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검색결과 163건 처리시간 0.025초

킬레이트 관능기가 도입된 활성탄소의 이산화탄소 흡착거동 ($CO_2$ Adsorption Behaviors of Activated Carbons Modified by Chelating Groups)

  • 장동일;박수진
    • 공업화학
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    • 제21권4호
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    • pp.396-400
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    • 2010
  • 본 연구에서는 킬레이트 관능기가 도입된 활성탄소의 이산화탄소 흡착거동에 관하여 고찰하였다. 활성탄소에 peroxide의 열분해를 통해 glycidyl methacrylate를 그래프트 중합한 후 에폭사이드기에 킬레이트 관능기로서 diethylene triamine을 도입하였다. 킬레이트 관능기가 처리된 활성탄소의 표면특성은 scanning electron microscope와 X-ray photoelectron spectroscopy를 사용하여 측정하였으며, 흡착표면적과 기공도는 BET법을 이용한 $N_2$ 기체 흡착을 통해 알아보았다. 또한 킬레이트 관능기 처리된 활성탄소의 흡착특성을 비교하기 위해 이산화탄소의 흡착실험을 수행하였다. 실험 결과, 활성탄소 표면에 도입된 킬레이트 관능기는 비표면적 감소에 따른 물리적 흡착량이 감소하더라도 이산화탄소에 대한 선택적, 화학적 흡착량을 향상시킴을 알 수 있었다.

북극의 관리체제와 국제기구 : 북극이사회(Arctic Council)를 중심으로 (Arctic Governance and International Organization : A Focus on the Arctic Council)

  • 진동민;서현교;최선웅
    • Ocean and Polar Research
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    • 제32권1호
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    • pp.85-95
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    • 2010
  • There is increasing consensus that global warming is seriously affecting the Arctic region. Sea Ice decreases and sea level rise have led to environmental change in Arctic Ecosystems, while also making the Arctic sea route more accessible to humans. There are complicated international governance dynamics in play, in addition to commercial and scientific interests in the Arctic region. This provides a unique opportunity for Korea to lead the future direction of Arctic policy in response to the global issues such as climate change and economic or scientific interests. Korea acquired Ad-hoc Observer status of the Arctic Council(AC) in 2008, which is the only pan-Arctic intergovernmental organization. It consists of six working groups: ACAP, AMAP, CAFF, PAME, EPPR, SDWG that implement research, survey, and monitoring. AC's Observer country has the opportunity to participate in a diverse range of activities such technical and expertise support, research and monitoring, financial support and conference organization. In order for Korea to expand its activities in the Arctic region, we suggest the following approach: First, Korea should become more actively engaged with the Arctic Council and its activities; Second, Korea should construct organized collaborative networks of national experts to respond to Arctic issues; Third, Korea should develop collaborations with Arctic states; Finally, Korea should intensify its research on international relations and international laws related to the Arctic region.

플렉시블 솔라셀과 Cds셀을 이용한 다중 가시광 수신기 (Multiple Visible Light Receiver Using A Flexible Solar Cell and Cds Cells)

  • 이성호
    • 전기전자학회논문지
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    • 제22권2호
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    • pp.432-439
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    • 2018
  • 본 논문에서는 플렉시블 솔라셀의 수광면을 원통형으로 만들어 수평면상에서 균일한 수광패턴을 가지는 전방향 가시광 검출기를 개발하였다. 이 솔라셀 광검출기는 서로 다른 위치에서 입사하는 여러 개의 신호광을 동시에 검출하며, 수신부의 ASK복조기에 전력을 공급한다. 실험에서는 시분할 전송 방식을 사용하여 서로 다른 방향으로부터 입사하는 3개 신호광을 솔라셀 광검출기로 수신하였다. 각 신호광은 40 kHz의 캐리어를 사용하여 ASK 변조하였으며, 시분할 전송에 필요한 동기펄스는 실내의 조명램프에 포함된 120 Hz의 AC 신호를 Cds셀로 검출하여 같은 주기로 생성하였다. 이러한 수신구조는 가시광통신에서 $N{\times}1$ 광연결을 구성하는 데에 적합하다.

관상동맥조영술상 정상소견을 보인 환자에서 전산화단층촬영술(CT)를 이용한 감쇠보정이 심근관류 SPECT의 판독에 미치는 영향 (The Effect of Attenuation Correction with CT on the Interpretation of Myocardial Perfusion SPECT: in Patients with Normal Coronary Angiogram)

  • 천경아;조인호;원규장;이형우;홍그루;신동구;김영조;심봉섭
    • 대한핵의학회지
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    • 제39권4호
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    • pp.246-251
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    • 2005
  • 목적: 심근관류 스펙트 검사에서 감쇠의 영향을 보정하기 위해 여러 가지 방법들이 사용되어 왔다. 본 연구는 CT를 이용한 감쇠보정이 관상동맥조영술이 정상인 환자들을 대상으로 하였을 때 어떠한 영향을 주는지 알아보고 기존의 감쇠보정방법들과 차이가 있는지를 알아보고자 하였다. 대상 및 방법: 관상동맥질환이 의심되어 심근 SPECT/CT를 시행한 환자들 중 관상동맥조영술상 정상소견을 보인 25명에서, Pryor 등의 방법으로 관상동맥질환의 위험도가 5.0% 미만인 15명의 환자를 대상으로 하였다. (남 6, 여 9, 평균연령 $58{\pm}8$세). CT가 장착된 Millennium VG (GE) 카메라로 감쇠보정을 하였으며, 영상의 판독은 육안분석과 극성지도를 이용한 정량적 분석을 시행하였다. 정량적 분석의 경우 극성지도 상에서 각 심근벽의 섭취율(최대 섭취율에 대한 %)을 구하여 감쇠보정을 하지 않은 영상과 감쇠보정을 한 영상을 비교하였다. 결과: 육안분석에서 감쇠보정을 한 경우 하벽의 섭취는 증가한 반면, 전벽과 심첨부 및 격벽의 섭취는 감소하였다. 간에서의 섭취도 감쇠보정을 한 경우에 증가하였다. 정량분석에서는 심첨부의 경우 감쇠보정 후 섭취율이 감소하였고, 하벽의 경우 증가하였다. 하벽의 경우 감쇠보정을 하여 판독에 도움을 받을 수 있었고, 반면 전벽이나 심첨부의 경우 감쇠보정 후 판독에 어려움이 있었다. 결론: 하벽의 경우 CT를 이용한 감쇠보정을 한 경우 판독에 도움이 되었으며, 감쇠보정전 영상이 정상인 경우 심첨부나 전벽등의 판독시는 주의가 필요하다.

CBD(Chemical Bath Deposition) 법으로 제조된 전기화학식 캐패시터용 NiO 나노박편 필름 (Nickel Oxide Nano-Flake Films Synthesized by Chemical Bath Deposition for Electrochemical Capacitors)

  • 김영하;박수진
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.163.2-163.2
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    • 2010
  • In this work, nano-flake shaped nickel oxide (NiO) films were synthesized by chemical bath deposition technique for electrochemical capacitors. The deposition was carried out for 1 and 2 h at room temperature using nickel foam as the substrate and the current collector. The structure and morphology of prepared NiO film were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). And, electrochemical properties were characterized by cyclic voltammetry, galvanostatic charge-discharge, and AC impedence measurement. It was found that the NiO film was constructed by many interconnected NiO nano-flakes which arranged vertically to the substrate, forming a net-like structure with large pores. The open macropores may facilitate the electrolyte penetration and ion migration, resulted in the utilization of nickel oxide due to the increased surface area for electrochemical reactions. Furthermore, it was found that the deposition onto nickel foam as substrate and curent collector led to decrease of the ion transfer resistance so that its specific capacitance of a NiO film had high value than NiO nano flake powder.

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Salinity Tolerance of Progenies between Korean Cultivars and IRRI's New Plant Type Lines in Rice

  • Lee, Seung-Yeob;Dharmawansa Senadhira
    • 한국작물학회지
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    • 제43권4호
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    • pp.234-238
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    • 1998
  • To select new germplasm for salinity tolerance from new plant type (NPT) breeding lines, the sixty F$_4$ lines selected from the crosses between Korean cultivars and IRRI's NPT lines were evaluated for salinity tolerance at the seedling stage with salinized culture solution (EC=12 dS/m) in the controlled conditions. Two NTP lines derived from a cross between 'Ilmibyeo' and 'IR66152-AC5-1', 'HR15258-7-1' and 'HR15258-27-1', were found to have good tolerance. The salinity tolerance of the lines was compared to their parents and the sensitive ('IR29') and tolerant ('Pokkali') checks in three salinity levels, no salinity (control) and an EC of 12 and 16 dS/m. Visual salinity score, shoot Na+ and Na-K ratio in two NPT lines was significantly low compared with the parents and IR29. Indicating that salinity tolerance of the lines might be derived from a transgressive segregation. The relative water content of the lines was higher than Pokkali, and the dry weight of shoot and root was proportionally decreased to salinity score and salinizing concentration. The visual salinity scores were significantly correlated with shoot Na concentration, Na-K ratio, relative water content, and reduction of dry weight (P<0.01). Their tolerance was attributed to root and shoot characteristics that led to high shoot water content, thus diluting the toxic effect of salts.

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The Preventive Effects of Colon Cancer and Imflammatory Bowel Disease of Supercritical Heat-Treated Radish Extracts

  • Kim, Hyun-Kyoung
    • International Journal of Internet, Broadcasting and Communication
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    • 제12권2호
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    • pp.98-112
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    • 2020
  • There is a strong connection between the diet rich in antioxidants and the decreased incidence of inflammatory bowel disease and cancerous diseases. Diets that are rich in anti-oxidants particularly include fruits and vegetables containing the high amounts of vitamin A-E, carotenoids, and minerals. The supercritical heat-treated radish extracts of the research result had an inhibitory effect on the development of aberrant crypt foci (ACF), namely, preneoplastic lesions having a potential to become cancer cells and reduced the number of the aberrant crypt foci (ACF) consisting of four or more aberrant crypts (AC) having high risk to become tumors by about half. The supercritical heat-treated radish extracts can reduce the incidence of preneoplastic lesions having a high risk of developing cancer by about 28 %. DSS-treated mice developed symptoms similar to those of human UC, such as severe bloody diarrhea and weight loss. Supercritical heat-treated radish extracts, as well as sulfasalazine, suppressed colonic length and mucosal inflammatory infiltration. In addition, supercritical heat-treated radish extracts treatment significantly reduced the expression of pro-inflammatory signaling molecules through suppression both mitogen-activated protein kinases (MAPK) and nuclear factor-kappa B (NF-kB) signaling pathways, and prevented the apoptosis of colon. Moreover, supercritical heat-treated radish extracts administration significantly led to the up-regulation of anti-oxidant enzyme including SOD and Catalase.

Effect of PTMGDA-PEGMA dopant on PVDF ultrafiltration membrane

  • Chen, Gui-E.;Huang, Hui-Hong;Xu, Zhen-Liang;Zhang, Ping-Yun;Wu, Wen-Zhi;Sun, Li;Liu, Yan-Jun
    • Membrane and Water Treatment
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    • 제7권6호
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    • pp.539-553
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    • 2016
  • As a novel hydrophobic monomer, polytetrahydrofuran diacrylate (PTMGDA) was synthesized by the esterification reaction between polyethylene tetrahydrofuran (PTMG) and acryloyl chloride (AC). In situ free radical polymerization reaction method was utilized to fabricate poly (vinylidene fluoride) (PVDF)-PTMGDA-poly(ethylene oxide) dimethacrylate (PEGMA) ulrafiltration (UF) membranes. The performances of PVDF-PTMGDA-PEGMA UF membranes in terms of morphologies, mechanical properties, separation properties and hydrophilicities were investigated. The introduction of the PTMGDA-PEGMA dopants not only increased the membranes' pure water flux, but also improved their mechanical properties and the dynamic contact angles. The addition of the PTMGDA/PEGMA dopants led to the formation of the finger-like structure in the membrane bulk. With the increase concentration of PTMGDA/PEGMA dopants, the porosity and the mean effective pore size increased. Those performances were coincide with the physicochemical properties of the casting solutions.

Synthesis of InP Nanocrystal Quantum Dots Using P(SiMe2tbu)3

  • 정소명;김영조;정소희
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.533-534
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    • 2012
  • Colloidal III-V semiconductor nanocrystal quantum dots (NQDs) have attracted attention as they can be applied in various areas such as LED, solar cell, biological imaging, and so on because they have decreased ionic lattices, lager exciton diameter, and reduced toxicity compared with II-VI compounds. However, the study and application of III-V semiconductor nanocrystals is limited by difficulties in control nucleation because the molecular bonds in III-V semiconductors are highly covalent compared to II-VI compounds. There is a need for a method that provides rapid and scalable production of highly quality nanoparticles. We present a new synthetic scheme for the preparation of InP nanocrystal quantum dots using new phosphorus precursor, P(SiMe2tbu)3. InP nanocrystals from 530nm to 600nm have been synthesized via the reaction of In(Ac)3 and new phosphorus precursor in noncoordinating solvent, ODE. This opens the way for the large-scale production of high quality Cd-free nanocrystal quantum dots.

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Corrosion Mechanisms of New Wrought Mg-Zn Based Alloys Alloying with Si, Ca and Ag

  • Ben-Hamu, G.;Eliezer, D.;Shin, K.S.;Wagner, L.
    • Corrosion Science and Technology
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    • 제7권3호
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    • pp.152-157
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    • 2008
  • New wrought magnesium alloys have increasingly been developed in recent years for the automotive industry due to their high potential as structural materials for low density and high strength/weight ratio demands. However, their poor mechanical properties and low corrosion resistance have led to a search for new kinds of magnesium alloys with better strength, ductility, and high corrosion resistance. The main objective of this research is to investigate the corrosion behaviour of new magnesium alloys: Mg-Zn-Ag (ZQ), Mg-Zn-Mn-Si (ZSM) and Mg-Zn-Mn-Si-Ca (ZSMX). These ZQ6X, ZSM6X1, and ZSM651+YCa alloys were prepared using hot extrusion. AC, DC polarization and immersion tests were carried out on the extruded rods. Microstructure was examined using optical and electron microscopy (SEM) and EDS. The addition of silver decreased the corrosion resistance. The additions of silicon and calcium also affected the corrosion behaviour. These results can be explained by the effects of alloying elements on the microstructure of Mg-Zn alloys such as grain size and precipitates caused by the change in precipitation and recrystallisation behaviour.