• 공업화학
• /
• 제19권6호
• /
• pp.633-639
• /
• 2008

상전환법을 이용하여 폴리설폰, n-메틸피롤리돈과 톨루엔으로 이루어진 제막용액으로부터 고분자 분리막이 제조되었다. 톨루엔은 폴리설폰에 대한 비용매로서 제막용액에 첨가되었으며, 침지용 비용매로는 이소프로필알코올이 사용되었다. 제조된 모든 분리막은 밀집 형상의 표면층과 스폰지 형상의 하부층으로 구성된 이중구조 형태의 비대칭성 구조를 보였다. 첨가된 톨루엔은 제막용액의 열역학적 성질을 변화시켜 열역학적 상분리를 촉진하는 역할을 할 수 있음을 보였으며, 제조된 분리막은 톨루엔을 첨가에 의해 막의 표면층 두께가 증가하는 특성을 보였다. 분리막의 투과 특성을 측정한 결과, 톨루엔이 첨가되었을 때 밀집 표면층의 두께 증가에도 불구하고 거의 동일한 배제율을 유지하면서 투과플럭스는 5배 이상 증대하는 효과를 보였다.

• 한국정보통신학회논문지
• /
• 제23권12호
• /
• pp.1673-1678
• /
• 2019

산업 통신에는 다양한 네트워크가 있으며 여러 가지 통신 방식을 사용한다. 기업에서는 생산 라인 확장, 공장 업그레이드, 네트워크 세분화, 시스템 통합 등을 위하여 산업용 장치와 네트워크 간에 통신 변환이 필요하다. 이것은 많은 제조회사가 제작한 설계자가 다른 다양한 기계 장치를 네트워크에 연결하고 전송하기 위하여 데이터 또는 프로토콜 변환을 위한 통신 장비가 제공되어야함을 의미한다. 본 논문에서는 적층형 통신 모듈을 사용하여 산업 통신 프로토콜 변환을 지원할 수 있는 산업용 통신 게이트웨이를 설계하였다. 제작된 게이트웨이는 RS485 시리얼 통신을 이용하는 개별 통신 모듈을 다층으로 연결하는 구조를 가지고 있다. 각각의 통신 모듈은 아날로그 데이터 카드, 디지털 데이터 카드, CAN 및 LAN 지원 카드로 구성하였다. 메인 보드 프로세서는 Atmega micro-processor를 사용하였고, RS485 시리얼 슬롯을 배치하여 적층형 통신 모듈 구조를 가지도록 하였다. 본 논문에서 제작된 적층형 산업용 통신 게이트웨이는 아날로그 및 디지털 I/O 기능과 CAN과 LAN을 지원할 수 있기 때문에 산업용 통신 제어 및 모니터링에 폭넓게 활용될 수 있다.

• 한국세라믹학회지
• /
• 제39권1호
• /
• pp.51-56
• /
• 2002

고순도 알루미나 분말에 소결조제로서 초산 마그네슘과 질산 마그네슘을 1000ppm첨가하여 제작한 소결체에 대해서 소결조제로 사용한 MgO의 출발물질의 종류가 소결체 특성에 미치는 영향을 고찰하였다. 초산 마그네슘과 질산 마그네슘을 사용해서 제작한 소결체에 대해서 소결온도 1$600^{\circ}C$에서 상대밀도의 급격한 감소가 확인되었고 SEM관찰결과 소결조제로 사용한 두 종류의 출발물질을 첨가한 경우에 동일하게 소결체의 outer layer에서는 입성장 및 기공이 형성되어있고 inner layer에서는 알루미나 입계에 제2상의 존재가 관찰되었다. 이 시편의 EPMA을 이용한 원소분석결과로부터 소결온도 1$600^{\circ}C$에서 알루미나 입계에 존재하는 제2상은 Mg를 함유한 혼합물이라는 것을 알 수 있었다.

• 한국기계가공학회지
• /
• 제14권4호
• /
• pp.134-139
• /
• 2015

PolyJet technology is an additive manufacturing (AM) technology commonly used for modeling, prototyping, and production applications. It is one of the techniques used for 3D printing. The PolyJet technique is a process that joins materials to fabricate a product from 3D CAD data in a layer-by-layer manner. The orientation of a layer can affect the mechanical properties of the product manufactured by the PolyJet technique because of its anisotropy. In this paper, tensile and shearing tests of specimens were developed with the PolyJet technique in order to study the mechanical properties according to the orientation of a layer. The mechanical properties of the specimens were determined on the basis of true stress-strain curves from tensile and shearing tests. In addition, the tensile and shearing tests were simulated under the same conditions as those of experiment, and the experiment and simulated results were compared. Through this study, the fracture criteria could be established.

• 한국표면공학회지
• /
• 제39권1호
• /
• pp.13-17
• /
• 2006

The effects of an organic additive, naphthalene trisulfonic acid (NTSA), contained in the nickel sulfamate bath on the surface properties of the electrodeposited nickel layer were investigated through electrochemical technique, x-ray diffraction analysis, and microscopic observation. The addition of NTSA facilitated the oxidation process of electrodeposited nickel layer during anodic scan and also increased the hardness and internal stress of the nickel film as the applied current density became higher. It seems that NTSA modulated the deposit structure during electrodeposition and so induced higher distribution of (110) orientation with respect to (200). With the increase of the NTSA in the bath, nickel layer was formed in small grain size, which resulted in enhanced surface evenness and brightness.

• Journal of Electrochemical Science and Technology
• /
• 제14권3호
• /
• pp.231-242
• /
• 2023

Li₂O-based cathodes utilizing oxide-peroxide conversion are innovative next-generation cathodes that have the potential to surpass the capacity of current commercial cathodes. However, these cathodes are exposed to severe cathode-electrolyte side reactions owing to the formation of highly reactive superoxides (O^x-, 1 ≤ x < 2) from O^2- ions in the Li₂O structure during charging. Succinonitrile (SN) has been used as a stabilizer at the cathode/electrolyte interface to mitigate cathode-electrolyte side reactions. SN forms a protective layer through decomposition during cycling, potentially reducing unwanted side reactions at the interface. In this study, a composite of Li₂O and Ni-embedded reduced graphene oxide (LNGO) was used as the Li₂O-based cathode. The addition of SN effectively thinned the interfacial layer formed during cycling. The presence of a N-derived layer resulting from the decomposition of SN was observed after cycling, potentially suppressing the formation of undesirable reaction products and the growth of the interfacial layer. The cell with the SN additive exhibited an enhanced electrochemical performance, including increased usable capacity and improved cyclic performance. The results confirm that incorporating the SN additive effectively stabilizes the cathode-electrolyte interface in Li₂O-based cathodes.

• Food Science and Biotechnology
• /
• 제14권4호
• /
• pp.456-460
• /
• 2005

To enforce the maximum residue limit for residual hexane (0.005 g/kg) in commercially available Korean vegetable oil, convenient and accurate quantification methods were investigated. Using dual surrogate standards, pentane and heptane were dissolved in ethanol, and then added to hexane-tree sunflower oil for setting up the calibration curve. Gas Chromatograph-Flame Ionization Detector with a porous layer open tubular column, indicated good chromatographic separation of hexane from other inhibiting matrix components. The lowest calibration level was $0.5\;{\mu}g/g$, not exceeding a relative standard deviation of 10% (RSD%), and 1.0\;{\mu}g/g$ not exceeding a deviation of 22% RSD% using heptane as an internal standard for the Static headspace analysis by using a headspace auto-sampler and manual injection, respectively. The residual hexane was detected in nine of the samples among 87 vegetable oil samples purchased on the local market.

• Structural Engineering and Mechanics
• /
• 제86권1호
• /
• pp.93-107
• /
• 2023

In this paper, a density based topology optimization is proposed for generating of supports required in additive manufacturing to maintain the overhanging regions of main structures during layer by layer fabrication process. For this purpose, isogeometric analysis method is employed to model geometry and structural analysis of main and support structures. In order to model the problem two cases are investigated. In the first case, design domain of supports can easily be separated from the main structure by using distinct isogeometric patches. The second case happens when the main structure itself is optimized by using topology optimization and the supports should be designed in the voids of optimum layout. In this case, in order to avoid boundary identification and re-meshing process for separating design domain of supports from main structure, a parameterization technique is proposed to identify the design domain of supports. To achieve this, two density functions are defined over the entire domain to describe the main structure and supporting areas. On the other hand, since supports are under gravity loads while main structure and its stiffness is not completed during manufacturing process, in the proposed method, stiffness of the main structure is considered to be trivial and the gravity loads are also naturally applied to design support structures. By doing so, the results show reasonable supports are created to protect, continuously, overhanging surfaces of the main structure. Several examples are presented to demonstrate the efficiency of the proposed method and compare the results with literature.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 1998년도 추계학술대회 논문집
• /
• pp.203-206
• /
• 1998

Effects of types of semicon compounds on electrical properties of XLPE were investigated. The amounts of charge of XLPE were changed with the contents of additive included in semicon electrodes, but homocharge in cathode was observed. In the aging experiment under high voltage, it was found that semiconductive layer with high impurity contents played an important role in the decrease of ACBD strength of XLPE.

• Journal of Magnetics
• /
• 제11권3호
• /
• pp.111-114
• /
• 2006

We electroplated copper-cobalt thin films on a silicon substrate, which had 150 nm thick copper seed layer. The adhesion between the two metallic layers could be increased by utilizing a proper organic additive, pulse plating technique, and high temperature annealing. The thin films exhibited columnar growth of the deposits and enhanced adhesion. This is attributed to the grain growth mechanism introduced by the additive and annealing.