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http://dx.doi.org/10.17702/jai.2019.20.1.15

Effects of Tri-functional Monomers on the Properties of UV-curable Pressure Sensitive Adhesives (PSAs)  

Won, Jong-Woo (BNTM Corporation)
Kim, Ju-Yeol (BNTM Corporation)
Jang, Ki-Deog (R&D Center, YONWOO Corporation)
Park, Myung-Chul (C&A Tech, Ltd.)
Chun, Jae Hwan (Korea Institute of Footwear and Leather Technology)
Kwon, Oh Hyeong (Department of Polymer Science and Engineering, Kumoh National Institute of Technology)
Hwang, Jin-Sang (BNTM Corporation)
Publication Information
Journal of Adhesion and Interface / v.20, no.1, 2019 , pp. 15-22 More about this Journal
Abstract
In this study, polybutadiene based di-functional urethane acrylate oligomer (PB-UAO) were synthesized from polybutadiene diol and isophorone diisocyanate. And then, pressure sensitive adhesive films were prepared by mixing with synthesized oligomer, tri-functional acrylate monomer (Tris(2-acryloyloxyethyl) isocyanurate (TAOEIC) or Trimethylolpropane triacrylate (TMPTA) or Pentaerythritol triacrylate (PETA)), mono-functional acrylate monomer (Stearyl acrylate) and UV initiators. Effects of types and contents of trifunctional acrylate monomers on peel strength, tensile strength, elongation, thermal stability and water absorption property were studied. As the contents of tri-functional acrylate monomer increased, and as the molecular weight of tri-functional acrylate monomer decreased, peel strength, elongation and water absorption showed a tendency to decrease whereas tensile strength and thermal stability showed a tendency to increase.
Keywords
PSA; Tri-functional acrylate; Peel Strength; Tensile Strength; Elongation; Water absorbption;
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  • Reference
1 I. T. Son and J. H. Lee, Journal of Adhesion and Interface, 16(3), 122 (2015)
2 B. K. Joo, E. H. Song, B. H. Kang and T. Y. Kim, Electronic Technology, 9, 10 (2014)
3 L. Hongbo, D. Jun, S. Wenfang, Polymer Degradation and Stability, 86, 217 (2004)   DOI
4 K. Igor, S. Kenneth, G. Robert, Journal of Applied Polymer Science, 99, 489 (2006)   DOI
5 J. S. Hwang, M. H. Kim, D. S. Seo, J. W. Won, D. K. Moon, Microelectronics Reliability, 49, 517 (2009)   DOI
6 E. Dzunuzovic, S. Tasic, B. Bozic, D. Babic and B. Dunjic, Progress in Organic Coatings, 52, 136 (2005).   DOI
7 M. Patel, J. Patel and K. Patel, Chemical Science Transactions, 1, 289 (2012)   DOI
8 M. J. Cho, H. J. Kang, and D. B. Kim, Journal of Adhesion and Interface, 18, 25 (2017)   DOI
9 B. K. Kim, K. H. Lee, and H. D. Kim, Journal of Applied Polymer Science, 60, 799 (1996).   DOI
10 F. J. Hua and C. P. Hu, Journal of Applied Polymer Science, 77, 1532 (2000)   DOI
11 B. J. Moon and S. H. Hwang, Polymer (Korea), 35, 183 (2011)   DOI
12 J. W. Yoo and D. S. Kim, Polymer (Korea), 23, 376 (1999)
13 T. Matynia, R. Kutyla, K. Bukat, and B. Pienkowska, Journal of Applied Polymer Science, 55, 1583 (1995)   DOI
14 M. Bajpai, V. Shukla, and A. Kumar, Progress in Organic Coatings, 44, 271 (2002).   DOI
15 T. Maruno, S. Ishibashi, and K. Nakamura, Journal of Polymer Science, Part A: Polymer Chemistry, 32, 3211 (1994)   DOI
16 T. R. Williams, Journal of Applied Polymer Science, 31, 1293. (1986)   DOI
17 M. J. Choi, B. Y. Jeong, J. M. Cheon, K. B. Park, and J. H. Chun, Journal of Adhesion and Interface, 18, 8 (2017)   DOI
18 J.H. Lee, S.D. Hong and Y.H. Kim, Polymer (Korea), 37, 2 (2013)
19 W. H. Shecut and H. H. Day, US Patent 3,965 (1845)
20 I. Benedek, Pressure-Sensitive Adhesives and Application, 2nd Ed., Marcel Dekker, Inc., New York, (2004)
21 C. Creton, Materials Science and Technology: A Comprehensive Treatment, VCH, Weinheim, 1997.
22 S. M. Taghizadeh, D. Ghasemi, Iran. Polym. J., 19, 343, (2011)
23 B. K. Kim, D. S. Lee, C. H. Do, and H. M. Jeong, Polyurethanes, 1, 329, (2006)
24 S. Akiyama, Y. Kobori, A Sugisaki, T. Koyama, I. Akiba, Polymer, 41, 4021, (2000)   DOI
25 K. M. Nam, et al., Journal of Adhesion and Interface, 18(4), 166 (2017)
26 C. Bluestein, Polymer-Plastics Technology and Engineering, 17, 83 (1981)   DOI
27 J. W. Won et al., Journal of Adhesion and Interface, 18, 127 (2017)
28 J. H. Sim, E. S. Seo, W. Y. Lee, and G. N. Kim, Journal of Adhesion and Interface, 18, 159 (2017)
29 J. W. Park, k. Y. Bae, P. S. Kim, D. H. Lim, H. J. Kim, J. K. Cho, B. J. Kim, and S. H. Lee, Journal of Adhesion and Interface, 11, 57 (2010)
30 S. S. Baek, S. J. Jang, S. H. Hwang, Elastomers and Composites, 49, 199 (2014)   DOI