• Title/Summary/Keyword: Active State

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Recent Progress in the Identification of Active Sites in Pyrolyzed Fe-N/C Catalysts and Insights into Their Role in Oxygen Reduction Reaction

  • Sa, Young Jin;Kim, Jae Hyung;Joo, Sang Hoon
    • Journal of Electrochemical Science and Technology
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    • v.8 no.3
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    • pp.169-182
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    • 2017
  • Iron and nitrogen codoped carbon (Fe-N/C) catalysts have emerged as one of the most promising replacements for state-of-the-art platinum-based electrocatalysts for oxygen reduction reaction (ORR) in polymer electrolyte fuel cells. During the last decade, significant progress has been achieved in Fe-N/C catalysts in terms of ORR activity improvement and active site identification. In this review, we focus on recent efforts towards advancing our understanding of the structure of active sites in Fe-N/C catalysts. We summarize the spectroscopic and electrochemical methods that are used to analyze active site structure in Fe-N/C catalysts, and the relationship between active site structure and ORR activity in these catalysts. We provide an overview of recently reported synthetic strategies that can generate active sites in Fe-N/C catalysts preferentially. We then discuss newly suggested active sites in Fe-N/C catalysts. Finally, we conclude this review with a brief future outlook.

A hybrid seismic response control to improve performance of a two-span bridge

  • Heo, Gwanghee;Kim, Chunggil;Jeon, Seunggon;Lee, Chinok;Jeon, Joonryong
    • Structural Engineering and Mechanics
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    • v.61 no.5
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    • pp.675-684
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    • 2017
  • In this paper, a hybrid seismic response control (HSRC) system was developed to control bridge behavior caused by the seismic load. It was aimed at optimum vibration control, composed of a rubber bearing of passive type and MR-damper of semi-active type. Its mathematical modeling was driven and applied to a bridge model so as to prove its validity. The bridge model was built for the experiment, a two-span bridge of 8.3 meters in length with the HSRC system put up on it. Then, inflicting the EI Centro seismic load on it, shaking table tests were carried out to confirm the system's validity. The experiments were conducted under the basic structure state (without an MR-damper applied) first, and then under the state with an MR-damper applied. It was also done under the basic structure state with a reinforced rubber bearing applied, then the passive on/off state of the HSRC system, and finally the semi-active state where the control algorithm was applied to the system. From the experiments, it was observed that pounding rather increased when the MR-damper alone was applied, and also that the application of the HSRC system effectively prevented it from occurring. That is, the experiments showed that the system successfully mitigated structural behavior by 70% against the basic structure state, and, further, when control algorithm is applied for the operation of the MR-damper, relative displacement was found to be effectively mitigated by 80%. As a result, the HSRC system was proven to be effective in mitigating responses of the two-span bridge under seismic load.

Vertical equipment isolation using piezoelectric inertial-type isolation system

  • Lu, Lyan-Ywan;Lin, Ging-Long;Chen, Yi-Siang;Hsiao, Kun-An
    • Smart Structures and Systems
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    • v.26 no.2
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    • pp.195-211
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    • 2020
  • Among anti-seismic technologies, base isolation is a very effective means of mitigating damage to structural and nonstructural components, such as equipment. However, most seismic isolation systems are designed for mitigating only horizontal seismic responses because the realization of a vertical isolation system (VIS) is difficult. The difficulty is primarily due to conflicting isolation stiffness demands in the static and dynamic states for a VIS, which requires sufficient rigidity to support the self-weight of the isolated object in the static state, but sufficient flexibility to lengthen the isolation period and uncouple the ground motion in the dynamic state. To overcome this problem, a semi-active VIS, called the piezoelectric inertia-type vertical isolation system (PIVIS), is proposed in this study. PIVIS is composed of a piezoelectric friction damper (PFD) and a leverage mechanism with a counterweight. The counterweight provides an uplifting force in the static state and an extra inertial force in the dynamic state; therefore, the effective vertical stiffness of PIVIS is higher in the static state and lower in the dynamic state. The PFD provides a controllable friction force for PIVIS to further prevent its excessive displacement. For experimental verification, a shaking table test was conducted on a prototype PIVIS controlled by a simple controller. The experimental results well agree with the theoretical results. To further investigate the isolation performance of PIVIS, the seismic responses of PIVIS were simulated numerically by considering 14 vertical ground motions with different characteristics. The responses of PIVIS were compared with those of a traditional VIS and a passive system (PIVIS without control). The numerical results demonstrate that compared with the traditional and passive systems, PIVIS can effectively suppress isolation displacement in all kinds of earthquake with various peak ground accelerations and frequency content while maintaining its isolation efficiency. The proposed system is particularly effective for near-fault earthquakes with long-period components, for which it prevents resonant-like motion.

Study of Synthesis and Property of Eu-PEG Phase Change Luminescent Materials (Eu-PEG로 구성된 상변환 발광재료의 합성 및 물성에 대한 연구)

  • Gu, Xiao-Hua;Xi, Peng;Shen, Xin-Yuan;Cheng, Bo-Wen
    • Polymer(Korea)
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    • v.32 no.4
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    • pp.305-312
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    • 2008
  • A novel TPC-PEG-TPC with active end-groups was obtained from the end-groups of polyethylene glycol (PEG) modified by terephthaloyl chloride (TPC). These active end-groups can link up with a rare earth ion, which is a luminescent center of a rare earth fluorescent complex. Complexes of Eu-PEG with novel ligands (TPC-PEG-PTC) were synthesized by the coordination of the active reactant (as the first ligand) and phenanthroline (as the second ligand) with $Eu^{3+}$.IR, $^1H$-NMR, element analysis, DSC, WAXD, fluorescent spectroscopy, TGA, and SEM were used to characterize the structure and properties of these complexes. The results showed that this type of complex is a heat storage material with the phase change character of polyethylene glycol (PEG) and the luminescent properties of europium. There was no thermal decomposition of the complex of Eu-PEG until $300^{\circ}C$. SEM showed that the complex of Eu-PEG can be dispersed in PE.

Nonlinear Controller Design of Active Magnetic Bearing Systems Based on Polytopic Quasi-LPV Models (Polytopic Quasi-LPV 모델 기반 능동자기베어링의 비선형제어기 설계)

  • Lee, Dong-Hwan;Park, Jin-Bae;Jeong, Hyun-Suk;Joo, Young-Hoon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.4
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    • pp.797-802
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    • 2010
  • In this paper, a systematic procedure to design a nonlinear controller for nonlinear active magnetic bearing (AMB) systems is presented. To do this, we effectively convert the AMB system into a polytopic quasi-linear parameter varying (LPV) system, which is a representation of nonlinear state-space models and is described by the convex combination of a set of precisely known vertices. Unlike the existing quasi-LPV systems, the nonlinear weighting functions, which construct the polytopic quasi-LPV model of the AMB system by connecting the vertices, include not only state variables but also the input ones. This allows us to treat the input nonlinearity effectively. By means of the derived polytopic quasi-LPV model and linear matrix inequality (LMI) conditions, nonlinear controller that stabilizes the AMB system is obtained. The effectiveness of the proposed controller design methodology is finally demonstrated through numerical simulations.

Tracking and Capturing a Moving Object Using Active Camera Mounted on a Mobile Robot (이동로봇에 장착된 능동 카메라를 이용한 이동물체의 추적과 포획)

  • Park, Jin-U;Park, Jae-Han;Yun, Gyeong-Sik;Lee, Jang-Myeong
    • Journal of Institute of Control, Robotics and Systems
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    • v.7 no.9
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    • pp.741-748
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    • 2001
  • In this paper, we propose a method of tracking and capturing a moving object by a mobile robot. The position of the moving object is acquired from the relation through color-based image information from a 2-DOF active camera mounted on the mobile robot. The direction and rotational angular velocity of the moving object are estimated using a state estimator. A Kalman fiber is used as the state estimator for taking characteristics of robustness against noises and uncertainties included in the input data. After estimating the trajectory of the moving object, we decide on the optimal trajectory and plan the motion of the mobile robot to capture the target object within the shortest distance and time. The effectiveness of the proposed method is demonstrated by the simulations and experiments.

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Design of Active Disturbance Rejection Control for Inductive Power Transfer Systems

  • Wang, Yanan;Dong, Lei;Liao, Xiaozhong;Ju, Xinglong;Xiao, Furong
    • Journal of Power Electronics
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    • v.18 no.5
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    • pp.1434-1447
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    • 2018
  • The control design of inductive power transfer (IPT) systems has attracted a lot of attention in the field of wireless power transmission. Due to the high-order resonant networks and multiple loads in IPT systems, a simplified model of an IPT system is preferred for analysis and control design, and a controller with strong robustness is required. Hence, an active disturbance rejection control (ADRC) for IPT systems is proposed in this paper. To realize the employment of ADRC, firstly a small-signal model of an LC series-compensative IPT system is derived based on generalized state-space averaging (GSSA), then the ADRC is implemented in the designed IPT system. The ADRC not only provides superior robustness to unknown internal and external disturbances, but also requires few knowledge of the IPT system. Due to the convenient realization of ADRC, the designed IPT system retains its simple structure without any additional circuits. Finally, a frequency domain analysis and experimental results have validated the effectiveness of the employed ADRC, especially its robustness in the presence of frequency drifts and other common disturbances.

Model Predictive Control for Shunt Active Power Filter in Synchronous Reference Frame

  • Al-Othman, A.K.;AlSharidah, M.E.;Ahmed, Nabil A.;Alajmi, Bader. N.
    • Journal of Electrical Engineering and Technology
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    • v.11 no.2
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    • pp.405-415
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    • 2016
  • This paper presents a model predictive control for shunt active power filters in synchronous reference frame using space vector pulse-width modulation (SVPWM). The three phase load currents are transformed into synchronous rotating reference frame in order to reduce the order of the control system. The proposed current controller calculates reference current command for harmonic current components in synchronous frame. The fundamental load current components are transformed into dc components revealing only the harmonics. The predictive current controller will add robustness and fast compensation to generate commands to the SVPWM which minimizes switching frequency while maintaining fast harmonic compensation. By using the model predictive control, the optimal switching state to be applied to the next sampling time is selected. The filter current contains only the harmonic components, which are the reference compensating currents. In this method the supply current will be equal to the fundamental component of load current and a part of the current at fundamental frequency for losses of the inverter. Mathematical analysis and the feasibility of the suggested approach are verified through simulation results under steady state and transient conditions for non-linear load. The effectiveness of the proposed controller is confirmed through experimental validation.

Integration Control of Air-Cell Seat and Semi-active Suspension Using Sliding Perturbation Observer Design (슬라이딩 섭동 관측기를 이용한 에어셀과 반능동 서스펜션의 통합 제어)

  • 유기성;윤정주;이민철;유완석
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.3
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    • pp.159-169
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    • 2004
  • In this study, integration control of air-cell seat and semi-active suspension is proposed to minimize the road-tyre force which can cause uncomfortable feeling to rider. The proposed integration control with sliding perturbation observer is consisted of air-cell seat control which uses the force generated by air-cell and the sky-hook control. The air-cell seat itself has been modeled as a 1 degree of freedom spring-damper system. The actual characteristics of the air-cell have been analyzed through experiments. In this paper, we introduces a new robust motion control algorithm using partial state feedback for a nonlinear system with modelling uncertainties and external disturbances. The major contribution of this work is the development and design of robust observer for the state and the perturbation. The combination skyhook controller and air-cell controller using the observer improves control performance, because of the robust routine called Sliding Observer Design for Integration Control of Air-Cell Seat and Semi-active Suspension. The simulation results show a high accuracy and a good performance.

Active damage localization technique based on energy propagation of Lamb waves

  • Wang, Lei;Yuan, F.G.
    • Smart Structures and Systems
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    • v.3 no.2
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    • pp.201-217
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    • 2007
  • An active damage detection technique is introduced to locate damage in an isotropic plate using Lamb waves. This technique uses a time-domain energy model of Lamb waves in plates that the wave amplitude inversely decays with the propagation distance along a ray direction. Accordingly the damage localization is formulated as a least-squares problem to minimize an error function between the model and the measured data. An active sensing system with integrated actuators/sensors is controlled to excite/receive $A_0$ mode of Lamb waves in the plate. Scattered wave signals from the damage can be obtained by subtracting the baseline signal of the undamaged plate from the recorded signal of the damaged plate. In the experimental study, after collecting the scattered wave signals, a discrete wavelet transform (DWT) is employed to extract the first scattered wave pack from the damage, then an iterative method is derived to solve the least-squares problem for locating the damage. Since this method does not rely on time-of-flight but wave energy measurement, it is more robust, reliable, and noise-tolerant. Both numerical and experimental examples are performed to verify the efficiency and accuracy of the method, and the results demonstrate that the estimated damage position stably converges to the targeted damage.