• Title/Summary/Keyword: Absorption performance

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Techno-economic Comparison of Absorption and Adsorption Processes for Carbon Monoxide (CO) Separation from Linze-Donawitz Gas (LDG) (Linze-Donawitz 가스로부터 일산화탄소(CO) 분리를 위한 흡수 및 흡착공정에 대한 기술경제성 비교)

  • Lim, Young-Il;Choi, Jinsoon;Moon, Hung-Man;Kim, Gook-Hee
    • Korean Chemical Engineering Research
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    • v.54 no.3
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    • pp.320-331
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    • 2016
  • Linze-Donawitz gas (LDG) adjunctively produced in the steel mill contains over 60% of CO. Two processes that recover high purity CO from LDG were considered: COSORB and CO-Pressure swing adsorption (PSA). This study aimed to decide which one is more economically feasible than the other by techno-economic analysis (TEA). From the technical point of view of TEA, the process flow diagram (PFD) was constructed, the mass and energy balances were calculated, and the equipment type and size were determined in order to estimate the total capital investment (TCI) and the total production cost (TPC). From the economic point of view of TEA, economic performance such as return on investment (ROI) and payback period (PBP) was evaluated, and the sensitivity analysis was carried out to identify key factors influencing ROI and PBP. It was found that CO-PSA is more economically feasible due to higher ROI and lower PBP. The CO price highly influenced ROI and PBP.

The Effects of functional foot orthotics on the balance according to Foot Shape (기능성 발보조기의 족부형태별 균형유지에 미치는 영향)

  • Chai, S.W.;Park, K.Y.;Kim, Y.S.
    • Journal of rehabilitation welfare engineering & assistive technology
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    • v.5 no.1
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    • pp.47-52
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    • 2011
  • The functional loot orthoses, when wearing shoes, are in the direct contact with bottom of foots to improve and recover the correctness of abnormal lower limb musculoskeletal imbalance and the primary role of foot and also, it can act to keep the balance and weight of body and support the weakened region, so that it is very helpful to keep body balance for the standing position. In this paper, it was researched that foot orthoses which is accommodable for the function of impact absorption including the gait stability affect on the balanced performances of body in according to the formation and the material of foot part. Taking into account the balanced performances by using the sway velocity, the estimation and comparison of the effects on the balanced performances by each formation and material for foot orthoses was evaluated into significant values(p<0.006) in only the eye-opening posture with Firm state, In this posture, the static process performed by each foot formation reveals in order of normal foot(p<0.010), flat foot(p<0.000) and hollow foot(p<0.003) and then, on the base of each formation of foot part, the result that analyze the effects of the materials of foot orthoses on the balance performance appeared showing that soft materials is more effective on the normal foot and, on the other hand, rigid materials is more effective in balancing on flat foot and hollow foot.

Toxicokinetics of rifapentine in beagle dogs (Beagle dog에 있어서 rifapentine의 독성동태연구)

  • Shin, Ho-chul;Lee, Hye-suk;Cha, Shin-woo;Han, Sang-seop;Roh, Jung-ku;Kim, Jin-suk;Lee, Won-chang
    • Korean Journal of Veterinary Research
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    • v.35 no.4
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    • pp.815-822
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    • 1995
  • The toxicokinetics of rifapentine was studied after an oral administration to beagle dogs. High-performance liquid chromatography(HPLC) using column-switching technique was performed to determine the serum concentrations of rifapentine. The pharmacokinetic profiles of rifapentine were analysed using one-compartment open model. Following a single oral administration of 10mg/kg, pharmacokinetic parameters were determined as follows: maximum serum concentration($C_{max}$), $28.90{\mu}g/ml$; maximum concentration time($T_{max}$), 3.7hr; elimination half-life($t_{1/2}$, 4.7hr; area under the curve(AUC), $339.0{\mu}g{\cdot}hr/ml$; volume of disiribution/bioavailability (Vd/F), 0.21 l/kg; lag time, 24min; absorption rate constant($k_a$), $0.445hr^{-1}$; elimination rate constant($k_{el}$), $0.148hr^{-1}$. After 6 month multiple oral doses of 10mg/kg/day, parameters were as follows: $C_{max}$, $34.40{\mu}g/ml$; $T_{max}$, 2.6hr; $t_{1/2}$, 6.7hr; AUC, $391.3{\mu}g{\cdot}hr/ml$; Vd/F, 0.291/kg; $k_a$, $0.976hr^{-1}$; $k_{el}$, $0.104hr^{-1}$. The consistant kinetic parameters after a single and multiple oral administration show that there was no accumulation of rifapentine after 6 month oral administration. We also simulated the concentration of rifapentine after oral multiple administration of 10 and 50mg/kg/ day, based on the parameters obtained form the single administration. The measured serum concentrations of rifapentine were well fitted to the simulated results. The simulated results show that rifapentine readily reaches to steady-state after about 3 doses and the steady-state serum concentrations($C_{ss}$) are fluctuated in between $2.2{\sim}25.2{\mu}g/ml$, and $10.6{\sim}125.2{\mu}g/ml$ at the doses of 10 and 50mg/kg/day, respectively.

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Fertility Management of Flooded Rice Soil:A Proposal to Minimize The Biological Production Potential-Performance Gap of High Yielding Varieties (수도작(水稻作)을 위(爲)한 비옥도관리(肥沃度管理) - 다수성(多收性) 수도(水稻)의 생산능력(生産能力) 최대발현(最大發現)을 위한 시비량(施肥量) 결정법(決定法) 시안(試案) -)

  • Park, Chon-Suh
    • Korean Journal of Soil Science and Fertilizer
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    • v.12 no.3
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    • pp.153-167
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    • 1979
  • Proposal on the ways to determine the optimum levels of nutrients application on rice to maximize the yield was made paying attention on the desirable ratios among the major nutrients including N (organic matter) K, $SiO_2$, Ca, Mg. Following are the summary of the discussion. 1. For the higher yields, the balanced nutrients absorption is important. 2. Silica plays an important role in leading the applied N to increased yield. 3. Level of N application should be determined taking account of soil organic matter and abailable silicate contents. The higher the ratio of $SiO_2$/O.M. the more N can be applied for higher yield. 4. Different rice cultivars responds to the ratio of $SiO_2$/O.M. in soils, in different manner, in translating the applied N into yield. 5. By altering the ratio of $SiO_2$/O.M. through the application of silicate fertilizer or organic matter, the requirement of N in accordance with varietal characteristics can be determined. 6. When amount of N determined by above mentioned approaches, level of K application can be determined upon the basis of the ratio of $K/\sqrt{Ca+Mg}$ in soils.

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An Improvement in the Properties of MH Electrode of Ni/MH Battery by the Copper Coating (Ni/MH 전지에서 Cu 도금에 의한 음극활물질의 전극 특성 향상)

  • Cho, Jin Hun;Kim, In Jung;Lee, Yun Sung;Nahm, Kee Suk;Kim, Ki Ju;Lee, Hong Ki
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.568-574
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    • 1997
  • The effect of microencapsulation of maetal hydride (MH) with copper on the electrode performance of a Ni/MH battery has been investigated. The MH electrodes were prepared with a combination of cold press and paste methods. The discharge capacity of the electrode increased with an addition of small amounts if CMC into the electrode, but decreased when heat-treated in an oxygen-free nitrogen flow. The capacity of a Cu-coated $LaNi_5$ electrode was higher than that of LaNi5electrode. The discharge capacity of the electrode prepared with Cu-coated $LaNi_5$ increased with the increase of copper content in the electrode. It is considered that the increase of copper content enhanced the current density on the electrode surface, leading to the increase of the discharge capacity The MH electrode coated by an acidic electroless plating method showed much higher discharge capacity than that using an alkaline electroless plating method. The discharge capacity of the $LaNi_{4.5}Al_{0.5}$ electrode was higher than that of the $LaNi_5$ electrode. Also, the effect of microencapsulation on the deactivation of $LaNi_5$ was studied using an absorption-desorption cycle in CO-containing hydrogen.

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Effects of Operating Variables on Sorption Capacity of CO2 Absorbents for SEWGS Process (SEWGS 공정용 CO2 흡수제들의 흡수능력에 미치는 조업변수들의 영향)

  • Ryu, Ho-Jung;Kim, Hyo-Sung;Lee, Seung-Yong;Lee, Dong-Ho;Kim, Jae-Chang
    • Korean Chemical Engineering Research
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    • v.50 no.6
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    • pp.994-1001
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    • 2012
  • The Effects of operating variables on reactivity of two $CO_2$ absorbents (PKM1-SU and P4-600) for SEWGS process were investigated in a pressurized fluidized bed reactor. For both $CO_2$ absorbents, $CO_2$ sorption capacity decreased as the number of absorption-regeneration cycles increased. PKM1-SU absorbent represented higher $CO_2$ sorption capacity than that of P4-600 absorbent. However, P4-600 absorbent represented better performance than PKM1-SU absorbent from the view points of regeneration temperature and regeneration rate. For PKM1-SU absorbent, $CO_2$ sorption capacity increased as the steam concentration increased. However, $CO_2$ sorption capacity increased initially as the steam concentration increased from 5% to 10%, but maintained thereafter for P4-600 absorbent. For both $CO_2$ absorbents, $CO_2$ sorption capacity increased as the final regeneration temperature increased. For PKM1-SU absorbent, $CO_2$ sorption capacity increased as the pressure increased and the increment tendency was drastic at higher pressure than 15 bar.

An Experimental Study on the Application of Measuring Method of Water Content for Quality Control of Concrete (콘크리트 품질관리를 위한 단위수량 측정 기법의 적용성에 관한 실험적 연구)

  • Kim, Yong-Ro;Choi, Il-Ho;Jung, Yang-Hee;Lee, Do-Bum
    • Journal of the Korea Concrete Institute
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    • v.19 no.2
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    • pp.179-188
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    • 2007
  • Recently, the concern on the receipt of poor ready-mixed concrete in the construction field and the durability of concrete has been increased. Based on the such background, a large number of measuring methods of water content for fresh concrete have been developed and enforced in a developed country. In this study, to investigate practicality for quality control of ready-mixed concrete among various water content measurement techniques, microwave range method, air meter method and capacitance measurement method as measuring methods of water content were selected. Then, it was evaluated estimating performance of water content according to the change of binder types, fine aggregate types, absorption ratio, water content and water-binder ratio in series I and II. Also, it was examined influence on error occurrence of water content according to change of properties of used materials in series III. Finally, based on this study, it was proposed fundamental data to utilize measurement technique of water content to quality control of ready-mixed concrete in construction field.

Study on the Safety of Playground Flooring Made of Polyolefin Foam Waste and Rubber Paving (폐폴리올레핀 폼과 탄성 포장재로 구성된 어린이 놀이터 바닥의 안전성에 관한 실험적 연구)

  • Choi, Soo-Kyung;Jun, Myoung-Hoon;Lee, Do-Heun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.3
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    • pp.246-254
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    • 2013
  • This study is purposed to verify the safety of the floor of the children's playground using polyolefin foam waste and rubber paving. The critical fall height, walking suitability, long term physical fatigue expectation and slipperiness were tested. Polyolefin foam wastes in thickness of 30mm, 50mm and 70mm were prepared with paving the rubber paving materials in 12mm and 15mm thickness respectively. The test on the critical fall height was carried out according to KS G 5758:2009. The floor hardness test equipment (O-Y HMA) was used for the test on hardness of the floor from a viewpoint of walking suitability and fatigue. A portable slipperiness tester (ONO PPSM) was used for slipperiness test. It was revealed from the test that the floor made of the polyolefin foam waste and rubber paving were considerably safe from a viewpoint of impact absorption. With regards to the hardness of the floor, it was shown the excellent performance in the aspects of walking and fatigue for male. But it was not suitable with walking on the shoes(middle heels) for female. And they will be very fatigue if they were in a long time walking or standing. As far as the slipperiness is concerned, it was shown that it was comparatively safe for the ordinary motions even though the surface was wet.

Surface Modification of Nafion by Layer-by-Layer Self-Assembled Films of Polyaniline and Sulfonated Poly(ether sulfone) for Direct Methanol Fuel Cell (직접 메탄올 연료전지용 나피온 막의 폴리아닐린/Sulfonated Poly(ether sulfone) 다층 자기조립 박막에 의한 표면 개질)

  • Ok, Jeong-Rim;Kim, Dong-Wook;Lee, Chang-Jin;Kang, Yong-Ku
    • Journal of the Korean Electrochemical Society
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    • v.11 no.4
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    • pp.256-261
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    • 2008
  • In this study, Nafion membrane was modified to prevent methanol crossover by layer-by-layer self assembly using polyaniline (PANi) as a polycation and sulfonated poly(ether sulfone) (SPES) as a polyanion onto the Nafion surface. Since PANi and SPES possess thermal and chemical stability and rigid backbone, their layer-by-layer self-assembled films on the Nafion are expected to reduce methanol permeability and to increase mechanical stability. UV-Vis absorption spectroscopy verified a linear build-up of the multilayers of PANi and SPES. We found that the thickness per bilayer was about 10 nm by TEM measurement. Although modified Nafion membrane exhibited 15% decrease of proton conductivity, it reduceded 67% of methanol permeability compared to that of the pristine Nafion membrane, resulting in 2.5 times larger selectivity. At the performance test of the fuel cell using 5M methanol as a fuel, the modified Nafion membrane showed 2.4 times higher maximum power density at $30^{\circ}C$ and 1.4 times larger at $60^{\circ}C$ than the pristine Nafion.

Development of $^{192}Ir$ Small-Focal Source for Non-Destructive Testing Application by Using Enriched Target Material (고농축 표적을 이용한 비파괴검사용 $^{192}Ir$ 미세초점선원 개발)

  • Son, K.J;Hong, S.B.;Jang, K.D.;Han, H.S.;Park, U.J.;Lee, J.S.;Kim, D.H.;Han, K.D.;Park, C.D.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.27 no.1
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    • pp.31-37
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    • 2007
  • A $^{192}Ir$ small-focal source has been developed by using the HANARO reactor and the radioisotope production facility at the Korea Atomic Energy Research Institute (KAERI). The small-focal source with the dimension of 0.5 mm in diameter and 0.5 mm in length was fabricated as an aluminum-encapsulated form by a specially designed pressing equipment. For the estimation of the radioactivity, neutron self-shielding and ${\gamma}-ray$ self-absorption effects on the measured activity was considered. From this estimation, it is realized that $^{192}Ir$ small-focal sources over 3 Ci activities can be produced from the HANARO. Field performance tests were performed by using a conventional source and the developed source to take images of a computer CPU and a piece of a carbon steel. The small-focal source showed better penetration sensitivity and geometrical sharpness than the conventional source does. It is concluded from the tests that the focal dimension of this source is small enough to maximize geometrical sharpness in the image taking for the close proximity shots, pipeline crawler applications and contact radiography.