• Title/Summary/Keyword: Absorption enhancement

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Measurement of Water Absorption in Anticorrosive Organic Coatings Using Quartz Crystal Microbalance (QCM) (수정진동자 미세저울을 이용한 방식도막의 물 흡수 측정)

  • 이근대;도윤정;김진호;박성수;홍성수;서차수;박진환
    • Journal of Ocean Engineering and Technology
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    • v.17 no.6
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    • pp.77-82
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    • 2003
  • The absorption of water into an anti-corrosive organic coating, such as alkyd and urethane resin coating, was investigated, using a quartz crystal microbalance (QCM). Anticorrosive properties of the coatings were also measured, by means of electrochemical impedance spectroscopy (EIS). The overall absorption of water in the coating is determined by the chemical nature of resin, and decreases with increasing thickness. The enhancement of anti-corrosive performance, through increase of coating thickness, was more remarkable in the case of the coating that hadlower equilibrium water absorption. The absorption kinetics curves were Fickian in nature. The EIS analysis confirmed that the resin, having lower equilibrium water absorption, shows higher anti-corrosive performan.

Enhancement of carbon dioxide absorption rate with metal nano particles (금속 나노입자를 이용한 이산화탄소 흡수 속도 촉진)

  • Choi, Young Ju;Youn, Min Hye;Park, Ki Tae;Kim, In Ho;Jeong, Soon Kwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.10
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    • pp.6439-6444
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    • 2015
  • With increasing concern about global warming, CCS (Carbon dioxide capture and storage) has attracted much attention as a promising technology for reducing $CO_2$ emission. It is necessary to develop the cost-effective absorbents materials in order to rapid commercialize CCS technologies. In this work, he study for the promotion of absorption rate in $CO_2$ capture system using metal nanoparticle were investigated. Three kinds of metal nanoparticle, cobalt, zinc, and nickel, were prepared by wet and dry method and effect of preparation method on the absorption rate of $CO_2$ were compared. Among the tested using pH method, nickel nanoparticle prepared by wet method showed the most significant improvement of $CO_2$ absorption rate. In case that metal nanoparticle is applied to CCS process, it is expected to be more efficient in $CO_2$ capture process due to reduce the size of absorption tower.

Evaluation of Dispersion Stability and Absorption Performance Enhancement of Binary Nanoemulsion Fluids (이성분 나노에멀전 유체의 분산안정성 및 흡수성능 촉진실험)

  • Lee, Jin-Ki;Kim, Young-Jin;Shin, Myung-Chul;Kim, Se-Won;Kang, Yong-Tae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.9
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    • pp.895-900
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    • 2012
  • This paper aims to examine the effect of nanodroplets on pool-type absorption heat transfer enhancement and to find the relationship between the dispersion stability and the absorption performance. The concentrations of oil and surfactant are considered as the key parameters. $C_{12}E_4$ and Tween20 are used as the surfactants and N-decane oil is added to the $NH_3/H_2O$ solution to make the binary nanoemulsion fluids. Binary nanoemulsion fluids are dispersed by the ultrasonic vibrator and the stirrer under specific conditions. The dispersion stability of binary nanoemulsion fluids for each oil concentrations is evaluated from the droplet size and Tyndall effect analysis. The absorption performance of binary nanoemulsion fluids is compared with the result of dispersion stability. In addition, it is found that the binary nanoemulsion fluid is a strong candidate as a new working fluid for absorption applications.

Effect of Polyoxyethylene Alkyl Esters on Permeation Enhancement and Impedance of Skin

  • Kim, Hee-Sun;Oh, Seaung-Youl
    • Biomolecules & Therapeutics
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    • v.19 no.1
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    • pp.109-117
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    • 2011
  • In this work, we have investigated the effect of polyoxyethylene alkyl ester nonionic surfactants on percutaneous permeation enhancement of a model drug, ketoprofen. We also investigated the mechanism involved in the enhancement using impedance and solubility measurement. Three groups of nonionic surfactants with different ethylene oxide content were studied. The permeation results showed that all surfactants enhanced the percutaneous absorption, irrespective of the molecular weight. The permeation results from PEG-45 monostearate (PEGMS45) were rather unexpected. Impedance and solubility results indicate that the mechanism involved in the enhancement of permeation by PEG-10 monooleate (PEGMO10) and PEGMS45 is rather different. The results from PEGMS45 suggest that it could be a potential candidate as a skin penetration enhancer with high molecular weight, which may poses less skin irritation and systemic side effect than the smaller surfactant molecules. Overall, this work provided some useful information on percutaneous transport enhancement and the mechanistic insights involved in skin permeation for these nonionic surfactants.

Heat Transfer Performance of Plate Type Absorber with Surfactant

  • Yoon, Jung-In;M. M. A. Sarker;Moon, Choon-Geun
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.2
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    • pp.243-251
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    • 2004
  • Absorption chiller/heater can utilize the unused energy of the daily life waste heat, the industry waste heat. the solar energy and the earth energy. These can contribute to energy savings. But the absorption chiller/heater has a demerit that the size of absorption chiller/heater is larger than that of the vapor compression type based on same capacity. In this study. the experimental apparatus of an absorber is manufactured as a plate. which is newly applied in an absorber. The experimental apparatus is composed of a plate type absorber. which can increase the heat exchange area per unit volume and thus facilitating to deeply investigate more detail features instead of that done by the existing type. i.e.. horizontal tube bundle type. The characteristics of heat transfer and refrigeration capacity are studied experimentally. The absorption enhancement by using surfactant is closely examined through the experiment and comparative figures are presented in quantitative and qualitative analysis.

A study on The Application of a Vertical Absorption System Cooled by Air (공냉형 수직 흡수식 시스템의 적용에 관한 연구)

  • 김정국;조금남
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2003.05a
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    • pp.351-357
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    • 2003
  • In absorption system, the performance of the absorber is critical the overall system performance, size, and first-cost. The objective of this paper is to provide a comprehensive review of the significant effects that researchers have made to numerically analysis model the coupled heat and mass transfer process that occur during falling-film absorption and experimental researches. This study includes experimental work in the enhancement of absorption performance, the effect of the geometry of a vertical absorber, and the effect of configuration of absorption system. This paper is used to highlight key areas which need attention such as film ans vapor hydrodynamics, especially the non-periodicity, instability, and recirculatory motion of waves in the vertical absorber case.

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Effect of Wavy Flow of Vertical Falling Film on the Absorption Performance

  • Kim, Jung-Kuk;Cho, Keum-Nam
    • International Journal of Air-Conditioning and Refrigeration
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    • v.13 no.3
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    • pp.158-166
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    • 2005
  • The present study investigated experimentally and numerically the enhancement of absorption performance due to the waviness of falling film in the vertical absorber tube. The momentum, energy and mass diffusion equations were utilized to find out temperature and concentration profiles at both the interfaces of liquid solution and refrigerant vapor and the wall. Flow visualization was performed to find out the wetting characteristics of the falling film. The maximum heat transfer coefficient was obtained for the wavy flow using spring as an insert device through both numerical and experimental studies. Based on the numerical and experimental results, the maximum absorption rate was found for the wavy-flow using spring as the insert device. The differences between experimental and analytical results ranged from $5.0\;to\;25\%\;when\;Re_j>100$.

Effect of Sunlight Polarization on the Absorption Efficiency of V-shaped Organic Solar Cells

  • Kang, Kyungnam;Kim, Jungho
    • Journal of the Optical Society of Korea
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    • v.18 no.1
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    • pp.9-14
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    • 2014
  • We numerically investigate the effect of sunlight polarization on the absorption efficiency of V-shaped organic solar cells (VOSCs) using the finite element method (FEM). The spectral distribution of absorbance and the spatial distribution of power dissipation are calculated as a function of the folding angle for s-and p-polarized light. The absorption enhancement caused by the light-trapping effect was more pronounced for s-polarized light at folding angles smaller than $20^{\circ}$, where s-polarized light has a relatively larger reflectance than p-polarized light. On the other hand, the absorption efficiency for p-polarized light is relatively larger for folding angles larger than $20^{\circ}$, where the smaller reflectance at the interface of the VOSC is more important in obtaining high absorption efficiency.

Enhancement of Absorption Performance Due to the Wavy Film of the Vertical Absorber Tube

  • Kim Jung-Kuk;Cho Keum-Nam
    • International Journal of Air-Conditioning and Refrigeration
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    • v.14 no.2
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    • pp.41-48
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    • 2006
  • Absorption performance at the vertical interface between refrigerant vapor and liquid solution of $LiBr-H_{2}O$ solution was enhanced by the waves formed due to the interfacial shear stress. The present study investigated experimentally and analytically the improvements of absorption performance in a falling film by wavy film flow. The dynamic parameter was the film Reynolds numbers ranged from 50 to 150. The energy and diffusion equations were solved simultaneously to find the temperature and concentration profiles at the interface of liquid solution and refrigerant vapor. Absorption characteristics due to heat and mass transfer were analyzed for the falling film of the LiBr aqueous solution contacted by refrigerant vapor in the absorber. Absorption performance showed a peak value at the solution flow rate of $Re_{f}>100$. Absorption performance for the wavy film flow was found to be greater by approximately 10% than that for uniform film flow. Based on numerical and experimental results, the maximum absorption rate was obtained for the wavy flow caused by spring insert. The difference between the measured and the predicted results were ranged from 5.8 to 12%.

A Study on the Separation of $CO_2$from Flue Gas by Chemical Absorption (화학흡수법에 의한 연소폐가스 중 지구온난화 가스 $CO_2$분리에 관한 연구)

  • 안성우;김영국;송호철;박진원
    • Journal of Energy Engineering
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    • v.6 no.2
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    • pp.203-211
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    • 1997
  • This study is on the separation of Global warming effect gas, CO$_2$by chemical absorption from mixture of CO$_2$-N$_2$which was modeled after flue gas of fire power plant. Investigation of optimum condition for absorbent was carried out by using sparged vessel apparatus. Through packed tower experiments, applicabilities of two absorption models were tested by comparing experimental results with theoretical values. Absorbent used in the experiments was Monoethanolamine (MEA) and gas mixture was made in the mole composition of 15% CO$_2$and 85% N$_2$. Through estimations of CO$_2$loading and CO$_2$removal efficiency, optimum concentration of absorbent was found in the range of 4-5 M. To find a rate of absorption, an enhancement factor was introduced. Values of rate of absorption were calculated by Film model and Higbie model, respectively. Higbie model showed good agreement with experimental results. Therefore, this models is considered to be applicable to the CO$_2$separation process for flue gas from fire power plant.

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