• Title/Summary/Keyword: Activation Model

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Kinetics of the Thermal Decomposition of Mg-Al Sulfate Hydrate (Mg-Al 복합 황산염 수화물의 열분해 속도)

  • 박홍채;오기동
    • Journal of the Korean Ceramic Society
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    • v.24 no.5
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    • pp.417-422
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    • 1987
  • Kinetic studies were made on the thermal decomposition of hydrated magnesium aluminum double sulfate by a nonisothermal TG method. Thermal analyses of the dehydration of tricosahydrate showed that the reaction proceeded via decahydrate to the anhydrous MgAl2(SO4)4 in the range 50$^{\circ}$to 400$^{\circ}C$. Decomposition of MgAl2(SO4)4 occurred as the two-step between 650$^{\circ}$ and 970$^{\circ}C$. Dehydration of MgAl2(SO4)4$.$23H2O and a 2D diffusion controlled with an activation energy of 16.6kcal/mole, respectively. MgAl2(SO4)4 fitted the contracting volume model with an activation energy of 10.5kcal/mole, and MgSO4 fitted a contracting area model with an activation of 4.5kcal/mole.

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Application of the Arrhenius Equation in Geotechnical Engineering

  • Yoon, Hyung-Koo
    • The Journal of Engineering Geology
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    • v.24 no.4
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    • pp.575-581
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    • 2014
  • The reliable measurement of geotechnical properties in cold regions should account for their fluctuations with temperature. The objective of this paper is to introduce a chemical model based on the Arrhenius equation that can predict the properties of materials as their temperature changes. The model can monitor phases and reaction rates as they change with temperature. It has been already applied in the fields of geology, construction, chemistry, materials engineering, and food science. The application of the Arrhenius equation requires a reliable estimate of the activation energy. Therefore, this study also demonstrates several methods for evaluating activation energy in different contexts through summaries and reviews of previous research related to the Arrhenius equation. This paper may be of wide use in obtaining temperature-dependent parameters in geotechnical engineering.

MAGNETIC FIELD DEPENDENCE OF MAGNETIZATION REVERSAL BEHAVIOR IN Co/Pt MULTILAYERS.

  • Cho, Yoon-Chul;Choe, Sug-Bong;Shin, Sung-Chul
    • Proceedings of the Korean Magnestics Society Conference
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    • 2000.09a
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    • pp.279-286
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    • 2000
  • Magnetic field dependence of magnetization reversal in Co/Pt multilayers has been quantitatively investigated. Serial samples of Co/Pt multilayers have been prepared by dc-magnetron sputtering under various Ar pressure. Magnetization reversal was monitored by magnetization viscosity measurement and direct domain observation using a magneto-optical microscope system, and the wall-motion speed and the nucleation rate R were determined using a domain reversal model based on time-resolved domain reversal patterns. Both and R were found to be exponentially dependent on the reversing applied field. From the exponential dependencies, the activation volumes of the wall motion and nucleation could be determined based on a thermally activated relaxation model, and the wall-motion activation volume was revealed to be slightly larger than the nucleation activation volume.

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The investigation of Magnetohydrodynamic nanofluid flow with Arrhenius energy activation

  • Sharif, Humaira;Khadimallah, Mohamed A.;Naeem, Muhammad Nawaz;Hussain, Muzamal;Mahmoud, S.R.;Al-Basyouni, K.S.;Tounsi, Abdelouahed
    • Advances in nano research
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    • v.10 no.5
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    • pp.437-448
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    • 2021
  • In this article, an analytically and numerically 3D nanoliquid flow by a porous rotatable disk is presented in the presence of gyrotactic microorganisms. The mathematical model in the form of partial differential system is transmuted into dimensionless form by utilizing the appropriate transformation. The homotopy analysis approach is applied to attain the analytic solution of the problem. The effect of promising parameters on velocity distribution, temperature profile, nanoparticles volume fraction and motile microorganism distribution field are evaluated through graphs and in tabular form. The existence of Brownian motion and thermophoresis impacts are more proficient for heat transfer enhancement. Further the unique features like heat absorption/generation and energy activation are also examined for the present flow problem. The obtained results are compared with the earliear investigation to check the accuracy of present model.

Prediction of Compressive Strength Using Setting Time and Apparent Activation Energy of Blast Furnace Slag Concrete (응결시간과 겉보기 활성화 에너지를 이용한 고로슬래그 콘크리트의 압축강도 예측에 관한 연구)

  • Kim, Han-Sol;Yang, Hyun-Min;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.101-102
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    • 2021
  • The compressive strength of concrete is greatly affected by the temperature inside the concrete at the initial age immediately after pouring. The apparent activation energy of cement and the setting time of concrete are major factors influencing the development of compressive strength of concrete. This study measured the apparent activation energy and setting time according to the change in W/B for each mixing rate of Ground Granulated Blast-Furnace Slag (GGBFS). And after calculating the compressive strength prediction model, the accuracy of the prediction model was evaluated by comparing the predicted compressive strength and the compressive strength.

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Torque Estimation of the Human Elbow Joint using the MVS (Muscle Volume Sensor) (근 부피 센서를 이용한 인체 팔꿈치 관절의 동작 토크 추정)

  • Lee, Hee Don;Lim, Dong Hwan;Kim, Wan Soo;Han, Jung Soo;Han, Chang Soo;An, Jae Yong
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.6
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    • pp.650-657
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    • 2013
  • This study uses a muscle activation sensor and elbow joint model to develop an estimation algorithm for human elbow joint torque for use in a human-robot interface. A modular-type MVS (Muscle Volume Sensor) and calibration algorithm are developed to measure the muscle activation signal, which is represented through the normalization of the calibrated signal of the MVS. A Hill-type model is applied to the muscle activation signal and the kinematic model of the muscle can be used to estimate the joint torques. Experiments were performed to evaluate the performance of the proposed algorithm by isotonic contraction motion using the KIN-COM$^{(R)}$ equipment at 5, 10, and 15Nm. The algorithm and its feasibility for use as a human-robot interface are verified by comparing the joint load condition and the torque estimated by the algorithm.

Sensitivity Test of the Parameterization Methods of Cloud Droplet Activation Process in Model Simulation of Cloud Formation (구름방울 활성화 과정 모수화 방법에 따른 구름 형성의 민감도 실험)

  • Kim, Ah-Hyun;Yum, Seong Soo;Chang, Dong Yeong
    • Atmosphere
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    • v.28 no.2
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    • pp.211-222
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    • 2018
  • Cloud droplet activation process is well described by $K{\ddot{o}}hler$ theory and several parameterizations based on $K{\ddot{o}}hler$ theory are used in a wide range of models to represent this process. Here, we test the two different method of calculating the solute effect in the $K{\ddot{o}}hler$ equation, i.e., osmotic coefficient method (OSM) and ${\kappa}-K{\ddot{o}}hler$ method (KK). To do that, each method is implemented in the cloud droplet activation parameterization module of WRF-CHEM (Weather Research and Forecasting model coupled with Chemistry) model. It is assumed that aerosols are composed of five major components (i.e., sulfate, organic matter, black carbon, mineral dust, and sea salt). Both methods calculate similar representative hygroscopicity parameter values of 0.2~0.3 over the land, and 0.6~0.7 over the ocean, which are close to estimated values in previous studies. Simulated precipitation, and meteorological variables (i.e., specific heat and temperature) show good agreement with reanalysis. Spatial patterns of precipitation and liquid water path from model results and satellite data show similarity in general, but on regional scale spatial patterns and intensity show some discrepancy. However, meteorological variables, precipitation, and liquid water path do not show significant differences between OSM and KK simulations. So we suggest that the relatively simple KK method can be a good alternative to the OSM method that requires various information of density, molecular weight and dissociation number of each individual species in calculating the solute effect.

The Effect of Waste Catalysts and Kinetic Study on the CO2-Lignite Gasification Reaction (CO2-갈탄 가스화 반응에 미치는 폐촉매의 영향 및 반응속도론 연구)

  • Seo, Seok-Jin;Lee, So-Jung;Sohn, Jung Min
    • Clean Technology
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    • v.20 no.1
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    • pp.72-79
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    • 2014
  • In this study, we investigated reaction rate constant and activation energy of $CO_2$ lignite gasification by using waste catalysts (I, II, III) and $K_2CO_3$. The gasification experiments were conducted with the lignite which was mixed physically with the catalysts of 1 wt%, 5 wt%, 10 wt% by thermogravimetry with TGA at $800^{\circ}C$, $850^{\circ}C$ and $900^{\circ}C$. The experimental data was analyzed with kinetic models (VRM, SCM and MVRM). MVRM was the most suitable among the three models. It was confirmed that gasification rate increased with increasing temperature and the activation energies of $CO_2$ gasification of lignite with mixed waste catalysts were lower than that of lignite alone at all temperatures. Especially, 10 wt% of waste catalyst III showed the lowest activation energy, 92.37 kJ/mol, among all lignite-char with catalysts.