• Title/Summary/Keyword: Acid and base

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EFFECTS OF NICARBAZIN AND HOT TEMPERATURE ON EVAPORATIVE WATER LOSS, ACID-BASE BALANCE, BODY TEMPERATURE AND CARBON DIOXIDE EXHALATION IN ADULT ROOSTERS

  • Lee, B.D.;Lee, S.K.;Hyun, W.J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.7 no.1
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    • pp.97-101
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    • 1994
  • Two experiments were conducted to study the effect of ambient temperature and nicarbazin on SCWL adult roosters. In Experiment 1, the effects of nicarbazin supplementation (125 ppm) on the water metabolism, blood acid-base balance; and rectal temperature of 16 birds in normal ($21^{\circ}C$) and hot ($35-36^{\circ}C$) temperature were investigated. In Experiment 2, the evaporative water loss and $CO_2$ exhalation from 8 birds were measured individually with an open-circuit gravimetric respiration apparatus in normal ($21^{\circ}C$) and hot ($33.5-34^{\circ}C$) temperature. The amount of water intake and evaporative water loss increased in birds under heat stress (HS). Nicarbazin exacerbated these effect in hot temperature. Also, nicarbazin decreased the blood $pCO_2$ and increased pH of HS birds. The rectal temperature of birds increased in hot temperature, and nicarbazin worsened this effect. The evaporative water loss, measured directly with respiration apparatus (Experiment 2), was increased in hot temperature. HS decreased the amount of $CO_2$ exhalation. Nicarbazin did not exert ant effect on either of these measurements, probably due to the limited duration (2 h) of the trial. The decrease in $CO_2$ exhalation by HS birds could be explained by reduced metabolic rate, which helps homeothermy of birds in hot temperature.

Properties of Carbon Black/SBR Rubber Composites Filled by Surface Modified Carbon Blacks

  • Dai, Shuang-Ye;Ao, Ge-You;Kim, Myung-Soo
    • Carbon letters
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    • v.8 no.2
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    • pp.115-119
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    • 2007
  • Properties of carbon blacks and carbon black/SBR rubber composites filled by surface modified carbon blacks were examined. Although the specific surface area of carbon blacks increased after the surface modifications with heat, acid, and base, there were no obvious changes in resistivity. The composites filled by heat treated carbon blacks showed a higher tensile strength and elongation than those filled by raw blacks. The acid and base treated carbon blacks filled composites also showed higher tensile strength but similar elongation values with those filled by raw blacks. With increasing loading ratio, both tensile strength and elongation increased, and appeared a maximum value at 30-40 phr. Modulus at 300% strain remained increasing with further loading of carbon blacks. At the same loading, the heat treated black filled composites showed similar modulus values with composites filled by raw blacks but for base and acid treated black filled composites much higher values were obtained. After the surface modification, the functional groups which played an important role in reinforcement action were changed.

Thermo- and Acid/base-induced Spectral Switching of a Poly(N-isopropylacrylamide) Copolymer Containing Benzopyran-based D-π-A type Dye Units

  • Lee, Eun-Mi;Gwon, Seon-Yeong;Ji, Byung-Chul;Kim, Sung-Hoon
    • Textile Coloration and Finishing
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    • v.22 no.3
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    • pp.181-186
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    • 2010
  • A thermoresponsive poly(NIPAM-co-dye) labeled with benzopyran-based D-$\pi$-A type dye was prepared by typical radical copolymerization. It can be also constructed a acid/base-induced molecular switch by modulation of intramolecular charge transfer with protonation/deprotonation. The lower critical solution temperature behavior was investigated by means of UV-vis spectroscopy which allows the measurement of the phase transition from $25^{\circ}C$ to $45^{\circ}C$ in aqueous DMSO solution. The morphology of the internal microstructure of the poly(NIPAM-co-dye) hydrogel was observed by scanning electron microscopy. The reversible switch could be obtained by thermal and acid/base stimuli.

Lewis Acid-Catalyzed Reactions of Anthrone: Preference for Cycloaddition Reaction over Conjugate Addition Depending on the Functionality of α,β-Unsaturated Carbonyl Compounds

  • Baik, Woon-Phil;Yoon, Cheol-Hoon;Koo, Sang-Ho;Kim, Ha-Kwon;Kim, Ji-Han;Kim, Jeong-Ryul;Hong, Soo-Dong
    • Bulletin of the Korean Chemical Society
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    • v.25 no.4
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    • pp.491-500
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    • 2004
  • The Lewis acid-catalyzed reactions of anthrone with a variety of ethylenic substrates under various conditions have been studied. It has been observed that depending on kinds of ethylenic substrates and catalysts, products were varied. In particular, the $ZnCl_2$-catalyzed reaction of anthrone with ${\alpha},{\beta}$ -unsaturated ester gave bridged compounds 3 (Diels-Alder adduct type) and mono-Michael adduct 4 exclusively, while the base-catalyzed reaction gave 10,10-bis-Michael adduct as a major product independent of the amount of ethylenic substrate and base. Bridged compounds 3 were easily converted to the corresponding mono-Michael adduct 4 by a catalytic amount of base. Further Michael reaction of mono-Michael adducts with different ethylenic substrates in the presence of a catalytic amount of alkoxide gave unsymmetrical 10,10-bis Michael adducts in good or moderate yields.

Performance of Graphite Electrode Modified with Acid Treatment for Lithium Ion Secondary Battery (산처리에 의해 개질된 리튬이온 이차전지용 흑연 전극의 특성)

  • Kim, Myung-Soo;Moon, Seung-Hwan;Kim, Mun-Geol;Kim, Taek-Rae;Hahm, Hyun-Sik;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.2
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    • pp.142-150
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    • 2005
  • The natural graphite particles A and heat-treated graphite particles B at $1800\;^{\circ}C$ after pitch-coating were used as the anode base materials for lithium ion secondary battery. In order to improve the performance of anode materials, the base anode materials were treated with various acids. With the acid treatments of 62% $HNO_3$ and 95% $H_2SO_4$ aqueous solution, the specific surface area and electrical conductivity of base anode materials were increased, and the initial charge-discharge capacity and cycle performance were improved due to the elimination of structural defects.

Production Biodiesel via In-situ Transesterification from Chlorella sp. using Microwave with Base Catalyst

  • Kalsum, Ummu;Kusuma, Heri Septya;Roesyadi, Achmad;Mahfud, Mahfud
    • Korean Chemical Engineering Research
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    • v.56 no.5
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    • pp.773-778
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    • 2018
  • In-situ transesterification of microalgae lipids using microwave irradiation has potential to simplify and accelerate biodiesel production, as it minimizes production cost and reaction time by direct transesterification of microalgae into biodiesel with microwave as a heating source. This study was conducted to research the effect of microwave irradiation with in-situ transesterification of microalgae under base catalyst condition. The process variables (reaction time, solvent ratio, microwave power) were studied using 2% of catalyst concentration. The maximum yield of FAME was obtained at about 32.18% at the reaction time of 30 min with biomass-methanol ratio 1:12 (w/v) and microwave power of 450 W. The GC MS analysis obtained that the main component of FAME from microalgal oils (or lipids) was palmitic acid, stearic acid and oleic acid. The results show that microwaves can be used as a heating source to synthesize biodiesel from microalgae in terms of major components resulting.

Studies on the Purification and Partial Characterization of Cysteinesulfinic Acid Decarboxylase from Porcine Liver

  • Lee, Hong-Mie;Jones, Evan E.
    • BMB Reports
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    • v.29 no.4
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    • pp.335-342
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    • 1996
  • Porcine liver cysteinesulfinic acid decarboxylase was purified approximately 460-fold by means of ammonium sulfate fractionation and sequential column chromatographic separation with Sephadex G-100, DEAE-cellulose and hydroxylapatite. The enzyme has a flat pH profile with maximum activity occurring between pH 6.0 and 7.6. Pyridoxal 5'-phosphate must be present in all buffers used for purification procedures in order to stabilize the enzyme. Addition of sulfhydryl reagents such as 2-mercaptoethanol are also necessary to maintain maximum enzyme activity throughout purification. The absorption spectrum shows that cysteinesulfinic acid decarboxylase is a pyridoxal 5' -phosphate-containing protein. The major absorption is at 280 nm with two smaller absorption regions, one at 425 nm which is ascribed to a Schiffs base between pyridoxal phosphate and protein, and another at 325 nm which is thought to be due to the interaction of 2-mercaptoethanol with the Schiffs base. A number of divalent cations tested did not affect enzyme activity with the exception of mercury, copper, and zinc which are inhibitory. The partially purified enzyme has an apparent $K_m$ of 0.94 mM for cysteinesulfinate. Cysteic acid is a competitive inhibitor of the enzyme with a $K_i$ of 1.32 mM. The molecular weight of the enzyme was estimated to be about 79,600 by using Sephadex G-200 column chromatography.

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A study of corrosion of welded bridge steel SWS400 in the acid-rain environment (산성비 분위기에서 교량용 강재 SWS400의 용접부 부식에 관한 연구)

  • 정원석;김정구;이병훈
    • Journal of Welding and Joining
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    • v.15 no.5
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    • pp.124-133
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    • 1997
  • Corrosion behavior of welded SWS400 steel used for bridges was studied in a range of the acid-rain environment using immersion, potentiodynamic polartization, polarization resistance, and galvanic corrosion tests. The SWS400 steel exhibited active corrosion behavior in the range of acid-rain environment, i.e. no passivation. As the results of immersion corrosion test, Tafel extrapolation method, and polarization resistance measurement, the average corrosion rats of the steels were 0.31-0.72 mm/year in the pH of 4-5, and 0.17 mm/yera in the pH 6, respectively. The steel showed a resistance to corrosion in the pH 6. The observed active behavior of SWS400 steel in chloride-containing environment indicated that the chloride ions exerts a detrimental influence on the formation of passive films. Galvanic corrosion was observed between the weld and the base metals because the weld is anodic to the base metal.

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Quality Characteristics of Yukwa base and Popped rice for Salyeotgangjung popped with salt during storage (소금으로 팽화시킨 유과바탕 및 쌀엿강정용 팽화쌀의 저장 중 품질 변화)

  • Lim, Kyung-Ryo;Lee, Kyung-Hee;Kwak, Eun-Jung;Lee, Young-Soon
    • Korean journal of food and cookery science
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    • v.20 no.5
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    • pp.462-467
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    • 2004
  • This study was carried out to improve the qualities and extend the shelf life of Yukwa and Salyeotgangjung, traditional Korean cookies, using fine hot salt instead of oil as the popping medium. The Yukwa and Salyeotgangjung that had been popped using fine salt were stored at 25\ulcornerfor one or two months, and then compared their sensory evaluation, lipid contents and acid and peroxide values with those popped in oil. In the sensory test, the Yukwa base and popped rice expanded in the salts and stored for one month were preferred to those expanded in oil with regard to flavor and overall acceptability. With respect to the whiteness, off-flavor, and crispness, these properties those expanded in salt had stronger whiteness and crispness but a weaker off-flavor compared to those expanded in oil. The lipid contents of the Yukwa base and popped rice expanded in oil were 37.73 and 49.65%, respectively, which were significantly higher than in those expanded in salts (0.10 and 0.53%, respectively). The acid and peroxide values were larger in those expanded oil than in salts after 8 weeks storage. In view of the above results, the conclusion was reached that the Yukwa base and popped rice expanded in salts were less likely to provide a calorie intake and to become rancid over a long storage time.

Properties of Mononuclear and Binuclear Cu(II) Schiff Base Complexes and Oxidation of Ascorbic Acid (단핵 및 이핵성 시프염기리간드 Cu(II) 착물의 특성과 Ascorbic Acid에 대한 산화반응)

  • Kim, Sun Deuk;Lee, Young Seuk;Park, Jung Eun
    • Analytical Science and Technology
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    • v.13 no.5
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    • pp.558-564
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    • 2000
  • Mononuclear schiff base ligand N,N'-bissalicylidene-1,2-phenylenediamine(BSPD) and binuclear schiff base ligands N,N',N',N'''-tetrasalicylidene-3,3',4,4'-tetraaminodiphenyl-methane (TSTM), N,N',N'',N'''-tetrasalicylidene-3,3'-diaminobenzidine (TSDB) have been synthesized. Proton dissociation constants of the ligands were determined by potentiometric method. The synthesized ligands and complexes formed with Cu(II) ion. These complexes were investigated by cyclic voltammetry and differential pulse voltammetry. The results revealed two step diffusion controlled redox process. The mononuclear complex Cu(II)-BSPD and binuclear complexes $Cu(II)_2$-TSDB and $Cu(II)_2$-TSTM were used in the oxidation reaction of ascorbic acid. The reaction rates were in the order of $Cu(II)_2$-TSTM>$Cu(II)_2$-TSDB>Cu(II)-BSPD, indicating that the binuclear $Cu(II)_2$-TSTM complex had the fastest values.

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