• Title/Summary/Keyword: Absorption/Adsorption

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Basic Properties of Permeable Block mixed with Diatomite (규조토를 혼입한 투수블록의 기초특성)

  • Kim, Min-Ho;Choi, Byung-Cheol;Yoo, Jae-Gyun;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.123-124
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    • 2021
  • Recently, the danger of fine dust has emerged worldwide. In general, fine dust refers to particulate matter less than 10㎛ and ultrafine dust less than 2.5㎛, and according to the announcement by HEI (Health Impact Research Institute) in 2015, the concentration of ultrafine dust in Korea is the second highest among OECD member countries. It was investigated. In this study, an experiment was conducted to analyze how the diatomaceous earth substitution rate affects the strength characteristics of the permeable block. As the replacement rate of diatomaceous earth increased, the strength decreased. The reason why the strength decreases with the use of diatomaceous earth is that the strength of the hardened body decreases as the structure of the hardened body becomes less dense as the amount of diatomaceous earth increases, and the reason that the strength decreases as the replacement rate of diatomaceous earth increases is the reason for the absorption performance of diatomaceous earth. Therefore, it is judged that a void was generated inside the hardened body while water was absorbed and then evaporated or discharged in the matrix, and accordingly, the strength decreased.

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Properties of Matrix According to the Replacement Ratio of Portland Cement-based Carbonation Sluge (시멘트 기반 탄화슬러지 치환율에 따른 경화체의 특성)

  • Kang, Yong-Mo;Lee, Hye-Eun;Lee, Sang Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.189-190
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    • 2021
  • Recently, the spread of intense social distancing and untact culture due to COVID-19 has increased the time spent indoors. In addition, according to the International Cancer Institute, fine dust was classified as a first-class carcinogen, a substance found to be carcinogenic, such as asbestos and benzene. As a result, interest in indoor air quality is increasing, and many studies are underway to reduce air pollutants. This study is a basic experiment of a board made to improve indoor air quality. The basic characteristics of the board, flexural strength and compressive strength, are analyzed and the results of the test are as follows. Experiments have shown that flexural strength and compressive strength tend to decrease as the replacement rate of hydrocarbons increases. It is believed that the strength of the sludge has decreased due to the increase in internal voids due to the increase in non-surface area, volume and diameter of microfiber as it undergoes the carbonation process. In addition, it is believed that the amount of moisture needed for curing during the mixing process was reduced due to the absorption of hydrocarbons.

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Dyeability and Functionality of Dried Dendropanax morbiferus Extracts (건조 황칠나무 부위별 추출물을 이용한 견직물의 염색성과 기능성)

  • Dayae Kang;Jungsoon Lee
    • Textile Coloration and Finishing
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    • v.35 no.2
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    • pp.67-81
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    • 2023
  • This study aims to examine the possibility of using dried Dondropanax morbiferus extract as a functional dye. The leaves and branches of were extracted with distilled water and 30% ethanol, and the dyeability and functionality of silk fabrics were examined according to the color characteristics of the extract and dyeing conditions. As a result of analyzing the ultraviolet and visible light absorption spectrum of the extract, it was possible to confirm the peak of flavonoid belonging to polyphenol, and the peak of riboflavin expressing yellow color was confirmed. Adsorption equilibrium was observed at 4% dyeing concentration and 60 minutes of dyeing time, and as the temperature increased, dyeing amount increased without color change of Y-series. Aluminum mordanting also increased the yellow color. The color fastness of washing and UV irradiation was low, but the color fastness of rubbing was evaluated as relatively good. The silk fabric dyed with the distilled water extract of the leaves showed a 99.9% bacteriostatic reduction against Staphylococcus aureus and Klebsiella pneumoniae, showing excellent antibacterial properties.

Determination of copper(II) in various samples by flame atomic absorption spectrophotometry after column separation by adsorption of its N-benzoylphenylhydroxylamine complex on benzophenone

  • Park, Moon-Hee;Choi, Hee-Seon
    • Analytical Science and Technology
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    • v.20 no.1
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    • pp.55-60
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    • 2007
  • A sensitive technique for the determination of trace Cu(II) in various samples after the column preconcentration by adsorbing its N-benzoylphenylhydroxylamine (BPHA) onto benzophenone was developed. Several experimental conditions such as the pH of the sample solution, the amount of chelating agent, the amount of benzophenone, and the flowrate of sample solution and so forth were optimized. The interfering effects of diverse concomitant ions were investigated. Fe(III) and $CN^-$ interfered with more seriously than any other ions. However, the interference by these ions could be overcome sufficiently by adjusting the added volume of 0.01M BPHA to 10 mL. The dynamic range, the correlation coefficient ($r^2$) and the detection limit obtained by this proposed technique were 5.0~120 ng/mL, 0.9974, and 2.1 ng/mL, respectively. For validating this proposed technique, the aqueous samples (stream water, reservoir water, and wastewater), the plastic sample and the diluted brass sample were used. Recovery yields of 93~102% were obtained. These measured data were not different from ICP-MS data at 95% confidence level. This method was also validated by the rice flour CRM (normal, fortified) samples. Based on the results from the experiment, it was found that this proposed technique could be applied to the determination of Cu(II) in various real samples.

Noncement-based Hydroball Evaluation of Permeable Block Strength Properties (무시멘트 기반 하이드로볼을 활용한 투수블록의 강도 특성)

  • Hwang, Woo-Jun;Lee, Chang-Woo;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.207-208
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    • 2022
  • Since 1960, the green area has decreased due to rapid urbanization and the artificial surface has increased, and the repair and water function of the previous surface has decreased due to the decrease in rainwater absorption capacity. In addition, the risk of carbon dioxide and fine dust is emerging due to the use of fossil fuels due to urbanization. As a result, permeable blocks, an eco-friendly product, are in the spotlight. Therefore, this study was conducted to examine the strength properties of the permeable block using a hydroball. As a result of the experiment, the flexural strength and compressive strength tended to decrease as the hydroball replacement rate increased. It is judged that the hydroball absorbs a large amount of moisture during the mixing process and lacks moisture required for curing, resulting in a decrease in strength. According to KS F 4419, since the hydroball replacement rate is satisfied up to 20%, further research is needed to analyze the adsorption performance of air pollutants in the future and evaluate their utilization as a permeable block in the future.

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Drug Delivery Study on Chitosan Nanoparticles Using Iron Oxide (II, III) and Valine (Iron Oxide(II, III)와 Valine을 이용한 키토산 나노입자의 약물전달 연구)

  • Jang, So-Hyeon;Kang, Ik-Joong
    • Korean Chemical Engineering Research
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    • v.59 no.4
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    • pp.514-520
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    • 2021
  • A drug delivery system (DDS) based on nanoparticles has been used as a mediator to improve the efficacy of a drug by controlling the amount of drug released and delivering it to a target place. Chitosan, which is non-toxic and biodegradable, has good biocompatibility and excellent adsorption, so it can be used as a drug delivery vehicle. Valine, the essential amino acids, helps muscle growth and tissue recovery, and along with other amino acids. It lowers blood sugar levels and increases growth hormone production. In this study, Valine was adsorbed on magnetic chitosan which is capable of drug absorption, and Fe3O4-Valine CNPs was prepared through cross-linking with TPP (Tripolyphosphate). And then absorption and release trends of valine were investigated with the Fe3O4-Valine CNPs. Fe3O4, which has relatively high stability, is used to make the drug carrier magnetic so that the drug can be delivered to a target place. At optimal conditions, the absorption and release tendency of Fe3O4-Valine CNP was confirmed by analyzing by UV-Vis through the Ninhydrin test which is the color reaction of amino acids and by measuring the size of the particles, it was confirmed that it is suitable as a drug carrier.

Enhancement of Antioxidant and Skin Cancer Inhibition Effects by Fermented Luffa aegyptiaca Extract (수세미오이 발효추출물의 항산화 및 피부암 억제 효과)

  • Kim, Song Yi;Gam, Da Hye;Kim, Jun Hee;Yeom, Suh Hee;Park, Jae-Hyun;Kim, Jin Woo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.3
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    • pp.408-414
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    • 2021
  • This study aimed to improve the production of bioactive materials with antioxidant activity using a fermented Luffa aegyripia extract and improve the anticancer effect by enhancing UV absorption and inhibiting melanoma cell growth. The total phenolic content (TPC) and antioxidant activity of the fermented extract were 30.23 mg GAE/g DM and 45.12%, respectively, which was 1.4 times higher than that of the hot-water extract (HWE). The fermented extract showed a UV adsorption rate of 53.9%, which was 1.5 times higher than HWE, and it was concluded that UV absorption was increased by TPC, which was increased through the fermentation of L. aegyptiaca extracts using Lactobacillus. In the anticancer effect test, fermented and HWE extracts had carcinogenic effects of 1.0 and 2.0 mg/mL, respectively. This suggests that the increased antioxidant activity due to the increase in TPC caused by fermentation contributed to the anticancer effect. The UV absorption rate of fermented extracts was 2.4 times higher than HWE, giving them potential use as cosmetics and pharmaceutical materials with high polyphenol contents and antioxidant properties and skin cancer prevention.

Feasibility of Activated-Carbon Adsorbent to Sequester Sunken Hazardous and Noxious Substances (HNS) (흡착제를 이용한 침강 HNS 처리 및 현장적용 가능성 연구 - 현장 처리를 위한 활성탄소 활용 조건 검토 및 제안 -)

  • Choi, Ki-young;Kim, Chang-joon;Kim, Hye-eun;Jung, Jun-mo;Hwang, Ho-jin;Lee, Moonjin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.7
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    • pp.858-863
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    • 2020
  • We experimented with the particle-settling velocity and CHCl3 absorption efficiency of seven activated-carbon and analyzed seven heavy metal contents by elution for application to the field treatment of sunken HNS on the marine seabed. The mean particle-settling velocity was in the range 0.5-8 cm/s, except when the 8-20 mesh was used. The larger the HNS particle, the faster the particle-settling velocity was, and the CHCl3 absorption efficiency increased considerably owing to the larger surface area. In addition, the elution test results showed that the total Zn and As contents in >100-meshed activated carbon was higher than the contents criteria for the standard for water-treatment agents, and Cr, Zn, and As were released at higher concentrations than those released by other activated-carbon groups. Taken together, the CHCl3 absorption efficiency, settling velocity, and elution test results suggested that the 20-60, 20-40, and 2mm&down mesh activated-carbon adsorbents could be applied to the field treatment of HNSs and that the minimum required amount for field treatment were 0.82, 0.90, and 1.28 ton/㎘, respectively, as calculated based on the HNS-adsorption-capacity priority.

An IRS Study on the Adsorption of Carbonmonoxide on Silica Supported Ni-Cu Alloys (실리카 지지 니켈-구리 합금에서 일산화탄소의 흡착에 관한 IRS 연구)

  • Ahn, Jeong-Soo;Yoon, Koo-Sik;Park, Sang-Youn;Park, Sung-Kyun
    • Journal of the Korean Chemical Society
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    • v.53 no.3
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    • pp.233-243
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    • 2009
  • We have investigated the infrared spectra for CO adsorbed on silica supported nickel(Ni-Si$O_2$), silica supported copper(Cu-Si$O_2$), silica supported nickel-copper alloys(Ni/Cu-Si$O_2$) of several compositions with varying CO pressures(0.2 $torr{\sim}$50 torr) at room temperature and on pumping to vacumn at room temperature within the frequency range of 1500 $cm^{-1}{\sim}2500\;cm^{-1}$. Four bands(2059.6 $cm^{-1},\;{\sim}$2036.5 $cm^{-1},\;{\sim}$ 1868.7 $cm^{-1},\;{\sim}$ 1697.1 $cm^{-1}$) were observed for Ni-Si$O_2$, two bands($\sim$2115.5 $cm^{-1},\;{\sim}$1743.0 $cm^{-1}$) were observed for Cu-Si$O_2$ and five bands(${\sim}2123.2\;cm^{-1}$, 2059.6 $cm^{-1},\;{\sim}$2036.4 $cm^{-1},\;{\sim}$1899.5 $cm^{-1},\;{\sim}$1697.1 $cm^{-1}$) were observed for Ni/Cu-Si$O_2$. These absorption bands correspond with those of the previous reports approximately. The bands below 1800 $cm^{-1}$ were only observed with Ni metal or Ni/Cu alloy crystal plane containing step at room temperature and the ${\sim}1697.1\;cm^{-1}$ bands observed with Ni-Si$O_2$ and Ni/Cu-Si$O_2$ may be ascribed to CO molecule adsorbed on the adsorption sites near step. The bands below 2000 $cm^{-1}$ were rarely observed with Cu metal crystal plane at room temperature and the 1743.0 $cm^{-1}$ bands may be ascribed to CO molecule adsorbed on the adsorption sites near step. The band shifts of adsorbed CO with varing Cu contents from 0 to 0.5 mole fraction at the same CO pressure or at the same pumping time to vacumn were below 21 $cm^{-1}$. and comparatively small than those with other ⅠB metal addition. It may means ligand effect of Cu d electron is small.

Prioritization of Species Selection Criteria for Urban Fine Dust Reduction Planting (도시 미세먼지 저감 식재를 위한 수종 선정 기준의 우선순위 도출)

  • Cho, Dong-Gil
    • Korean Journal of Environment and Ecology
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    • v.33 no.4
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    • pp.472-480
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    • 2019
  • Selection of the plant material for planting to reduce fine dust should comprehensively consider the visual characteristics, such as the shape and texture of the plant leaves and form of bark, which affect the adsorption function of the plant. However, previous studies on reduction of fine dust through plants have focused on the absorption function rather than the adsorption function of plants and on foliage plants, which are indoor plants, rather than the outdoor plants. In particular, the criterion for selection of fine dust reduction species is not specific, so research on the selection criteria for plant materials for fine dust reduction in urban areas is needed. The purpose of this study is to identify the priorities of eight indicators that affect the fine dust reduction by using the fuzzy multi-criteria decision-making model (MCDM) and establish the tree selection criteria for the urban planting to reduce fine dust. For the purpose, we conducted a questionnaire survey of those who majored in fine dust-related academic fields and those with experience of researching fine dust. A result of the survey showed that the area of leaf and the tree species received the highest score as the factors that affect the fine dust reduction. They were followed by the surface roughness of leaves, tree height, growth rate, complexity of leaves, edge shape of leaves, and bark feature in that order. When selecting the species that have leaves with the coarse surface, it is better to select the trees with wooly, glossy, and waxy layers on the leaves. When considering the shape of the leaves, it is better to select the two-type or three-type leaves and palm-shaped leaves than the single-type leaves and to select the serrated leaves than the smooth edged leaves to increase the surface area for adsorbing fine dust in the air on the surface of the leaves. When considering the characteristics of the bark, it is better to select trees that have cork layers or show or are likely to show the bark loosening or cracks than to select those with lenticel or patterned barks. This study is significant in that it presents the priorities of the selection criteria of plant material based on the visual characteristics that affect the adsorption of fine dust for the planning of planting to reduce fine dust in the urban area. The results of this study can be used as basic data for the selection of trees for plantation planning in the urban area.