• Title/Summary/Keyword: A-CN-K

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Curve Number for a Small Forested Mountainous Catchment (산지 소유역 유출곡선지수)

  • Oh, Kyoung-Doo;Jun, Byong-Ho;Han, Hyung-Geun;Jung, Sung-Won;Cho, Young-Ho;Park, Soo-Yun
    • Journal of Korea Water Resources Association
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    • v.38 no.8 s.157
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    • pp.605-616
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    • 2005
  • In this paper, runoff curve numbers (CN's) for a small forested mountainous catchment are estimated using rainfall-runoff data measured at Sulma experimental catchment every 10 minutes and a new guideline for applying the antecedent rainfall conditions (ARC's) for small mountainous watersheds in Korea is proposed. Sulma experimental catchment is a typical natural mountainous basin with $97\%$ of forested land cover and CN's are estimated to be in the range between 51 and 89 with median value of 72. The test hypothesis stating as 1-day ARC is better than 5-day ARC in determining CN's for a small mountainous watershed is shown to be acceptable. Also, linear regression equations for the estimation of CN's for small mountainous catchments are proposed. As there is no significant investigations available on CN's for small mountainous catchments, the newly proposed relationships between CN's and ARC may be used as a preliminary guideline to assign CN's for the estimation of floods from rainfall data on mountainous regions.

Reaction of the Fe(II) Macrocyclic Complexes with Dioxygen : Preparation of New Unsaturated Ring Systems by Oxidative Dehydrogenation Reactions of Fe(II) Macrocyclic Ligands (이가철 거대고리 리간드의 착화합물과 산소 분자간의 반응 : 이가철 거대고리 리간드 착화합물의 산화성 탈수소 반응에 의한 새로운 불포화 고리계의 합성)

  • Myunghyun Paik;Shin-Geol Kang;Kyu Whan Woo
    • Journal of the Korean Chemical Society
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    • v.28 no.6
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    • pp.384-392
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    • 1984
  • Reaction of the Fe(II) complex of a fully saturated tetradentate macrocyclic ligand [Fe([14]aneN$_4)(CH_3CN)_2]^{2+}$, where [14]ane$N_4$ represents 1,4,8,11-tetraazacyclotetradecane, with $O_2$ has been investigated in acetonitrile solutions. [Fe([14]aneN$_4)(CH_3CN)_2]^{2+}$ reacts with oxygen to yield low spin Fe(III) species, [Fe([14]aneN$_4)(CH_3CN)_2]^{3+}$, which undergoes metal ion assisted oxidative dehydrogenation of the macrocyclic ligand to produce low spin Fe(II) complex, [Fe([14]tetraeneN$_4)(CH_3CN)_2]^{2+}$. The macrocyclic ligand in [Fe([14]tetraeneN$_4)(CH_3CN)_2]^{2+}$ is highly unsaturated and its double bonds are conjugated. [Fe([14]dieneN$_4)(CH_3CN)_2]^{2+}$ and [Fe([14]dieneN$_4)(CH_3CN)_2]^{3+}$ are isolated as the intermediates of the reaction. The Fe(II) complexes involved in this oxidative dehydrogenation reaction react with carbon monoxide to give respective carbon monoxide derivatives, [FeL$(CH_3CN)(CO)]^{2+}$ (where L = macrocyclic ligand). The values of $v_{CO}$ of [FeL$(CH_3CN)(CO)]^{2+}$, and the electrochemical oxidation potentials of Fe(II) ${\to}$ Fe(III) and the qualitative stability toward air-oxidation for [FeL(CH$_3CN_2)^{2+}$ increase as the degree of unsaturation of the macrocyclic ligands increase.

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Algebraic Kripke-style semantics for an extension of HpsUL, CnHpsUL* (CnHpsUL*을 위한 대수적 크립키형 의미론)

  • Yang, Eunsuk
    • Korean Journal of Logic
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    • v.19 no.1
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    • pp.107-126
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    • 2016
  • This paper deals with Kripke-style semantics for weakening-free non-commutative fuzzy logics. As an example, we consider an algebraic Kripke-style semantics for an extension of the pseudo-uninorm based fuzzy logic HpsUL, $CnHpsUL^*$. For this, first, we recall the system $CnHpsUL^*$, define its corresponding algebraic structures $CnHpsUL^*$-algebras, and algebraic completeness results for it. We next introduce a Kripke-style semantics for $CnHpsUL^*$, and connect it with algebraic semantics.

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Fabrication and Characteristics of $SnO_{2}/Al_{2}O_{3}/Pd$ Thick Film Devices for Detection of $CH_{3}CN$ Vapor ($CH_{3}CN$ 감지를 위한 $SnO_{2}/Al_{2}O_{3}/Pd$ 후막소자의 제조 및 그 특성)

  • Park, Hyo-Derk;Jo, Sung-Guk;Sohn, Jong-Rack;Lee, Duk-Dong
    • Journal of Sensor Science and Technology
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    • v.1 no.2
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    • pp.107-116
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    • 1992
  • The optimum base material was selected by the thermal decomposition temperature of $CH_{3}CN$ on the surface of various metal oxides, and the FT-IR analyses of its products. On the surface of $SnO_{2}$, $CH_{3}CN$ was initiated to decompose at $130^{\circ}C$ and produced a lot of products at $200^{\circ}C$. The products from the reaction were found to be $H_{2}O$, $NH_{3}$ and CO, but $N_{2}O$ has started to produce at $320^{\circ}C$. The sensing characteristics of $SnO_{2}$ sensor to $CH_{3}CN$ are influenced by the absorbed species which are produced by the oxidation reaction of $CH_{3}CN$ on the surface of metal oxide. The gaseous species produced from the surface of sensing material in the oxidation reaction were found to be CO, $NH_{3}$, $H_{2}O$ and $NO_{x}$ etc.. It was assumed that the amount of $NO_{x}$ play a great role to the determining sensing properties. In the condition of 170 ppm $CH_{3}CN$, the sensitivity and optimum operating temperature of $SnO_{2}$ were 70% and $300^{\circ}C$, respectively. In this research, the response time of $CH_{3}CN$ to $SnO_{2}/Al_{2}O_{3}/Pd$ sensor added with 0.2 wt % Pd was found about 10 sec and sensitivity was also found relatively high.

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Comparison of Nursing Performance by Career Levels in a Nurse Career Ladder System (경력개발시스템 경력단계별 수술실 간호사 업무수행능력 비교)

  • Kim, Myoung-Sook;Park, Sung-Ae
    • The Journal of Korean Academic Society of Nursing Education
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    • v.18 no.2
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    • pp.284-292
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    • 2012
  • Purpose: This study was to compare nursing performance by career levels in a career ladder system. Methods: This survey was conducted with 140 OR staff nurses. Ten unit managers evaluated their own staff with a performance evaluation tool composed of 51 items. Data were analyzed by frequency, t-test, one-way ANOVA, ${\chi}^2$-test, and ANCOVA. Results: In career level CN II, nursing performance showed differences by personal characteristics. However, there was no significant difference in level CN III. CN IIIs' nursing performance was significantly higher than CN IIs' in all domains. Nursing performance of CN III was significantly higher than CN IIs' in 5 to 10 years of clinical experience. Although there was no significant difference in other clinical experience groups, CN IIIs' scores were always higher than CN IIs' Conclusion: The results indicate that nursing performance improves with career ladder advancement. Organizations should encourage advancement to higher levels and eliminate obstacles.

Enhanced Electrochemical Performance of NaxFe2(CN)6 Positive Electrode Materials for Lithium-ion Batteries (리튬이온 이차전지용 양극물질로서 NaxFe2(CN)6의 전기화학적 성능개선 연구)

  • Yoo, Seong Tae;Yoon, Seung Ju;Kang, Jeong Min;Kim, Haebeen;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.23 no.1
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    • pp.11-17
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    • 2020
  • The Prussian blue analogues of Fe2(CN)6 and NaxFe2(CN)6 are prepared by precipitation method and evaluated the electrochemical characteristics as positive electrode materials for lithium-ion batteries (LIBs) because of their low cost. Fe2(CN)6 shows a low reversible capacity of 34.6 mAh g-1, whereas sodium-containing NaxFe2(CN)6 exhibits a reversible capacity of 107.5 mAh g-1 when the discharge process proceeds first. When charging is first carried out to remove sodium in the structure, the reversible capacity of 114.1 mAh g-1 is achieved and the cycle performance is further improved. In addition, Nax-Fe2(CN)6 is synthesized at 0℃, room temperature (RT), and 60℃, respectively. Regardless of the synthesis temperature, NaxFe2(CN)6 shows similar initial reversible capacity, but the crystallite size is formed smaller and improved cycle performance when synthetic temperature is lower. The sample synthesized at 0℃ shows a reversible capacity of 86.4 mAh g-1 at the 120th cycle and maintains 76.8% of the initial capacity.

Determination of Allantoin in Dioscorea Rhizoma by High Performance Liquid Chromatography Using Cyano Columns

  • Yoon, Kee-Dong;Yang, Min-Hye;Chin, Young-Won;Park, Ju-Hyun;Kim, Jin-Woong
    • Natural Product Sciences
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    • v.14 no.4
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    • pp.254-259
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    • 2008
  • An easy and reliable HPLC method was developed to determine allantoin in Dioscorea Rhizoma using cyano columns. Qualitative and quantitative analyses of allantoin were performed successfully by cyano columns (YMC-Pack CN column, Zorbax SB-CN column and Discovery$^{(R)}$ Cyano column). The intraday precision were 0.58 - 3.33% for YMC-Pack CN, 0.41 - 2.20 for Zorbax SB-CN and 0.45 - 1.93% Discovery$^{(R)}$ Cyano columns, while interday variations were 0.09 - 1.84%, 0.04 - 2.59% and 0.87 - 5.18% for YMC-Pack CN, Zorbax SB-CN and Discovery$^{(R)}$ Cyano columns. The recoveries of allantoin were in the range at 98.8 - 102.6% (RSD 1.1 - 1.6%) for YMC-Pack CN column, 99.7 - 110.5% (RSD 1.3 - 4.9%) for Zorbax SB-CN column, and 97.2 - 110.1% (RSD 1.8 - 5.7%) for Discovery$^{(R)}$ Cyano column. The contents of allantoin in four Dioscorea Rhizoma samples were determined by cyano columms and ranged at 4.1-7.1 mg/g dry weight. The present study indicated that HPLC method using cyano column for determining allantoin is a reliable method and this method can be applied to verify allantoin in Dioscorea Rhizoma.

Protective Effects of Ginsenosides on Cyanide-induced Neurotoxicity in Cultured Rat Cerebellar Granule Cells

  • Seong, yeon-Hee;Koh, Sang-Bum;Jo, Soon-Ok
    • Journal of Ginseng Research
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    • v.24 no.4
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    • pp.196-201
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    • 2000
  • Effects of ginsenosides on NaCN-induced neuronal cell death were studied in cultured rat cerebellar granule cells. NaCN produced a concentration-dependent (1-10 mM) reduction of cell viability (measured by frypan blue exclusion test), that was blocked by N-methyl-D-aspartate receptor antagonist (MK-801) and L-type Ca$\^$2+/ channel blocker (verapamil). Pretreatment with ginsenosides (Rb$_1$, Rc, Re, Rf and Rg$_1$) significantly decreased the neuronal cell death in a concentration range of 0.5∼5$\mu\textrm{g}$/ml. Ginsenosides Rb$_1$ and Rc (5 $\mu\textrm{g}$/ml) inhibited glutamate release into medium induced by NaCN (5 mM). NaCN (1 mM)-induced increase of [Ca$\^$2+/], was significantly inhibited by the pretreatment of Rb$_1$ and Rc (5 $\mu\textrm{g}$/ml). Other ginsenosides caused relatively little inhibition on the elevation of glutamate release and of (Ca$\^$2+/). These results suggest that the NaCN-induced neurotoxicity was related to a series of cell responses consisting of glutamate release and [Ca$\^$2+/]i elevation via glutamate (NMDA and kainate) receptors and resultant cell death, and that ginsenosides, especially Rb$_1$ and Rc, prevented the neuronal cell death by the blockade of the NaCN-induced Ca$\^$2+/influx.

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Chemical Weathering Trend of Granitic Rock in Hwangtohyun, Korea (한반도 서부 황토현 일대 적색토의 화학적 풍화 경향)

  • Kim, Young-Rae
    • Journal of the Korean association of regional geographers
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    • v.18 no.1
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    • pp.17-26
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    • 2012
  • In Hwangtohyun, meaning 'red soil pass', reddish surface mantles is widespread. Other granitic hills, exceptionally Naju and Youngam area, in Korean peninsula don't commonly have that color. This paper attempts to address this issue by CIA(chemical index of alteration). CIA data and A-CN-K diagram provide crucial insights into the changes in the relative contributions of chemical physical weathering in difference of grus regolith and saprolite. CaO and $Na_2O$ show strong depletion and $K_2O$ is progressive loss. In grus regolith, weathering trends are (sub)parallel to the CN-A join of the A-CN-K diagram, but the sample's composition plot ever closer to the A-K join in saprolite. The difference of weathering trend obtained using CIA data corresponds closely with the visual interpretation of soil color and texture.

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Characteristics of Aerosol and Cloud Condensation Nuclei Concentrations Measured over the Yellow Sea on a Meteorological Research Vessel, GISANG 1 (기상 관측선 기상 1호에서 관측한 황해의 에어로졸과 구름응결핵 수농도 특성 연구)

  • Park, Minsu;Yum, Seong Soo;Kim, Najin;Cha, Joo Wan;Ryoo, Sang Boom
    • Atmosphere
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    • v.26 no.2
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    • pp.243-256
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    • 2016
  • Total number concentration of aerosols larger than 10 nm ($N_{CN10}$), 3 nm ($N_{CN3}$), and cloud condensation nuclei ($N_{CCN}$) were measured during four different ship cruises over the Yellow Sea. Average values of $N_{CN10}$ and $N_{CCN}$ at 0.6% supersaturation were 6914 and $3353cm^{-3}$, respectively, and the minimum value of $N_{CN10}$ was $2000cm^{-3}$, suggesting significant anthropogenic influence even at relatively clean marine environment. Although $N_{CN10}$ and $N_{CN3}$ increased near the coast due to anthropogenic influence, $N_{CCN}$ was relatively constant and therefore $N_{CCN}/N_{CN10}$ ratio tended to decrease, suggesting that coastal aerosols were relatively less hygroscopic. In general $N_{CN10}$, $N_{CN3}$, and $N_{CCN}$ during the cruises seemed to be significantly influenced by wet scavenging effects (e.g. fog) and boundary layer height variation. Only one new particle formation (NPF) event was observed during the measurement period. Interestingly, the NPF event occurred during a dust storm event and spatial scale of the NPF event was estimated to be larger than 100 km. These results demonstrate that aerosol and CCN concentration over the Yellow Sea can vary due to various different factors.