• Title/Summary/Keyword: Absorption edge

Search Result 269, Processing Time 0.024 seconds

Study on the Color of High Index Glass Containing $TiO_2$ ($TiO_2$ 함유 고굴절솔 유리의 착색에 관한 연구)

  • 김병훈
    • Journal of the Korean Ceramic Society
    • /
    • v.17 no.4
    • /
    • pp.203-207
    • /
    • 1980
  • The optical absorption of high index glasses of the system TiO2-BaO-B2O3 prepared from the raw materials for an optical waveguide glass has been measured in the near ultraviolet region. The amount of Ti3+ in the glass could be reduced to a level less than 5 ppm by melting a batch added with pure nitric acid, using a fused quartz crucible in an oxygen gas atmosphere. The ultra-pure glass of 10mm thick prepared in such a way did not show any appreciable color even for the one containing 30 mol% TiO2 and having refractive index nD of 1.84 and Abbe's number vD of 28.8. The wavelength of ultraviolet absorptin edge was longer for the glass of higher index and higher dispersdion. The melting of a TiO2 containing glass in a platinum crucible resulted in a coloration of the glass due to the dissolved plutinum from the crucible, which was more intense for the one containing larger amount of TiO2.

  • PDF

Development of Noise Barrier Analysis Program (방음벽해석 프로그램의 개발)

  • Kim, Hyun-Sil;Kim, Jae-Seung;Kang, Hyun-Ju;Kim, Bong-Ki;Kim, Sang-Ryul
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
    • /
    • 2007.11a
    • /
    • pp.960-963
    • /
    • 2007
  • In this paper, development of the noise barrier analysis program is described. The upper part of barriers may have complicated shapes like "Y", "T", inverted L, and other shapes. The insertion loss of the barrier is predicted by summation of multiple diffractions occurring at top edge points. In addition, the program considers diffractions occurring at both vertical sides, while reflections from ground due to mirror images are also included. In case of two barriers at both sides of the road, reflections from the other side of barriers are considered, in which magnitudes are decreased by the ratio of absorption coefficient.

  • PDF

Preparation and Characterization of Ultra Thin TaN Films Prepared by RF Magnetron Sputtering

  • Reddy, Akepati Sivasankar;Jo, Hyeon-Cheol;Lee, Gi-Seon
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2011.10a
    • /
    • pp.32.1-32.1
    • /
    • 2011
  • Ultra thin tantalum nitride (TaNx) films with various thicknesses (10 nm to 40 nm) have been deposited by rf magnetron sputtering technique on glass substrates. The as deposited films were systematically characterized by several analytical techniques such as X-ray diffraction, X-ray photoelectron spectroscopy, field emission scanning electron microscopy, atomic force microscopy, UV-Vis-NIR double beam spectrophotometer and four point probe method. From the XRD results, the as deposited films are in amorphous nature, irrespective of the film thicknesses. The films composition was changed greatly with increasing the film thickness. SEM micrographs exhibited the densely pack microstructure, and homogeneous surface covered by small size grains at lower thickness deposited films. The surface roughness of the films was linearly increases with increasing the films thickness, consequently the transmittance decreased. The absorption edge was shifted towards higher wavelength as the film thickness increases.

  • PDF

Investigation of the ZnO based TFT interface properties with synchrotron radiation analysis

  • Choi, Jong-Kwon;Baik, Min-Kyung;Joo, Min-Ho;Park, Kyu-Ho;Lee, Jay-Man;Kim, Myung-Seop;Yang, Joong-Hwan
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2007.08b
    • /
    • pp.1298-1300
    • /
    • 2007
  • The interface between SiNx and ZnO was investigated with Near Edge X-ray Absorption Fine Structure (NEXAFS) for ZnO based thin film transistor (TFT) applications. Impurity species were interstitial $N_2$ molecules at the SiNx / ZnO interface. The evolution of $N_2$ is decreased with increasing of anneal temperature.

  • PDF

The effect of ZnS on the Characteristics of CdZnS thin films (ZnS첨가에 따른 CdZnS박막 특성에 관한 연구)

  • 이재형;남준현;송우창;박용관
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1995.11a
    • /
    • pp.40-43
    • /
    • 1995
  • In this paper, structual, optical and electrical properties of CdZnS thin films prepared by electron beam evaporation method were studied. The crysta1 structure of CdZnS films deposited was hexagonal type with preferential orientation of the (002) plane parallel to the substrate. The results of optical transmittance of the CdZnS film show that absorption edge is shifted to ZnS and optical bandgap was larger wish increasing ZnS content. The resistivity of the CdZnS film is decreasing with increasing ZnS content and mininum for 20 mole%.

  • PDF

Nanospace Confinement of Conducting Polymers using Mesoporous Silica and Organosilica

  • Itahara, Hiroshi;Inagaki, Shinji;Asahi, Ryoji
    • Proceedings of the Polymer Society of Korea Conference
    • /
    • 2006.10a
    • /
    • pp.277-277
    • /
    • 2006
  • Conducting polymers (e.g. poly[2-methoxy-5-(2'-ethyl-hexyloxy)-1,4-phenylen vinylene] (MEH-PPV)) confined in one-dimensional nanoscale channels of mesoporous materials, are expected to lead the novel applications for electroconductive and optoelectronic devices. We investigated the adsorption behavior of MEH-PPV on organically surface-modified mesoporous silica (FSM-16) and mesoporous organosilica. The amount of the confined MEH-PPV was found to strongly depend on the surface modifications of the mesoporous materials. The optical absorption edge of the confined MHE-PPV was clearly blue-shifted when compared to that of a free MHE-PPV.

  • PDF

Deposition of Heavy Metal Oxide Glass Thin Films by R.F. Magnetron Sputtering (스퍼터링 방법을 이용한 중금속 산화물 유리 박막의 증착)

  • Kim, Woong-Kwern;Heo, Jong;Je, Jung-Ho
    • Journal of the Korean Ceramic Society
    • /
    • v.32 no.6
    • /
    • pp.669-676
    • /
    • 1995
  • In this study, EO glass films were deposited by R.F. magnetron sputtering using EO glass target. The glass formation of the EO film was greatly dependent on the substrate temperature and the crystallization started at approximately 28$0^{\circ}C$. As the temperature of the substrate or the oxygen content in the sputtering gas increased, UV/VIS/NIR absorption edge moved toward longer wavelength. A wave guiding phenomenon was observed from the prism-coupler experiment and a fluorescence of 1.06${\mu}{\textrm}{m}$ originated from 4Fe3/2longrightarrow4I11/2 transition of Nd3+ was detected from the film containing Nd3+ ions.

  • PDF

A study on the properties of amorphous (Se,S)-system thin films for reversible hologram device development (가역적 Hologram 소자개발을 위한 비정질 (Se,S)계 박막 특성에 관한 연구)

  • 김상덕;이재규;김종빈
    • Journal of the Korean Institute of Telematics and Electronics A
    • /
    • v.31A no.12
    • /
    • pp.71-79
    • /
    • 1994
  • In this paper, $As_{40}Se_{50-x}S_[x}Ge_{10}$(x=0, 25, 35, at.%) bulk and thin films, to develope device of reversible hologram, proved amorphous by X-RD analysis. On the thin films with composition rate, as Se-doped-quantity increased, absorption edge shifted to long wavelength, and we found that reversible photodarkening effect occurred when thin films are exposed and annealed. Optical energy gap was larger when thin films are annealed than exposed. In this effect thin films structurally stabilized by annealing. It is to formed grating hologram by the bragg method on the $As_{40}Se_{15}S_[35}Ge_{10}$ thisn films with the best transmittance properties As polariging angle grew larger, we found that maximum diffraction efficiency became smaller, and obtained it of 4.5% on the thin fim thicknesss of 0.6 m, polarizing angle of 40$^[\circ}$ and exposing for 20sec.

  • PDF

Boundary Element Analysis of Singular Stresses in a Viscoelastic Thin Film due to Moisture Absorption (수분 흡수로 인해 점탄성 필름에 발생하는 특이 응력의 경계요소해석)

  • Lee, Sang-Sun
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.24 no.3 s.174
    • /
    • pp.685-690
    • /
    • 2000
  • This paper deals with the stress singularity induced at the interface corner between the viscoelastic thin film and the rigid substrate as the film absorbs moisture from the ambient environment. Th e time domain boundary element method is employed to investigate the behavior of interface stresses. The order of the free-edge singularity is obtained numerically for a given viscoelastic model. It is shown that the stress singularity factor is relaxed with time, while the order of the singularity increases with time for the viscoelastic model considered.

Reaction of NO on Vanadium Oxide Surfaces: Observation of the NO Dimer Formation

  • Jeong, Hyun-Suck;Kim, Chang-Min
    • Bulletin of the Korean Chemical Society
    • /
    • v.28 no.3
    • /
    • pp.413-416
    • /
    • 2007
  • The adsorption and surface reactions of NO on a VO/V(110) surface have been investigated using X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine structure, and temperature programmed desorption (TPD) technique. NO is molecularly adsorbed on VO/V(110) at 80 K. As the surface coverage of NO increases, the NO dimer is formed on the surface at 80 K. Both NO and (NO)2 are adsorbed on the surface with the N-O bond perpendicular to the surface. (NO)2 decomposes at ~100 K and the reaction product is desorbed as N2O. Decomposition of NO takes place when the surface temperature is higher than 273 K.