• Journal of the Korean institute of surface engineering
• /
• v.49 no.6
• /
• pp.498-506
• /
• 2016

Electrochemical measurement using a LSCF6428 electrode was performed to estimate the oxygen potential gradient in the electrode layer and a long time stability test was performed by applied potential to learn the overpotential effect on the LSCF6428 electrode. By fitting the observed impedance spectra, it was obtained that the amount of faradic current decreased with distance from cathode/electrolyte interface. Oxygen potential gradient was estimated to occur within 1 um region from the cathode/electrolyte interface at an oxygen partial pressure of 10-1 bar. The segregation of cation rich phases in the LSCF6428 electrode suggests that kinetic decomposition took place. However, impedance response after applying the potential showed no changes in the electrode compared with before applying potential. The obtained results suggest that segregation of a secondary phase in a LSCF6428 cathode is not related to performance degradation for solid oxide fuel cells (SOFCs).

• Journal of the Korean Ceramic Society
• /
• v.35 no.10
• /
• pp.1070-1077
• /
• 1998

Effect of current collecting layer on the cathode was characterized by AC impedance spectroscopy at 800$^{\circ}C$ under flowing air. LSM-YSZ composite cathode showed lower polarization resistance due to the in-crease of triple phase (LSM/YSZ/Pore) boundary length by incorporation of YSZ. Ohmic resistance {{{{ {R }_{1 } }} of LSM-YSZ was higher than that of pure LSM however because in-plane resistance of the cathode was fair-ly high due to its high specific resistivity. To reduce the in-plane resistance of LSM-YSZ cathode cathode side current collecting layer was required. Ohmic resistance {{{{ {R }_{1 } }} was reduced after forming LSM current col-lecting layer on the LSM-YSZ cathode. In case of pure LSM cathode the formation of Pt, or LSCO current collecting layer reduced polarization resistance {{{{ {R }_{p } }} but ohmic resistance {{{{ {R }_{1 } }} was relatively constant. After annealing of LSM cathode with Pt current collector at higher temperature polarization resistance {{{{ {R }_{p } }} was in-creased but ohmic resistance {{{{ {R }_{1 } }} was constant. These phenomena indicate that Pt or LSCo current col-lecting layers act as a catalytic layer for oxygen reduction of pure LSM cathode. LSCO current collector was effective in reducing the ohmic and polarization resistance of LSM-YSZ cathode.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.29 no.11
• /
• pp.89-95
• /
• 2015

As a solution of improving the energy efficiency in power system, Low Voltage DC (LVDC) distribution systems different from conventional ones have been constantly researched. As in conventional AC distribution system, LVDC distribution system can suffer from High Impedance Fault (HIF) which may cause a failure of protective relay due to relatively low change in magnitude of fault current. In order to solve the problem, a scheme for detecting HIFs is presented in this paper. Closing Opening Difference Operation (CODO) based on Mathematical Morphology (MM), one of the MM-based filters, is utilized to make fault signals discriminable. To verify performance of the scheme, a simple LVDC distribution system is modeled by using ElectroMagnetic Transient Program (EMTP) software. Computer simulations according to various conditions are performed and comparison studies with a scheme using Wavelet Transform (WT) in an aspect of simulation time are also conducted.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.34 no.3
• /
• pp.98-102
• /
• 2024

In this study, the crystal characteristics of commercial AlN powders with sizes of "㎛" and "nm" were selected through XRD analysis and then sintered at different temperatures through an induction heating furnace to investigate the optimized sintering temperature and physical properties. The sintering temperature was 1,500, 1,700, and 1,900℃ in the N₂ atmosphere, and the optimized sintering temperature conditions were established for the sintered AlN pellets using SEM, XRD, and Raman analysis. Additionally, impedance analysis was performed to confirm the electrical properties of the optimized AlN pellet without sintering additives.

• Journal of the Korean Electrochemical Society
• /
• v.13 no.3
• /
• pp.211-216
• /
• 2010

Boron trifluoride lithium methacrylate ($BF_3$LiMA)-based gel polymer electrolytes (GPEs) were synthesized with various $BF_3$LiMA concentration to elucidate the effect on ionic conductivity and electrochemical stability by a AC impedance and linear sweep voltammetry (LSV). As a result, the highest ionic conductivity reached $5.3{\times}10^{-4}Scm^{-1}$ at $25^{\circ}C$ was obtained for 4 wt% of $BF_3$LiMA. Furthermore, high electrochemical stability up to 4.3 V of the $BF_3$LiMA-based GPE was observed in LSV measurement since the counter anion was immobilized in this self-doped system. On the other hand, it was assumed that there was a rapid decomposition of electrolytes on a lithium metal electrode which results in a high solid electrolyte interface (SEI) resistance. However, a high stability toward graphite or lithium cobalt oxide (LCO) electrode thereby a low SEI resistance was observed from the AC impedance measurement as a function of storage time at $25^{\circ}C$. Consequently, the high ionic conductivity, good electrochemical stability and the good interfacial compatibility with graphite and LCO were achieved in $BF_3$LiMA-based GPE.

• Journal of the Korean Electrochemical Society
• /
• v.2 no.4
• /
• pp.202-208
• /
• 1999

Composite cathodes of $50/50\;vol\%$ LSM-YSZ $(La_{-x}Sr_xMnO_3-yttria\;stabilized\;zirconia)$ were deposited onto dense YSZ electrolytes by colloidal deposition technique. The cathode characteristics were then examined by scanning electron microscopy (SEM) and studied by ac-impedance spectroscopy (IS). The conditioning effects on LSM-YSZ cathodes were seen and remedies for these effects were noted in order to improve the performance of a solid oxide fuel cell (SOFC). The effects of temperature on impedance, surface contamination on cathode bonding to YSZ electrolyte, changing Pt paste, aerosol spray technique applied to curved surface on microstructure and cell to cell variability were solved by testing at $900^{\circ}C$, sanding the YSZ surface, using only one batch of Pt paste, using flat YSZ plates and using consistent procedures and techniques, respectively. And then, reproducible impedance spectra were confirmed by using the improved cell and the typical spectra measured for an (air)LSM-YSZ/YSZ/LSM-YSZ(air) cell at $900^{\circ}C$ were composed of two depressed arcs. Impedance characteristics of the LSM-YSZ cathodes were also affected by experimental conditions such as catalytic interlayer, composite cathode compositions and applied current.

• Applied Microscopy
• /
• v.47 no.3
• /
• pp.121-125
• /
• 2017

This study deals the prediction of temperature effect on low-frequency dispersion of alternating current (AC) conductivity spectra of composite materials based on copolymer reinforced with carbon black (CB) particles. A sample of ethylene butylacrylate loaded with 13% of CB particles were prepared and investigated using the impedance spectroscopy representation in the frequency range from 40 Hz to 0.1 MHz and temperature range from $20^{\circ}C$ to $125^{\circ}C$. The dielectric constant, ${\varepsilon}^{\prime}$, and dielectric losses, ${\varepsilon}^{{\prime}{\prime}}$, were found to decrease with increasing frequency. The frequency dependence of the AC conductivity follows the universal power law with a large deviation in the high frequency region, the positive temperature coefficient in resistivity effect has been observed below the melting temperature which makes this composite potentially remarkable for industrial applications.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2003.07a
• /
• pp.752-755
• /
• 2003

An EMI emission of 42" AC-PDP panel is studied in this paper. First, the EMI emission level is roughly estimated using both simple electric dipole type and magnetic dipole type radiator model. The value of current required for estimation has been obtained from Fourier Transform of the measured current in time domain. Second, we investigate which type of EMI radiation is dominant by FEM calculation of the wave impedance. The result shows that electric dipole type radiation is dominant EMI source.

• Proceedings of the KSR Conference
• /
• 2000.11a
• /
• pp.712-719
• /
• 2000

This paper presents a new algorithm to analyze a train voltages of multi-trains in auto-transformer-fed AC railway systems, using electrical equivalent change. The train current will be divided into circulation and return currents, and these current values are the same. By evaluating each current independently, the result will be more precise. The train current flows through the all auto-transformer corresponding to track impedance. In analyzing the railway system, the algorithm is based on the K.C.L, K.V.L, superposition and circuit separation method. Multi-train's voltages are determined by calculating the catenary voltage at each train's position and adding up these train's voltage drop. Case studies use a field operational data, show that tile proposed method is easily applied.

• Proceedings of the KIPE Conference
• /
• 2002.07a
• /
• pp.506-509
• /
• 2002

In this paper, a design method of LCL filter at the AC input side of a voltage source PWM converter is proposed. Effective method to prevent pollution of the utility caused by high frequency current ripple is to use a LCL filter instead of the L filter The C elements in the filter provide a low impedance path for the high frequency component, preventing them from entering the utility. A resistor in series with a capacitor is used for damping the resonance in the filter. The design examples are shown and the validity of the proposed design method is verified through the PSIM simulation.