• Title/Summary/Keyword: Acid dyeing

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A Study on the Tannin Weighting of Silk (견의 탄닌가공에 관한 연구)

  • Jeong, In-Mo;Lee, Yong-U;Lee, Gi-Won
    • Journal of Sericultural and Entomological Science
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    • v.28 no.1
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    • pp.72-78
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    • 1986
  • The studies were performed to investigate the optimum conditions for tannic processing of silk by use Chinese Gallotannin and synthesized tannic acid, which are aimed at weighting, dyeing and physical properties of tannin treated silk. 1. It was reasonable that the concentration of tannin solution is 30 grams per liter of Chinese Gallotannin, 15 grams per liter of tannic acid for the efficient weighting of processed silk. The temperature and time for tannin treatment was optimum at 80$^{\circ}C$, 60 minutes and the acidity of tannin solution at pH 2 to 3. 2. In dyeing the tannintreated silk by Acid dye Orange II, the temperature and time was reasonable at 60$^{\circ}C$, 90 minutes to control the desorption of tannin components weighted onto silk. 3. The colour differences ($\Delta$E) of dyed silk fabric by soaping could be remarkably narrowed by tannin treatment, resulting in improving the washing fastness of tannin treated silk by two grades more than that of untreated one. 4. The light fastness of tannin treated silk could be drastically improved by reducing the dye-loss of dyed silk fabric which was coused from the Ultra-violet ray irrdiation. 5. The rubbing fastness and water repellency of tannin treated silk was at the same level with that of untreated one. However, the Drape coefficient of tannin treated silk was decreased more than that of untreated one, which is closely related with fabric softness and dressing appearence.

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Dental Erosion in two Factories using Acids (일부 산(Acid)취급 근로자의 치아산식증)

  • Cheon, Yong-Hee;Kwon, Ho-Kwun;Moon, Young-Han;Roh, Jae-Hoon
    • Journal of Preventive Medicine and Public Health
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    • v.15 no.1
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    • pp.83-87
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    • 1982
  • Acid erosion of teeth was studied in two factories. The A was the textile factory possessing dyeing process using acids. The B was the metal product manufactoring factory possessing electroplating process. The control group was selected at the same factory not exposed to acids. The results were summarized as below. 1. The pH of saliva was the range of $6.6{\sim}6.8$ in both factories. 2. The prevalence rate of erosion of teeth was higher in case group at the B. It was statistically significant. 3. The rate of erosion of incisor were the range of $12%{\sim}16%$(case group), $7%{\sim}21%$(control group) at the A and $10%{\sim}20%$ (case group), $2%{\sim}15%$ (control group) at the B. 4. The rate of erosion of degree 3 which is necessary for conforming, owing to occupational induction, were 8.9% (incisor: A) and 6.8% (incisor: B).

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Syntheses of New Film-Forming Aromatic Poly(amide-imide)s Containing Isoindoloquinazolinedione Unit in the Backbone: Poly(biphenylphthalicdianhydride-oxydianiline-4,4-diamino-3-carbamoyl-benzanilide) (Poly(BPDA-ODA-DACB))

  • Kang, Seog-Joo;Hong, Sung-Il;Park, Chong-Rae;Oh, Tae-Jin
    • Fibers and Polymers
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    • v.2 no.2
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    • pp.92-97
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    • 2001
  • New film forming aromatic poly(amide-imide)s containing isoindoloquinazolinedione (IQ) unit in the backbone chain (polymer XIV) have been successfully synthesized by preparing prepolymers of poly(amic acid-carbonamide). followed by subsequent thermal cyclization of the prepolymers. 4,4-Diamino-3-carbamoylbenzanilide (DACB) V has been synthesized by reduction of 3-carbamoyl-4-amino-4-nitrobenzanilide IV. The prepolymers of poly(amic-acid-carbonamide) (polymers VII and VIII) which exhibit viscosities ranging from 1.4 to 1.7 dl/g have been prepared by a condensation polymerization of monomers such as BPDA, ODA, and DACB. Polymer XIV has been obtained by thermal cyclization of the polymers VII and VIII. During the thermal cyclization reaction, imide ring structure was first introduced and then transformed to the structure of IQ unit. The thermal degradation rate of the resultant polymers were influenced by the cleavage of amide bond but the final char yield was comparable to that of poly(BPDA-ODA).

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A Study on the Treatment of Wastewater from the Weight-Reduction Process of Polyester (폴리에스테르 감량가공(減量加工) 폐수(廢水)의 최적(最適) 처리방안(處理方案)에 관한 연구(硏究))

  • Chung, Yoon Jin;Yang, Tae Du;Kim, Woong Ha
    • Journal of Korean Society of Water and Wastewater
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    • v.7 no.1
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    • pp.20-28
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    • 1993
  • The Wastewater from the weight reduction process of polyester is more difficult to be treated biologically than the general wastewater from dyeing and finishing processes in textile industries. Above wastewater shows high pH, high organic strength and wide variation of organic loading. These characteristics are due to TPA and EG resulting from alkaline weight-reduction process and make trouble in the operation of activated sludge process. Therefore, the objective of this study is to develop the pretreatment method for the successful operation of treatment process. For the successful pretreatment process, the wastewater from weight-reduction process should be segregated from other wastewater stream and then acidified with concentrated sulfuric acid to precipitate out TPA from DST solution. At the optimum pH of 2. 2, the initial $COD_{cr}$ 60,000mg/l is reduced to 11,500mg/l and the removal efficiency of $COD_{cr}$ is 81.1%. The required amount of sulfuric acid for pretreatment is not greater than the amount for the the existing neutralization process. Moreover, the supernatant of pretreatment process can be reused in acidification of wastewater.

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Studies on the Dyeing of Hanji by Natural Dye-stuffs(I) -With a Focus on the Color Tone of Yellow Color Series- (천연염료를 이용한 한지염색에 관한 연구(I) -황색계열의 색상을 중심으로-)

  • Jeon, Cheol;Jin, Yeong-Mun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.3
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    • pp.48-56
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    • 2000
  • Yellow dye-stuffs in natural plant were extracted from a gardenia, saffron, safflower, amur tree and pagoda. And then they were used to color Korean handmade paper(Hanji) on using a mordant. The results of the degree of discoloration are as follows. 1. As for a gardenia(Gardenia jasminodes Ellis for. grandiflora Makino), the effects of coloring were outstanding in the acid area. But for the preservation, it might be desirable that used a lye in a dye-stuff obtained at $40{\pm}5^{\circ}C$. 2. As for saffron(Curcuma longa L.), when used alum as a mordant, it was colored to a medium yellow color with green color. But easily discolorated and was not desirable. And, it didn't fit in a dye-stuff of Hanji. 3. For safflower(Carthamus tinctorius L.), when pH was in the low acid it was colored to the cleaner yellow color. It was the distinction of discoloration that the degree of brightness's increase was low. 4. For amur cork-tree(Phellodendron amurense Rupr.), the effects of yellow coloring were great in the areas of acidity and alkali. But, when used alum, the degree of the discoloration was high and was not effective. 5. For pagoda tree(Styphnolobium Japonica L.), using a calcium hydroxide as a mordant, enabled the more than average yellow to be gained. The degree of discoloration was good.

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Iron-loaded Natural Clay as Heterogeneous Catalyst for Fenton-like Discoloration of Dyeing Wastewater

  • Xu, Huan-Yan;Ha, Xiu-Lan;Wu, Ze;Shan, Lian-Wei;Zhang, Wei-Dong
    • Bulletin of the Korean Chemical Society
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    • v.30 no.10
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    • pp.2249-2252
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    • 2009
  • The clay-based Fe-bearing catalyst was successfully prepared through ion-exchange reaction and applied as heterogeneous catalyst for discoloration of acid fuchsine (AF) in an aqueous solution by Fenton-like reaction. Experimental results demonstrated that the AF discoloration ratios increased by increasing Fe-loaded clay dosage and initial $H_2O_2$ concentration, and by decreasing the pH, respectively. The lower the initial AF concentration, the shorter the reaction time needed to achieve complete discoloration of AF. Comparative studies indicated that AF discoloration ratios were much higher in presence of Fe-loaded clay and $H_2O_2$ than those in presence of $H_2O_2$, raw natural clay or Fe-loaded clay only and raw natural clay and $H_2O_2$ jointly. After AF discoloration, there existed no new phases in the clay samples detected by XRD and no change in the clay crystal morphology observed by SEM. A mechanism proposed suggested adsorption and Fenton-like reaction were responsible for discoloration of AF.

The Effect of Rosehip Extracts Addition on Permanent Wave and Hair Dye during Repetition Procedure (퍼머넌트 웨이브와 산성 염색 반복시술시 로즈힙 추출물 첨가의 효능)

  • Kim, Miyeon;Ko, Kyoungsook
    • Journal of Fashion Business
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    • v.17 no.2
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    • pp.151-163
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    • 2013
  • In this research, with a goal of lessening the damage to hair by adding rose hip extract to permanent wave 1 solution and performing permanent wave procedure prior to acid dyeing and maximizing the effect of the procedure, rose hip extract 15%, 20% was added to each thioglycolate 1 solution and cysteine 1 solution and the procedure was performed. As a result, when performing the procedure by adding rose hip extract to permanent wave 1 solution thioglycolate and cysteine permanent wave 1 solution, the effect of wave effectiveness is increased and the damage to hair was confirmed to be low. Depending on the rose hip additive status in thioglycolate, the treatment effect of hair was shown to be beneficial. However, the limit of this research is that the thickness of hair strands for each person differs as well as the location of the hair contributing to the difference and therefore exact judgement regarding the shape of waves as well as the level of damage cannot be fully measured. In the following clinical tests, we will test the procedure on variety of hair types.

Content Analysis of Chungtaejeon Tea and Green Tea Produced in Jangheung District (장흥지역 청태전과 녹차의 성분분석)

  • Park, Yong-Seo;Lee, Mi-Kyung;Ryu, Hyeun-Hee;Heo, Buk-Gu
    • The Korean Journal of Community Living Science
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    • v.19 no.1
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    • pp.55-61
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    • 2008
  • This study was conducted to compare the nutrient and chemical contents of traditional Chungtaejeon tea with that of green tea which was harvested in Jangheung, Jeonnam district. Vitamin C, amino acids and total nitrogen contents of Chungtaejeon tea were lower than that of green tea by 0.30, 2.30 and 4.20g/100g, respectively. The tannin, caffeine, reducing sugar and chlorophyll contents in Chungtaejeon tea were the same as those in green tea. Comparing catechin contents, catechin (C), epicatechin (EC), and epigallocatechin (EGC) in Chungtaejeon tea were lower than those of green tea. However, gallocatechin (GC), epicatechin gallate (ECG), epigallocatechin gallate (EGCG) and catechin gallate (CG) showed no significant difference between Chungtaejeon tea and green tea. The flavonoid contents of Chungtaejeon tea and green tea showed higher quercetin and kaempferol contents in green tea, and higher myricetin content in Chungtaejeon tea. The measured amino acid contents for threonine and aspartic acid were lower, and for glutamic acid were higher in Chungtaejeon tea compared with those in green tea. However, free amino acid content in Chungtaejeon tea and green tea showed no significant difference. Potassium and magnesium contents in Chungtaejeon tea were lower compared to green tea but no significant difference was found for iron, manganese or calcium contents when comparing the two teas.

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Functional Dyeing and Finishing using Catechins Extracted from Green Tea(I) - Extraction Optimization, Stability, and Content Analysis of Catechins - (녹차추출 카테킨을 활용한 기능성 염색가공(I) - 카테킨의 추출 최적화와 안정성 및 함량 분석 -)

  • Kim, Tae-Kyeong;Son, Song-I;Jung, Jong-Suc;Jang, Kyung-Jin;Kwon, Oh-Kyung;Choi, Young-Hee;Jeong, Young-Han
    • Textile Coloration and Finishing
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    • v.20 no.2
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    • pp.75-82
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    • 2008
  • The optimum extraction conditions of green tea used for a bath were investigated for application to textiles. The stability of the extracts and content of active ingredients were analyzed as well. The extraction was more effective in water and methanol than in ethanol. The optimum extraction temperature was determined as $80^{\circ}C$ in water and $60^{\circ}C$ in methanol. The solid extracts were obtained about 7% in water and 9% in methanol on the weight of dry green tea. The extracts were more stable in acid and neutral conditions than in alkaline region. From the analysis of contents of active ingredients, about 20% of effective catechins was appeared to be contained in the extract solid, which was thought to be available for application to textiles.

Application of Natural Dyes for Developing Colored Wood Furniture (III) - Prevention of Discoloration of Chestnut Wood by Natural Dyes - (색채 목가구 개발을 위한 천연염료의 이용에 관한 연구(제3보) - 천연염색 밤나무 목재의 변색 방지 -)

  • Moon, Sun-Ok;Kim, Chul-Hwan;Kim, Gyeong-Yun;Jung, Ho-Gyeong;Shin, Tae-Gi;Kim, Jong-Gab;Park, Chong-Yawl
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.3
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    • pp.79-87
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    • 2007
  • This study investigated the effects of lacquer-finishing to prevent discoloration of coloring chestnut wood coated with natural dyes from deteriorating factors such as lights (indoor, 500 lux and outdoor, 50,000~70,000 lux), acid, alkali, and heat through measurement of color difference. Lacquer-finishing coating contributed to protection of intrinsic color of the natural dyeing woods in spite of severe treatment. In particular, dyeing liquor with alkali pH played a great role in prevention of light discoloration.