• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.12
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• pp.8637-8642
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• 2015

Typical aging for the rubber using the current military adhesive combat boots was spread with a regular aging caused by heat stress. In this study, the aging test of the rubber for combat boots was carried out and the reaction rate constant, k was calculated at aging temperature $60^{\circ}C$, $80^{\circ}C$ and $100^{\circ}C$, using the Arrhenius equation. The lifetime limit was assumed that the tensile strength of the product is reduced to 30%, the elongation is reduced to 50% and abrasion resistance ratio is 380%. ln($P/P_0$) and the lifetime was predicted with the consideration of the activation energy constant. According to the above, the lifetime of the rubber for combat boots with influenced by aging temperature was predicted. As the result, the estimate lifetime at $20^{\circ}C$ was confirmed more than 10 years.

• Journal of Conservation Science
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• v.35 no.5
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• pp.416-429
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• 2019

Bongchae is primarily employed for toning, which is the last step in the conservation treatment of paper's cultural properties. The objective of this study is to identify the coloring patterns of four types of Bongchae(Bonram, Gamboge, Yeonji, and Daeja) and determine the associated color change patterns through accelerated aging experiments. By examining the coloring patterns, it is observed that Yeonji, Bonram, and Daeja are painted as particles, whereas Gamboge indicates a close state of coating. Results obtained from X-ray diffraction analysis of Bongchae indicate that the presence of quartz, calcite, and pyrophyllite can be equally detected in Bonram, Yeonji, and Daeja. Additionally, the presence of goethite is also detected in Daeja. Gamboge becomes discolored from yellow to orange color during wet thermal aging, and Gamboge and Yeonji become decolorized during UV irradiation aging. Hence, cultural properties of paper colored with Gamboge can be predicted to become discolored to orange color by alkalis and can be darkened by UV rays because the decolorization of Gamboge and Yeonji occurs preferentially.

• Fire Science and Engineering
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• v.18 no.3
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• pp.45-50
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• 2004

Thermal degradation of PVC which used for insulator of 600V vinyl insulated wire has been studied by thermo gravimetry analysis and accelerated thermal aging test. The activation energy using thermo gravimetry analysis was determined by the kinetic methods, such as Kissinger and Flynn-Wall-Ozawa. The activation energy was determined to from 89.29 kJ/mol to 111.39 kJ/mol in 600V PVC insulated wire and from 97.80 kJ/mol to 119.25 kJ/mol in 600v heat-resistant PVC insulated wire. And also, the activation energy through a long-term thermal aging test was calculated by using Arrhenius equation In the low temperature of 8$0^{\circ}C$, 9$0^{\circ}C$, 10$0^{\circ}C$. The results showed that 600V PVC insulated wire was 92.16 kJ/mol, and 600v heat-resistant PVC insulated wire was 97.52 kJ/mol. Consequently, the activation energy of 600V heat-resistant PVC insulated wire is larger than 600V PVC insulated wire. Therefore, it can be predicted that 600V heat-resistant PVC insulated wire has a long-term stability relatively.

• Journal of the Korean Society of Propulsion Engineers
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• v.21 no.3
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• pp.84-90
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• 2017

Explosive bolt is coupled in a variety of guided weapons and space projectiles, to perform the separation function. Thus, the role of the explosive bolt in guided weapons systems is very important, as it can cause failure of the entire system in the case of mission failure. For this reason, the design life prediction for explosive bolt is highly and frequently required recently, but its accurate prediction method has not been presented. In order to apply the existing accelerated aging process, we should know the activation energy and the acceleration factor of the explosive bolt. Since the information required for accelerated aging is not presently secured, it is difficult to predict the design life of explosive. Thus, in the present study, we have evaluated the performance of actual explosive bolts in the condition of natural aging over 10 years in order to present a minimum design life.

• Korean Journal of Metals and Materials
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• v.48 no.10
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• pp.957-963
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• 2010

The aging behavior of aluminum borate whisker ($Al_{18}B_4O_{33}$) reinforced AS52+Sr magnesium matrix composites was investigated with Vickers hardness measurements, bending tests, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Experimental results showed that aging is accelerated in the $AS52+Sr/Al_{18}B_4O_{33}$ composite compared with an unreinforced AS52+Sr alloy. The hardness of the alloy and composite increases monotonically as a function of the aging time before reaching its peak hardness and then gradually decreases. The composite reaches its peak hardness in 10 h, whereas the matrix alloy requires 30h, indicating accelerated age-hardening in the $AS52+Sr/Al_{18}B_4O_{33}$ composite compared with the unreinforced AS52+Sr alloy at $170^{\circ}C$. The interfacial reaction of $AS52+Sr/Al_{18}B_4O_{33}$ magnesium matrix composite is considered to play a dominant role in the strengthening mechanism, ultimately affecting the mechanical properties of the composite.

• Journal of the Korean Society of Safety
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• v.37 no.6
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• pp.1-8
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• 2022

This study analyzed the characteristics of insulation resistance and operating time based on an accelerated degradation test of a low-voltage circuit breaker. The experimental sample used a molded case circuit breaker (MCCB) and an earth leakage circuit breaker (ELCB). After measuring the insulation resistance of the circuit breakers, the leakage current was affected by an external rather than an internal structure. Furthermore, the insulation resistance of the circuit breakers with accelerated degradation was measured using a Megger insulation tester. In the accelerated degradation test, aging times of five, ten, 15, and 20 years were applied according to a temperature derived using the Arrhenius equation. Circuit breakers with an equivalent life of ten, 15, and 20 years had increased insulation resistance compared to those with less degradation time. In particular, the circuit breaker with an equivalent life of ten years had the highest insulation resistance. Component analysis of the circuit breaker manufactured through an accelerated degradation test confirmed that the timing of the increase in insulation resistance and the time of additive loss were the same. Finally, after analyzing the operating time of the circuit breakers with degradation, it was confirmed that the MCCB did not change, but the ELCB breaker failed.

• Bulletin of the Korean Chemical Society
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• v.31 no.9
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• pp.2613-2617
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• 2010

Chloroprene is a chlorine substituent of 1,3-butadiene. Butadiene rubber (BR) and chloroprene rubber (CR) composites were thermally aged at 60, 70, 80, and $90^{\circ}C$ for 2 - 185 days in a convection oven and changes of the crosslink densities by the accelerated thermal aging were investigated. The crosslink densities increased as the aging time elapsed and as the aging temperature became higher. Degrees of the crosslink density changes of the BR composite were on the whole larger than those of the CR one except the short-term thermal aging at 60 and $70^{\circ}C$. The crosslink densities abnormally increased after themal aging at high temperatures for a long time. Activation energies for the crosslink density changes of the rubber composites tended to increase with increase of the aging time and the variation showed a local minimum. The activation energies of the CR composite were lower than those of the BR one. The experimental results were explained with a role of ligand of chlorine atom of CR in a zinc complex, steric hindrance by chlorine atom of CR, and oxidation of rubber chain.

• Nuclear Engineering and Technology
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• v.54 no.2
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• pp.709-731
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• 2022

Loss of fracture resistance due to thermal aging degradation is a potential limiting factor affecting the long-term (80+ year) viability of nuclear reactors. To evaluate the effects of decades of aging in a practical time frame, accelerated aging must be employed prior to mechanical characterization. In this study, a variety of chemically and microstructurally diverse austenitic stainless steels were aged between 0 and 30,000 h at 290-400 ℃ to simulate 0-80+ years of operation. Over 600 static fracture tests were carried out between room temperature and 400 ℃. The results presented include selected J-R curves of each material as well as K_0.2mm fracture toughness values mapped against aging condition and ferrite content in order to display any trends related to those variables. Results regarding differences in processing, optimal ferrite content under light aging, and the relationship between test temperature and Mo content were observed. Overall, it was found that both the ferrite volume fraction and molybdenum content had significant effects on thermal degradation susceptibility. It was determined that materials with >25 vol% ferrite are unlikely to be viable for 80 years, particularly if they have high Mo contents (>2 wt%), while materials less than 15 vol% ferrite are viable regardless of Mo content.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.737-742
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• 2002

The chief factors for the penetration and diffusion of chloride ions in concrete are water-cement ratio(w/c), aging, thickness of cover concrete, chloride ions concentration of given environment, wet and dry conditions and etc. In this study, effect of w/c and aging on the characteristics of chloride ions diffusion in concrete were researched when environmental factors for the penetration and diffusion of chloride ions were constant. For this purpose, the voltages passing through the diffusion cell were measured by using accelerated test method using potential difference, and then diffusion coefficients of chloride ions by using Andrade's method were estimated for 44%, 49.5% and 55% of w/c, respectively. As a result, correlation among diffusion coefficients of chloride ions, w/c and aging were concluded through multiple regression model.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2001.11a
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• pp.13-16
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• 2001

In this paper, the emission and aging properties of ZnS:Cu electroluminescent device were experiment respectively at room temperature and 7$0^{\circ}C$ relative humidity 100%. ZnS:Cu and BaTiO$_3$were respectively used for phosphor and dielectric. While AC 100V on 400Hz frequency were applied to the devices at room temperature and 70$_3$relative humidity 100%, the change of brightness were measured and compared. The surface of aged devices were investigated by scanning electron microscope. With the continuously operated environment of room temperature and 7$0^{\circ}C$ relative humidity 100%, the decay time were measured and the dark spot and aging status on the surface of the device were investigated. ZnS:Cu electroluminescent properties were deteriorated by the Increased temperature and humidity. Also the deteriorated properties were confirmed by the brightness and surface chanties of device, and the aging mechanism from the simulation on sulfur vacancy and deep tracts density.