• Title/Summary/Keyword: Active chemical

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Improvement in Catalytic Activity of Ag Catalyst via Simple Mixing with Carbon

  • Choun, Myounghoon;Baek, Ji Yun;Eom, Taehyoung
    • KEPCO Journal on Electric Power and Energy
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    • v.5 no.4
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    • pp.331-335
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    • 2019
  • In this study we investigate catalytic activity and selectivity of mixture of Ag and ketjenblack according to their ratios by product analysis and electrochemical experiments, such as cyclic voltammetry, linear sweep voltammetry and chronoamperometry. We reveal that catalytic activity toward CO2 reduction to CO is improved by simple mixing Ag nanoparticle and ketjenblack because addition of ketjenblack suppresses aggregation of Ag nanoparticles and brings increase in electrochemical active surface area. However, excess amount of ketjenblack rather inhibit the CO2 reduction to CO. These observations provide clues to develop highly active Ag catalyst or electrode toward electrochemical reduction of CO2.

Biologically active compounds from natural and marine natural organisms with antituberculosis, antimalarial, leishmaniasis, trypanosomiasis, anthelmintic, antibacterial, antifungal, antiprotozoal, and antiviral activities

  • Asif, Mohammad
    • CELLMED
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    • v.6 no.4
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    • pp.22.1-22.19
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    • 2016
  • The biologically active compounds derived from different natural organisms such as animals, plants, and microorganisms like algae, fungi, bacteria and merine organisms. These natural compounds possess diverse biological activities like anthelmintic, antibacterial, antifungal, antimalarial, antiprotozoal, antituberculosis, and antiviral activities. These biological active compounds were acted by variety of molecular targets and thus may potentially contribute to several pharmacological classes. The synthesis of natural products and their analogues provides effect of structural modifications on the parent compounds which may be useful in the discovery of potential new drug molecules with different biological activities. Natural organisms have developed complex chemical defense systems by repelling or killing predators, such as insects, microorganisms, animals etc. These defense systems have the ability to produce large numbers of diverse compounds which can be used as new drugs. Thus, research on natural products for novel therapeutic agents with broad spectrum activities and will continue to provide important new drug molecules.

Metabolismus von 14C-Chlorsulfuron in Verschieden Empfindlichen Kulturpflanzen und Unkrautern (감수성(感受性)이 다른 작물(作物)과 잡초(雜草)에 있어서 Chlorsulfuron 의 대사작용(代謝作用))

  • Kang, Byeung-Hoa
    • Korean Journal of Weed Science
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    • v.4 no.2
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    • pp.115-124
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    • 1984
  • Chlorsulfuron (chemical name : 2-Chloro-N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-aminocarbonyl-benzenesulfonamide) is a herbicidally active ingredient which shows effect against susceptible weeds already at such low rates like 5-20g active ingredient per hectare. In the here reported trials metabolism in several sensitive cultivated plants and weeds have been analysed using ^{14}C-labelled active ingredient. The uptake of chlorsulfuron by leaves or the root system is good in all plants species, and translocation takes place either symplasmatically or apoplasmatically. Metabolism takes place in all investigated plant species by development of hydrophile suhstances in roots and shoots. Decomposition of chlorsulfuron in roots and shoots of tolerant species (Triticum aestivum and Hordeum vulgare) to polare substances takes place quantitatively faster and quicker than in susceptible species (Beta vulgaris and Matricaria chamomilla).

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An isolation of the active component of Carthamus tinctorius L. Semen and the evaluation of its hepato-protective effect

  • Jeong, Jeong-Suk;Jeong, Choon-Sik;Jung, Ki-Hwa
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1998.11a
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    • pp.179-179
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    • 1998
  • We previously reported the hepato-protective effect of butanol soluble fraction of methanolic extract of Carthamus tinctorius L. Semen on carbon tetrachloride induced hepatotoxicity. In this study, the active component from the butanol soluble fraction was isolated by column chromatographic separation using Silica gel and Sephadex LH -20 and identified by spectroscopic methods such as Mass, $^1$H - NMR and $\^$13/C-NMR. The hepato-protective effect of the isolated active component on the CCl$_4$-induced liver damaged rats has been evaluated by performing blood chemical analysis and biotransformational enzyme analysis.

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Fabrication of $1{\mu}$ m Gate GaAs MESFET and Analysis of Correlation Between DC Characteristics and Channel Parameters ($1{\mu}$ 게이트 GaAs MESFET의 제조 및 DC 특성과 채널 파라미터들 사이의 상호관게 분석)

  • 엄경숙;이유종;강광남
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.24 no.5
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    • pp.804-812
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    • 1987
  • 1\ulcorner gate MESFETs are fabricated on MOCVD and VPE grown GaAs wafers using photolithography, chemical wet etching and lift-off techniques. DC characteristics such as Vt, Gm, Rs, etc. are studied and active channel parameters of MESFET(a, n, Leff, \ulcorner)are analyzed for 1-4 \ulcorner gate FETs and 100\ulcorner FAT FET. The correlation between DC data and active channel parameters are experimentally analyzed. The measured transconductance and low-field mobility in the active channel for the 1\ulcorner gate MESFET made on MOCVD wafer are 67mS/mm and 2980cm\ulcornerVs respectively.

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Ammonia decomposition over titanium carbides

  • Choi, Jeong-Gil
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.6
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    • pp.269-273
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    • 2012
  • Ammonia decomposition over titanium carbides were investigated using eight different samples which have been synthesized by TPR (temperature-programmed reduction) method of titanium oxide ($TiO_2$) with pure $CH_4$. The resulting materials which were synthesized using wo different heating rates and space velocity exhibited the different surface areas. These results indicated that the structural properties of these materials have been related to heating rates and space velocity employed. The titanium carbides prepared in this study proved to be active for ammonia decomposition, and the activity changed with the particle size/surface area. These showed the relationship between ammonia decomposition activity and the different active species. Compared to molybdenum carbide, the titanium carbides were one order of magnitude less active, suggesting the correlation between the activity difference and the degree of electron transfer between metals and carbon in metal carbides.

Kraft Bagasse Pulp Delignification with Dimethyldioxirane

  • Yousef, Hussein-Abou
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.5
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    • pp.25-29
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    • 2001
  • Dimethyldioxirane (DMD), which is a source of active oxygen, is effective agent that can be used in chemical pulp bleaching. In this study, delignification of kraft bagasse pulp has been carried out by using DMD. The effect of the applied charge of DMD (as active oxygen) and pH of the delignification medium were studied. The optimum conditions of the applied DMD charge and pH of the delignification reaction were achieved at pH range from 8~9, 2% of DMD (as active oxygen) and the rest of delignification reaction conditions were $25^{\circ}C$, 60 min, and 12% pulp consistency. The development of brightness per unit kappa number removal (ΔBrightness/ Δ Kappa number) has highest value at the optimum condition. The study showed that the reactivity of kraft bagasse pulp be enhanced to wards alkaline hydrogen peroxide bleaching by pulp treatment with DMD.

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Conductive Polymer Coated Electro-active Paper (EAPap) as Hybrid Actuator (전도성 폴리머와 셀룰로오스 종이를 결합한 EAPap 작동기)

  • Yun, Sung-Ryul;Kim, Jae-Hwan;Ounaies, Zoubeida;Deshpande, S.D.
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2004.11a
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    • pp.275-278
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    • 2004
  • Electro-Active Paper (EAPap) is attractive for EAP actuator due to its merit in terms of light weight, dry condition, large displacement output, low actuation voltage and low power consumption. The EAPap is based on cellulose paper, and is shown to involve primarily transport of ions in response to an external electric field. This actuating mechanism is similar to conductive polymer based actuators. For performance improvement of EAPap, hybrid actuators are tried. The actuators based on cellulose paper attached conducting polypyrrole, polyaniline and single wall carbon nanotube/polyaniline(emeraldine base) have been achieved by Electro chemical deposition and mechanical deposition of the polymers onto cellulose paper.

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Effects of Source and Mixing Ratio of Topsoil onPhysicoChemical Properties of Green (토양개량제 혼합비율이 Green Topsoil의 물리 화학성에 미치는 영향)

  • 박찬무;한동식;황규석;이용범
    • Asian Journal of Turfgrass Science
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    • v.5 no.2
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    • pp.59-68
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    • 1991
  • This experiment was carried out to investigate the mixing ratio of soil amending materials such as peat perlite, active carbon and zeolite for improvements of physiochemical properties of topsoil, of creeping bentgrass (Agrostis palustris var. Penncross). The results were as followed :1.Appropriate addition of soil improvement material was increased the soil porosity due to the decrease of bulk density. Over supplement of soil improvement material induced the decrease of infiltration of water into soil.2Content of organic matter was increased in treatment of peat and active carbon . Soil reaction was decreased in peat treatment, but increased in perlite, zeolite and active carbon. Exchangeable cation capacity was increased by the addition of all kinds of soil improvement materials used in this experiment.

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Development of Magnetically Separable Immobilized Lipase by Using Cellulose Derivatives and Their Application in Enantioselective Esterification of Ibuprofen

  • Lee, Go-Woun;Joo, Hong-Il;Kim, Jung-Bae;Lee, Jung-Heon
    • Journal of Microbiology and Biotechnology
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    • v.18 no.3
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    • pp.465-471
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    • 2008
  • Highly active, stable, and magnetically separable immobilized enzymes were developed using carboxymethyl cellulose (CMC) and diethylaminoethyl cellulose DEAE-C; hereafter designated "DEAE" as supporting materials. Iron oxide nanoparticles penetrated the micropores of the supporting materials, rendering them magnetically separable. Lipase (LP) was immobilized on the surface of the supporting materials by using cross-linked enzyme aggregation (CLEA) by glutaraldehyde. The activity of enzyme aggregates coated on DEAE was approximately 2 times higher than that of enzyme aggregates coated on CMC. This is explained by the fact that enzyme aggregates with amine residues are more efficient than those with carboxyl residues. After a 96-h enantioselective ibuprofen esterification reaction, 6% ibuprofen propyl ester was produced from the racemic mixture of ibuprofen by using DEAE-LP, and 2.8% using CMC-LP.