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Photocatalytic Degradation of Rhodamine B Using Cd0.5Zn0.5S/ZnO Photocatalysts under Visible Light Irradiation (가시광선하에서 Cd0.5Zn0.5S/ZnO 광촉매를 이용한 로다민 B의 광분해 반응)

  • Lee, Hyun Jung;Jin, Youngeup;Park, Seong Soo;Hong, Seong Soo;Lee, Gun Dae
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.356-361
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    • 2015
  • $Cd_{0.5}Zn_{0.5}S/ZnO$ composite photocatalysts were synthesized using the precipitation method and characterized by XRD, UV-vis DRS, PL and FE-SEM. Photocatalytic activities of the materials were evaluated by measuring the degradation of rhodamine B under visible light irradiation. Contrary to ZnO, $Cd_{0.5}Zn_{0.5}S/ZnO$ materials absorb visible light as well as UV and their absorption intensities in visible region increased with increasing the $Cd_{0.5}Zn_{0.5}S$ amount. The increment in the $Cd_{0.5}Zn_{0.5}S$ content in $Cd_{0.5}Zn_{0.5}S/ZnO$ also leads to reducing the particle size and consequently increasing the specific surface area. $Cd_{0.5}Zn_{0.5}S/ZnO$ materials with the larger $Cd_{0.5}Zn_{0.5}S$ content showed the higher activity in the photocatalytic degradation of rhodamine B under visible light irradiation. Therefore, the heterojunction effect between $Cd_{0.5}Zn_{0.5}S$ and ZnO as well as the adsorption capacity seems to give important contributions to the photocatalytic activity of the $Cd_{0.5}Zn_{0.5}S/ZnO$.

Direct Interaction of KIF5s and Actin-Based Transport Motor, Myo9s (KIF5s와 직접 결합하는 액틴 결합 운동단백질 Myo9s의 규명)

  • Seog, Dae-Hyun
    • Journal of Life Science
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    • v.21 no.8
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    • pp.1076-1082
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    • 2011
  • Microtubule-based kinesin motor proteins are used for long-range vesicular transport. KIF5s (KIF5A, KIF5B and KIF5C) mediate the transport of various membranous vesicles along microtubules, but the mechanism behind how they recognize and bind to a specific cargo has not yet been completely elucidated. To identify the interaction protein for KIF5B, yeast two-hybrid screening was performed and a specific interaction with the unconventional myosin Myo9b, an actin-based vesicle transport motor, was found. The GTPase-activating protein (GAP) domain of Myo9s was essential for interaction with KIF5B in the yeast two-hybrid assay. Myo9b bound to the carboxyl-terminal region of KIF5B and to other KIF5 members. In addition, glutathione S-transferase (GST) pull-downs showed that Myo9s specifically interact to the complete Kinesin-I complex. An antibody to KIF5B specifically co-immunoprecipitated KIF5B associated with Myo9s from mouse brain extracts. These results suggest that kinesin-I motor protein interacts directly with actin-based motor proteins in the cell.

Allyl-isothiocyanate Content and Physiological Responses of Wasabia japonica Matusum as Affected by Different EC Levels in Hydroponics (고추냉이 수경재배시 배양액의 EC 수준이 Allyl-isothiocyanate 함량과 생리적 반응에 미치는 영향)

  • Choi, Ki-Young;Lee, Yong-Beom;Cho, Young-Yeol
    • Horticultural Science & Technology
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    • v.29 no.4
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    • pp.311-316
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    • 2011
  • This study aimed to determine the effect of EC (electrical conductivity) levels of nutrient solution in hydroponic culture on allyl-isothiocyanate (AITC) content within plant tissues, Vitamin C content and physiological responses in wasabi plant (Wasabia japonica M. 'Darma'). The 'Darma' was grown for 5 weeks with a deep flow technique (DFT) system controlled at 5 different EC levels, including 0.5, 1, 2, 3, and $5dS{\cdot}m^{-1}$. In result, the highest total content of AITC showed at EC level 5 and $3dS{\cdot}m^{-1}$ for 1 or 5- week, respectively. The total content of AITC increased about 1.2-1.4 times when the plants were grown in the EC levels between 0.5 and $2dS{\cdot}m^{-1}$, whereas the content decreased about 6 and 56 % in the EC level 3 and $5dS{\cdot}m^{-1}$, respectively. The content of AITC was relatively higher in petiole tissue, about 53 %, taken from 1 week-grown plants when the EC was controlled between 0.5 and $2dS{\cdot}m^{-1}$. Root tissue also had relatively higher content of AITC, about 45.1 %, when the EC was controlled at 3 and $5dS{\cdot}m^{-1}$. However, a 5-fold decrease in the AITC content was found in blade tissue and a 6.8-fold decrease in root when the EC was controlled at $5dS{\cdot}m^{-1}$ for 5 weeks. There was no significant difference in the vitamin C content in 1-week grown leaf tissues under the different EC level treatments; but, the content increased about 27% in 5-week grown plants at the EC level between 0.5 and $2dS{\cdot}m^{-1}$, compared to the 1 week-grown leaf tissue. Electrolyte leakage of leaf tissue taken from 3-week grown plant was 3-fold higher at the EC level $5dS{\cdot}m^{-1}$, compared to the EC level between 0.5 and $2dS{\cdot}m^{-1}$. Chlorophyll content, photosynthesis rate and transpiration rate were decreased when the EC was controlled at higher than $2dS{\cdot}m^{-1}$. Leaf water content, specific leaf area and growth were decreased when the EC was controlled at $5dS{\cdot}m^{-1}$ for 5 weeks. All the integrated results in this study suggest that the EC level of nutrient solution should be maintained at lower than $3dS{\cdot}m^{-1}$ in order to improve nutritional value and quantity required for hydroponically grown wasabi as functional vegetable.

Synthesis of a Precursor of Bulgecinine, (4S,5R)-1-Acetyl-2-formyl-5-benzyloxymethyl-4-pyrrolidinol (Bulgecinine 선구물질인 (4S,5R)-1-Acetyl-2-formyl-5-benzyloxymethyl-4-pyrrolidinol의 합성)

  • Jeon, Hak Rim;Yoon, Shin Sook;Shin, Young Sook;Nam Shin, Jeong E.
    • Journal of the Korean Chemical Society
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    • v.41 no.3
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    • pp.150-156
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    • 1997
  • A precursor of bulgecinine, (4S,5R)-1-acetyl-2-formyl-5-benzyloxymethyl-4-pyrrolidinol (15) has been synthesized from diacetone-D-glucose. Barton deoxygenation, conversion to an L-sugar and displacement with $N_3^-$ at C-5, and one-pot reductive cyclization at C-2 produced (6R)-6-Ο-benzyloxymethyl-(3R)-3-methoxy-2-oxa-5-azabicyclo-[2,2,1]heptane(13), a key intermediate for bulgecinine. N-Acetylation and acid hydrolysis of 13 furnished a precursor of bulgecinine, (2S,4S,5R)-pyrrolidinol derivative 15 and its (2R,4S,5R)-diastereomer.

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Synthetic Studies on the Nucleophilic Addition of 1-Methyl-5-mercapto-1,2,3,4-tetrazole to Vinylsulfilimines (Vinylsulfilimine유도체에 대한 1-methyl-5-mercapto-1,2,3,4-tetrazole의 친핵성 첨가물에 관한 연구)

  • Tae-Rin Kim;So-Young Lee;Sang-Yong Pyun
    • Journal of the Korean Chemical Society
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    • v.36 no.2
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    • pp.318-323
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    • 1992
  • Following seven new nucleophilic adducts of sulfilimine compounds were prepared by the addition of 1-methyl-5-mercapto-1,2,3,4-tetrazole to vinylsulfilimine derivatives; S-Phenyl-S-2-(1-methyl-1,2,3,4-tetrazole-5-thio)-ethyl-N-p-tosylsulfilimine, S-p-tolyl-S-2-(1-methyl-1,2,3,4-tetrazole-5-thio)-ethyl-N-p-tosylsulfilimine, S-m-tolyl-S-2-(1-methyl-1,2,3,4-tetrazole-5-thio)-ethyl-N-p-tosylsulfilimine, S-p-chlorophenyl-S-2-(1-methyl-1,2,3,4-tetrazole-5-thio)-ethyl-N-p-tosylsulfilimine, S-p-bromophenyl-S-2-(1-methyl-1,2,3,4-tetrazole-5-thio)-ethyl-N-p-tosylsulfilimine, S-p-methoxyphenyl-S-2-(1-methyl-1,2,3,4-tetrazole-5-thio)-ethyl-N-p-tosylsulfilimine and S-p-nitrophenyl-S-2-(1-methyl-1,2,3,4-tetrazole-5-thio)-ethyl-N-p-tosylsulfilimine. The structures of these adducts were confirmed by elemental analyses, MP, UV, IR-and NMR-Spectra.

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The Quality characteristics of sponge cake added with the ingredients of Sagoonja-Tang (사군자탕(四君子湯) 재료를 첨가한 스폰지 케이크의 품질특성)

  • Nam, Hae-Young
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.1066-1075
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    • 2017
  • This study was carried out to determine the functional works and basic ingredients of Sagoonja-Tang on sponge cake. The experimental groups consisted of 6% mixtures of five (Ed-confirm the number) kinds powders : S1 for Sagoonja-Tang powder, S2 for Panax ginseng, S3 for Poria cocos, Koidz, S4 for Atractylodes macrocephala, and S5 for Glycyrrhiza uralensis Fisch. The volume of sponge cake somewhat decreased after adding the ingredients, and the volume differences in order from highest to lowest, were control>S1>S3>S2>S4>S5. In the microbiological quality test, viable cell counts were high in control groups of sponge cake, and the numbers of viable cell for control sponge cake reached to $9{\times}10^7CFU/g$ on the 7th day of storage, and decreased to $2.5{\times}10^5CFU/g$ on the 10th day of storage. All sponge cakes added with ingredient's powder showed pretty low viable cell counts. Especially, the group S5 showed the lowest counts of $1.2{\times}10^2CFU/g$ on the 7th day of storing. In the texture analyses of sponge cake, All groups showed higher degree of hardness, gumminess and chewiness than SC. The antioxidative activity of the Sagoonja-Tang's ingredients was measured. The POV value measured was S5>S4>S3>S2 >S1>control in order of highest to lowest. In sensory test, the overall acceptability of sponge cake was from highest to lowest S3>SC S2>S1>S5>S4.

Effect of the Concentration of Nutrient Solution on the Growth of Tomato(Lycopersicon esculentum Mill.) in Substrate Culture (고형배지경에서 배양액농도가 토마토의 생육에 미치는 영향)

  • 노미영;배종향;이용범;박권우;권영삼
    • Journal of Bio-Environment Control
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    • v.4 no.1
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    • pp.25-31
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    • 1995
  • This study was carried out to investigate the effect of the concentration of nutrient solution on the growth of tomato(Lycopersicon esculentum Mill. cv. seokwang) in substrate culture. The substrates used in the experiment were perlite, vermiculite, and peatmoss. Tomato plants were treated with different concentrations of nutrient solution, viz. 0.5, 1.0, 2.0, 3.0, and 5.0mS/cm at seedling stage and transferred to different treatments, 1.0, 2.0, and 3.0mS/cm after transplanting in each substrate. As the concentrations of nutrient solution increased from 0.5 to 3.0mS/cm at seedling stage, the $CO_2$ assimilation rates of seedlings increased in all three substrate culture. Beyond this range, the $CO_2$ assimilation rates of seedlings decreased. By increasing the concentrations of nutrient solution, plant height, leaf length, leaf width, stem diameter, and top dry weight increased in perlite and were high at 2-5mS/cm in vermiculite. On the other hand, in peatmoss, the best result was shown at 3.0mS/cm. Therefore, the adequate concentration of nutrient solution on early growth of seedlings differed among substrates and was shown to be 3.0-5.0mS/cm in perlite, 2.0-5.0mS/cm in vermiculite, and 3.0mS/cm in peatmoss. Generally, as the concentrations of nutrient solution increased from 1.0 to 3.0mS/cm after transplanting, dry weight increased significantly in all three substrate culture. However, dry weights of tomato plants grown under high concentration of 5.0mS/cm slightly increased both at seedling stage and after transplanting.

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Assessment of Climate Change Impacts on Hydrology and Snowmelt by Applying RCP Scenarios using SWAT Model for Hanriver Watersheds (SWAT 모델링을 이용한 한강유역의 RCP 시나리오에 따른 미래수문 및 융설 영향평가)

  • Jung, Chung Gil;Moon, Jang Won;Jang, Cheol Hee;Lee, Dong Ryul
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.5
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    • pp.37-48
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    • 2013
  • The objective of this study is to assess the impact of potential climate change on the hydrological components, especially on the streamflow, evapotranspiration and snowmelt, by using the Soil Water Assessment Tool (SWAT) for 17 Hanriver middle watersheds of South Korea. For future assessment, the SWAT model was calibrated in multiple sites using 4 years (2006-2009) and validated by using 2 years (2010-2011) daily observed data. For the model validation, the Nash-Sutcliffe model efficiency (NSE) for streamflow were 0.30-0.75. By applying the future scenarios predicted five future time periods Baseline (1992-2011), 2040s (2021-2040), 2060s (2041-2060), 2080s (2061-2080) and 2100s (2081-2100) to SWAT model, the 17 middle watersheds hydrological components of evapotranspiration, streamflow and snowmelt were evaluated. For the future precipitation and temperature of RCP 4.5 scenario increased 41.7 mm (2100s), $+3^{\circ}C$ conditions, the future streamflow showed +32.5 % (2040s), +24.8 % (2060s), +50.5 % (2080s) and +55.0 % (2100s). For the precipitation and temperature of RCP 8.5 scenario increased 63.9 mm (2100s), $+5.8^{\circ}C$ conditions, the future streamflow showed +35.5 % (2040s), +68.9 % (2060s), +58.0 % (2080s) and +63.6 % (2100s). To determine the impact on snowmelt for Hanriver middle watersheds, snowmelt parameters of SWAT model were determined through evaluating observed streamflow data during snowmelt periods (November-April). The results showed that average SMR (snowmelt / runoff) of 17 Hanriver middle watersheds was 62.0 % (Baseline). The annual average SMR were 42.0 % (2040s), 39.8 % (2060s), 29.4 % (2080s) and 27.9 % (2100s) by applying RCP 4.5 scenario. Also, the annual average SMR by applying RCP 8.5 scenario were 40.1 % (2040s), 29.4 % (2060s), 18.3 % (2080s) and 12.7 % (2100s).

Performance Evaluation of YOLOv5s for Brain Hemorrhage Detection Using Computed Tomography Images (전산화단층영상 기반 뇌출혈 검출을 위한 YOLOv5s 성능 평가)

  • Kim, Sungmin;Lee, Seungwan
    • Journal of the Korean Society of Radiology
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    • v.16 no.1
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    • pp.25-34
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    • 2022
  • Brain computed tomography (CT) is useful for brain lesion diagnosis, such as brain hemorrhage, due to non-invasive methodology, 3-dimensional image provision, low radiation dose. However, there has been numerous misdiagnosis owing to a lack of radiologist and heavy workload. Recently, object detection technologies based on artificial intelligence have been developed in order to overcome the limitations of traditional diagnosis. In this study, the applicability of a deep learning-based YOLOv5s model was evaluated for brain hemorrhage detection using brain CT images. Also, the effect of hyperparameters in the trained YOLOv5s model was analyzed. The YOLOv5s model consisted of backbone, neck and output modules. The trained model was able to detect a region of brain hemorrhage and provide the information of the region. The YOLOv5s model was trained with various activation functions, optimizer functions, loss functions and epochs, and the performance of the trained model was evaluated in terms of brain hemorrhage detection accuracy and training time. The results showed that the trained YOLOv5s model is able to provide a bounding box for a region of brain hemorrhage and the accuracy of the corresponding box. The performance of the YOLOv5s model was improved by using the mish activation function, the stochastic gradient descent (SGD) optimizer function and the completed intersection over union (CIoU) loss function. Also, the accuracy and training time of the YOLOv5s model increased with the number of epochs. Therefore, the YOLOv5s model is suitable for brain hemorrhage detection using brain CT images, and the performance of the model can be maximized by using appropriate hyperparameters.