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Water - Assisted Efficient Growth of Multi-walled Carbon Nanotubes by Thermal Chemical Vapor Deposition

  • Choi, In-Sung;Jeon, Hong-Jun;Kim, Young-Rae;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.418-418
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    • 2009
  • Vertically aligned arrays of multi-walled carbon nanotube (MWCNT) on layered Si substrates have been synthesized by water-assisted thermal chemical vapor deposition (CVD). We studied changes in growth by parameters of growth temperature, growth time, rates of gas and annealing time of catalyst. Also, We grew CNTs by adding a little amount of water vapor to enhance the growth of CNTs. $H_2$, Ar, and $C_2H_2$ were used as carrier gas and feedstock, respectively. Before growth, Fe served as catalyst, underneath which AI were coated as an underlayer and a diffusion barrier, respectively, on the Si substrate. The water vapor had a greater effect on the growth of CNTs on a smaller thickness of catalyst. When the water vapor was introduced, the growth of CNTs was enhanced than without water. CNTs grew 1.29 mm for 10 min long by adding the water vapor, while CNTs were 0.73 mm long without water vapor for the same period of time. CNTs grew up to 1.97 mm for 30 min prior to growth termination under adding water vapor. As-grown CNTs were characterized by using scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), and Raman spectroscopy.

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Some Considerations on the On-site Applicability of PSA(Pulse Sequence Analysis) as a Partial Discharge Analysis Method (부분방전 해석 방법으로 PSA(Pulse Sequence Analysis)의 현장 적용성에 대한 고찰)

  • Kim, Jeong-Tae;Lee, Ho-Keun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.5
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    • pp.484-489
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    • 2005
  • Because of its effectiveness for the PD(Partial Discharge) pattern recognition, PSA(Pulse Sequence Analysis) has been considered as a new analytic method instead of conventional PRPDA(Phase Resolved Partial Discharge Analysis). However, it is generally thought that PSA has some possibility to misjudge patterns in case of data-missing resulting from poor sensitivity because it analyses the correlation between sequential pulses, which leads to hesitate to apply it to on-site. Therefore, in this paper, the problems of PSA such as data-missing and noise-adding cases were investigated. for the purpose, PD data obtained from various defects including noise-adding data were used and analyzed. As a result, it was shown that both cases could cause fatal errors in recognizing PD patterns. In case of the data missing, the error was dependant on the kinds of defect and the degree of degradation Also, it could be noticed that the error due to adding noises was larger than that due to some data missing.

Effect of Metal Ions on the Degradation and Adsorption of Two Cellobiohydrolases on Microcrystalline Cellulose

  • Kim, Dong Won;Jang, Yeong Heon;Kim, Chang Seok;Lee, Nam Su
    • Bulletin of the Korean Chemical Society
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    • v.22 no.7
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    • pp.716-720
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    • 2001
  • To test the metal ion effect, hydrolysis experiments for two cellobiohydrolases (CBHⅠ and CBH Ⅱ) from Trichoderma reesei have been carried out in the presence of 10 mM metal ions, such as Cu++, Mn++, Ca++, Hg++, Ba++, Pb++, and Cd++. The addition of Mn++, Ba++, and Ca++(10 mM) during the hydrolysis of Avicel PH 101 caused an increase in the total reducing sugar (TRS) for CBH Ⅰ by 142, 135, and 114 percent, respectively. Those for CBH Ⅱ increased by 177, 175, and 115 percent, respectively. The Mn++ was the most stimulatory metal ion, whereas Hg++ was the most inhibitory metal ion. The adsorption experiments were performed to investigate how the influence of Mn++ and Hg++ on the hydrolysis is related to the adsorption of cellobiohydrolases on cellulose. The increase in TRS during hydrolysis by adding Mn++ caused an increase in adsorption affinity (Kad) and tightness (ΔHa). While, the decrease of TRS during hydrolysis by adding Hg++ caused a decrease in the adsorption affinity (Kad) and tightness (ΔHa). These results indicate the changes in the tightness and affinity of adsorption by adding metal ions play a crucial role in the degradation of the microcrystalline cellulose.

Effect of a Nonionic Surfactant on the Adsorption and Kinetic Mechanism for the Hydrolysis of Microcrystalline Cellulose by Endoglucanase Ⅰ and Exoglucanase II

  • 김동원;장영훈;정영규;손기향
    • Bulletin of the Korean Chemical Society
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    • v.18 no.3
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    • pp.300-305
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    • 1997
  • Effect of a nonionic surfactant, Tween 20 on the adsorption and kinetic mechanism for the hydrolysis of a microcrystalline cellulose, Avicel PH 101, by endoglucanase Ⅰ (Endo Ⅰ) and exoglucanase Ⅱ (Exo Ⅱ) isolated from Trichoderma viride were studied. The Langmuir isotherm parameters, amount of maximum adsorption (Amax) and adsorption equilibrium constant (Kad) for the adsorption, were obtained in the presence and the absence of nonionic surfactant. On the addition of Tween 20, the Kad and Amax values of Exo Ⅱ were decreased, while those of Endo Ⅰ were not affected. These indicate that the adsorption affinity of Exo Ⅱ on the cellulose is weakened by nonionic surfactant, and the surfactant enhanced desorption of Exo Ⅱ from insoluble substrate. The enzymatic hydrolysis of the cellulose can be described by two parallel pseudo-first order reactions using the percentages of easily (Ca) and hardly (Cb) hydrolyzable cellulose in Avicel PH 101 and associated rate constants (ka and kb). The Ca value was increased by adding Tween 20 for all enzyme samples (Exo Ⅱ, Endo Ⅰ and their 1:1 mixture) implying that the low-ordered crystalline fraction in the cellulose may be partly dispersed by surfactant. The ka value was not affect by adding Tween 20 for all enzyme samples (Exo Ⅱ, Endo Ⅰ and their 1:1 mixture). The kb value of Exo Ⅱ was increased by adding Tween 20, while that of Endo Ⅰ was not affected. This suggests that the surfactant helps the Exo Ⅱ desorb from microcrystalline cellulose, and increase the hydrolysis rate. These results were show that the increase of hydrolysis of cellulose by the nonionic surfactant is due to both the activation of Exo Ⅱ and partial defibrillation of the cellulose.

Experimental and numerical analysis of the punching behavior of RC isolated footings

  • Walid, Mansour;Sabry, Fayed;Ali, Basha
    • Steel and Composite Structures
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    • v.45 no.5
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    • pp.665-682
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    • 2022
  • In the current study, punching behavior of Reinforced concrete (RC) isolated footings was experimentally and numerically investigated. The experimental program consisted of four half-scale RC isolated footing specimens. The test matrix was proposed to show effect of footing area, reinforcement mesh ratio, adding internal longitudinal reinforcement bars and stirrups on the punching response of RC isolated footings. Footings area varied from 1200×1200 mm2 to 1500×1500 mm2 while the mesh reinforcement ratio was in the range from 0.36 to 0.45%. On the other hand, a 3D non-linear finite element model was constructed using ABAQUS/standard program and verified against the experimental program. The numerical results agreed well with the experimental records. The validated numerical model was used to study effect of concrete compressive strength; longitudinal reinforcement bars ratio and stirrups concentration along one or two directions on the ultimate load, deflection, stiffness and failure patterns of RC isolated footings. Results concluded that adding longitudinal reinforcement bars did not significantly affect the punching response of RC isolated footings even high steel ratios were used. On the contrary, as the stirrups ratio increased, the ultimate load of RC isolated footings increased. Footing with stirrups ratio of 1.5% had ultimate load equal to 1331 kN, 19.6% higher than the bare footing. Moreover, adding stirrups along two directions with lower ratio (0.5 and 0.7%) significantly enhanced the ultimate load of RC isolated footings compared to their counterparts with higher stirrups ratio (1.0 and 1.5%).

Effects of activated carbon on the compressive strength of Portland cement concrete

  • Sungmin Youn;Andrew Ball;Claire Fulks;Sanghoon Lee;Sukjoon Na
    • Geomechanics and Engineering
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    • v.33 no.1
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    • pp.19-27
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    • 2023
  • A series of experiments were performed to evaluate the effects of activated carbon on the compressive strength and air content of Portland Cement Concrete (PCC). Activated carbon/PCC composites were prepared by mixing concrete components with commercial activated carbon granules with weight fractions of 0, 0.5%, 1%, and 2% to cement. All PCC specimens were then tested for compressive strength on 7, 14, 21, and 28 days. The experimental results showed that adding 0.5% of activated carbon increased the compressive strength significantly over the curing periods compared to the normal PCC without activated carbon. For the specimens has 0.5% activated carbon, the 7, 14, 21, and 28-day compressive strengths increased by 28.7%, 22.2%, 26.8%, and 22.9%, respectively. However, adding excessive amounts of more than 1% activated carbon had a minimal effect on the compressive strength or even decreased it, which agrees with other studies. Regarding the air contents of the mixtures, adding activated carbon decreased the air content from 3.6% to around 1.5%. The surface morphologies of fine aggregates and activated carbon particles were compared using a novel image processing technique. The results indicated that the surface of activated carbon significantly differs from that of aggregates.

The Amounts of the Electromagnetic Wave Penetrating From a Cellular Phone under the Conditions of Wearing - Inside the Pocket of Men's Dress shirt - (착의 상태에 따른 휴대폰의 전자파 투과량 - 남성용 드레스 셔츠 포켓 내에서를 중심으로 -)

  • 송명견
    • The Korean Journal of Community Living Science
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    • v.13 no.2
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    • pp.1-11
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    • 2002
  • This study was conducted to estimate the amounts of the electromagnetic wave penetrating from a cellular phone in a pocket of dress shirt, as well as to test how different the penetration amounts were under the conditions of wearing. It was also investigated the possibilities that the amounts of the electromagnetic wave penetrating could be decreased by using twofold pocket or electromagnetic wave free fabric. The amounts of the electromagnetic wave penetrating were measured in the following five cases; one-layered pocket with 10 different fabrics as dress shirt, a pocket adding a layer of knitted cotton, two-layered pocket with same fabric as dress shirt, two-layered pocket adding a layer of knitted cotton, and one-layered pocket adding a layer of electromagnetic wave free fabric. Each of these five cases were measured using the front and back sides of a cellular phone facing to the body. The results were as follows; 1) The amounts of the electromagnetic wave penetrating were not significantly different in 10 different fabrics and were all above the caution range (0.02mW/$cm^2$). 2) The amounts of the electromagnetic wave penetrating in cases of the back side of the cellular phone to the body, were more than in cases of the front side. 3) There is a significantly differences in part on adding a knitted under wear to one and two layers of the pocket in the case of penetration amount under the wearing conditions. 4) The amounts of the electromagnetic wave penetrating in cases of adding a layer of electromagnetic wave free fabric, were close to the safe standard value of it. The above results suggested that facing the front side of cellular phone to the body and using extra layering with some electromagnetic wave free fabrics might have some protective effects again to the penetration amounts.

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Effects of Concentration of Inhibitor on the Production of $\alpha$-amylase and Growth of Bacillus amyloliquefaciens (Bacillus amyloliquefaciens 성장과 $\alpha$-amylase 생합성에 미치는 저해제의 영향)

  • 김종균;김종수차월석
    • KSBB Journal
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    • v.11 no.2
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    • pp.125-131
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    • 1996
  • In this study, Bucillus amyloliquefaciens was adopted as bacterial source to investigate the concentration of carbon source by adding inhibitors in the batch culture. By adding acetic acid at $10g/\ell$ of initial glucose concentration, maximum dry cell density was obtained with the highest value of /$\3.9gell$ at $1.0g/\ell$ of initial acetic acid concentration. By adding acetic acid al 10g/$\ell$ of initial glucose concentration, maximum ${\alpha}$-amylase production was obtained with 331.55unit/m1 at $2.0g/\ell$ of initial acetic acid concentration. ${\alpha}$-Amylase production was decreased with the increase of initial acetic acrid concentration. By adding acetic acid to the medium, cell growth and ${\alpha}$-amylase production was higher in glucose than in maltose. By adding lactic acid to the medium, cell growth was decreased.

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A study on aging characteristics of epoxy resins for conservation treatment of cultural heritage by adding UV stabilizer (자외선 안정제 첨가에 따른 문화재 보존처리용 에폭시계수지의 노화특성 연구)

  • Jeong, Se-Ri;Cho, Nam-Chul
    • Analytical Science and Technology
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    • v.24 no.5
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    • pp.336-344
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    • 2011
  • The study attempted to find out any effect to prevent photo aging of epoxy resin used for conservation by way of adding UV stabilizer, one of plastic additives. Specimens were made by adding HALS and UVA UV stabilizer as each concentration to 3 kinds of epoxy resin, which are most frequently used for artifacts joining and restoration process, and aging effects were investigated through Color change, SEM, contact angle, FTIR analysis during UV aging experiments. Last, usage suitability was checked when UV stabilizer was added through Universal Tensile strength tester. In result, it is impossible to prevent decomposition of chemical structure in spite of adding UV stabilizer but in the case of epoxy A and R, it is believed that photo aging such as yellowing or crack can be minimized without giving a big influence to adhesive strength of epoxy resin through adding less than 0.1% of UVA. It is expected that above will solve photo aging problem of epoxy resin used for joining and restoration of artifacts and will extend its life as joining and restoration materials.

Effects of $CO/CO_{2}$ Additives on The Reaction of Methane Activation using The Zeolite Catalyst (지오라이트 촉매를 이용한 메탄의 활성화 반응에서 일산화탄소/이산화탄소 첨가에 따른 영향)

  • Chung, Gui-Yung
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.2
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    • pp.139-143
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    • 2000
  • There appeared enhancements of the conversion of methane by adding a small amount of CO in the aromatization reaction of methane using the Mo-zeolite catalyst. In case of adding $CO_{2}$, $CO_{2}$ changed to CO first, and then the conversion reaction occurred. It was observed by using isotopes as reactants that CO is related to the aromatization reaction of methane.