• Transactions on Electrical and Electronic Materials
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• 제11권5호
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• pp.216-221
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• 2010

The microstructure, electrical properties, and DC-accelerated aging behavior of the Zn-Pr-Co-Cr-Y-Er (ZPCC-YE) varistors were investigated for different amounts of erbium oxide ($Er_2O_3$). The microstructure consisted of zinc oxide grain and an intergranular layer ($Pr_6O_{11}$, $Y_2O_3$, and $Er_2O_3$-rich phase) as a secondary phase. The increase of $Er_2O_3$ amount decreased the average grain size and increased the sintered density. As the $Er_2O_3$ amount increased, the breakdown field increased from 5094 V/cm to 6966 V/cm and the nonlinear coefficient increased from 27.8 to 45.1. The ZPCC-YE varistors added with 0.5 to 1.0 mol% $Er_2O_3$ are appropriate for high voltage, with high nonlinearity and stability against DC-accelerated aging stress.

• Transactions on Electrical and Electronic Materials
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• 제10권4호
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• pp.125-130
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• 2009

The clamping voltage characteristics and accelerated aging behavior of CoCrTb-doped Zn/Pr-based varistors were investigated for different sintering temperatures. The best clamping voltage characteristics were obtained for the varistors sintered at $1330^{\circ}C$, with a clamping voltage ratio (K) of 1.63 at a surge current of 5 A and 1.75 at a surge current of 10 A. The varistors sintered at $1330^{\circ}C$ exhibited the highest stability, with -0.1% in $%{\Delta}E_{1\;mA}$, -0.2% in $%{\Delta}{\alpha}$, and +15.5% in $%{\Delta}J_L$ for E-J characteristics under a stress state of 0.90 $E_{1\;mA/120^{\circ}C$ /24 h. Furthermore, it exhibited $%{\Delta}{\varepsilon}_{APP}$' of -0.7% and $%{\Delta}tan{\delta}$ of +5.7% for dielectric characteristics under the same stress state.

• 한국전기전자재료학회논문지
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• 제15권3호
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• pp.244-252
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• 2002

The electrical and dielectric behavior fort DC accelerated aging stress of P $r_{6}$ $O_{11}$-based Zno varistors cnsisting of ZnO-P $r_{6}$ $O_{11}$-CoO-C $r_2$ $O_3$-E $r_2$ $O_3$ were investigated with sintering temperature in the range of 1325~1345$^{\circ}C$. The varistor ceramics with increasing sintering temperature were more densified. A more densified varistors leaded to high stability for DC accelerated aging stress. Furthermore, the stability for DC accelerated aging stress was increased with the leakage current and dtan $\delta$/dV decreasing in order of 1325longrightarrow1335longrightarrow1345longrightarrow134$0^{\circ}C$ in sintering temperature. It was found that the stability for DC stress is affected more greatly by the leakage current and dtan $\delta$/dV than the densification. It is considered that the stability of varistors for DC stress can be estimated by considering the factors, such as the densification, leakage current, and dtan $\delta$/dV. As a result, the varistor sintered at 134$0^{\circ}C$ exhibited the highest stability, with %$\Delta$ $V_{lmA}$=-1.54%, %$\Delta$$\alpha$=-2.49%, %$\Delta$ $I_{\ell}$=+240.68%, 5%$\Delta$tan$\delta$=+29.96%.96%.96%.%.

• 한국염색가공학회지
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• 제29권3호
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• pp.155-161
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• 2017

In CPB(Cold-Pad-Batch) dyeing, the rubber of the padder roll is influenced by the heat, chemical and mechanical influences and thus aging of the padder roll rubber occurs. This study presents an accelerated thermal aging test of the CPB padder roll rubber with strong alkali conditions. Using Arrhenius formula of the various property values for the various aging temperatures($80^{\circ}C$, $90^{\circ}C$, $100^{\circ}C$) of the padder roll, the accelerated life predictions could be calculated. The threshold value of the property was set at different values. The hardness was set at the point where 5% degradation occurs based on the actual use conditions, and the tensile strength was set at the point where 50% degradation occurs based on the general life prediction standards. From the results of the different physical properties at differing temperatures, the Arrhenius plot could be obtained. Through the usage of the Arrhenius Equation, significant duration expectation could be predicted, and the chemical aging behavior of the CPB padder roll could be found at the arbitrary and actual temperatures.

• 펄프종이기술
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• 제41권1호
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• pp.37-43
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• 2009

In this study, the physical properties of base paper for the manufacture of mulching mat for afforestation seedling were investigated. The base paper for mulching mat was prepared by stock conditions of PAE and AKD addition into the screened slurry of KOCC for the strengthening effects of wet tensile and burst strength. The optimum additions of PAE and AKD were considered at 2% and 0.5%, respectively. The accelerated aging by ISO 5630-1 and wet heat aging method under hot water for 2 kinds of commercial mulching and wet strength paper were compared with the base paper prepared for mulching mat manufacture. The accelerated aging test for the base paper prepared for mulching mat manufacture resulted in the same tendency of physical properties as two kinds of commercial products. However, the results of wet heat aging test under hot water indicated that the physical strength for base paper prepared was much higher than others. In addition, the opacity behavior for base paper prepared was enough effects to obstruct weeds growth by isolating transmission of sunlight.

• 한국전기전자재료학회논문지
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• 제32권6호
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• pp.490-495
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• 2019

This study performs the thermal aging of chlorosulfonated polyethylene (CSPE) for 807.36 and 1,614.48 hours at $110^{\circ}C$, which is equivalent to 40 and 80 years of aging at $50^{\circ}C$ in nuclear power plants, respectively. Flat-type CSPEs were soaked in seawater for five days and then dried for five days at room temperature. Furthermore, the soaked CSPEs were cleaned for 5 days with fresh water and dried for 1,100 days at room temperature. Through this process, the log IV of the CSPEs decreases, whereas the dissipation factor of the CSPEs increases as thermally accelerated aged years increase at the measured frequency. Although the phase degree of the response voltage versus excitation voltage of the CSPEs increases, that of the response current versus excitation voltage decreases with the thermally accelerated aging. The thermal conductivity of the CSPEs increases slightly, but the thermal diffusivity does not vary with the thermally accelerated aged year increase. The displacement of the compressive strength of the CSPEs decreases gradually as the thermally accelerated aged years increase.

• Transactions on Electrical and Electronic Materials
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• 제15권5호
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• pp.284-289
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• 2014

The effects of additives (Nb, Bi and Cr) on the microstructure, varistor properties, and aging behavior of V/Mn/Co/ La/Dy co-doped zinc oxide ceramics were systematically investigated. An analysis of the microstructure showed that all of the ceramics that were modified with various additives were composed of zinc oxide grain as the main phase, and secondary phases such as $Zn_3(VO_4)_2$, $ZnV_2O_4$, and $DyVO_4$. The $Bi_2O_3$-modified samples exhibited the lowest density, the $Nb_2O_5$-modified sample exhibited the largest average grain size, and the $Cr_2O_3$-modified samples exhibited the highest breakdown field. All additives improved the non-ohmic coefficient (${\alpha}$) by either a small or a large margin, and in particular an $Nb_2O_5$ additive noticeably increased the non-ohmic coefficient to be as large as 36. The $Bi_2O_3$-modified samples exhibited the highest stability with variation rates for the breakdown field and for the non-ohmic coefficient (${\alpha}$) of -1.2% and -26.3%, respectively, after application of a DC accelerated aging stress of 0.85 EB/$85^{\circ}C$/24 h.

• 콘크리트학회논문집
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• 제25권2호
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• pp.137-144
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• 2013

철근콘크리트(reinforced concrete) 구조부재에서 철근의 부식으로 인한 문제점을 개선하고자 섬유보강 복합재료(FRP) 보강근(rebar)을 사용하는 것에 대한 연구가 꾸준히 진행되어져 오고 있다. 하지만 이러한 FRP 보강근을 사용한 콘크리트 부재의 환경에 대한 장기거동에 대한 연구가 아직도 미흡한 수준이다. 이 연구는 GFRP(glass fiber reinforced polymer) 보강근을 사용한 콘크리트 부재를 온도 약 $46^{\circ}C$와 습도가 80%인 인위적인 실험실에서 최대 300일까지 노출시킨 후의 장기 거동에 대한 실험적 연구를 제시하였다. 비교를 위하여 두가지 서로 다른 GFRP 보강근과 철근을 보강한 콘크리트 보 시험체를 제작하였다. 실험 결과, 장기 노출환경에서도 GFRP 보강근을 보강한 콘크리트 보 시험체의 파괴형태는 철근 보강 콘크리트 보시험체와 매우 유사한 파괴형태를 나타내었으며, 노출 시간에 따른 하중저항 감소값은 철근이 보강된 경우가 GFRP 보강근이 보강된 경우보다 하중저항 감소값이 크게 일어났다. 또한 GFRP 보강근 보강 콘크리트 보 시험체를 설계할 시에는 철근 보강보다 취성파괴에 대한 충분한 대비가 요구됨을 알 수 있었다. 그리고 압축파괴에 대한 변형도 계수(deformability factor)는 모든 경우에서 노출시간에 관계없이 큰 변화가 없음을 알 수 있었다.

• 한국재료학회지
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• 제30권10호
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• pp.502-508
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• 2020

This paper focuses on the electrical properties and stability against DC accelerated aging stress of ZnO-V₂O₅-MnO₂-Nb₂O₅-Bi₂O₃-Co₃O₄-Dy₂O₃ (ZVMNBCD) varistor ceramics sintered at 850 - 925 ℃. With the increase of sintering temperature, the average grain size increases from 4.4 to 11.8 mm, and the density of the sintered pellets decreases from 5.53 to 5.40 g/㎤ due to the volatility of V₂O₅, which has a low melting point. The breakdown field abruptly decreases from 8016 to 1,715 V/cm with the increase of the sintering temperature. The maximum non-ohmic coefficient (59) is obtained when the sample is sintered at 875 ℃. The samples sintered at below 900 ℃ exhibit a relatively low leakage current, less than 60 mA/㎠. The apparent dielectric constant increases due to the increase of the average grain size with the increase of the sintering temperature. The change tendency of dissipation factor at 1 kHz according to the sintering temperature coincides with the tendency of the leakage current. In terms of stability, the samples sintered at 900 ℃ exhibit both high non-ohmic coefficient (45) and excellent stability, 0.8% in 𝚫E_B/E_B and -0.7 % in 𝚫α/α after application of DC accelerated aging stress (0.85 E_B/85 ℃/24 h).

• 펄프종이기술
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• 제47권4호
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• pp.151-159
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• 2015

Paper records were generally degraded by some factors from atmospheric environments, like temperature, relative humidity or air pollutants. In this study, the degradation behavior of paper records by single or mixed gases of $NO_2$, $SO_2$, HCHO and TVOC was evaluated. The mechanical, optical and chemical properties of 4 kinds of paper (acid and neutral-based printing paper, traditional Hanji, and filter paper) were directly and indirectly affected by gaseous harmful materials. The brightness and $L^*$ value in all papers were slightly increased by accelerated aging under gaseous HCHO and TVOCs, but highly decreased by conditions under gases $NO_2$ and $SO_2$. The optical properties of paper records were most vulnerable in acid-based paper and high stable in filter paper and traditional Hanji by air pollutant degradation. The aging treatments under mixed gas pollutants including $NO_2$ resulted in decrease of physical, mechanical and optical properties of paper, so it was supposed that the concentration of $NO_2$ gas would be strictly controlled for optimum indoor air quality management in domestic storage centers for paper records.