• 제목/요약/키워드: Absorption system

검색결과 2,013건 처리시간 0.033초

Study of HOMO and LUMO Energy Levels for Spirolactam Ring Moiety Using Electrochemical Approach

  • Kim, Hyungjoo;Lee, Sehoon;Son, Young-A
    • 한국염색가공학회지
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    • 제25권2호
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    • pp.83-88
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    • 2013
  • Rhodamine dyes have been studied in various scientific areas due to their excellent photophysical properties. In particular, these rhodamine dyes are one of the most famous fluorophores as signal unit in chemosensor study. This is related to spirolactam ring system in rhodamine dyes. When the spirolactam ring is closed, there is nonfluorescence and colorless. Whereas, ring-opening of the corresponding spirolactam induces strong fluorescence and color. These absorption and emission changes are related to structural changes as well as electron energy potential levels such as HOMO and LUMO values. In this study, two different structures of rhodamine 6G hydrazide depending on the spirolactam ring system were investigated using absorption measurement, electrochemical measurement and computational calculations.

확산형 흡수식 냉동시스템의 기포펌프 성능실험 (Experimental Performance Study of the Bubble Pump for the Diffusion Absorption Refrigerating System)

  • 이재효;정의갑;윤재호;정의갑
    • 설비공학논문집
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    • 제16권3호
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    • pp.287-292
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    • 2004
  • An experimental investigation was carried out to study the performance of a bubble pump for the diffusion absorption refrigerating system. Ammonia was used as the refrigerant and the helium was charged in order to balance the pressure between the low and high pressure side. As experimental variables, the concentration of ammonia charged into system, heat input, and the pressure of helium were selected. Experimental results show that the generation rate of ammonia vapor and the circulation rate of diluted ammonia solution were increased as the heat input increases, but the ratio of the solution to vapor flow rate was decreased. The generation rate of refrigerant vapor and the circulation rate of diluted ammonia solution increased as the system pressure decreased. Finally under the condition of 25 bars, the concentration of rich ammonia solution was not affected by the generation rate of ammonia vapor and the circulation of diluted ammonia solution.

Estimation of Plastic Energy Dissipation Amount of Multi-bent Spatial structure by Equivalent Linear Analysis

  • 이승재
    • 한국공간구조학회논문집
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    • 제6권2호
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    • pp.131-136
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    • 2006
  • It is important to evaluate energy absorption capacity of frames required during a design earthquake. An inelastic computer analysis based on mathematical modelling of energy absorbing frames and elements makes it possible to evaluate required energy absorption capacity. But such an analysis sometimes consumes much computation time particularly in case of complicated structural system. This paper presents a proposal to predict energy absorption of multi-bent steel frames by simple equivalent linear method.

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수평원관상의 $LiBr-H_2O$ 흡수특성에 대한 연구 (Parametric Study on the $LiBr-H_2O$ Absorption Process on Horizontal Tubes)

  • 민준기;최도형
    • 한국전산유체공학회지
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    • 제5권1호
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    • pp.33-42
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    • 2000
  • The LiBr-H₂O absorption process on a horizontal tube has been analyzed numerically. The flow field, which was calculated in the authors' previous study by solving the fully elliptic Navier-Stokes equations with accurate free-surface-tracking method, is used to solve the temperature and concentration distributions in the absorption film. With the assumption that the absorbent is linear, calculations have been made for various inlet temperature and flow-rate conditions. For low inlet temperature, the absorption rate is large in the upstream region but the mean temperature also increases and as a result the absorption decreases as the film flows to downstream while high-inlet-temperature case does the opposite. The difference in the absorption rate due to the inlet temperature change becomes smaller in the downstream than that in the upstream. For large flow rate, the heat transfer to the wall becomes poor due to the thick film and so does the absorption rate. The analyses have also been carried out for multiple tube arrangement and the results show that the absorption rate converges after a few tube rows.

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Fe계 나노결정립 분말 시트에 첨가된 CNT의 볼밀 공정에 따른 전자파 흡수 특성 변화 (The Characteristic Changes of Electromagnetic Wave Absorption in Fe-based Nanocrystalline P/M Sheets Mixed with Ball-Milled Carbon Nanotubes)

  • 김선이;김미래;손근용;박원욱
    • 한국분말재료학회지
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    • 제16권6호
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    • pp.424-430
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    • 2009
  • Electromagnetic wave energies are consumed in the form of thermal energy, which is mainly caused by magnetic loss, dielectric loss and conductive loss. In this study, CNT was added to the nanocrystalline soft magnetic materials inducing a high magnetic loss, in order to improve the dielectric loss of the EM wave absorption sheet. Generally, the aspect ratio and the dispersion state of CNT can be changed by the pre-ball milling process, which affects the absorbing properties. After the various ball-milling processes, 1wt% of CNTs were mixed with the nanocrystalline $Fe_{73}Si_{16}B_7Nb_{3}Cu_1$ base powder, and then further processed to make EM absorption sheets. As a result, the addition of CNT to Fe-based nanocrystalline materials improved the absorption properties. However, the increase of ball-milling time for more than 1h was not desirable for the powder mixture, because the ballmilling caused the shortening of CNT length and the agglomeration of the CNT flakes.

Simulation of $H_2O/LiBr$ Triple Effect Absorption Systems with a Modified Reverse Flow

  • Jo, Young-Kyong;Kim, Jin-Kyeong;Kang, Yang-Tae
    • International Journal of Air-Conditioning and Refrigeration
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    • 제15권3호
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    • pp.114-121
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    • 2007
  • In this study, a modified reverse flow type, one of the triple effect absorption cycles, is studied for performance improvement. The cycle simulation is carried out by using EES(Engineering Equation Solver) program for the working fluid of $H_2O/LiBr$ solution. The split-ratios of solution flow rate, UA of each component, pumping mass flow rate of solution are considered as key parameters. The results show that the optimal SRH (split ratio of high side) and SRL (split ratio of low side) values are 0.596 and 0.521, respectively. Under these conditions, the COP is maximized to 2.1. The optimal pumping mass flow rate is selected as 3 kg/s and the corresponding UAEV A is 121 kW/K in the present system. The present simulation results are compared to the other literature results from Kaita's (2002) and Cho's (1998) triple effect absorption systems. The present system has a lower solution temperature and a higher COP than the Kaita's modified reverse flow, and it also gives a higher COP than the Cho's parallel flow by adjusting split ratios.

응축기 배열회수에 의한 흡수식 냉동기의 고효율화에 관한 연구 (A Study on the COP Improvement of Absorption Chillers by Recovering Heat from the Condenser)

  • 박찬우
    • 설비공학논문집
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    • 제18권9호
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    • pp.738-744
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    • 2006
  • In order to utilize the condensation heat of refrigerants in condenser on the absorption chiller system, the solution cooled condenser (SCC) was proposed using the weak solution of absorber as a cooling medium. The increase of COP with the increase of UA of the solution cooled condenser was approximately 0.009 in maximum with single effect one, and is about maximum 0.008 in occasion of double effect one with series flow compared to that without. In the case of heat exchanger, effectiveness is about 0.85, it's increments are 0.008 and 0.0072, respectively. And solution cooled condenser is more effective device in the single effect absorption system than double effect system for the principle of operation. On the other hand, as the solution split ratio increases when the value of UA is fixed, COP is increased and as the solution split ratio increases when the value of UA is fixed, COP is increased. If the flow rate of cooling water or the value of UA is reduced in order to increases the heat recovery of solution cooled condenser, heat recovery of solution cooled condenser is increased a little but COP is decreased as the system pressure is increased.

응축기 배열 회수에 의한 흡수식 냉동기의 고효율화에 관한 연구 (A study on the Characteristics of the High Efficiency absorption Chiller by Heat Recovering from Condenser)

  • 박찬우
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2006년도 하계학술발표대회 논문집
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    • pp.46-51
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    • 2006
  • In order to utilize the refrigerants condensation heat of condenser on the absorption chiller system, the solution cooling condenser(SCC) were proposed, which weak solution of absorber outlet use as a cooling water. As the UA of the solution cooling condenser increased, increasement of COP is about maximum 0.09 in occasion of single effect and is about maximum 0.08 in occasion of double effect series flow. In the case of heat exchanger efficiency is about 0.85, it's increments are 0.08 and 0.072, each. And solution cooling condenser is a more effective device in the single effect absorption system more than double effect system for the principle of operation. In order to increases the heat of solution cooling condenser, if reduce the flow rate of cooling water or the value of UA, it makes COP increase a little, but it brought COP decrease because of increasing the pressure of system.

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Development of EM Wave Absorber for Hi-pass System Using Amorphous Metal Powder

  • Kim, Dong-Il;Yoo, Gun-Suk;Choi, Dong-Soo
    • 한국항해항만학회지
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    • 제35권9호
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    • pp.717-720
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    • 2011
  • In this paper, we designed and fabricated the Electromagnetic(EM) wave absorber for an Electronic Toll Collection(ETC or Hi-pass) system by using Amorphous metal powder and CPE. The material properties and the absorption properties of the samples containing 50 wt.%, 60 wt.%, 70 wt.%, and 80 wt.% of Amorphous. Moreover, the EM wave absorption abilities were simulated for the different thicknesses of the EM absorbers by adopting the measured permittivity and permeability, and then the EM wave absorber was fabricated based on the simulated design values. As a result, the EM wave absorber with the composition of Amorphous metal powder : CPE = 50 : 50 wt.% with the thickness of 2.6 mm has excellent absorption ability more than 40 dB at 5.8 GHz.

흡음형과 공명형 덕트 소음기의 소음저감 성능에 관한 실험적 고찰 (An Experimental Investigation on Noise Reduction Performance of the Absorption and the Resonance Type Duct Silencers)

  • 이영섭;정광섭;이동훈
    • 설비공학논문집
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    • 제22권12호
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    • pp.897-901
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    • 2010
  • A silencer has been widely used for the purpose of suppressing the noises propagated from duct of air conditioning system. The absorption type silencer is usually applied to reduce the noise with high frequency bandwidth. On the order hand, the resonance type silencer is applied to reduce the noise with low-middle frequency bandwidth. The insertion loss of silencer is measured in the reverberation room. The cut-off frequency of reverberation room is 100 Hz. The insertion loss of absorption type silencer is more larger than that for resonance type silencer regardless of changing the flow velocity.