• Title/Summary/Keyword: 5V

Search Result 19,701, Processing Time 0.046 seconds

Synthesis and Photovoltaic Properties of New π-conjugated Polymers Based on Benzo[1,2,5]thiadiazole (Benzo[1,2,5]thiadiazole을 기본 골격으로 한 공액고분자의 합성 및 광전변환특성 연구)

  • Bea, Jun Huei;Lim, Gyeong Eun;Kim, Joo Hyun
    • Applied Chemistry for Engineering
    • /
    • v.24 no.4
    • /
    • pp.396-401
    • /
    • 2013
  • Alternating copolymers, poly[9-(2-octyl-dodecyl)-9H-carbazole-alt-4,7-di-thiophen-2-yl-benzo[1,2,5]thiadiazole] (PCD20TBT) and poly[9,10-bis-(2-octyl-dodecyloxy)-phenanthrene-alt-4,7-di-thiophen-2-yl-benzo[1,2,5]thiadiazole] (PN40TBT), were synthesized by the Suzuki coupling reaction. The copolymers were soluble in common organic solvents such as chloroform, chlorobenzene, 1,2-dichlorobenzene, tetrahydrofuran and toluene. The maximum absorption wavelength and the band gap of PCD20TBT were 535 nm and 1.75 eV, respectively. The maximum absorption wavelength and the band gap of PN40TBT were 560 nm and 1.97 eV, respectively. The HOMO and the LUMO energy level of PCD20TBT were -5.11 eV and -3.36 eV, respectively. As for PN40TBT, the HOMO and the LUMO energy level of PCD20TBT were -5.31 eV and -3.34 eV, respectively. The polymer solar cells (PSCs) based on the blend of copolymer and PCBM (1 : 2 by weight ratio) were fabricated. The power conversion efficiencies of PSCs based on PCD20TBT and PN40TBT were 0.52% and 0.60%, respectively. The short circuit current density ($J_{SC}$), fill factor (FF) and open circuit voltage ($V_{OC}$) of the device with PCD20TBT were $-1.97mA/cm^2$, 38.2% and 0.69 V. For PN40TBT, the $J_{SC}$, FF, and $V_{OC}$ were $-1.77mA/cm^2$, 42.9%, and 0.79 V, respectively.

Characteristics of C-V for Double gate MOSFET (Double gate MOSFET의 C-V 특성)

  • 나영일;김근호;고석웅;정학기;이재형
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
    • /
    • 2003.10a
    • /
    • pp.777-779
    • /
    • 2003
  • In this paper, we have investigated Characteristics of C-V for Double gate MOSFET with main gate and side gate. DG MOSFET has the main gate length of 50nm and the side gate length of 70nm. We have investigated characteristics of C-V and main gate voltage is changed from -5V to +5V. Also we have investigated characteristics of C-V for DG MOSFET when the side gate length is changed from 40nm to 90nm. As the side gate length is reduced, the transconductance is increased and the capacitance is reduced. When the side gate voltage is 3V, we know that C-V curves are bending at near the main gate voltage of 1.8V. We have simulated using ISE-TCAD tool for characteristics analysis of device.

  • PDF

Application Analysis of Vitex rotundifolia by Difference of the Shallow-Extensive Green Roof System (저관리 옥상녹화의 식재기반 시스템 차이에 따른 순비기나무의 활용성 평가)

  • Park, Jun-Suk;Ju, Jin-Hee;Kim, Won-Tae;Yoon, Young-Han
    • Journal of the Korean Society of Environmental Restoration Technology
    • /
    • v.13 no.4
    • /
    • pp.10-17
    • /
    • 2010
  • The objectives of this study were to compare the growth of Vitex rotundifolia as affected by the difference of soil depth and mixture ratio in a shallow-extensive green roof module system, and to identify the level of soil thickness and mixture ratio as suitable growing condition to achieve the desired plant growth in green roof. Different soil thickness levels were achieved under 7cm, 15cm and 25cm of shallow-extensive green roof module systems made by woody frame of $500{\times}500{\times}300mm$. Soil mixture ratio were eight types for perlite : peatmoss : leafmold = 7 : 1 : 2 (v/v/v, $P_7P_1L_2$), perlite : peatmoss : leafmold = 6 : 2 : 2 (v/v/v, $P_6P_2L_2$), perlite : peatmoss : leafmold = 5 : 3 : 2 (v/v/v, $P_5P_3L_2$), perlite : peatmoss : leafmold = 4 : 4 : 2 (v/v/v, $P_4P_4L_2$), only sand ($S_{10}$), sand : leafmold = 7 : 3 (v/v, $S_7L_3$), sand : leafmold = 5 : 5 (v/v, $S_5L_5$) and only leafmold ($L_{10}$). The growth response of Vitex rotundifolia had fine and sustain condition in $P_6P_2L_2$, $P_5P_3L_2$ and $P_4P_4L_2$., Especially, in case of $P_6P_2L_2$, growth response appeared to be good even in soil thickness 7cm, which showed low survival rates of Vitex rotundifolia in other soil mixtures. Tree height, root diameter, photosynthesis and chlorophyll contents tended to increase with increased soil thickness.

A SUFFICIENT CONDITION FOR ACYCLIC 5-CHOOSABILITY OF PLANAR GRAPHS WITHOUT 5-CYCLES

  • Sun, Lin
    • Bulletin of the Korean Mathematical Society
    • /
    • v.55 no.2
    • /
    • pp.415-430
    • /
    • 2018
  • A proper vertex coloring of a graph G is acyclic if G contains no bicolored cycle. A graph G is acyclically L-list colorable if for a given list assignment $L=\{L(v):v{\in}V(G)\}$, there exists an acyclic coloring ${\phi}$ of G such that ${\phi}(v){\in}L(v)$ for all $v{\in}V(G)$ A graph G is acyclically k-choosable if G is acyclically L-list colorable for any list assignment with $L(v){\geq}k$ for all $v{\in}V(G)$. Let G be a planar graph without 5-cycles and adjacent 4-cycles. In this article, we prove that G is acyclically 5-choosable if every vertex v in G is incident with at most one i-cycle, $i {\in}\{6,7\}$.

Study on the Electrical Conductivity and Catalytic Property by Structural Change of 70V2O5-10Fe2O3-13P2O5-7B2O3 Glass with Crystallization

  • Jeong, Hwa-Jin;Cha, Jae-Min;Ryu, Bong-Ki
    • Journal of the Korean Ceramic Society
    • /
    • v.54 no.5
    • /
    • pp.406-412
    • /
    • 2017
  • $70V_2O_5-10Fe_2O_3-13P_2O_5-7B_2O_3$ glasses were prepared to study the electrical conductivity and catalytic properties of the structural change with crystallization. The structural changes were analyzed by determining the molecular volume from the sample density; using X-Ray Diffraction (XRD) analysis, which indicated that $V_2O_5$, $VO_2$ and $B_2O_3$ crystals in heat-treated more than 1h samples. Especially a new crystalline phase of non-stoichiometric $Fe_{0.12}V_2O_5$ was formed after 6 h heat treatment. The V-O bonding change after crystallization was analyzed by Fourier Transform Infrared Spectroscopy (FTIR); V ion change from $V^{5+}$ to $V^{4+}$ was shown by XPS. Conductivity and catalytic properties were examined based on the polaronic hopping of V and Fe ions, which exhibited different valence states with crystallization.

A Study on the Characteristics of Semiconductor Oxides with V2O5 (V2O5가 첨가된 반도체 산화물의 특성개선연구)

  • Lee, Don-Kyu
    • Journal of IKEEE
    • /
    • v.22 no.4
    • /
    • pp.965-969
    • /
    • 2018
  • In the dye-sensitized solar cell, the semiconductor oxide plays an important role in the generation and transport of electrons, and thus extensive research on this has been continuously carried out. In this study, the characteristics of dye-sensitized solar cell are studied by fabricating semiconductor oxide doped with $V_2O_5$. The $TiO_2$ paste with $V_2O_5$ is prepared by the screen printing method of the sol - gel process and the surface and electrical properties are measured. The addition of $V_2O_5$ increased grain size and improved the open circuit voltage, short circuit current, charge factor and conversion efficiency of the dye sensitized solar cell.

Sol-gel growth and structural, electrical, and optical properties of vanadium-based oxide thin films (바나듐 옥사이드 박막의 성장 및 그 구조적, 전기적, 광학적 특성)

  • Park, Young-Ran;Kim, Kwang-Joo
    • Journal of the Korean Vacuum Society
    • /
    • v.15 no.5
    • /
    • pp.534-540
    • /
    • 2006
  • Thin films of $V_2O_3$, $VO_2$, and $V_2O_5$ were obtained from a single precursor solution through post-annealing processes under different annealing conditions. As annealed in air, the deposited films became $V_2O_5$ with orthorhombic crystal structure, while they were $V_2O_3$ and $VO_2$ with rhombohedral and monoclinic crystal structure as annealed in vacuums with base pressure of $1{\times}10^{-6}$ Torr and with 10 mTorr $O_2$ pressure, respectively. Electrical and optical measurements indicated that the $V_2O_5$ and $VO_2$ films are semiconducting, while the $V_2O_3$ films are metallic at room temperature. Chromium doping in $VO_2$ resulted in a decrease of the resistivity and changed the conduction type from n-type to p-type. 10% Cr-doped $VO_2$ films were found to have orthorhombic crystal structure, which is different from that of the undoped $VO_2$. Spectral features in the optical absorption spectra of all the films were interpreted as the transitions involving O 2p and V 3d bands. The crystal-field splittings between $t_{2g}$ and $e_g$ states of the V 3d bands are estimated to be about 1.5 and 1.0 eV for $V_2O_5$ and $VO_2$, respectively.

Electro-chemical properties of $Li_{2}O=P_{2}O_{5}-V_{2}O_{5}$ Glass-ceramics for Cathode Materials (정극재료용 $Li_{2}O=P_{2}O_{5}-V_{2}O_{5}$ 계 결정화 유리의 전기화학적 특성)

  • 손명모;이헌수;구할본;김윤선
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.11a
    • /
    • pp.295-298
    • /
    • 2000
  • Vanadate glasses in the Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ system containing 10~20mo1% glass former, P$_2$O$_{5}$ were prepared by melting the batch in pt. crucible followed by quenching on the copper plate. We found that Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ g1ass-ceramics obtained from crystallization of glass showed significantly higher capacity and longer cycle life than Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ g1ass. In the present paper, we describe electro-chemical properties during crystallization process and find the best crystallization condition of Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ g1ass as cathod material. Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass-ceramics shows superior rechargeable capacity of 220 mAh/g in the cycling between 2.0 and 3.9V. between 2.0 and 3.9V.

  • PDF

Effect of Cornstarch-Based Absorbent Polymer on the Growth of Cool Season Turfgrasses in Sand-Based Mixture (옥수수 전분이 주성분인 토양보습제 첨가가 모래 배양토에서 한지형 잔디의 생육에 미치는 영향)

  • Choi, Joon-Soo;Yang, Geun-Mo;Ahn, Sang-Hyun;Cho, Yun-Sik
    • Asian Journal of Turfgrass Science
    • /
    • v.22 no.1
    • /
    • pp.75-84
    • /
    • 2008
  • This study was carried out to examine the effects of cornstarch-based absorbent polymer (CAP) on the growth of cool season turfgrasses in sand-based soil mixture. Kentucky bluegrass + perennial ryegrass mixtures seeded at May 18 in 2006 on sand-based soil mixture. Sand + peat (5%, v/v), sand + CAP $20g{\cdot}m^{-2}$, sand + CAP $20g{\cdot}m^{-2}$ + peat (5%, v/v), and sand + CAP $40g{\cdot}m^{-2}$ + peat (5%, v/v) mixtures were compared. Ground coverage of sand + CAP $20g{\cdot}m^{-2}$ + peat (5%, v/v), and sand + CAP $40g{\cdot}m^{-2}$ + peat (5%, v/v) treatments showed 50% at a month after seeding. But the coverage of sand + peat (5%, v/v), sand + CAP $20g{\cdot}m^{-2}$ resulted in 36.7%. Mixing of CAP with sand was considered to be efficient method for increasing ground coverage as much as peat. Dry weight of turfgrass tiller at sand + CAP $20g{\cdot}m^{-2}$ + peat (5%, v/v), and sand + CAP $40g{\cdot}m^{-2}$ + peat (5%, v/v) were also significantly higher than sand + peat (5%, v/v), sand + CAP $20g{\cdot}m^{-2}$ mixtures at a month after seeding. Soil water retention at the sand + CAP $20g{\cdot}m^{-2}$, sand + CAP $40g{\cdot}m^{-2}$ + peat (5%, v/v) mixing were lower than sand + peat (5%, v/v) and sand + CAP $20g{\cdot}m^{-2}$ + peat (5%, v/v) during the dry periods. From the results, the mixing of CAP with sand is useful to increased ground coverage of kentucky bluegrass and perennial ryegrass.

Solid-State 51V NMR and Infrared Spectroscopic Study of Vanadium Oxide Supported on $ZrO_2-WO_3$

  • 손종락;이만호;도임자;배영일
    • Bulletin of the Korean Chemical Society
    • /
    • v.19 no.8
    • /
    • pp.856-862
    • /
    • 1998
  • Vanadium oxide catalyst supported on ZrO2-WO3 was prepared by adding the Zr(OH)4 powder into a mixed aqueous solution of ammonium metavanadate and ammonium metatungstate followed by drying and calcining at high temperatures. The characterization of prepared catalysts was performed using solid-state 51V NMR and FTIR. In the case of calcination temperature at 773 K, for the samples containing low loading V2O5 below 18 wt % vanadium oxide was in a highly dispersed state, while for samples containing high loading V2O5 equal to or above 18 wt % vanadium oxide was well crystallized due to the V2O5 loading exceeding the formation of monolayer on the surface of ZrO2-WO3. The ZrV2O7 compound was formed through the reaction Of V2O5 and ZrO2 at 873 K and the compound decomposed into V2O5 and ZrO2 at 1073 K, which were confirmed by FTIR and 51V NMR.