• 제목/요약/키워드: AC Etching

검색결과 30건 처리시간 0.03초

알루미늄 음극박의 에치 피트 성장 (Growth of Etch Pits on Aluminium Cathode Film)

  • 김홍일;김성한;김영삼;신진식;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.338-339
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    • 2005
  • The wider surface of the aluminum foil, electrochemically very important and it is necessary to increase the surface area. A study has been made of the fabrication condition for etching cube texture of high purity aluminium foil and of electrochemical etching of the aluminium foil. In the present work, it is shown there exists a relation between the influence of the pre-treatment time in the NaOH & HCI solution and $H_2SO_4$ concentration in the conversion solution. Also effect of temperature during AC etching was also studied. Result of the etched aluminum film is shown in the typical SEM images. Its electrochemical characteristics were investigated by cyclic voltammetry. And effects of current density and frequency is also reported. Cyclic voltammogram showed that the protective oxide film was formedon the inner surfaces of etch pit. the frequency influence resistance of oxide film in AC etching.

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알루미늄 전해 커패시터용 음극박의 에칭 피트 성장 (Etch Pit Growth on Aluminum of Cathode Film for Aluminum Electrolytic Capacitor)

  • 김홍일;최호길;김성한;김영삼;신진식;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.407-408
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    • 2005
  • High surface area electrodes for aluminum electrolytic capacitors are produced by AC electrochemical processes. Optimization of crystallographic etch pit growth on aluminium during AC etching of cathode film for aluminium as electrolytic capacitor has been established. In this work, we present the observations of pit distributions by galvanostatic measurements. The effects of electrolyte concentration, current density, frequency, various pre-treatments and etching time have been studied. The specimen was pretreated in 0.5M NaOH and 1M HCl at $40\sim60^{\circ}C$, and transferred into a cell containing 1M HCl, then various mol $H_2SO_4$ etchant was added. Pit size distributions were determined with scanning electron microscopy (SEM).

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염산용액내에 황산 첨가에 의한 알루미늄의 교류에칭 특성 (Effect of Sulfuric Acid Addition on the Aluminum AC Etching in HCl Solution)

  • 김행영;최진섭;탁용석
    • 공업화학
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    • 제9권4호
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    • pp.463-468
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    • 1998
  • 알루미늄의 부식에 있어서 HCI 용액내에 황산을 첨가하는 경우 황산이온의 화학적 흡착에 의한 부식억제 효과가 나타나며, CV (cyclic voltammetry) 실험결과 황산이온은 핏트내부에 보호성 산화피막을 생성함으로서 에치핏트가 핏트내부와 알루미늄 표면에 함께 생성되어 핏트의 밀도가 증가하였다. 알루미늄 교류에칭시에 핏트분포는 황산이온의 농도와 환원전류량에 의하여 크게 영향을 받으며, 환원전류인가시 $0.8mC/cm^2$ 이하의 전하량에서 핏트내부에 생성된 산화피막은 황산이온 농도의 증가에 따라 핏트발생에 대한 저항성이 중가하였으나, $0.8mC/cm^2$ 이상에서는 산화피막내에 국부적인 구조변화가 발생하며 황산이온 농도에 관계없이 산화피막의 파괴가 빠르게 진행되었다.

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Effect of Aluminum Fence-type electrode Design on Characteristics of AC-PDP

  • Lee, Seog-Young;Lee, Dong-Heon;Kim, Yong-Seog
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.408-411
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    • 2008
  • In an attempt to enhance luminance efficiency and to reduce discharge delays of test panels with aluminum fence-electrodes, various designs of the electrodes were prepared by chemically etching the aluminum foils bonded to soda-lime glass substrate via anodic bonding process. The effects of fence design on luminance and discharge characteristics were investigated and compared with conventional ac-PDPs. These results showed a possibility of using fence-type aluminum electrode at front plates of ac-PDDs without sacrificing its performance.

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Hot AC Anodising as a Cr(VI)-free Pre-treatment for Structural Bonding of Aluminium

  • Lapique, Fabrice;Bjorgum, Astrid;Johnsen, Bernt;Walmsley, John
    • 접착 및 계면
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    • 제4권2호
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    • pp.21-29
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    • 2003
  • Hot AC anodising has been evaluated us pre-treatment for aluminium prior to structural adhesive bonding. Phosphoric and sulphuric acid hot AC anodising showed very promising adhesion promoter capabilities with durability comparable with the best standard DC anodising procedures. AC anodising does not required etching prior to anodising and offers u pre-treatment time down to 20 seconds. The interface/interphase between the aluminium substrate and the adhesive was investigated in order to get a better understanding of the involved adhesion mechanisms and to explain the long-tenn properties. The alkaline medium formed at the oxide layer/adhesive interface has been shown to induce a partial dissolution of the oxide layer leading to the formation of metallic ions which diffuse in the adhesive (EPMA measurements). The effect of diffusion of the Al ions on adhesion and joint durability is still uncertain but studies showed that pre-bond moisture affected the joints durability and to some extent the diffusion length. specially for DC anodised samples. So far no direct correlation could be established between the diffusion length d and the joints durability but new trials with better control over the elapsed time between bonding and adhesive curing are expected to help getting a better understanding of the involved mechanisms.

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등방성 언더컷 식각에 의한 에어-브리지 소자 격리 구조를 갖는 AaGaAs/GaAs HBT의 제작에 관한 연구 (A study of the fabrication of AlGaAs/GaAs HBT with an air-bridge isolation structure induced by isotropic undercut etching)

  • 김연태;이제희;윤상호;권오섭;반용찬;원태영
    • 전자공학회논문지D
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    • 제35D권5호
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    • pp.40-47
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    • 1998
  • This paper report sthe design, fabrication and characterization of an AlGaAs/GaAs HBT (heterojunction bipolar transistor) with an air-bridge isolation structure which is made to improve high frequency characteristics for the application to the mobile communication system in the next genration. We found that the size, shape and structure of HBT have an effect on the high frequency operation. The measured dc and ac characteristics of the four type HBTs were compared and analyzed. An E-type HBT with an air-bridge structure by undercut etching exhibited .beta.=56, $V_{off-set}$ = 0.3 V, B $V_{CEO}$=7.0V with $f_{T}$=40 GHz and $f_{max}$=45GHz at a collector current density of 7.1*10$^{4}$ A/c $m^{2}$.>.

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$C_4F_{8}O_2$ 공정기체와 E-ICP를 이용한 산화막 식각 ($SiO_2$ Etching in $C_4F_{8}$ Plasma by E-ICP)

  • 송호영;조수범;이종근;오범환;박세근
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 하계종합학술대회 논문집(2)
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    • pp.197-200
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    • 2001
  • Novel Enhanced Inductively Coupled Plasma is applied to etch $SiO_2$. Effect of $O_2$ or Ar addition to $C_{4}F_{8}$ gas is monitored by Optical Emission Spectroscopy and Quadrupole Mass Spectrometer. It is fund that Ar or $O_2$ dilution to $C_{4}F_{8}$ increases F emission intensity and decreases $CF_2$ intensity. However, the ac frequency to the Helmholtz coil decreases the F intensity and thus increases $CF_2$/F ratio. By adjusting the ac frequency, the optimum etch rate and PR to $SiO_2$ selectivity can be obtained in E-lCP.

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다공성 실리콘막을 포함한 전기침투 방식 펌프에서의 비대칭적 인 유동 (Asymmetric Flows for Porous Silicon Electroosmotic Pumps)

  • 김대중
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 춘계학술대회논문집
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    • pp.703-704
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    • 2008
  • We fabricated and tested porous silicon-based electroosmotic pumps. Compared to other pumping media, porous silicon is beneficial for obtaining comparable flow rates with much lowered electric potential, while maintaining enough mechanical properties. We fabricated porous silicon with two sided-reactive etching processes. We found higher flow rate per electric potential (consistent with previous studies) and we also found asymmetric flow rates for different pumping directions. We plan to utilize this asymmetry for AC pumping applications.

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Template 방법을 이용한 Hybrid Supercapacitor 전극용 알루미늄 분말 디스크 제조와 에칭 조건 연구 (Fabrication of Aluminum Powder Disk by a Template Method and Its Etching Condition for an Electrode of Hybrid Supercapacitor)

  • 진창수;이용성;신경희;김종휘;윤수길
    • 전기화학회지
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    • 제6권2호
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    • pp.145-152
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    • 2003
  • 전해 캐패시터와 supercapacitor의 특성을 함께 가지는 하이브리드 캐패시터의 용량은 표면이 산화물로 피복된 양극에 의해서 좌우된다 본 연구에서는 고전압 하이브리드 슈퍼캐패시터의 제조를 위해 양극의 용량 최적화를 수행하였다. $40{\mu}m$의 입자경을 갖는 알루미늄 분말과 NaCl분말을 4:1의 무게비로 혼합하여 디스크 형태의 전극을 만들고 열처리를 하였다. 열처리 후 $50^{\circ}C$의 증류수에서 NaCl을 용해시켜 열처리 온도에 따른 용량과 저항을 비교하였다. 최적의 열처리 과정을 거친 후 electropolishing 및 화학처리, 1차 및 2차 에칭을 단계별로 행하였고 각각의 단계에서 최적의 조건을 조사하였다 각각의 단계에서의 용량과 저항은 ac impedance analyzer를 사용하여 측정하였으며 전극의 표면은 SEM을 이용하여 관찰하였다. 2차 에칭 후 내전압이 300V급인 전극으로 만들기 위하여 365V로 양극산화 시켰으며, 산화된 알루미늄 디스크 전극을 사용하여 단위 셀을 제조하여 주파수에 따른 용량과 저항 특성을 기존의 300V급 알루미늄 전해 캐패시터와 비교하였다.