• Title/Summary/Keyword: Accelerated corrosion test

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Stir-Accelerated Corrosion Test of High Chromium Cast Iron for Application in Slurry Pumps (슬러리 펌프용 고크롬 주철의 교반 가속 부식법)

  • Lee, Jun-Seob;Lee, Jun-Hyeong;Lee, Ye-Jin;Oh, Jun-Seok;Kim, Jung-Gu;Lee, Je-hyun
    • Corrosion Science and Technology
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    • v.21 no.5
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    • pp.418-421
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    • 2022
  • Stir-accelerated corrosion test of a high chromium cast iron was attempted in 0.1 mol dm-3 H2SO4 + 0.05 mol dm-3 HCl + 10 wt% SiC solution for 48 h at room temperature or at 45 ℃. The high chromium cast iron was composed of 2.8 wt% C and 27 wt% Cr and balanced with Fe. The high chromium cast iron was positioned into a 500 mL beaker with stirring of the solution at 1050 rpm using a magnetic hot plate. The corrosion rate was increased by agitating the solution. In addition, the corroded depth of the high chromium cast iron surface was increased by agitating the solution. The surface morphology of the high chromium cast iron after the stir-accelerated corrosion test revealed that a dendritic austenite phase partially remained in the corroded region after agitating the solution, indicating that solution movement during agitating could accelerate the corrosion rate of the high chromium cast iron.

Local Corrosion and Fatigue Damages of Steel Plates at the Boundary with Concrete (콘크리트에 접해있는 강재의 국부부식과 피로손상)

  • Kim, In Tae;Kainmua, Shigenobu;Cheung, Jin Hwan
    • Journal of Korean Society of Steel Construction
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    • v.20 no.2
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    • pp.313-321
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    • 2008
  • Recently in Japan, fracturing was observed on the diagonal member of a through truss bridge at the boundary region with the concrete slab. Local corrosion damage where the diagonal member was enclosed in the concrete slab is an important factor in the fracture. In this study, accelerated exposure tests were carried out on concrete-steel model specimens simulating steel members at the boundary with concrete. Fatigue tests were then performed on the corroded model specimens. Accelerated exposure tests of the S6-cycle, which is carried out on the model specimens for 150, 300, 450 and 600 da ys. Their surface geometry was then measured. From the accelerated exposure test results, change in maximum and mean corrosion depths was determined according to the testing periods. The effect of local corrosion on fatigue strength was also presented based on the fatigue test results.

A Study on Corrosion CoCrMo Magnetic Thin Films (CoCrMo 자성박막의 부식에 관한 연구)

  • 남인탁;홍양기
    • Journal of the Korean Magnetics Society
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    • v.3 no.3
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    • pp.221-228
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    • 1993
  • The general requirements of recording media include recording performance, environmental stability, runnability on the drive or deck, and manufacturability. CoCrMo thin films were prepared using RF sputtering system for a study on chemical stability. Surface degradation of the CoCrMo thin film was studied by SEM, XPS and AES. Surface degradation was found to be dependent of sputtering condition and Mo content. Addition of Mo to CoCr thin film improved dramatically its surface degradation resistance in dilute sulfuric acid, as indicated by active-passive transition appeared in electrochemical polarization curve. Futhermore, the passive current density was decreased with increasing Mo content. The reduction in a number density of corrosion sites by Mo addition vms observed, after accelerated corrosion test. AES survey indicated that corrosion occured on the site with Cr depletion and highly concentrated chloride ions.

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Failure Analysis on Scale Formation of Thermostat Housing and Development of Accelerated Test Methodology (써모스타트 하우징의 침전물 생성에 관한 고장분석 및 가속시험법 개발)

  • Cho, In-Hee;Hyung, Sin-Jong;Choi, Kil-Yeong;Weon, Jong-Il
    • Applied Chemistry for Engineering
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    • v.20 no.2
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    • pp.177-185
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    • 2009
  • The failure analysis of scales deposited on automotive thermostat housing has been carried out. Observations using energy dispersive spectroscopy and electron probe micro analyzer indicate that the main components of scales are some of additives of coolant used. For a detailed investigation of organic matters pyrolysis-GC/MS is employed. The result shows that the main organic component is benzoic acid and furthermore, a small amount of acetophenone, benzene and phenyl group is detected. Based on the results of failure analysis performed, the scales on automotive thermostat housing appear due to the deposition of coolant components, followed by crevice corrosion, into gap between housing and rubber horse. New accelerated test methodology, which could mimic the scale formation and the crevice corrosion on thermostat housing, is developed considering the above results. In order to reproduce the real operating conditions, the accelerating factors, i.e. temperature and humidity, are changed and programmed. The reproducibility of the accelerated test proposed is confirmed after analyzing the scales obtained from the accelerated test.

Electro Chemical Protection Property for Reinforced Geo-Polymer Specimen Under Ocean Environment and Accelerated Test (철근보강 지오폴리머 콘크리트 시험체에 전기화학적 방식기법 적용과 방식성능 분석)

  • Park, Dong-Cheon;Cho, Gyu-hwan
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.178-179
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    • 2014
  • Corrosion is very serious problem in RC structure under ocean environment. There is no enough experiment information using the reinforced geo polymer concrete applied by electo chemical protection system. Three condition, such as tidal zone, submerged zone and crack were simulated to geo polymer specimen. Corrosion rate and natural electrode potential were measured through accelerated test. Anti corrosion property of geo polymer was better than OPC regardless of specimen condition and applied time.

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Evaluation on the Properties of Modified-sulfur Concrete as a Basic Study for Development of Anti-corrosive Concrete (내부식성 콘크리트 개발을 위한 기초연구로서 개질유황 혼합 콘크리트의 물성 평가)

  • Park, Sang-Soon;Na, Ok-Jung
    • Corrosion Science and Technology
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    • v.15 no.1
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    • pp.28-37
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    • 2016
  • Due to the increased construction of offshore concrete structures and the use of de-icing salts for the purpose of snow removal, the needs for the development of anti-corrosive concrete are increasing. To solve these problems, an evaluation of the mechanical and durability properties for concrete were conducted by mixing modified-sulfur as 0 %, 5 %, 10 %, 15 % cement weight ratio. Both strengths and the properties affecting durability such as water absorption coefficient, chloride ion permeability, accelerated carbonation resistance, rapid freezing and thawing, and chemical resistance were evaluated. All evaluations performed were according to the test specifications associated KS. The results indicate that mixing of modified-sulfur lowed chloride ion permeability and improved chemical resistance.

The Effect of Annealing on Corrosion Behavior of CoCrTa/CrNi Magnetic Recording Media (CoCrTa/CrNi 자기기록매체의 열처리에 따른 부식거동 변화)

  • 우준형;남인탁
    • Journal of the Korean Magnetics Society
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    • v.9 no.4
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    • pp.210-216
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    • 1999
  • The objective of this paper is to investigate corrosion behaviors of CoCrTa/CrNi thin film and post heat-treatment effect. An electron beam evaporator was used for films deposition. After evaporation, post heat-treatment was carried out under $5.0{\times}10^3$ Torr vacuum condition. Annealing temperature and time were 400 $^{\circ}C$ and 30 min, respectively. To understand the effect of annealing on corrosion behavior of CoCrTa/CrNi, potentiodynamic polarization technique and accelerated corrosion chamber test were undertaken. Corrosion potential is higher for the annealed samples (CoCrTa 400$\AA$/CrNi 1000$\AA$) than for as-deposited one. This is attributed to an enrichment of Cr in the surface layer of the thinfilm resulting in a more corrosion resistant material.

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Study on Corrosion of Automotive Coil Spring Steel by Electrochemical Impedance Spectroscopy (전기화학 임피던스 분석을 통한 자동차용 코일스프링 강의 부식 평가)

  • Lee, Kyu Hyuk;Park, Jung-Hyun;Ahn, Seung Ho;Seo, Ji Won;Jang, HeeJin
    • Corrosion Science and Technology
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    • v.16 no.6
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    • pp.298-304
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    • 2017
  • Coil spring steels from the automobile suspension part after field exposure for 10 years and those after anti-corrosion validation test in proving ground of 5,000 ~ 10,000 km were examined for corrosion damages. Partial loss of paint, accumulation of corrosion product, and cracking of paint and superficial material were observed. The surface and subsurface region of spring steels had compressive residual stress and high hardness by shot peening. The surface hardness values of the specimens were 620 ~ 670 Hv. They were 60 ~ 80 Hv higher than those of the samples taken from the middle part of the spring. The maximum compressive stress was -916 ~ -1208 MPa measured at depth of about $100{\mu}m$. Electrochemical impedance spectroscopy showed that the resistances of charge transfer and the paint layer of the spring steels ranged from several tens to millions ${\Omega}{\cdot}cm^2$. The resistance of the field samples was much higher than that of the proving ground samples used in this study, implying that the proving ground test condition would be more corrosive than the field environment.

A Study on the Stress Corrosion Cracking Evaluation for Weld Joint of TMCP steel by SP-SSRT Method (SP-SSRT법에 의한 TMCP강 용접부의 응력부식균열 평가에 관한 연구)

  • 유효선;정희돈;정세희
    • Journal of Welding and Joining
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    • v.15 no.1
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    • pp.46-54
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    • 1997
  • The object of this paper is to evaluate SCC(stress corrosion cracking) susceptibility for parent metal and bond line region of weld joints which have the various weld heat input condtions in TMCP(thermo-mechanical control process) steel by SP-SSRT(small punch-slow strain rate test) method. And the SCC test results of TMCP steel are compared with those of the conventional HT50 steel which has te almost same tensile strength level like TMCP steel. The loading rate used was $3\times10^{-4}$mm/min and the corrosive environment was synthetic sea water. According to the test results, in the case of parent metal, TMCP steel showed higher SCC susceptibility than HT50 steel because of the high plastic strain level of ferrite microstructure obtained by accelerated cooling. And in the case of bond line, the both TMCP steel and HT50 steel showed low load-displacement behaviors and higher SCC susceptibility above 0.6. These results may be caused by theembrittled martensite structure on HT50 steel and by the coarsened grain and the proeutectoid ferrite structure obtained by the impart of accelerated cooling effect on TMCP steel.

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A Basic Study on Accelerated Life Test Method and Device of DSA (Dimensionally Stable Anode) Electrode (촉매성 산화물 전극 (DSA, Dimensionally Stable Anode)의 가속수명 테스트 방법과 장치에 관한 기초 연구)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.27 no.6
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    • pp.467-475
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    • 2018
  • The lifetime of the electrode is one of the most important factors on the stability of the electrode. Since the lifetime of the DSA (Dimensionally stable anode) electrode is long, an accelerated lifetime test is required to reduce the test time. Beacuse there is no basis or standard method for accelerated lifetime testing, many researchers use different methods. Therefore, there is a need for basis and methods for accelerated lifetime testing that other researchers can follow. We designed a reactor system for accelerated lifetime testing and planned specific methods. Reactor system was circulating batch reactor. Reactor volume and cooling water tank were 12.5 L and 100 L, respectively. Electrode size was $2cm{\times}3cm$ (real electrolysis area, $5cm^2$). In order to maintain the harsh conditions, accelerated lifetime test was carried out in a high current density ($0.6A/cm^2$) and low electrolyte concentration (NaCl, 0.068 mol/L). Maintaining a constant temperature was an important operation parameter for exact accelerated lifetime test. As the accelerated lifetime test progressed, the active component of electrode surface was consumed and desorption occurred. At the point of 5 V rise, corrosion of the surface of the base material(titanium) also started.