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The Dielectric Properties of $BaTiO_3/SrTiO_3$ Heterolayered Thick Films with Stacking Periodicity (적층주기에 따른 $BaTiO_3/SrTiO_3$ 이종층 후막의 유전 특성)

  • Lee, Yoe-Bok;Choi, Eui-Sun;Lee, Moon-Kee;Ryu, Ki-Won;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 2004.11a
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    • pp.194-196
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    • 2004
  • $BaTiO_3/SrTiO_3$ heterolayered thick films on the $Al_2O_3$ substrate by screen printing method with stacking periodicity. The stacking periodicity of $BaTiO_3/SrTiO_3$ heterolayer structure was varied from $(BaTi_O_3)_1/(SrTiO_3)_1$ to $(BaTi_O_3)_3/(SrTiO_3)_3$. The total thickness of the $BaTiO_3/SrTiO_3$ films was about $120{\mu}m$. There was an interdiffusion at the interface of the $BaTiO_3$ and $SrTiO_3$ layers. The dielectric constant of $BaTiO_3/SrTiO_3$ heterolayered thick films was increased with decreasing stacking periodicity of the $BaTiO_3/SrTiO_3$. The dielectric constant of the ($(BaTi_O_3)_1/(SrTiO_3)_1$ herterolayered thick films was about 1780.

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Calendering Effects on the Properties of TiO$_2$ Highly Leaded Paper (캘린더링이 TiO$_2$ 고 충전지의 특성에 미치는 영향)

  • 오세중;서영범
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.4
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    • pp.69-78
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    • 1998
  • Papers loaded with 10-40% $TiO_2$ by dry weight were calendered under the various combinations of calendering conditions such as calender type, linear pressure, and roll temperature. After being calendered, light scattering coefficient, surface roughness, density, and tensile strength of the papers were measured and the results were summerized as follows: 1. To increase the light scattering coefficient of $TiO_2$-highly-loaded paper further by calendering, the calender roll pressure and temperature should be kept low. Under these conditions, the physical strength of the paper was not significantly affected. 2. At low roll temperature, soft nip calender and machine calender type showed the same relationship between paper density and its roughness. At high roll temperature, soft nip calender type gave much lower roughness than machine calender type at the same density. 3. At high roll temperature of both calenders, the density as well as the tensile strength of the TiO$_2$-loaded paper was increased significantly.

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Photoelectrochemical Converision with $SrTiO_3$ Ceramic Electrodes ($SrTiO_3$ 세라믹 전극에 의한 광전기 화학변환)

  • 윤기현;김태희
    • Journal of the Korean Ceramic Society
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    • v.22 no.3
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    • pp.19-24
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    • 1985
  • The phtoelectrochemical porperties of $Nb_2O_5$, $Sb_2O_3$ and $V_2O_5$ doped and pure $SrTiO_3$ ceramic electodes were investigated. Shapes of I-V and I-λ characteristics of the pure $SrTiO_3$ ceramic electrode are similar to those of SrTiO3 single crystal electorde ; the anodic current strats at -0.9V (vs. Ag/AgCI) in 1 N-NaOH aqueous solution and the photoresponse appears at a wavelength of about 390nm and the quantum efficiency is about 3.5% at wavelength of 390nm under 0.5V vs. Ag/AgCl. Photocurrents of $Nb_2O_5$, $Sb_2O_3$ and $V_2O_5$ doped electrodes and $V_2O_5$ doped ceramic electrode appears at wavelength of 390nm and 500nm respectively.

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Preparation and Electrical Properties of Ferroelectric $Bi_{3.3}Eu_{0.7}Ti_3O_{12}$ Thin Films for Memory Applications (강유전체 메모리용 $Bi_{3.3}Eu_{0.7}Ti_3O_{12}$ 박막의 증착과 전기적 특성)

  • Kang, Dong-Kyun;Park, Won-Tae;Kim, Byong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.39-40
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    • 2005
  • Ferroelectric Eu-substituted $Bi_4Ti_3O_{12}$ (BET) thin films with a thickness of 200 nm were deposited on Pt(111)/Ti/SiO$_2$/Si(100) substrate by means of the liquid delivery MOCVD system and annealed at several temperatures in an oxygen atmosphere. At annealing temperature above $600^{\circ}C$, the microstructure of layered perovskite phase was observed. The remanent polarization of these films increased with increase in annealing temperature. The remanent polarization values ($2P_r$) of the BET thin films annealed at $720^{\circ}C$ were $37.71{\mu}C/cm^2$ at an applied voltage of 5 V.

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Nanotube Morphology Change of Ti-6Al-4V Alloys by Heat Treatment

  • Kim, Sung-Hwan;Choe, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2013.05a
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    • pp.194-194
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    • 2013
  • In order to investigate nanotube morphology change of Ti-6Al-4V alloys by heat treatments, the Ti-6Al-4V alloys were used in this study. In non-treated Ti-6Al-4V alloy case, nanotubes only exhibited at ${\alpha}$ phase region with dissolved V-oxide area of ${\beta}$ phase. However, in Ti-6Al-4V alloy at $800^{\circ}C$ WQ case, nanotubes exhibited at both ${\alpha}$ and ${\beta}$ phase region. Electrochemical corrosion studies showed that the nanotubular alloy at $800^{\circ}C$WQ possesses slightly higher corrosion resistance than non-treated nanotubular alloy.

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Effect of Mo, Ti, Nb on the hot salt corrosion behavior of ferritic stainless steels for automotive exhaust system (자동차배기관용 페라이트계 스테인레스강의 고온염부식에 미치는 Mo, Ti, Nb 원소의 영향)

  • 김수정;안용식
    • Journal of Ocean Engineering and Technology
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    • v.11 no.3
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    • pp.48-55
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    • 1997
  • The steel for automotive exhaust system needs a good corrosion resistance at the atmosphere of high temperature NaCl. Effect of the alloying elements Me, Ti, Nb on the NaCl induced hot corrosion behavior was investigated at the temperatures between 55$0^{\circ}C$ and 75$0^{\circ}C$ for 18Cr ferritic stainless steels. The weight loss by corrosion has increased linearly with corrosion cycle time, and the corrosion rate has accelerated at higher temperature. The alloying of Mo significantly improved corrosion resistance of the steel and the effect was more pronounced at higher temperature. The addition of alloying elements Ti, Nb have also shown improved corrosion resistance by formation of Ti(C,N) or Nb(C, N) precipitates.

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Preparation and Sinterability of Nano-Size $TiO_2$ Powders Using Supercritical Fluids (초임계 유체를 이용한 나노크기 $TiO_2$ 분말제조 및 소결특성)

  • 송정환;이정석;박인석;임대영
    • Journal of the Korean Ceramic Society
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    • v.37 no.7
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    • pp.625-631
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    • 2000
  • In this study, the characteristics and sinterablities of TiO2 powders which were fabricated on sol-gel process and supercritical fluid process were examined. The powders fabricated on sol-gel process were amorphous. The particle size and shape were changed with the amount of water used for hydrolysis of titanium ethoxide. The powders were changed from amorphous to crystalline by heating at 400℃. The crystalline anatase TiO2 powders were directly prepared in ethanol supercritical fluid condition that temperature was 270±3℃ and pressure was 7.3 MPa. It's primary crystalline size was 20 nm and agglomerated as spherical shape whose size was 0.7∼1㎛. The powders prepared on sol-gel process were not sintered densely at 900℃ because of abnormal grain growth. However, the powders which prepared on supercritical fluid process were sintered densely at the comparatively low temperature of 800℃ by ideal growth of grain, which are fired at 900℃.

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A Study on the Squareness of Circular Pocket Machining of SCM415 Steel (SCM415강의 원형포켓 가공시 직각도에 관한 연구)

  • Kim, Jin-su;Choi, Chul-Woong;Shin, Mi-Jung
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.18 no.7
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    • pp.42-47
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    • 2019
  • In this research, we try to study the change of squareness in the cutting process while changing cutting conditions such as feed rate and spindle rotational speed with chromium molybdenum steel (SCM415) material and TiCN, TiAlN coated end mill tool. The TiCN coating tool had the best straightness at 4,000 rpm at a feed rate of 200 mm/min. The TiAlN coating tool was best measured at 3,000 rpm at a feed rate of 200 mm/min. TiAlN coated tools had excellent dimensional tolerance when comparing the coating tool specifics.

A Study on Microstructure, Mechanical Properties, Friction and Adhesion of TiN Thin Films Coated on SKD61 and Radical Nitrided SKD61 Substrates by Arc Ion Plating (SKD61과 Radical Nitriding 처리된 SKD61 기판상에 Arc Ion Plating으로 증착된 TiN 박막의 미세구조 및 기계적 특성, 마찰 및 접착력에 관한 연구)

  • Joo, Yun-Kon;Yoon, Jae-Hong;Fang, Wei;Zhang, Shi-Hong;Cho, Tong-Yul;Ha, Sung-Sik
    • Journal of the Korean institute of surface engineering
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    • v.40 no.6
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    • pp.254-257
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    • 2007
  • TiN coating on tool steel has been widely used for the improvement of durability of tools. In this work, radical nitriding(RN) is carried out on SKD61 at $450^{\circ}C$ for 5 hours in the ammonia gas pressure $2.7{\times}10^3\;Pa$. The TiN coating is carried out by arc ion plating(AIP) with the process parameters: arc power 150 A, bias voltage -50V, coating time 40 minutes and nitrogen gas pressure $4{\times}10^3\;Pa$. Hardness, elastic modulus, friction coefficient and adhesion of TiN coating on substrates of both TiN/SKD61 and TiN/RN SKD61 coatings are investigated comparatively. The primary crystalline faces of TiN surface are(200) and(111) for TiN/SKD61 and TiN/RN SKD61 respectively. In addition to the primary phase, Fe phase exists in TiN/SKD61 coating, but not in TIN/RN SKD61. The hardness of TiN/RN SKD61 is about 700 Hv, 250 Hv(56%) higher than that of TiN/SKD61 at the near interface of TiN and substrates. At the TiN surface, hardness of TiN/RN SKD61 is 2,149 Hv, 71 Hv(3%) higher than that of TiN/SKD61. The elastic modulus of TiN coating is improved to 26.7 GPa(6%) by radical nitriding. The adhesion is improved by the RN coating showing no spalling. buckling and chipping on the scratch test track which are shown on the non-RN TiN/SKD61.

SUPERELASTICITY OF CAST SHAPE MEMORY Ni-Ti ALLOY (주조 형상기억 니켈-티타늄 합금의 초탄성)

  • Choi, Dong-Ik;Choie, Mok-Kyun
    • Journal of the Korean Academy of Esthetic Dentistry
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    • v.3 no.1
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    • pp.32-43
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    • 1995
  • Ni-Ti alloy has excellent corrosion resistance, biocompatibility, shape memory effect and superelasticity, so it has been used widely in biomedical fields. But it has difficulty in casting due to its high melting temperature and oxygen affinity at high temperature. Recently it has been attempted to cast Ni-Ti alloy using new casting machine and investment. The purpose of this study was to examine the superelastic behavior of cast shape memory Ni-Ti alloy and to compare the mechanical properties of the cast shape memory alloy with those of commercial alloys for removable partial denture framework. Ni-Ti alloy(Ni 50.25%, Ti 49.75% : atomic ratio) was cast with dental argon-arc pressure casting machine and Type IV gold alloy, Co-Cr alloy, Ni-Cr alloy, pure titanium were cast as reference. Experimental cast Ni-Ti alloy was treated with heat($500{\pm}2^{\circ}C$) in muffle furnace for 1 hour. Transformation temperature range of cast Ni-Ti alloy was measured with differential scanning calorimetry. The superelastic behavior and mechanical properties of cat Ni-Ti alloy were observed and evaluated by three point bending test, ultimate tensile test, Vickers microhardness test and scanning electron microscope. The results were as follows : 1. Cast Ni-Ti alloy(Ni 50.25%, Ti 49.75% : atomic ratio) was found to have superelastic behavior. 2. Stiffness of cast Ni-Ti alloy was considerably lesser than that of commercial alloys for removable partial denture. 3. Permanent deformation was observed in commercial alloys for removable partial denture framework at three point bending test over proportional limit(1.5mm deflection), but was not nearly observed in cast Ni-Ti alloy. 4. On the mechanical properties of ultimate tensile strength, elongation and Vickers microhardness number, cast Ni-Ti alloy was similiar to Type IV gold alloy, Co-Cr alloy, Ni-Cr alloy and pure titanium. With these results, cast Ni-Ti alloy had superelastic behavior and low stiffness. Therefore, it is suggested that cast Ni-Ti alloy may be applicated to base metal alloy for removable partial denture framework.

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