• Title/Summary/Keyword: 6LiF

Search Result 408, Processing Time 0.02 seconds

UNICITY OF MERMORPHIC FUNCTIONS CONCERNING SHARED FUNCTIONS WITH THEIR DIFFERENCE

  • Deng, Bingmao;Fang, Mingliang;Liu, Dan
    • Bulletin of the Korean Mathematical Society
    • /
    • v.56 no.6
    • /
    • pp.1511-1524
    • /
    • 2019
  • In this paper, we investigate the uniqueness of meromorphic functions of finite order concerning sharing small functions and prove that if f(z) and ${\Delta}_cf(z)$ share a(z), b(z), ${\infty}$ CM, where a(z), b(z)(${\neq}{\infty}$) are two distinct small functions of f(z), then $f(z){\equiv}{\Delta}_cf(z)$. The result improves the results due to Li et al. ([9]), Cui et al. ([1]) and $L{\ddot{u}}$ et al. ([12]).

Synthesis of $Cp^*Ru(CO)(PR_3)H$ Type Complexes and Photo-Induced H/D Exchange Reaction ($Cp^*Ru(CO)(PR_3)H$형 착물의 합성과 광반응에 의한 H/D 교환반응)

  • Lee, Dong Hwan;Kim, Sng Il;Kim, Jang Il;Oh, Yung Hee;Kam, Sang Kyu
    • Journal of the Korean Chemical Society
    • /
    • v.41 no.12
    • /
    • pp.645-652
    • /
    • 1997
  • Hydride complexes Cp*Ru(CO)(PR3)H (Cp*=η5-C5Me5, PR3=PMe3, PEt3, PMePh2, PPh3, PCy3)(4a-4f) were synthesized by the reaction of the corresponding chloro complex Cp*Ru(CO)(PR3)Cl (3a-3f) with various hydridic reagent (NaBH4, LiAlH4, LiBEt3H) or NaOMe. Irradiation of Cp*Ru(CO)(PCy3)H (5e) in C6D6 solution with UV light caused H/D exchange reaction between coordinated Cp*, PCy3 and/or Ru-H ligand proton and a deuterium of the deuterated aromatic solvent through a series of inter- and intramolecular C-H activation. The proposed mechanism was described.

  • PDF

A LiPF6-LiFSI Blended-Salt Electrolyte System for Improved Electrochemical Performance of Anode-Free Batteries

  • Choi, Haeyoung;Bae, YeoJi;Lee, Sang-Min;Ha, Yoon-Cheol;Shin, Heon-Cheol;Kim, Byung Gon
    • Journal of Electrochemical Science and Technology
    • /
    • v.13 no.1
    • /
    • pp.78-89
    • /
    • 2022
  • ANODE-free Li-metal batteries (AFLMBs) operating with Li of cathode material have attracted enormous attention due to their exceptional energy density originating from anode-free structure in the confined cell volume. However, uncontrolled dendritic growth of lithium on a copper current collector can limit its practical application as it causes fatal issues for stable cycling such as dead Li formation, unstable solid electrolyte interphase, electrolyte exhaustion, and internal short-circuit. To overcome this limitation, here, we report a novel dual-salt electrolyte comprising of 0.2 M LiPF6 + 3.8 M lithium bis(fluorosulfonyl)imide in a carbonate/ester co-solvent with 5 wt% fluoroethylene carbonate, 2 wt% vinylene carbonate, and 0.2 wt% LiNO3 additives. Because the dual-salt electrolyte facilitates uniform/dense Li deposition on the current collector and can form robust/ionic conductive LiF-based SEI layer on the deposited Li, a Li/Li symmetrical cell exhibits improved cycling performance and low polarization for over 200 h operation. Furthermore, the anode-free LiFePO4/Cu cells in the carbonate electrolyte shows significantly enhanced cycling stability compared to the counterparts consisting of different salt ratios. This study shows an importance of electrolyte design guiding uniform Li deposition and forming stable SEI layer for AFLMBs.

Preparation and Characterization of Microporous PVdF Membrane for Li-ion Rechargeable Battery (이차전지용 미세다공성 PVdF 분리막의 제조와 물성)

  • Nam, Sang-Yong;Yu, Dae-Hyun;Jeong, Mi-Ae;Rhim, Ji-Won;Byun, Hong-Sik;Jeong, Chul-Ho;Lee, Young-Moo;Seo, Myung-Su
    • Membrane Journal
    • /
    • v.17 no.3
    • /
    • pp.233-243
    • /
    • 2007
  • In this study, a separate. which is a microporous membrane based on poly(vinylidene fluoride)(PVdF) was prepared by phase inversion method. Being prepared by dissolving the PVdF in the N,N'-dimethylformamide(DMF) with mechanical stirring, the homogenous casting solution was cast onto a clean glass plate. Pore size and porosity of the membranes were controlled by changing preparation condition. The highest porosity of the membrane was 78.6%. The mechanical property of the membrane was determined by using an universal testing machine(UTM). The morphology of the membrane was investigated by scanning electron microscopy(SEM). The cross-section of the membrane shows sponge-like small micro-pores.

Preparation and Characterization of PVdF-HFP Microporous Membranes for Li-ion Rechargeable Battery (Poly(vinylidene fluoride-hexafluoropropylene)를 이용한 이차전지용 미세다공성 분리막의 제조와 물성)

  • Nam, Sang-Yong;Yu, Dae-Hyun;Jeong, Mi-Ae;Rhim, Ji-Won;Byun, Hong-Sik;Yoo, Hyun-Oh;Kim, Jong-Man;Seo, Myung-Su
    • Membrane Journal
    • /
    • v.17 no.4
    • /
    • pp.359-368
    • /
    • 2007
  • The copolymer membranes, poly(vinylidene fluoride-hexafluoropropylene) (PVdF-HFP) were prepared by phase inversion method using as an additive with N,N-dimethylformamid as a solvent. The pores are generated during the solvent and non-solvent exchange process in the coagulation bath filled with non-solvent (distilled water). The highest porosity of the membrane was 60%. The surface and cross-section of the membranes was observed with a scanning electron microscopy (SEM). The mechanical property of the membrane was determined by using an universal testing machine (UTM). Tensile strength of measured membranes is presented the maximum 6.57 MPa at 30 wt% of PVdF-HFP.

Crystallographic and Magnetic Properties of Li0.5Fe2.5-χRhχO4 by Using Applied Field Mossbauer Spectrometer (외부자기장 뫼스바우어 분광기를 이용한 Li0.5Fe2.5-χRhχO4의 자기적 성질과 결정학적 구조에 관한 연구)

  • Kang, Kun-Uk;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
    • /
    • v.14 no.6
    • /
    • pp.219-223
    • /
    • 2004
  • L $i_{0.5}$F $e_{2.5-{\chi}}$R $h_{\chi}$ $O_4$ ($\chi$ = 0.25, 0.50, 0.75, 1.00) has been prepared by solid state reaction. Crystallographic and magnetic properties were investigated by Mossbauer spectroscopy, SQUID magnetometry, and x-ray diffraction. The crystal structure is found to be a cubic spinel structure with space group Fd3m for all the samples. The lattice constant $a_{0}$ increases from 8.3365 $\AA$ to 8.3932 $\AA$ with increasing Rh concentration $\chi$. The migration of Li ion has been confirmed by x-ray patterns and the results of applied field Mossbauer analysis. The temperature dependence of the absorption area of each site was analyzed with the Debye model for the recoil-free fraction. The Debye temperature for the octahedral sites is almost as large as for the tetrahedral sites, thereby suggesting similar inter-atomic binding forces for the octahedral and the tetrahedral sites. The saturated magnetic moment and the Mossbauer spectra taken at 4.2 K under the applied field (6 T) show that the spin structure of L $i_{0.5}$F $e_{2.5-{\chi}}$R $h_{\chi}$ $O_4$ is compatible with the collinear Neel Model.

Simulation of a neutron imaging detector prototype based on SiPM array readout

  • Mengjiao Tang;Lianjun Zhang;Bin Tang;Gaokui He;Chang Huang;Jiangbin Zhao;Yang Liu
    • Nuclear Engineering and Technology
    • /
    • v.55 no.9
    • /
    • pp.3133-3139
    • /
    • 2023
  • Neutron imaging technology as a means of non-destructive detection of materials is complementary to X-ray imaging. Silicon photomultiplier (SiPM), a new type of optical readout device, has overcome some shortcomings of traditional photomultiplier tube (PMT), such as high-power consumption, large volume, high price, uneven gain response, and inability to work in strong magnetic fields. Its application in the field of neutron detection will be an irresistible general trend. In this paper, a thermal neutron imaging detector based on 6LiF/ZnS scintillation screen and SiPM array readout was developed. The design of the detector geometry was optimized by geant4 Monte Carlo simulation software. The optimized detector was evaluated with a step wedge sample. The results show that the detector prototype with a 48 mm × 48 mm sensitive area can achieve about 38% detection efficiency and 0.26 mm position resolution when using a 300 ㎛ thick 6LiF/ZnS scintillation screen and a 2 mm thick Bk7 optical guide coupled with SiPM array, and has good neutron imaging capability. It provides effective data support for developing high-performance imaging detectors applied to the China Spallation Neutron Source (CSNS).

A NOTE ON CONVEXITY OF CONVOLUTIONS OF HARMONIC MAPPINGS

  • JIANG, YUE-PING;RASILA, ANTTI;SUN, YONG
    • Bulletin of the Korean Mathematical Society
    • /
    • v.52 no.6
    • /
    • pp.1925-1935
    • /
    • 2015
  • In this paper, we study right half-plane harmonic mappings $f_0$ and f, where $f_0$ is fIxed and f is such that its dilatation of a conformal automorphism of the unit disk. We obtain a sufficient condition for the convolution of such mappings to be convex in the direction of the real axis. The result of the paper is a generalization of the result of by Li and Ponnusamy [11], which itself originates from a problem posed by Dorff et al. in [7].

Photoluminescence of Li-doped Y2O3:Eu3+ thin film phosphors grown by pulsed laser deposition

  • Yi, Soung-Soo
    • Journal of Sensor Science and Technology
    • /
    • v.11 no.6
    • /
    • pp.371-377
    • /
    • 2002
  • $Y_2O_3:Eu^{3+}$ and Li-doped $Y_2O_3:Eu^{3+}$ thin films have been grown on sapphire substrates using a pulsed laser deposition technique. The thin film phosphors were deposited at a substrate temperature of $600^{\circ}C$ under the oxygen pressure of 100, 200 and 300 mTorr. The films grown under different deposition conditions have been characterized using microstructural and luminescent measurements. The crystallinity and photoluminescence (PL) of the films are highly dependent on the oxygen pressure. The PL brightness data obtained from $Y_2O_3:Eu^{3+}$ films grown under optimized conditions have indicated that sapphire is one of the most promising substrate for the growth of high quality $Y_2O_3:Eu^{3+}$ thin film red phosphor. In particular, the incorporation of $Li^{+}$ ions into $Y_2O_3$ lattice could induce a remarkable increase of PL. The highest emission intensity was observed with LiF-doped $Y_{1.84}Li_{0.08}Eu_{0.08}O_3(Y_2O_3LiEu)$, whose brightness was increased by a factor of 2.7 in comparison with that of $Y_2O_3:Eu^{3+}$ films. This phosphor may promise for application to the flat panel displays.

Fabrication and Characterization of High Performance Green OLEDs using $Alq_3$-C545T Systems ($Alq_3$-C545T시스템을 이용한 고성능 녹색 유기발광다이오드의 제작과 특성 평가)

  • Jang Ji-Geun;Kim Hee-Won;Shin Se-Jin;Kang Eui-Jung;Ahn Jong-Myong;Lim Yong-Gyu
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.13 no.1 s.38
    • /
    • pp.51-55
    • /
    • 2006
  • The green emitting high performance OLEDs using the $Alq_3$-C545T fluorescent system have been fabricated and characterized. In the device fabrication, 2-TNATA [4,4',4'-tris(2-naphthylphenyl-phenylamino)-triphenylamine] as a hole injection material and NPB [N,N'-bis(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] as a hole transport material were deposited on the ITO(indium thin oxide)/glass substrate by vacuum evaporation. And then, green color emission layer was deposited using $Alq_3$ as a host material and C-545T[10-(2-benzothiazolyl)-1,1,7,7- tetramethyl-2,3,6,7-tetrahydro-1H,5H,11H-[1]/benzopyrano[6,7,8-ij]-quinolizin-11-one] as a dopant. Finally, small molecule OLEDs with structure of ITO/2-TNATA/NPB/$Alq_3$:C545T/$Alq_3$/LiF/Al were obtained by in-situ deposition of $Alq_3$, LiF and Al as the electron transport material, electron injection material and cathode, respectively. Green OLEDs fabricated in our experiments showed the color coordinate of CIE(0.29, 0.65) and the maximum power efficiency of 7.3 lm/W at 12 V with the peak emission wavelength of 521 nm.

  • PDF