• Title/Summary/Keyword: Absorption Features

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Difference in the spatial distribution between $H_2O$ and $CO_2$ ices in M 82 found with AKARI

  • Yamagishi, Mitsuyoshi;Kaneda, Hidehiro;Oyabu, Shinki;Ishihara, Daisuke;Onaka, Takashi;Shimonishi, Takashi;Suzuki, Toyoaki;Minh, Young Chol
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.34.1-34.1
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    • 2013
  • Interstellar ices (e.g., $H_2O$, $CO_2$, and CO ices) are formed on the surface of dust grains in dense molecular clouds. In a near-infrared spectrum, we can observe deep absorption features particularly due to $H_2O$ ice at $3.05{\mu}m$ and $CO_2$ ice at $4.27{\mu}m$. These interstellar ices have many pieces of information on the interstellar environment. Among various ices, $CO_2$ ice is one of the most important ones as a probe of the interstellar environment. That is because $CO_2$ ice is a secondary product unlike $H_2O$ and CO ices which are primarily formed on dust grains. Past studies for $CO_2$ ice in nearby galaxies were performed only for the galactic center in a few galaxies. In order to utilize the information from $CO_2$ ice effectively, it is valuable to perform mapping observations of ices on a galactic scale. With AKARI, we obtain the spatially-resolved near-infrared ($2.5-5.0{\mu}m$) spectra for the central ~1 kpc region of the nearby starburst galaxy M 82. These spectra clearly show the absorption features due to interstellar $H_2O$ and $CO_2$ ices, and we created their column density maps. As a result, we find that the spatial distribution of $H_2O$ ice is significantly different from that of $CO_2$ ice; $H_2O$ ice is widely distributed, while $CO_2$ ice is concentrated near the galactic center. Our result for the first time reveals spatial variations in $CO_2/H_2O$ ice abundance ratio on a galactic scale, suggesting that the ice-forming interstellar environment changes within a galaxy. In this presentation, we discuss the cause of the variations in the ice abundance ratio.

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A Study on the Availability of Pohang's Mudstone as a Reclamation Material (매립재로서 포항지역 이암의 유용성에 관한 연구)

  • Lee, Kyu-Hwan;Jung, Dae-Suck;Yang, Tae-Sun
    • Journal of the Korean Geotechnical Society
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    • v.23 no.8
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    • pp.149-158
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    • 2007
  • Recently, the selection of procurement material for reclamation or road at Pohang area is getting harder. so, it is attempted that mudstones are used for road base material and harbor reclamation. But there is no example that use mudstone to reclamation and the features of the reclaimed land using mudstones have not been made clear yet. We will make clear these features-especially the water absorption and softening, slaking behavior and the geological mechanism, so we will obtain the method to forecast a land subsidence and a decline of land strength. In this study, we examined the adaptedness judgment of mudstones as a reclamation material for road basis material or harbor reclamation material through the laboratory test and pilot test.

Changes of Sound Absorption Capability of Wood by Organosolv Pretreatment (유기용매 전처리에 의한 목재의 흡음성능 변화)

  • Kang, Chun-Won;Choi, In-Gyu;Gwak, Ki-Seob;Yeo, Hwan-Myeong;Lee, Nam-Ho;Kang, Ho-Yang
    • Journal of the Korean Wood Science and Technology
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    • v.40 no.4
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    • pp.237-243
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    • 2012
  • Sound absorption capability and anatomical features of the organosolv pretreated Japanese larch and yellow poplar wood were estimated by stereoscopic observation and two microphone transfer function method. Sound absorption capabilities of organosolv treated wood, in the entire estimated frequency range (50~6,400 Hz), were higher than those of control specimen. Especially, the treated wood's absorption capabilities measured in the frequency range of 2~4 kHz were about two times higher than those of control specimen. By the organosolv pretreatment (at $70{\sim}120^{\circ}C$), the weight loss of wood occurred in less than 1% of total weight of wood and the porosity of wood increased slightly. In addition, it was presupposed that microstructural changes of wood occurred during organosolv pretreatment and this structural changes cause the increasing of the sound absorption capability of wood.

A study on the adsorption characteristic and safety assessment of railway subsoil material (철도 노반 재료의 중금속 흡착특성과 안전성에 관한 연구)

  • Paek, Seoungbong;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.17 no.2
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    • pp.146-154
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    • 2015
  • Domestic railway industry has grown in numbers, scale of railway ndustrial and operation because was focused on an environmentally sustainable transportation. However, it is not enough to treat and prevent heavy metals which occur as the railway operation increases. The heavy metals occurred when the operating railway and it will be flow into water system with rainfall effluent during rainfall. will flow out along with the rainfall effluent when rainfall comes. In case of a railway bridge, In particular, heavy metals were flow into the water system without any treatment from railway bridges where located nearby rivers and lakes. So, rainfall effluent from railway facilities was occurred pollution of water system. For the prevent of heavy metal runoff during rainfall, the adsorptivity of material in railway roadbed is important.In this study, adsorptivity of gravel which is main gravel and blast-furnace slag were conducted adsorption test and deducted Freundlich's and Langmuir's isothermal adsorption equations. Safety as railway subbase course material was evaluated using modeling. As a result, absorption amount of slag, Cd and Cu, was shown higher than gravel and Pb along with Zn showed higher absorption amount of gravel. However, absorption amount of slag was shown higher than gravel used as railway subbase course material as time passes by. Absorption features had more suitable determination coefficient of heavy metals in warm absorption type such as Langnmuir compared to warm absorption type like Freundlich. To add, they showed less transformation by about 10% compared to gravel in safety evaluation through modeling. This is a railway subbase course material that prevents water outflow of heavy metal thus we can know slag is needed to be used.

A Study on the Physical Characteristics of Building Stone Resources (석재자원에 대한 물리적 특성에 관한 연구)

  • 이창신;강추원;정순오
    • Explosives and Blasting
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    • v.22 no.1
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    • pp.81-91
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    • 2004
  • Samples examined in this paper were selected from Samwoo building stone, Sinra building stone, Gana building stone, and Chung gin building stone in Kyunggi province and Whakwang industry, Gomoch building stone, and Sejin building stone in Kyungbuk province. The point of this study is to examine the physical and mechanical features of Pochun rock, Munkyung rock and Ildong rock through specific gravity, porosity, absorption, point load test, triaxial compressive test Brazilian test, petrology test and chemical analysis test.

Synthesis and Characterization of a New PPV Derivative Containing a Sterically Hindered 2,5-Dimethylphenyl Group

  • Kim, Yun-Hi;Lee, Hyun-Ouk;Lee, Ki-Suk;Kwon, Soon-Ki
    • Macromolecular Research
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    • v.11 no.6
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    • pp.471-475
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    • 2003
  • A new poly[2-(2',5'-dimethylphenyl)-1,4-phenylenevinylene] (PDMPPV) that features a bulky 2',5'-dimethylphenyl substituent, which can induce steric hindrance between the PPV backbone and the methyl groups, was designed and synthesized. The polymer structure having no TBB defects was confirmed by $^1$H-NMR and $\^$13/CNMR spectroscopy. The polymer showed good thermal stability with high T$\_$g/. The polymer film showed a maximum absorption at 415 nm with an absorption onset at 480 nm. The maximum emission peak showed at ca. 515 nm, with a shoulder at 530 nm. The turn-on voltages of ITO/PEDOT/PDMPPV/Al and ITO/PDMPPV/Al devices were 8 and 10 V, respectively. The electroluminescence spectrum from the device showed a maximum peak at 510 nm with a shoulder at ca. 535 nm.

A Scheme to Control Laser Power and Exposure Time for Fabricating Precise Threedimensional Microstructures in Nano-stereolithography (nSL) Process (3 차원 나노 스테레오리소그래피의 정밀화를 위한 펨토초 레이저 출력-조사시간 제어방법)

  • 박상후;임태우;양동열
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.1365-1368
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    • 2004
  • A scheme to control the laser power and the exposure time was studied to fabricate precise microstructures using the nanostereolithography (nSL) process. Some recent works have shown that a three-dimensional (3D) microstructure can be fabricated by the photopolymerizing process which is induced by two-photon absorption (TPA) with a femtosecond pulse laser. TPA provides the ability to confine photochemical and physical reactions within the order of laser wavelength, so neardiffraction limit features can be produced. In the nSL process, voxels are continuously generated to form a layer and then another layer is stacked in the normal direction of a plane to construct a 3D structure. Thus, fabrication of a voxel with low aspect ratio and small diameter is one of the most important parameters for fabricating precise 3D microstructures. In this work, the mechanism of a voxel formation is studied and a scheme on the control of laser power and exposure for minimizing aspect ratio of a voxel is proposed.

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The study of the $BiO_{6}$ octahedra structure in superconducting $Ba_{0.6}K_{0.4}BiO_3$ single crystal by extended x-ray absorption spectroscopy (EXAFS에 의한 $Ba_{0.6}K_{0.4}BiO_3$ 단결정의 초전도 상태에서 $BiO_{6}$ octahedra 구조의 연구)

  • 김봉준;김영철;김현탁;강광용;이재민
    • Progress in Superconductivity
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    • v.4 no.2
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    • pp.148-152
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    • 2003
  • We have observed the temperature dependences of Bi $L_{III}$ edge spectra by extended X-ray absorption spectroscopy for a high quality single crystal and a powder of the $Ba_{0.6}K_{0.4}BiO_3$ superconductor. $Ba_{0.6}K_{0.4}BiO_3$ has the cubic structure and metallic states. The deformation of the $BiO_{6}$ octahedra, which is due to the anomalies of the Bi-O and Bi-Ba bond length, was showed by the double-shell fit. It was clearly found that these anomalies are owing to the difference in the strength of Bi-O bonds. The temperature dependences of both bond lengths and the Debye-Walter factor ${\sigma}^2$ of the Bi-O and Bi-(Ba,K) bond are discussed to illustrate local structural features of the $Ba_{0.6}K_{0.4}BiO_3$

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Noise Map Analysis for the Design of Noise Barrier at School Site (학교부지의 방음벽 설계를 위한 소음지도 해석)

  • Yun, Junho;Kim, Wonjin
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.4
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    • pp.232-238
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    • 2012
  • In this study, the noise mapping simulation is executed to design an effective barrier reducing noise levels of a school site. The geographical features of the ambient site and the school buildings are modelled in detail in order to consider sound propagation, deflection, and absorption phenomena etc. The main sound source, sound power level of expressway, is estimated on the basis of measured noise levels at several points of the site. The noise mapping simulation is performed by using ENPro, environmental noise prediction program based on ISO 9613 to analysis the effectiveness of noise barrier. Consequently, the noise barrier is designed to meet an environmental noise standard and satisfy low cost and safety conditions.

QUANTITATIVE FT-IR ANALYSIS FOR CHONDRITIC METEORITES: SEARCH FOR $C_{60}$ IN METEORITES

  • Kim, Chung-Lee;Yang, Jong-Mann
    • Journal of Astronomy and Space Sciences
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    • v.15 no.1
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    • pp.151-162
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    • 1998
  • Infrared absorption spectra of 9 bulk samples and 3 acid residues of meteorites were obtained in the mid-infrared region ($4000~400cm^{-1}$). From the know composition of meteorites studied, the possible absorption modes were investigated. Most bands of bulk samples occur in the region below $1200cm^{-1}$ and they are due to metallic oxides and silicates. The spectra of each group can be distinguished by its own characteristic bands. Acid residues show very distinct features from their bulk samples, and absorp-tion bands due to organic compounds are not evident in their spectra. Quantiative analyses for two carbonaceous (Allende CV3 and Murchison CM2) and one ordinary (Carraweena L3.9) chondrites were performed for the presence of fullerene ($C_{60}$) in the meteorites. We calculated the concentration of $C_{60}$ in the acid residues by curve-fitting the spectra with Gaussian functions. The upper limit of $C_{60}$ concentration in these meteorites appears to be less than an order of a few hundred ppm.

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