• 제목/요약/키워드: Activation Model

검색결과 1,755건 처리시간 0.03초

Mg-Al 복합 황산염 수화물의 열분해 속도 (Kinetics of the Thermal Decomposition of Mg-Al Sulfate Hydrate)

  • 박홍채;오기동
    • 한국세라믹학회지
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    • 제24권5호
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    • pp.417-422
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    • 1987
  • Kinetic studies were made on the thermal decomposition of hydrated magnesium aluminum double sulfate by a nonisothermal TG method. Thermal analyses of the dehydration of tricosahydrate showed that the reaction proceeded via decahydrate to the anhydrous MgAl2(SO4)4 in the range 50$^{\circ}$to 400$^{\circ}C$. Decomposition of MgAl2(SO4)4 occurred as the two-step between 650$^{\circ}$ and 970$^{\circ}C$. Dehydration of MgAl2(SO4)4$.$23H2O and a 2D diffusion controlled with an activation energy of 16.6kcal/mole, respectively. MgAl2(SO4)4 fitted the contracting volume model with an activation energy of 10.5kcal/mole, and MgSO4 fitted a contracting area model with an activation of 4.5kcal/mole.

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Application of the Arrhenius Equation in Geotechnical Engineering

  • Yoon, Hyung-Koo
    • 지질공학
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    • 제24권4호
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    • pp.575-581
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    • 2014
  • The reliable measurement of geotechnical properties in cold regions should account for their fluctuations with temperature. The objective of this paper is to introduce a chemical model based on the Arrhenius equation that can predict the properties of materials as their temperature changes. The model can monitor phases and reaction rates as they change with temperature. It has been already applied in the fields of geology, construction, chemistry, materials engineering, and food science. The application of the Arrhenius equation requires a reliable estimate of the activation energy. Therefore, this study also demonstrates several methods for evaluating activation energy in different contexts through summaries and reviews of previous research related to the Arrhenius equation. This paper may be of wide use in obtaining temperature-dependent parameters in geotechnical engineering.

MAGNETIC FIELD DEPENDENCE OF MAGNETIZATION REVERSAL BEHAVIOR IN Co/Pt MULTILAYERS.

  • Cho, Yoon-Chul;Choe, Sug-Bong;Shin, Sung-Chul
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2000년도 International Symposium on Magnetics The 2000 Fall Conference
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    • pp.279-286
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    • 2000
  • Magnetic field dependence of magnetization reversal in Co/Pt multilayers has been quantitatively investigated. Serial samples of Co/Pt multilayers have been prepared by dc-magnetron sputtering under various Ar pressure. Magnetization reversal was monitored by magnetization viscosity measurement and direct domain observation using a magneto-optical microscope system, and the wall-motion speed and the nucleation rate R were determined using a domain reversal model based on time-resolved domain reversal patterns. Both and R were found to be exponentially dependent on the reversing applied field. From the exponential dependencies, the activation volumes of the wall motion and nucleation could be determined based on a thermally activated relaxation model, and the wall-motion activation volume was revealed to be slightly larger than the nucleation activation volume.

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The investigation of Magnetohydrodynamic nanofluid flow with Arrhenius energy activation

  • Sharif, Humaira;Khadimallah, Mohamed A.;Naeem, Muhammad Nawaz;Hussain, Muzamal;Mahmoud, S.R.;Al-Basyouni, K.S.;Tounsi, Abdelouahed
    • Advances in nano research
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    • 제10권5호
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    • pp.437-448
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    • 2021
  • In this article, an analytically and numerically 3D nanoliquid flow by a porous rotatable disk is presented in the presence of gyrotactic microorganisms. The mathematical model in the form of partial differential system is transmuted into dimensionless form by utilizing the appropriate transformation. The homotopy analysis approach is applied to attain the analytic solution of the problem. The effect of promising parameters on velocity distribution, temperature profile, nanoparticles volume fraction and motile microorganism distribution field are evaluated through graphs and in tabular form. The existence of Brownian motion and thermophoresis impacts are more proficient for heat transfer enhancement. Further the unique features like heat absorption/generation and energy activation are also examined for the present flow problem. The obtained results are compared with the earliear investigation to check the accuracy of present model.

응결시간과 겉보기 활성화 에너지를 이용한 고로슬래그 콘크리트의 압축강도 예측에 관한 연구 (Prediction of Compressive Strength Using Setting Time and Apparent Activation Energy of Blast Furnace Slag Concrete)

  • 김한솔;양현민;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2021년도 가을 학술논문 발표대회
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    • pp.101-102
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    • 2021
  • The compressive strength of concrete is greatly affected by the temperature inside the concrete at the initial age immediately after pouring. The apparent activation energy of cement and the setting time of concrete are major factors influencing the development of compressive strength of concrete. This study measured the apparent activation energy and setting time according to the change in W/B for each mixing rate of Ground Granulated Blast-Furnace Slag (GGBFS). And after calculating the compressive strength prediction model, the accuracy of the prediction model was evaluated by comparing the predicted compressive strength and the compressive strength.

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근 부피 센서를 이용한 인체 팔꿈치 관절의 동작 토크 추정 (Torque Estimation of the Human Elbow Joint using the MVS (Muscle Volume Sensor))

  • 이희돈;임동환;김완수;한정수;한창수;안재용
    • 한국정밀공학회지
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    • 제30권6호
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    • pp.650-657
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    • 2013
  • This study uses a muscle activation sensor and elbow joint model to develop an estimation algorithm for human elbow joint torque for use in a human-robot interface. A modular-type MVS (Muscle Volume Sensor) and calibration algorithm are developed to measure the muscle activation signal, which is represented through the normalization of the calibrated signal of the MVS. A Hill-type model is applied to the muscle activation signal and the kinematic model of the muscle can be used to estimate the joint torques. Experiments were performed to evaluate the performance of the proposed algorithm by isotonic contraction motion using the KIN-COM$^{(R)}$ equipment at 5, 10, and 15Nm. The algorithm and its feasibility for use as a human-robot interface are verified by comparing the joint load condition and the torque estimated by the algorithm.

구름방울 활성화 과정 모수화 방법에 따른 구름 형성의 민감도 실험 (Sensitivity Test of the Parameterization Methods of Cloud Droplet Activation Process in Model Simulation of Cloud Formation)

  • 김아현;염성수;장동영
    • 대기
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    • 제28권2호
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    • pp.211-222
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    • 2018
  • Cloud droplet activation process is well described by $K{\ddot{o}}hler$ theory and several parameterizations based on $K{\ddot{o}}hler$ theory are used in a wide range of models to represent this process. Here, we test the two different method of calculating the solute effect in the $K{\ddot{o}}hler$ equation, i.e., osmotic coefficient method (OSM) and ${\kappa}-K{\ddot{o}}hler$ method (KK). To do that, each method is implemented in the cloud droplet activation parameterization module of WRF-CHEM (Weather Research and Forecasting model coupled with Chemistry) model. It is assumed that aerosols are composed of five major components (i.e., sulfate, organic matter, black carbon, mineral dust, and sea salt). Both methods calculate similar representative hygroscopicity parameter values of 0.2~0.3 over the land, and 0.6~0.7 over the ocean, which are close to estimated values in previous studies. Simulated precipitation, and meteorological variables (i.e., specific heat and temperature) show good agreement with reanalysis. Spatial patterns of precipitation and liquid water path from model results and satellite data show similarity in general, but on regional scale spatial patterns and intensity show some discrepancy. However, meteorological variables, precipitation, and liquid water path do not show significant differences between OSM and KK simulations. So we suggest that the relatively simple KK method can be a good alternative to the OSM method that requires various information of density, molecular weight and dissociation number of each individual species in calculating the solute effect.

CO2-갈탄 가스화 반응에 미치는 폐촉매의 영향 및 반응속도론 연구 (The Effect of Waste Catalysts and Kinetic Study on the CO2-Lignite Gasification Reaction)

  • 서석진;이소정;손정민
    • 청정기술
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    • 제20권1호
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    • pp.72-79
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    • 2014
  • 본 연구에서는 갈탄에 폐촉매(I, II, III) 및 $K_2CO_3$를 이용한 $CO_2$ 가스화의 반응속도상수 및 활성화 에너지를 조사하였다. 가스화 실험은 1 wt%, 5 wt%, 10 wt%의 촉매를 물리적으로 혼합한 갈탄을 열중량분석(Thermogravity analysis, TGA)을 이용하여 가스화 온도 $800^{\circ}C$, $850^{\circ}C$, $900^{\circ}C$ 범위에서 수행하였다. 실험 데이터를 세 가지 반응속도 모델(volumetric reaction model, VRM; shrinking core model, SCM; modified volumetric reaction model, MVRM)에 적용한 결과 MVRM이 가장 적합하였다. 가스화 속도는 온도가 높아짐에 따라 증가하는 것으로 관찰되었으며, 모든 실험 온도에서 폐촉매를 이용한 가스화 반응의 활성화 에너지는 촉매를 혼합하지 않은 갈탄 보다 낮게 나타났다. 특히, 폐촉매 III 10 wt%의 경우 활성화 에너지가 92.37 kJ/mol로 가장 낮게 얻어졌다.