and binder, respectively. Carbon aerogel, which is a highly mesoporous and ultralight material, was prepared via pyrolysis of resorcinol-formaldehyde gels synthesized from polycondensation of two starting materials using sodium carbonate as the base catalyst. Successful formation of carbon aerogel was well confirmed by Fourier-transform infrared spectroscopy and $N_2$ adsorption-desorption analysis. Electrochemical performances of the assembled organic supercapacitor cells were evaluated by cyclic voltammetry, galvanostatic charge/discharge, and electrochemical impedance spectroscopy measurements. Amount of conductive additive was found to strongly affect the charge transfer resistance of the supercapacitor electrodes, leading to a different optimal amount of conductive additive in organic supercapacitor electrodes depending on the applied charge-discharge rate. A high-rate charge-discharge process required a relatively high amount of conductive additive. Through this work, we came to conclude that determining the optimal amount of conductive additive in developing an efficient organic supercapacitor should include a significant consideration of supercapacitor end use, especially the rate employed for the charge-discharge process.

Thermal and Electrochemical Studies of Tris(2,4,6-trimethoxyphenyl)Phosphine as a Flame Retardant Additive for Li-ion Battery (리튬이차전지 난연성 전해액 첨가제로서의 Tris(2,4,6-trimethoxyphenyl)Phosphine의 열적, 전기화학적 특성)

  • Ahn, Se-Young;Kim, Ke-Tack;Kim, Hyun-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.12
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    • pp.1130-1134
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    • 2008
  • Thermal and electrochemical properties were discussed with tris(2,4,6-trimethoxyphenyl)Phosphine (TTMPP) as a flame retradant additive for Li-ion battery. TTMPP showed excellent thermal stability with charged cathodes. Addition of 1 wt.% of the additive to the electrolyte improved the thermal stability without damaging the performance of the battery. The oxygne evolution reaction delayed nearly by $60^{\circ}C$. The capacity retention ratio in cycle life tests of the battery with 1 wt.% TTMPP was slightly improved comparing to the no additive cells.

Micro-Structural Enhancement of XLPE Insulation Using Additive Diffusion Method

  • Park, Se-Eun;Shim, Sung-Ik;Cho, Dae-Hee;Youn, Bok-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.238-239
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    • 2005
  • With the aim of developing XLPE insulation for extra high voltage cable, we investigated the morphology of cross-linked polyethylene. We used a kind of base materials and additives, and controlled curing condition and amount of additives. The effect of addition of additives on morphology of XLPE such as lamellar density, orientation and additive layer were analyzed using TEM analysis. We applied this result to diffused additive amount was analyzed using FT-IR analysis, and the change of microstructure as the degree of additive diffusion was analyzed using TEM analysis.

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A study on the electrical characteristic of PZT ceramics with additive. (첨가제에 의한 PZT세라믹의 전기적 특성에 관한 연구)

  • 김현철;김진섭;김혁동;배선기
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.236-239
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    • 1999
  • This paper is the study for electrical characteristic of PZT ceramics with Sb$_2$O$_3$, CoO additive. Effect of Sb$_2$O$_3$, CoO additive ranged from 0.0 wt% to 1.2wt% on the electrical characteristic of the PZT ceramics have been investigated. In the case of Sb$_2$O$_3$ 0.6wt%, the maximum vague of mechanical quality factor(Qm) was obtained 124.11 at l15$0^{\circ}C$. And, additive CoO 1.2wt% was obtained 184.12 at l15$0^{\circ}C$. The electromechanical coupling factor(kp) was increased by increasing the amount of Sb$_2$O$_3$, CoO additive. The maximum value of electromechanical coupling factor(kp) was obtained 58.35 with Sb$_2$O$_3$1.2wt% additive at l15$0^{\circ}C$. Dopped with additive CoO 0.9wt%, electromechanical coupling factor(kp) was obtained 47.84 at 115$0^{\circ}C$.

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The Effect of Graphite Addition and Pouring Temperature on the Coating State in Vaccum Process (감압조형시 흑연첨가 및 주입온도가 피복상태에 미치는 영향)

  • 조성준
    • Journal of the Korean Ceramic Society
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    • v.34 no.5
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    • pp.544-551
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    • 1997
  • We tried to improve the coating capability of the coating material using an additive(hexagonal cystalline graphite) of 2%, 3%, 4% and 6% under various pouring temperature for the easy isolation of sand and coating material from the final product. As a result in case of using a 2% and 3% additive generally no burning state has been occurred under the low pouring temperature, but it has been gradually increased with the pouring temperature. On the other hand in case of using a 4% and 6% additive there has been no burning state through out the whole pouring temperature. From this result we could see that the best state of the final product without sand and coating material could generally be obtained if 4% and/or 6% of the crystalline graphite and the pouring temperature of 140$0^{\circ}C$$\pm$5$^{\circ}C$ would be used.

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Effects of organic silicone additive material on physical and mechanical properties of mudstone

  • Chai, Zhaoyun;Kang, Tianhe;Chen, Weiyi
    • Geomechanics and Engineering
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    • v.6 no.2
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    • pp.139-151
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    • 2014
  • Mudstone is a very common rock that, when in contact with water, can exhibit considerable volume change and breakdown. This behavior of mudstone is frequently encountered in geotechnical engineering and has a considerable influence on infrastructure stability. This is particularly important in the present work, which focuses on mitigating the harmful properties of mudstone. The samples studied are of Permian Age mudstone from Shandong Province, China. Modification tests using organic silicone additive material were carried out. The mechanisms of physical properties modification of mudstone were comparatively studied using corresponding test methods, and the modification mechanism of organic silicone additive material acting on mudstone was analyzed. The following conclusions were drawn. The surface texture and characters of mudstone changed dramatically, surface character turns from hydrophilic to hydrophobic after organic silicone additive material modification. The changes in the surface character indicate a reduction in the water sensitivity of mudstone. After modification, the shape of porosity and fracture of mudstone changed unremarkable, and the total and free expansion ratios decreased obviously, whereas the strength increased markedly.