• Title/Summary/Keyword: Activation Properties

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A Numerical Analysis of Activation Energy by a Slope of TSC Curve (열자격전류곡선의 경사에 의한 활성화에너지의 수치해석)

  • 김기준;김상진;송자윤
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.163-166
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    • 1995
  • It was investigated the properties of TSC (Thermally Stimulated Current) to understand carriers behavior from long ago. Activation Energy of their properties is very important to verify electrical characteristics. So, for many years, many researchers were worked to get the activation energy, more compeletely. But, if boundary conditions were not satisfied, the values of activation energy contained several errors. In this work, to obtain the activation energy related to charged particles, the peak temperature Tp and the slope of tangential line on any coordinates of Arrhenius plot are applied. The calculation process can be denied with by computer, and the result of observation shows that the cures of calculation data and simulation data coincide very compeletely.

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Effect of Muscle Pre-activation Properties on the Magnitude of Joint Torque during Voluntary Isometric Knee Extension (등척성 무릎 토크 발생 시 사전활성화 유형의 차이가 최대 자발적 토크 생성에 미치는 영향)

  • Kim, Jong-Ah;Shin, Narae;Lee, Sungjune;Xu, Dayuan;Park, Jaebum
    • Korean Journal of Applied Biomechanics
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    • v.31 no.2
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    • pp.140-147
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    • 2021
  • Objective: The purpose of this study is to identify the mechanism of changes in maximum voluntary torque with the magnitude and duration of pre-activation torque during voluntary isometric knee extension. Method: 11 male subjects (age: 25.91±2.43 yrs., height: 173.12±3.51 cm, weight: 76.45±7.74 kg) participated in this study. The subjects were required to produce maximal voluntary isometric torque with a particular pre-activation torque condition. The properties of pre-activation torque consisted of the combinations of 1) three levels of magnitude, e.g., 32 Nm, 64 Nm, 96 Nm, and 2) two levels of duration, e.g., 1 sec, and 3 sec; thus, a total of six conditions were given to the subjects. The force and EMG data were measured using the force transducers and wireless EMG sensor, respectively. Results: The results showed that the maximum voluntary torque increased the most with relatively large and fast (96 Nm, 1 sec) pre-activation condition. Similarly, with relatively large and fast (96 Nm, 1 sec) preactivation, it was found that the integrated EMG (iEMG) of the agonist muscles increased, while no significant changes in the co-contraction of the antagonist muscles for the knee extension. Also, the effect of pre-activation conditions on the rate of torque development was not statistically significant. Conclusion: The current findings suggest that relatively larger in magnitude and shorter in duration as the properties of pre-activation lead to a larger magnitude of maximal voluntary torque, possibly due to the increased activity of the agonist muscles during knee extension.

Effect of Pore Structure of Activated Carbon Fiber on Mechanical Properties (활성탄소섬유의 기공구조가 기계적 특성에 미치는 영향)

  • Choi, Yun Jeong;Lee, Young-Seak;Im, Ji Sun
    • Applied Chemistry for Engineering
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    • v.29 no.3
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    • pp.318-324
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    • 2018
  • In this study, PAN (polyacrylonitrile) based activated carbon fibers were prepared by water vapor activation method which is a physical activation method. Activation was performed with temperature and time as parameters. When the activation temperature reached 700, 750 and $800^{\circ}C$, the activation was carried out under the condition of a water vapor flow rate of 200 ml/min. In order to analyze the pore structure of activated carbon fibers, the specific surface area ($S_{BET}$) was measured by the adsorption/desorption isotherm of nitrogen gas and AFM analysis was performed for the surface analysis. Tensile tests were also conducted to investigate the effect of the pore structure on mechanical properties of fibers. As a result, the $S_{BET}$ of fibers after the activation showed a value of $448{\sim}902m^2/g$, the tensile strength decreased 58.16~84.92% and the tensile modulus decreased to 69.81~83.89%.

Immune Activation by siRNA/Liposome Complexes in Mice Is Sequence- independent: Lack of a Role for Toll-like Receptor 3 Signaling

  • Kim, Ji Young;Choung, Sorim;Lee, Eun-Ju;Kim, Young Joo;Choi, Young-Chul
    • Molecules and Cells
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    • v.24 no.2
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    • pp.247-254
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    • 2007
  • Improvement in the pharmacokinetic properties of short interfering RNAs (siRNAs) is a prerequisite for the therapeutic application of RNA interference technology. When injected into mice as unmodified siRNAs complexed to DOTAP/Chol-based cationic liposomes, all 12 tested siRNA duplexes caused a strong induction of cytokines including interferon ${\alpha}$, indicating that the immune activation by siRNA duplexes is independent of sequence context. When modified by various combinations of 2'-OMe, 2'-F, and phosphorothioate substitutions, introduction of as little as three 2'-OMe substitutions into the sense strand was sufficient to suppress immune activation by siRNA duplexes, whereas the same modifications were much less efficient at inhibiting the immune response of single stranded siRNAs. It is unlikely that Toll-like receptor 3 (TLR3) signaling is involved in immune stimulation by siRNA/liposome complexes since potent immune activation by ds siRNAs was induced in TLR3 knockout mice. Together, our results indicate that chemical modification of siRNA provides an effective means to avoid unwanted immune activation by therapeutic siRNAs. This improvement in the in vivo properties of siRNAs should greatly facilitate successful development of siRNA therapeutics.

Effect of Chemical Activation on Electrochemical behaviors of Ni-loaded Graphite Nanofibers (화학적 활성화에 따른 Ni 담지된 흑연나노섬유의 전기화학적 거동)

  • Yoo, Hye-Min;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.159.2-159.2
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    • 2011
  • In this study, we prepared the activated graphite nanofibers (A-GNFs) via chemical activation with KOH reagent. The effect of A-GNFs on the surface and textural properties of Ni-loaded graphite nanofibers (Ni/GNFs) was investigated by X-ray diffraction (XRD), transmission electron microscope (TEM), and Brunauer-Emmett-Teller (BET). The textural properties of samples were investigated by $N_2$/77K adsorption isotherms. The electrochemical performances were investigated by cyclic voltammetry. As a results, the electrochemical performances of Ni/GNFs were improved with usage of A-GNFs. This could be interpreted by the high specific surface area and large total pore volume of the A-GNFs.

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Mechanical Properties and Surface Characteristics of Ti-25Ta-xHf Alloys

  • Park, Seon-Yeong;Kim, Jeong-Jae;Choe, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.187-187
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    • 2014
  • In this study, we investigated mechanical properties and surface characteristics of Ti-25Ta-xHf alloys. The samples were manufactured for composition of Ti-25Ta-xHf(x=0 to 15 wt. %) alloys. Each alloy was melted twenty times in an arc-melting vacuum furnace. The microstructural phases and phase transformation of Ti-25Ta-xHf alloys were identified with the aid of an XRF, XRD and DSC. And mechanical properties were investigated using Vickers hardness, nanoindentation, and tensile test.

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Effect of Activation Energy and Crystallization Kinetics of Polyethylenes on the Stability of Film Casting Processes

  • Lee, Joo-Sung;Cho, Joon-Hee
    • Korea-Australia Rheology Journal
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    • v.21 no.2
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    • pp.135-141
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    • 2009
  • Effect of activation energy and crystallization kinetics of polyethylenes (PEs) on the dynamics and stability has been investigated by changing rheological properties and crystallization rate in film casting process. The effect of changes of these properties has been shown using a typical example of short-chain branching (SCB) in linear polyethylenes. SCBs in linear polymers generally lead to the increase of the flow activation energy, and to the decrease of the crystallization rate, making polymer viscosity lower in the case of equivalent molecular weight. In general, the increment of the crystallinity of polymers under partially crystallized state helps to enhance the process stability by increasing tension, and lower fluid viscoelasticity possesses the stabilizing effect for linear polymers. It has been found that the fluid viscoelasticity plays a key role in the control of process stability than crystallization kinetics which critically depends on the cooling to stabilize the film casting process of short-chain branched polymers operated under the low aspect ratio condition.

Effect of KOH Activation on Electrochemical Behaviors of Graphite Nanofibers (KOH 활성화 효과에 의한 흑연나노섬유의 전기화학적 거동)

  • Yoo, Hye-Min;Min, Byung-Gak;Lee, Kyu-Hwan;Byun, Joon-Hyung;Park, Soo-Jin
    • Polymer(Korea)
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    • v.36 no.3
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    • pp.321-325
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    • 2012
  • In this work, we prepared the activated graphite nanofibers (A-GNFs) via chemical activation with KOH/GNFs ratios in a range of 0 to 5. The effect of KOH activation was studied in the surface and pore properties of the samples for electrochemical performance. The surface properties of A-GNFs were characterized by XRD and SEM measurements. The textural properties of the A-GNFs were investigated by $N_2$/77 K adsorption isotherms using Brunauer-Emmett-Teller (BET) equation. Their electrochemical behaviors were investigated by cyclic voltammetry and galvanostatic charge-discharge performance. From the results, electrochemical performances of the A-GNFs were improved with increasing the ratio of KOH reagent. It was found that specific surface area and total pore volume of the A-GNFs were increased by KOH activation.

Electrochemical Behaviors of Binary Ti-Zr Alloys

  • Oh, M.Y.;Kim, W.G.;Choe, H.C.;Ko, Y.M.
    • Corrosion Science and Technology
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    • v.8 no.2
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    • pp.89-92
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    • 2009
  • Pure Ti as well as Ti-6Al-4V alloy exhibit excellent properties for dental implant applications. However, for a better biocompatibility it seems important to avoid in the composition the presence of V due to the toxic effects of V ion release. Thus Al and V free and composed of non-toxic element such as Nb, Zr alloys as biomaterials have been developed. Especially, Zr contains to same family in periodic table as Ti. The addition of Zr to Ti alloy has an excellent mechanical properties, good corrosion resistance, and biocompatibility. In this study, the electrochemical characteristics of Ti-Zr alloys for biomaterials have been investigated using by electrochemical methods. Methods: Ti-Zr(10, 20, 30 and 40 wt%) alloys were prepared by arc melting and homogenized for 24 hr at $1000^{\circ}C$ in argon atmosphere. Phase constitutions and microstructure of the specimens were characterized by XRD, OM and SEM. The corrosion properties of the specimens were examined through potentiodynamic test (potential range of -1500 ~ 2000 mV), potentiostatic test (const. potential of 300 mV) in artificial saliva solution by potentiostat (EG&G Co, PARSTAT 2273. USA).

Influence of Activation Temperature on Surface and Adsorption Properties of PAN-based Activated Carbon Fibers/Phenolic Resin Matrix Composites (활성화 온도에 의한 PAN계 활성탄소섬유/페놀수지 복합재료의 표면 및 흡착특성)

  • 박수진;김기동;이재락
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.97-104
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    • 2000
  • PAN-based activated carbon fibers/phenolic resin matrix composites (ACFCs) were manufactured via molding process with oxidized carbon fabrics (plain-type) and phenolic resin (resole-type) compounded by 70 : 30 wt%. The green body (as molded) was submitted to carbonization (at 100$0^{\circ}C$) in an inert environment and activation (at 700, 800, 900 and 100$0^{\circ}C$) in a $CO_2$ environment. In this work, the influence of activation temperatures was investigated in surface properties, such as pH, acid- and base-values by titration method, and in adsorption properties, i.e., specific surface area and pore structures by BET-method of the composites. Also, the pressure drops of the specimens were calibrated by ASTM. As a result, the activation temperature influenced the surface property of ACFCs. When the activation temperature was higher than 90$0^{\circ}C$, the surface was gradually developed in basic nature. And, the evolutions of specific surface area, total pore volume and pore size distribution of ACFCs could be easily confirmed the dependence on the activation temperature. Among them, well-developed pore structure from adsorption characteristics was changed of the ACFCs activated at 90$0^{\circ}C$. Also, the pressure drop was slightly decreased with increasing the temperature due to increasing the burn-off with heat treatment temperature of ACFCs.

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