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Management of water quality by estimated the point source in Mokpo inner bay (점 오염원 조사를 통한 목포 내항의 수질관리)

  • Kim, Do-Hee;Lee, Ha-Ju
    • Proceedings of KOSOMES biannual meeting
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    • 2006.05a
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    • pp.121-128
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    • 2006
  • The results of COD researched on August of 2004 were 6.8 ppm in North Mokpo inner Bay, 4.4 ppm in front of YongSang Bank and 4.6 ppm in front of ShinAn Beach Hotel which is over III level Marine-Environmental Standard. The other five stations sea water quality of Mokpo inner bay were reached II-III level. Concentration of total nitrogen range from 1.23 ppm to 3.56 ppm and total phosphorous was range from 0.07 ppm to 0.12 ppm which were II-III level. This results show that the Mokpo inner bay is unsuitable for aquaculture and growth of fish and for use of marine resort, it can be only available for industrial and harbour use. In results of estimated point source flow into Mokpo inner bay, the occupation ratio from YoungSang river in total inflow of TN and TP were up to 49-89 % respectively. It is indicate that in order to improve the water quality of MokPo inner bay have to control the discharge from YoungSang river first of all, then control the discharge from North Harbour domestic wastewater treatment, InAm river and NamHae domestic wastewater treatment.

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Physiological Responses and Lactation to Cutaneous Evaporative Heat Loss in Bos indicus, Bos taurus, and Their Crossbreds

  • Jian, Wang;Ke, Yang;Cheng, Lu
    • Asian-Australasian Journal of Animal Sciences
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    • v.28 no.11
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    • pp.1558-1564
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    • 2015
  • Cutaneous evaporative heat loss in Bos indicus and Bos taurus has been well documented. Nonetheless, how crossbreds with different fractional genetic proportions respond to such circumstances is of interest. A study to examine the physiological responses to cutaneous evaporative heat loss, also lactation period and milk yield, were conducted in Sahiwal (Bos indicus, n = 10, $444{\pm}64.8kg$, $9{\pm}2.9years$), Holstein Friesian (Bos taurus, HF100% (n = 10, $488{\pm}97.9kg$, $6{\pm}2.8years$)) and the following crossbreds: HF50% (n = 10, $355{\pm}40.7kg$, $2{\pm}0years$) and HF87.5% (n = 10, $489{\pm}76.8kg$, $7{\pm}1.8years$). They were allocated so as to determine the physiological responses of sweating rate (SR), respiration rate (RR), rectal temperature (RT), and skin temperature (ST) with and without hair from 06:00 h am to 15:00 h pm. And milk yield during 180 days were collected at days from 30 to 180. The ambient temperature-humidity-index (THI) increased from less than 80 in the early morning to more than 90 in the late afternoon. The interaction of THI and breed were highly affected on SR, RR, RT, and ST (p<0.01). The SR was highest in Sahiwal ($595g/m^2/h$) compared to HF100% ($227g/m^2/h$), and their crossbreds both HF50% ($335g/m^2/h$) and HF87.5% ($299g/m^2/h$). On the other hand, RR was higher in HF87.5% (54 bpm) and both HF100% (48 bpm) and HF50% (42 bpm) than Sahiwal (25 bpm) (p<0.01). The RT showed no significant differences as a result of breed (p>0.05) but did change over time. The ST with and without hair were similar, and was higher in HF100% ($37.4^{\circ}C$; $38.0^{\circ}C$) and their crossbred HF50% ($35.5^{\circ}C$; $35.5^{\circ}C$) and HF87.5% ($37.1^{\circ}C$; $37.9^{\circ}C$) than Sahiwal ($34.8^{\circ}C$; $34.8^{\circ}C$) (p<0.01). Moreover, the early lactation were higher at HF100% (25 kg) and 87.5% (25 kg) than HF50% (23 kg) which were higher than Sahiwal (18 kg) while the peak period of lactation was higher at HF100% (35 kg) than crossbreds both HF87.5% and HF50% (32 kg) which was higher than Sahiwal (26 kg) (p<0.05). In conclusion, sweating and respiration were the main vehicle for dissipating excess body heat for Sahiwal, HF and crossbreds, respectively. The THI at 76 to 80 were the critical points where the physiological responses to elevated temperature displayed change.

Analytical Method of Bentazone Residue in Agricultural Commodities Using HPLC-UVD/MS (HPLC-UVD/MS를 이용한 농산물 중 bentazone의 분석법 확립)

  • Kim, Young-Hak;Lee, Su-Jin;Song, Lee-Seul;Hwang, Young-Sun;Lee, Young-Deuk;Choung, Myoung-Gun
    • The Korean Journal of Pesticide Science
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    • v.15 no.2
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    • pp.149-159
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    • 2011
  • Bentazone is benzothiadiazole group herbicide, and used to foliage treatment. This herbicide have already been widely used for cereals and vegetables planting in worldwide. This experiment was conducted to establish a determination method for bentazone residue in crops using HPLC-UVD/MS. Bentazone residue was extracted with acetone (adjusted pH 1 with phosphoric acid) from representative samples of five raw products which comprised hulled rice, soybean, apple, green pepper, and Chinese cabbage. The extract was diluted with saline water, and dichloromethane partition was followed to recover bentazone from the aqueous phase. Florisil column chromatography was additionally employed for final clean up of the extract. The bentazone was quantitated by HPLC with UVD, using a YMC ODS AM 303 ($4.6{\times}250$ mm) column. The crops were fortified with bentazone at 3 levels per crop. Mean recovery ratio were ranged from 82.0% for a 0.2 mg/kg in apple to 97.9% for a 0.02 mg/kg in Chinese cabbage. The coefficients of variation were ranged from 0.5% for a 0.02 mg/kg in soybean to 9.7% for a 0.02 mg/kg in Chinese cabbage. Quantitative limit of bentazone was 0.02 mg/kg in representative five crop samples. A LC/MS with selected-ion monitoring was also provided to confirm the suspected residue. Therefore, this analytical method was reproducible and sensitive enough to determine the residue of bentazone in agricultural commodities.

New Liquid Crystal-Embedded PVdF-co-HFP-Based Polymer Electrolytes for Dye-Sensitized Solar Cell Applications

  • Vijayakumar, G.;Lee, Meyoung-Jin;Song, Myung-Kwan;Jin, Sung-Ho;Lee, Jae-Wook;Lee, Chan-Woo;Gal, Yeong-Soon;Shim, Hyo-Jin;Kang, Yong-Ku;Lee, Gi-Won;Kim, Kyung-Kon;Park, Nam-Gyu;Kim, Suhk-Mann
    • Macromolecular Research
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    • v.17 no.12
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    • pp.963-968
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    • 2009
  • Liquid crystal (LC; E7 and/or ML-0249)-embedded, poly(vinylidenefluoride-co-hexafluoropropylene) (PVdF-co-HFP)-based, polymer electrolytes were prepared for use in dye-sensitized solar cells (DSSCs). The electrolytes contained 1-methyl-3-propylimidazolium iodide (PMII), tetrabutylammonium iodide (TBAI), and iodine ($I_2$), which participate in the $I_3^-/I^-$ redox couple. The incorporation of photochemically stable PVdF-co-HFP in the DSSCs created a stable polymer electrolyte that resisted leakage and volatilization. DSSCs, with liquid crystal(LC)-embedded PVdF-co-HFP-based polymer electrolytes between the amphiphilic ruthenium dye N719 absorbed to the nanocrystalline $TiO_2$ photoanode and the Pt counter electrode, were fabricated. These DSSCs displayed enhanced redox couple reduction and reduced charge recombination in comparison to that fabricated from the conventional PVdF-co-HFP-based polymer electrolyte. The behavior of the polymer electrolyte was improved by the addition of optimized amounts of plasticizers, such as ethylene carbonate (EC) and propylene carbonate (PC). The significantly increased short-circuit current density ($J_{sc}$, $14.60\;mA/cm^2$) and open-circuit voltage ($V_{oc}$, 0.68 V) of these DSSCs led to a high power conversion efficiency (PCE) of 6.42% and a fill factor of 0.65 under a standard light intensity of $100\;mW/cm^2$ irradiation of AM 1.5 sunlight. A DSSC fabricated by using E7-embedded PVdF-co-HFP-based polymer electrolyte exhibited a maximum incident photon-to-current conversion efficiency (IPCE) of 50%.

Petrographical study for the enclaves of the granitic rocks, in the Gyeongsang Basin, Korea (경상분지 화강암류에서 발견되는 엔클레이브(포유암)에 대한 암석기재적 연구)

  • 김종선;김건기;좌용주;이준동
    • The Journal of the Petrological Society of Korea
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    • v.13 no.1
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    • pp.1-15
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    • 2004
  • In this study we propose that the ‘enclaves’ which occur in the granites should be translated into ‘Po-yu-am’in Korean. Also we suggest some criteria to discriminate the mafic microgranular enclaves (MME) of igneous origin from the xenoliths, which possibly come from the plutonic, volcanic and sedimentary country rocks. The color of the MME is gray green∼dark gray and the mineral grains are fine and equigranular. The MME are generally of ellipsoidal shape and can be easily found within the granites. They do not show any evidence of contact metamorphism by granite host. On the other hand. the xenoliths are generally of angular shape and are of the same mineral assemblage and texture as the country rocks around the granites. The distribution of the xenoliths is mostly concentrated along the intruding plane of the granites near the country rocks. The xenoliths were partly metamorphosed by the granite intrusion. The xenoliths from the plutonic rocks are easily distinguished from the MME in terms of their angular shape and coarser grain size, but they do not have any metamorphic mineral assemblage and texture. The xenoliths from the tuffaceous rocks show angular shape and porphyritic and pyroclastic textures. Large size xenoliths from the sedimentary rocks specifically preserve bedding structure which are indicative of the sedimentary strata. However, the sedimentary xenoliths of small size are often difficult to distinguish from the MME. Metamorphic minerals and texture are a useful key to discriminate the small-sized sedimentary xenoliths from the MME. In summary the xenoliths in the granites can be megascopic ally distinguished from the MME by comparing their color, shape, grain size and remnant original structure like bedding. Additionally the metamorphic mineral assemblage and texture are microscopic discriminators between the xenoliths and the MME in the granites.

Wavelength Conversion Lanthanide(III)-cored Complex for Highly Efficient Dye-sensitized Solar Cells

  • Oh, Jung-Hwan;Song, Hae-Min;Eom, Yu-Kyung;Ryu, Jung-Ho;Ju, Myung-Jong;Kim, Hwan-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2743-2750
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    • 2011
  • Lanthanide(III)-cored complex as a wavelength conversion material has been successfully designed and synthesized for highly efficient dye-sensitized solar cells, for the first time, since light with a short wavelength has not been effectively used for generating electric power owing to the limited absorption of these DSSCs in the UV region. A black dye (BD) was chosen and used as a sensitizer, because BD has a relatively weak light absorption at shorter wavelengths. The overall conversion efficiency of the BD/WCM device was remarkably increased, even with the relatively small amount of WCM added to the device. The enhancement in $V_{oc}$ by WCM, like DCA, could be correlated with the suppression of electron recombination between the injected electrons and $I_3{^-}$ ions. Furthermore, the short-circuit current density was significantly increased by WCM with a strong UV light-harvesting effect. The energy transfer from the Eu(III)-cored complex to the $TiO_2$ film occurred via the dye, so the number of electrons injected into the $TiO_2$ surface increased, i.e., the short-circuit current density was increased. As a result, BD/WCM-sensitized solar cells exhibit superior device performance with the enhanced conversion efficiency by a factor of 1.22 under AM 1.5 sunlight: The photovoltaic performance of the BD/WCM-based DSSC exhibited remarkably high values, $J_{sc}$ of 17.72 mA/$cm^2$, $V_{oc}$ of 720 mV, and a conversion efficiency of 9.28% at 100 mW $cm^{-2}$, compared to a standard DSSC with $J_{sc}$ of 15.53 mA/$cm^2$, $V_{oc}$ of 689 mV, and a conversion efficiency of 7.58% at 100 mW $cm^{-2}$. Therefore, the Eu(III)-cored complex is a promising candidate as a new wavelength conversion coadsorbent for highly efficient dye-sensitized solar cells to improve UV light harvesting through energy transfer processes. The abstract should be a single paragraph which summaries the content of the article.

An Analysis of Wind Energy Resources using Synoptic Observational Data in North Korea (종관 바람 관측 자료를 이용한 북한 지역의 풍력자원 분석)

  • Yun, Jun-Hee;Seo, Eun-Kyoung;Park, Young-San;Kim, Hak-Seong
    • Journal of the Korean earth science society
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    • v.31 no.3
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    • pp.225-233
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    • 2010
  • Wind power density distribution over the North Korea territory was investigated by using 30-year wind observations at 27 meteorological stations. The mean annual wind power density over North Korea turned out to be 58.6W/$m^2$, which corresponds to the wind power class of 1. The wind power density shows a seasonal variation, having the highest density in spring and the lowest in summer. In particular, the wind power density in summer is about a half of that in spring. The diurnal variation of the wind power density shows that the highest and lowest densities occur in the afternoon and between 3 and 6 am in local time, respectively. The most potential wind energy generation regions are the Gaema Plateau in the central region, the northeast part of Hamgyeongbuk-do, the south coast of Pyongan-do and the west coast of Hwanghae-do. The mean annual wind power density in Changjin is 151.2W/$m^2$, which is equivalent to the class of 3. In Ryongyon, the annual mean wind power density is 102.4W/$m^2$, which belongs to the class of 2.

Effect of modeling liquid on the shear-bond strength of zirconia core - porcelain veneer (도재 전용액이 지르코니아 코어-도재 비니어의 전단결합강도에 미치는 영향)

  • Choi, Byung-Hwan;Kim, Im-Sun
    • Journal of Technologic Dentistry
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    • v.36 no.2
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    • pp.83-89
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    • 2014
  • Purpose: This study is to evaluate the effect of modeling liquid on the shear-bond strength between zirconia core and veneering ceramic. Methods: Disk-shaped (diameter: 12.0mm; height: 3.0mm) zirconia were randomly divided into six groups according to the surface conditioning method and whether modeling liquid is used or not to be applied (N=60, n=10 per group): group 1-control group with distilled water(ZD); group 2-control group with modeling liquid(ZM); group 3-airborne particle abrasion with $110-{\mu}m$ $Al_2O_3$(AD) with distilled water; group 4-airborne particle abrasion with $110-{\mu}m$ $Al_2O_3$ with modeling liquid(AM); group 5-liner with distilled water(LD); group $6{\pounds}{\neq}liner$ with modeling liquid(LM). Contact angles were determined by the sessile drop method at room temperature using a contact angle measurement apparatus. The specimens were prepared using dentin veneering ceramics, veneered, 3mm high and 2.8mm in diameter, over the cores. The shear bond strength test was performed in a Shear bond test machine. Load was applied at a cross-head speed of 0.50mm/min until failure. The fractured zirconia surfaces were evaluated by using stereomicroscope (${\times}30$). Collected data were analyzed using SPSS(Statistical Package for Social Sciences) Win 12.0 statistics program. Results: ZD showed the highest contact angle($50.6{\pm}5.4^{\circ}$) and LD showed the lowest value($6.7{\pm}1.3^{\circ}$). Control groups and zirconia liner groups were significantly higher contact angle than liner groups(p<0.05). LD was the highest shear bond strength($43.9{\pm}3.8MPa$) and ZD was the lowest shear bond strength($24.8{\pm}4.9MPa$). Shear bond strengths of control groups and contact angle of liner groups were not significantly different((p>0.05). Liner groups presented adhesive failures. The others groups showed cohesive and adhesive failures. Conclusion: Modeling liquid groups showed lower contact angles and lower shear bond strength compared to those of distilled water groups.

Management of Water Quality by the Point Source in Mokpo Inner Bay (점 오염원 조사를 통한 목포 내항의 수질관리)

  • Kim, Do-Hee
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.12 no.4 s.27
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    • pp.273-283
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    • 2006
  • The results of COD concentration on August of 2004 were 6.80 ppm in North Mokpo Inner Bay, 4.42 ppm un front of YongSang Bank and 4.60 ppm in front of ShinAn Beach Hotel which is over III level Marine Environmental Standard. The others researched five stations sea water quality of Mokpo inner bay are reached II-III level. The concentration of total nitrogen range from 1.23 ppm to 3.56 ppm and total phosphorous concentration was range from 0.07 ppm to 0.12 ppm which are to be II-III level. This results show that the Mokpo inner bay is unsuitable for aquaculture and for use of marine resort, it can be only avaliable for industrial and harbour port use. In this study, we researched 12 point source flow into Mokpo Inner bay. The rate from YoungSang river in total inflow of TN was up to 70-93 % and rate of TP was up to 31-91 % respectively. In this results, we have to control the discharge from YoungSang river first of all then control the discharge from North Harbour domestic wastewater treatment, InAm river and NamHae domestic wastewater treatment in order to improve the water quality of Mokpo Inner bay.

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Correlation Between the Microclimate and the Crown of Platanus orientalis and Ulmus davidiana (버즘나무(Platanus orientalis)와 느릅나무(Ulmus davidiana)의 수관부와 미기후간의 상호 관계)

  • Lee, Jae-yoon;Ki, Kyong-Seok
    • Korean Journal of Environment and Ecology
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    • v.30 no.4
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    • pp.793-799
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    • 2016
  • This study examined Platanus orientalis and Ulmus davidiana planted in downtown parks to identify the correlations among microclimatic factors such as temperature in the crown, air flow, and wind speed. For the field survey, measurements were taken at 1 hour intervals from 09:00 am to 06:00 pm in August. For the measurement of microclimatic factors, data on temperature, light intensity, air flow, and wind speed were collected using a quantum sensor (PAR Quantum Sensor SKP215), a precision thermometer (Pt1000-Sensor), and a combination anemometer (1467 G4 & HG4). The results of the analysis demonstrated that both Platanus orientalis and Ulmus davidiana, showed a greater cooling effect inside the crown as compared with the outside temperature. The cooling effect inside the crown was more evident with air flow and wind speed factors. With relation to wind, the inner temperature of the crown of Platanus orientalis decreased due to air flow while that of Ulmus davidiana decreased due to wind speed. With no wind, the average variation in temperature inside the crown was $-0.9^{\circ}C$ for Ulmus davidiana and $-0.958^{\circ}C$ for Platanus orientalis, indicating that Platanus orientalis was relatively more effective in lowering the temperature of the planting space than Ulmus davidiana. This study is significant because it shows that different tree species have different effects on the microclimate and that factors affecting the formation of the microclimate of trees may vary with species. Further studies on species other than broad leaf trees, such as evergreen trees and shrubs, are required in order to plan the distribution of landscaping trees that are effective in regulating the microclimate within urban green spaces.