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NUCLEAR DATA MEASUREMENT OF 186RE PRODUCTION VIA VARIOUS REACTIONS

  • Bidokhti, Pooneh Saidi;Sadeghi, Mahdi;Fateh, Behrooz;Matloobi, Mitra;Aslani, Gholamreza
    • Nuclear Engineering and Technology
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    • v.42 no.5
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    • pp.600-607
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    • 2010
  • Rhenium-186, having a half-life of 90.64 h, is an important radionuclide, used in metabolic radiotherapy and radio immunotherapy. $^{186}Re$ hydroxyethylidene diphosphonate (HEDP) is a new compound used for the palliation of painful skeletal metastases. Its production is achieved via charged-particle-induced reactions; the data are available in EXFOR library. For the work discussed in this paper, production of $^{186}Re$ was done via $^{nat}W(p,n)^{186}Re$ nuclear reaction. Pellets of $^{nat}W$ were used as targets and were irradiated with 15, 17.5, 20, 22.5, 25 MeV proton beams at 5 ${\mu}A$ current. The radiochemical separation was performed by the ion exchange chromatography method. The production yield achieved at 25 MeV was 1.91 $MBq{\cdot}{\mu}A^{-1}{\cdot}h^{-1}$. Excitation functions for the $^{186}Re$ radionuclide, via $^{186}W(p,n)^{186}Re$ and $^{186}W(d,2n)^{186}Re$ reactions were calculated by ALICE-ASH and TALYS-1.0 codes to validate and fit the experimental data and to obtain a recommended set of data for $^{186}W(p,n)^{186}Re$ reaction. Required thickness of the targets was obtained by SRIM code for each reaction.

Measurement of Thermophysical Properties of Various Starches in the Freezing Processes (동결 과정중의 전분의 열역학적 특성에 관한 연구)

  • Kong, Jai-Yul;Kim, Min-Yong;Cheong, Jin-Woong
    • Korean Journal of Food Science and Technology
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    • v.20 no.6
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    • pp.820-826
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    • 1988
  • The freezing point$(t_f)$, latent heat of freezing$({\triangle}\;H_f)$ and kinetic constant of fleering$(k_f)$ were determined from DSC thermogram at cooling rate $-2.5^{\circ}C/min{\sim}-10.0^{\circ}C/min$. The freezing point of various starches was decreased with an increase in cooling rate, and that of whole starches were lower than defatted starches. Changes of the latent heat of freezing was not observed at above cooling rate $-2.5^{\circ}C/min$. The latent heat of freezing$({\triangle}\;H_f)$ could be deduced as a function of water content(W) as follows: ${\triangle}\;H_f=0.700W-13.048$, (Kcal/kg) $(35%{\leqq}W{\leqq}70%)\;{\triangle}\;H_f=1.569W-73.861,\;(Kcal/kg)\;(W{\geqq}70%$) In the water content range $35{\sim}90$(wt %), the activation energy of various starches in freezing process was determined $126{\sim}270$ Kcal/mol.

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Screening and Identification of an Inulinase Producing Microorganism and Optimal Condition for the Enzyme Production (Inulinase 생산균주의 분리.동정 및 효소 생산최적조건)

  • 임성일;이대희;홍석산;유진영
    • Microbiology and Biotechnology Letters
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    • v.28 no.3
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    • pp.156-160
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    • 2000
  • In an attempt to develop an unique enzyme (inulinase) for fructan utilization. bacterial strains were isolated [yom soil. Stram 96-11 secreting inulinase o[ high activity was tentatively identificated as Arthrobacter protophmmiae/ranwsus. The optimum culture conditions o[the slnin for the production of the inulinase were as follow: inorganic saIl basal medium contained sources fl % (w/v) inulin, 1 % (w/v) tryptone, and 1 % (w/v) $NH_4Cl$]. $35^{\circ}C$, initial pH 7.5. aeration 1 vvm and agitation 200 rpm.

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W/TiN 금속 게이트 MOS 소자의 물리.전기적 특성 분석

  • 윤선필;노관종;노용한
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.123-123
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    • 2000
  • 선폭이 초미세화됨에 따라 게이트 전극에서의 공핍 현상 및 불순물 확산의 물제를 갖는 poly-Si 게이트를 대체할 전극 물질로 텅스텐(W)이 많이 연구되어 왔다. 반도체 소자의 배선물질로 일찍부터 사용되어온 텅스텐은 내화성 금속의 일종으로 용융점이 높고, 저항이 낮다. 그러나, 일반적으로 사용되고 있는 CVD에 의한 텅스텐의 증착은 반응가스(WF6)로부터 오는 불소(F)의 게이트 산화막내로의 확산으로 인해 MOS 소자가 크게 열화될수 있다. 본 연구에서는 W/TiN 이중 게이트 전극 구조를 갖는 MOS 캐패시터를 제작하여 전기적 특성을 살펴보았다. P-Type (100) Si위에 RTP를 이용, 85$0^{\circ}C$에서 110 의 열산화막을 성장 및 POA를 수행한 후, 반응성 스퍼터링법에 의해 상온, 6mTorr, N2/Ar=1/6 sccm, 100W 조건에서 TiN 박막을 150, 300, 500 의 3그룹으로 증착하였다. 그 위에 LPCVD 방법으로 35$0^{\circ}C$, 0.7Torr, WF6/SiH4/H2=5/5~10/500sccm 조건에서 2000~3000 의 텅스텐을 증착하였다. Photolithography 공정 및 습식 에칭을 통해 200$\mu\textrm{m}$$\times$200$\mu\textrm{m}$ 크기의 W/TiN 복층 게이트 MOSC를 제작하였다. W/TiN 복측 게이트 소자와 비교분석하기 위해 같은 조건의 산화막을 이용한 알루미늄(Al) 게이트, 텅스텐 게이트 MOSC를 제작하였다. 35$0^{\circ}C$에서 증착된 텅스텐 박막은 10~11$\Omega$/ 의 면저항을 가졌고 미소한 W(110) peak값을 나타내는 것으로 보아 비정질 상태에 가까웠다. TiN 박막의 경우 120~130$\Omega$/ 의 면저항을 가졌고 TiN (200)의 peak 값이 크게 나타난 반면, TiN(111) peak가 미소하게 나타났다. TiN 박막의 두께와 WF/SiH4의 가스비를 변화시켜가며 제작된 MOS 캐패시터를 HF 및 QS C-V, I-V 그리고 FNT를 통한 전자주입 방법을 이용하여 TiN 박막의 불소에 대한 확산 방지막 역할을 살펴 보았다. W/TiN 게이트 MOS 소자는 모두 순수 텅스텐 게이트보다 우수하였고, Al 게이트와 유사한 전기적 특성을 보여주었다. W/TiN 게이트 MOS 소자는 모두 순수 텅스텐 게이트보다 우수하였고, Al 게이트와 유사한 전기적 특성을 보여주었다. TiN 박막이 300 , 500 이고 WF6/SiH4의 가스비가 5:10인 경우 소자 특성이 우수하였으나, 5:5의 경우에는 FNT 전자주입 특성이 열화되기 시작하였다. 그리고, TiN박막의 두께가 150 으로 얇아질 경우에는 WF6/SiH4의 가스비가 5:10인 경우에서도 소자 특성이 열화되기 시작하였다. W/TiN 복층 게이트 MOS 캐패시터를 제작하여 전기적인 특성 분석결과, 순수 텅스텐 게이트 소자의 큰 저전계 누설 전류 특성을 해결할 수 있었으며, 불소확산에 영향을 주는 조건이 WF6/SiH4의 가스비에 크게 의존됨을 알 수 있었다. TiN 박막의 증착 공정이 최적화 될 경우, 0.1$\mu\textrm{m}$이하의 초미세소자용 게이트 전극으로서 텅스텐의 사용이 가능할 것으로 보여진다.

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Effects of Distribution of Axle Load and Inflation Pressure of Tires on Fuel Efficiency of Tractor Operations (차축의 중량 분포와 타이어의 공기압이 트랙터 작업의 연료 효율에 미치는 영향)

  • Lee, Jin-Woong;Kim, Kyeong-Uk;Gim, Dong-Hyeon;Choi, Kyu-Jeong
    • Journal of Biosystems Engineering
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    • v.36 no.5
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    • pp.303-313
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    • 2011
  • This study was conducted to investigate the effects of axle weight distribution and inflation pressure of tire on the fuel economy of tractors as well as operational range of tractor engine in terms of engine speed and power when a 4WD tractor of 38.2 kW rated power at 2500 rpm is used for plowing and flooded-field rotavating in paddy fields. (1) Plowing operation required an average engine power of 9.6~13.5 kW which equals 25~35% of rated PTO power. Engine speed ranged from 1,320.4 to 1,737.4 rpm, work velocity from 3.4 to 4.8 km/h, and fuel consumption from 3.2 to 4.2 L/h, respectively. (2) Flooded-field rotavating required an average engine power of 11.5~18.5 kW which equals 30~48.4% of rated PTO power. Out of this 6.2~12.2 kW was used for PTO power. Engine speed ranged from 1,557 to 2,067 rpm, work velocity from 2.5~5.4 km/h and fuel consumption from 3.2~5.5 L/h, respectively. (3) Axle weight distribution, inflation pressure of tire and moisture content of soil did not affect significantly the specific volumetric fuel consumption but affected significantly the fuel consumption per unit area of operation. Fuel savings amounted to 65% in plowing operation and 20% in flooded-field rotavating when the axle weight distribution and inflation pressure of tire were optimally adjusted. (4) Optimal adjustment of axle weight distribution and inflation pressure of tire are expected to save fuel consumption by 10~65% per unit area of operation in plowing and 10~20% in flooded-field rotavating.

Isolation and Characterization of Oil Degrading Bacteria from Southern Sea of Korea (남해안 해수로부터 원유 분해 세균의 분리 및 특성)

  • 김학주;김봉조;공재열;구헌서
    • KSBB Journal
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    • v.15 no.1
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    • pp.27-34
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    • 2000
  • A marine bacterium having a high oil-degrading activity was isolated form the oil-polluted southern sea of Korea, and was identified as Pseudomonas aeruginosa and was named Pseudomonas aeruginosa BYK-2. The optimal tmeperatur, culture time, pH and NaCl concentration for biosurfactant production and cell growth showed $25^{\circ}C$, 48h, 7.0 and 0%(w/v), respectively. After cultivation at $25^{\circ}C$, 180 rpm in 250 mL erlenmeyer flask for 7days, 1%(w/v) arabian light crude oil and bunker C oil which are considered to be hardly degradable compounds were degraded 92.1%(w/w) and 76%(w/w) respectively. And then, cell adherence was measured on various carbon sources. The cell adherence indicated over 80% on hydrocarbons(arabian light crude oil, kuwait curde oil, bunker C oil, n-paraffine, n-hexadecane, n-tetradecane) as carbon sources. Lecithin among fatty acids(oleic acid, olive oil, lecithin) showed highest cell adherence of 91.5%. The cell adherence of sugars(arabinose, trehalose, dextrose, galactose, lactose, fructose, maltose, sorbitol, sucrose) observed to be less than 70% except for arabinose, galactose, sorbitol and sucrose.

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Microwave Dielectric Properties of Sr-Substituted Ba(Mg0.5W0.5)O3 Ceramics

  • Yoon, Sang-Ok;Choi, Dong-Kyu;Oh, Jun-Hyuk;Kim, Shin
    • Journal of the Korean Ceramic Society
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    • v.55 no.4
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    • pp.364-367
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    • 2018
  • The phase evolution, microstructure, and microwave dielectric properties of Sr-substituted $Ba(Mg_{0.5}W_{0.5})O_3$ ceramics, i.e., $(Ba_{1-x}Sr_x)(Mg_{0.5}W_{0.5})O_3$ ($0{\leq}x{\leq}0.30$), sintered at $1700^{\circ}C$ for 1 h were investigated. All compositions showed a 1 : 1 ordered perovskite structure. In all the compositions, $BaWO_4$ was detected as the secondary phase. With increasing x in ($Ba_{1-x}Sr_x$) $(Mg_{0.5}W_{0.5})O_3$, the lattice parameter increased linearly, indicating that a substitutional solid solution occurred. All compositions exhibited a dense microstructure. The value of ${\varepsilon}_r$ increased slightly with increasing x. The value of $Q{\times}f_0$ increased with the increase in x up to x = 0.10 and reached a saturated value of about 100,000 GHz. The composition for x = 0.20, i.e., $(Ba_{0.80}Sr_{0.20})(Mg_{0.5}W_{0.5})O_3$, sintered at $1700^{\circ}C$ for 1 h exhibited superior microwave dielectric properties of ${\varepsilon}_r=19.6$, $Q{\times}f_0=99,358GHz$, and ${\tau}_f=0.0ppm/^{\circ}C$, respectively.

An Experimental Study on the Mechanical Properties According to the Mixture of Hwang-toh (황토의 역학적 특성에 관한 실험적 연구)

  • Kim, Soon-Chul;Yang, Il-seung;Yang, Hae-Dong
    • KIEAE Journal
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    • v.7 no.3
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    • pp.89-96
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    • 2007
  • The purpose of this experimental study is to investigate the compressive strength, shear strength, bending strength, and crack control by the mixture of the hwang-toh. The size of compressive specimens is $200{\times}200{\times}400(mm)$, and the size of shear, bending specimens is $200{\times}200{\times}600(mm)$. Finally, crack control specimens for comparative comparison is $200{\times}200{\times}15(mm)$. The mixture of the hwang-toh is as follows; Hwangtoh( H)+Water(W), H+W+Sand(S), H+W+S+sTraw(0.5%), H+W+S+sT(1.0%). The actual height, width, and the length are measured at the center of all specimens. The main parameters are mixture ratio of hwang-toh, straw and age of specimens. The test results are as follows. (1) The compressive strength is linearly increased until 15 weeks according to specimen ages. (2) About crack control, the specimen added in 1% straw is the most effective.

$^1H$ NMR Study of 4-Aminopyrimidine Coordinated to the Paramagnetic Undecatung-stocobalto(Ⅱ)silicate Anion: Rates of Internal Rotation of the Amine Group

  • 김병안;소현수
    • Bulletin of the Korean Chemical Society
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    • v.20 no.10
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    • pp.1149-1152
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    • 1999
  • 1H NMR spectrum of a DMF-d7 solution containing 4-aminopyrimidine and [SiW11CoIIO39]6- (SiW11Co) shows separate peaks from two linkage isomers, a and b, in which N(1) and N(3) of the pyrimidine ring are coordinated to SiW11Co, respectively. The signal from the amine group in the isomer a exhibits temperature dependence that is characteristic of a two-site exchange problem. Rates of internal rotation of the amine group were determined by simulating the NMR spectra at 5-35℃. The amine group of free 4-aminopyrimidine also shows temperature-dependent spectra at lower temperatures; rates of internal rotation at (-25)-25℃ were determined. The internal rotation of the amine group in the complex is much slower than that for free 4-aminopyrimidine, indicating that π-character of the C-N bond increases on coordination to SiW11Co. The amine group in the isomer b does not show such behavior. It is probable that hydrogen bonding between N-H and a bridging oxygen atom of SiW11Co prevents it from rotating at low temperatures.