• Journal of the Korea Concrete Institute
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• v.18 no.6 s.96
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• pp.785-791
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• 2006

The purpose of this study is to clarify the effect of the monomer ratio on properties of the polymer-modified mortars based on styrene and butyl acrylate latexes, and to obtain basic data necessary to develop appropriate latexes for cement modifiers. This paper deals with the effects of monomer ratio on the typical properties of the polymer-modified mortars with styrene and butyl acrylate latexes. The polymer-modified mortars using the styrene and butyl acrylate latexes polymerized with various monomer ratios are prepared with different polymer-cement ratios, and tested for the particle size of polymer latexes, air contents, water-cement ratios, flexural and compressive strengths, water absorption, and chloride-ion penetration. From the test results, the polymer-modified mortars using styrene and butyl acrylate latexes with the mix proportions of synthesis having monomer ratios of 50:50 to 60:40 for the appropriate mix proportions can be recommended for practical applications. Their basic properties are greatly affected by the polymer-cement ratio rather than the monomer ratio, and are improved over un-modified mortar.

• Journal of Adhesion and Interface
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• v.20 no.1
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• pp.15-22
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• 2019

In this study, polybutadiene based di-functional urethane acrylate oligomer (PB-UAO) were synthesized from polybutadiene diol and isophorone diisocyanate. And then, pressure sensitive adhesive films were prepared by mixing with synthesized oligomer, tri-functional acrylate monomer (Tris(2-acryloyloxyethyl) isocyanurate (TAOEIC) or Trimethylolpropane triacrylate (TMPTA) or Pentaerythritol triacrylate (PETA)), mono-functional acrylate monomer (Stearyl acrylate) and UV initiators. Effects of types and contents of trifunctional acrylate monomers on peel strength, tensile strength, elongation, thermal stability and water absorption property were studied. As the contents of tri-functional acrylate monomer increased, and as the molecular weight of tri-functional acrylate monomer decreased, peel strength, elongation and water absorption showed a tendency to decrease whereas tensile strength and thermal stability showed a tendency to increase.

• KIEE International Transactions on Electrophysics and Applications
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• v.11C no.3
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• pp.75-80
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• 2001

Holographic polymer dispersed liquid crystals (HPDLCs) have fabricated by irradiating an Ar-ion laser ( ${\lambda}$=514nm) at various intensity on LC/acrylate monomer mixtures which were sandwitched between two ITO coated glass plates. Monomer systems were composed of dipentaerythritol-hydroxy penta acrylate (DPHPA, f=5)/monofunctional acrylate monofunctional monomers. The LC used in this system was E7 (BL001, Merck). Gratings were fabricated by periodic interference of twobeams. Reflection efficiency-irradiation intensity-monomer type relationships were obtained from the UV-visible spectra of the HPDLC films. Peaks were found at a bit smaller wavelength than 514nm, due to the shrinkage of mixture volume upon polymerization. Real time measurements of diffraction efficiency have been obtained according to monomer types and LC contents.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.123-128
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• 2001

The Purpose of this study is to clarify the effect of the monomer ratio on properties of the polymer-modified mortars using methyl methacrylate-butyl acrylate latexes, and to obtain basic data necessary to develop appropriate latexes for cement modifiers. This paper deals with the effect of the monomer ratio on the typical properties of polymer-modified mortars with methyl methacrylate-butyl acrylate latexes. The polymer latex-modified mortars are prepared with 5, 10, IS and 20% of polymer cement ratio respectively, and properties of modified mortars such as water absorption, compressive and flexural strengths, chloride-ion penetration depth are tested. The test results indicate that the monomer ratio is very important factors to characterize the strength properties of polymer-modified mortars, but the water absorption and chloride-ion penetration depth are influenced by polymer-cement ratio rather than monomer ratios.

• Polymer(Korea)
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• v.33 no.4
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• pp.342-346
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• 2009

The effects of the monomer ratios on the typical properties of polymer modified mortars that contain styrene and butyl acrylate latexes was investigated. Basic data was also obtained that is necessary for the development of appropriate latexes for cement modifiers. Polymer modified mortars that contain styrene and butyl acrylate latexes polymerized with various monomer ratios were prepared for different polymer-cement ratios. They were then tested to obtain the particle size of the polymer latexes, air contents, water-cement ratios, flexural and compressive strengths, water absorption, and chloride-ion penetration. From the test results, the polymer modified mortars that have styrene and butyl acrylate latexes (with the mix proportions of synthesis having monomer ratios of between 40:60 to 60:40 for the appropriate mix proportions) could be recommended for practical applications. The basic properties of the polymer modified mortars were more affected by the polymer-cement ratio than by the monomer ratio, and were improved over unmodified mortar.

• Journal of Adhesion and Interface
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• v.17 no.2
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• pp.56-61
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• 2016

This study was to investigate the effect of main monomer, butyl acrylate instead of 2-ethylhexyl acrylate, of acrylic PSAs on adhesive properties. The copolymers of butyl acrylate, acrylic acid and 2-hydroxyethyl acrylate were synthesized and their adhesive properties were investigated after crosslinking with two different agents. Comparing to 2-hydroxyethyl acrylate-based one which has branch-like side groups, butyl acrylate-based PSA with linear side groups show poor adhesive properties. In case of crosslinking agent, epoxy-typed agent than isocyanate-typed one showed better properties than isocyanate-typed one because epoxy-typed agent has more crosslinking sites and produces more flexible bonds, ester and ether, than isocynate-typed one. Most adhesive properties of PSAs were increased with acid content.

• Elastomers and Composites
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• v.48 no.4
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• pp.249-255
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• 2013

Hydroxypropyl terminated PDMS was synthesized by the hydrosilylation reaction with allyl alcohol in the presence of Karstedt's catalyst. And them, an one-pot reaction with HDI isocyanurate trimer and hydroxyethyl methacrylate was conducted to give a silicone-modified urethane acrylate oligomer (PUA oligomer) having 9000 g/mol, weight average molecular weight. The synthesized PUA oligomer was characterized by using FT-IR and GPC. The UV-curable coatings were prepared by PUA oligomer blending with a reactive monomer (phenylthioethyl acrylate) under the different mole ratios. It was found that the refractive index of cured film increased when the reactive monomer was added but there was no relationship between the refractive index and amount of reactive monomer. Also, their transmittance for cured films was not change as increasing the content of reactive monomer.

• Applied Chemistry for Engineering
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• v.18 no.2
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• pp.121-125
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• 2007

Siloxane monomer and oligomer were introduced to n-butyl acrylate and methyl methacrylate copolymer for improvement of water resistance and tactile sensation of acryl-type emulsion. Terpolymerimerization of n-butylacrylate, methyl methacrylate and siloxane monomer or oligomer was carried out in aqueous solution. The glass transition temperature (Tg) of terpolymer decreased with increasing siloxane monomer, however, the Tg of terpolymer increased with increasing siloxane oligomer due to the crosslinking of acrylated end group. The adhesion property and surface energy of the obtained terpolymer decreased with introducing siloxane monomer or oligomer in terpolymer. Decrement of tack and surface energy means the enhancement of water resistance and tactile sensation of the emulsion.

• Journal of the Korean Applied Science and Technology
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• v.30 no.2
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• pp.297-304
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• 2013

Free-radical copolymerization of glycidyl methacrylate(GMA) and N-phthalimidoethyl acrylate(NPEA) were carried out at $60^{\circ}C$ in dimethylformamide(DMF) solution in the presence of benzoylperoxide(BPO) at low conversion. The polymers were characterized by IR and $^1H$-NMR. The compositions of the copolymer was analyzed by ultra violet(UV/Vis) spectrophotometry. The reactivity ratios of the monomer was determined by the application of Fineman-Ross(FR) and Kelen-T$\ddot{u}$d$\ddot{o}$s(KT) methods. The monomer reactivity ratios of the system and Alfrey-Price's resonance effect(Q) and polar effect(e) value for NIEA were determined as follow. The reactivity ratios of the monomer obtained from FR and KT are found to be $r_1$=0.87, $r_2$=0.98 and $r_1$=0.88, $r_2$=0.99 respectively. The Q and e values of poly(GMA-co-NPEM) calculated from $r_1$ and $r_2$ was Q= 1.31, e=0.75 respectively.

• Journal of Adhesion and Interface
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• v.20 no.4
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• pp.135-139
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• 2019

In this work, flame retardant acrylic emulsion pressure sensitive adhesives were newly polymerized combining phosphorous flame retardant monomer and acrylic monomer like butyl acrylate, 2-ethylhexyl acrylate, methyl methacrylate, acrylic acid, and 2-hydroxyethyl methacrylate. The process of polymerization showed 100% of conversion at solid content of 65%, and viscosity of acrylic emulsion was increased up to 5500 cps when phosphorous flame retardant monomer was added into acrylic emulsion. The structure of flame retardant acrylic emulsion was identified using FT-IR and thermal properties like glass transition temperature (Tg) were checked by differential scanning calorimeter (DSC). Acrylic emulsion without phosphorous flame retardant monomer had Tg of -44.1℃ and peel strength of 2,100gf/inch, however, flame retardant acrylic emulsion showed maximum Tg (-31.4℃) and peel strength of 200gf/inch when 15 part of phosphorous flame retardant monomer was added. Flammability test was also conducted to confirm the application of flame retardant acrylic emulsion as the flame retardant addtive.