• Title/Summary/Keyword: 53C25

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Annealing Effect of Surface Magnetic Properties in CoTi Thin Films (열처리 효과가 CoTi계 박막의 표면자기특성에 미치는 영향)

  • 김약연;백종성;이성재;임우영;이수형
    • Journal of the Korean Magnetics Society
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    • v.7 no.1
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    • pp.38-43
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    • 1997
  • For amorphous $Co_{1-x}Ti_x$(X=0.13, 0.16, 0.21 at.%) thin films deposited by DC magnetron sputtering method ferromagnetic resonance experiments have been used to investigate the dependence of surface magnetic properties according to annealing temperature (150~225 $^{\circ}C$). Spin wave resonance spectra for all annealing temperatures consist of several volume modes and one(or two) surface mode. It is suggested that both surfaces of the film have a perpendicular hard axis to the film plane(negative surface anisotropy). Also, the surface anisotropy $K_{s2}$ at substrate film interface is varied slowly from -0.11 to -0.25 erg/ $\textrm{cm}^2$ and the surface anisotropy $K_{s1}$ at film-air interface is varied from 0.16 to -0.53 erg/ $\textrm{cm}^2$ with increasing annealing temperature. We conjecture that the variation of surface anisotropy $K_{s1}$ is due to the increase of Co concentration resulted from Ti oxidation for low temperature annealing(150~200 $^{\circ}C$) and the diffusion of Co atoms near the film surfaces for high temperature annealing(225~250 $^{\circ}C$).

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Effects of Maturing Period and Moisture Content of Swine Manure on Composting Potentials (돈분의 수분조절 및 부숙기간이 퇴비화에 미치는 영향)

  • 김원호;정광화;서성;백광수;신동은;유성오;김원영
    • Journal of Animal Environmental Science
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    • v.4 no.1
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    • pp.47-53
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    • 1998
  • The purpose of this study was to investigate the change of temperature, moisture content, weight and chemical properties in swine manure during the maturing process and moisture content of swine manure. The manure production on the early time(1 days), middle(25 days: and late(50 days) were made by moisture 45%, 55%, 65%, 75% in swine manure, according to manure treatment of the early time, the highest temperature of swine manure treatment was 59$^{\circ}C$ as moisture 75% after mixed 24 hours, the lowest 45% in mixed 25 days(middle time), 32$^{\circ}C$ as moisture 45% in mixed 50 days(late time). 2. Weight change during maturing manure, the most treatment of weight decrease was 17.4% as moisture 45%, the least of those was 12.2% as moisture 75% during maturing process of swine manure. 3. Volume change during maturing manure, the most treatment of volume decrease was 37.1% as moisture 65%, the least of those was 32.1% as moisture 55% during maturing swine manure, but not big difference between treatment. 4. T-N, P2O5, K2O content of compost were increased during maturing process, On the contrary, T-C content and C/N ratio were reduced.

Performance variation of catalyst for hydrogen peroxide thruster with drying condition (과산화수소 추력기용 촉매의 건조 조건 변화에 따른 성능 변화)

  • Lee, Jeong-Sub;An, Sung-Yong;Kwon, Se-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.53-56
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    • 2009
  • In this paper, performance evaluation of catalyst for hydrogen peroxide thruster with drying condition is described. Platinum was selected as a catalyst, and alumina of pellet type was chosen as a catalyst support. Evaporation method known as general method for catalyst production was used to make the catalyst. From previous experiments, it is favorable during catalyst making process that solution of active material has low pH level. Therefore, some kinds of low pH level solution had been tested. The drying temperatures are 25, 50, 70, and $90^{\circ}C$. From experimental results, it shows better performance that drying temperature was $90^{\circ}C$ since the catalyst particle could not be crystallized but be evenly spreaded out due to the rapid evaporation of solvent.

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Powder Preparation by Hydroxide Coprecipitation and Phase Development of Pb0.97La0.02(Zr0.64Sn0.25Ti0.11)O3 Ceramics

  • Lee, Joon-Hyung;Chiang, Yet-Ming
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.260-267
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    • 1998
  • A homogeneous and stoichimetric fine powder of the ferroelectric $Pb_[0.97}La_{0.02}(Zr_{0.64}Sn_{0.25}Ti_{0.11})O_3$ (PLZST) has been prepared by the hydroxide coprecipitation method. Studies on the crystallization behavior of precursor as a function of temperature by X-ray powder diffraction and transmission electron microscopy technique were consistent with the formation of the pyrochlore phase from amorphous, initially at low temperatures around 500~$550^{\circ}C$. Further heat treatment up to $750^{\circ}C$ resulted in development of the perovskite phase with no significant pyrochlore crystallite growth. At intermediate temperatures the precursor yields a fine mixture of pyrochlore and perovskite phases. When the pyrochlore phase was heat teated in air, slight weight increase was observed in the temperature range of 300~$700^{\circ}C$, which is thought to be caused from oxygen absorption. In argon atmosphere, weight increase was not observed. On the other hand, weight loss began to occur near $700^{\circ}C$, with giving off mostly CO2 gas. This implies that the pyrochlore phase seems to be crystallorgraphycally and thermodynamically metastable. An apparent activation energy of 53.9 ㎉/mol was estimated for the pyrochlore-perovskite phase transformation.

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Thermostability of Superoxide Dismutase from Cucumber(Cucumis sativa) (오이 추출물에 존재하는 Superoxide Dismutase의 열안정성)

  • 박인식;김은애;김기남;길지은;이민경;김석환;서정식
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.27 no.6
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    • pp.1105-1109
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    • 1998
  • The superoxide dismutase(SOD) in peeled pericarp of cucumber was most stable at pH 8.0 and relatively stabe between pH 5.0 and 9.0. The enzyme was stable up to 6$0^{\circ}C$ and retained 12% by heat treatment at 10$0^{\circ}C$ for 5 min. At pH 2.0, the peeled pericarp enzyme activity was decreased to 10% by incubation for 3 hrs. However, the enzyme activity was increased above 25% after incubating the enzyme at pH 7.0 for 6 hrs. Retention of SOD activity in cucumber by various heating methods was also measured. The residual SOD activities of peeled pericarp and whole cucumber was estimated to be 25% and 27% after blanching(2 min), respectively. The skin enzyme retained 53% of its activity after steaming (3 min). When the peeled pericarp enzyme was incubated at 4$^{\circ}C$ for 20 days, the enzyme activity remained about 81%. However, when the enzyme incubated at 3$0^{\circ}C$ for 20 days, the peeled pericarp enzyme activity decreased to 17% of its original activity. The enzyme activity of peeled pericarp cucumber was not changed after exhaustive dialysis for 3 days, which indicated that the SOD activity in cucumber seems to have molecular weight above 12,000.

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Kinetic Studies on the Change of Fructose from the Rice Stored at Fluctuating Temperature Conditions (백미 변온 저장중 과당의 변화)

  • 정연화;강문선;김무남;전순실
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.22 no.6
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    • pp.785-791
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    • 1993
  • Kinetic studies were performed to investigate free-fructose content change in rice during storage. The rice was stored at various water activities(0.44, 0.52, 0.65 and 0.75) and at fluctuating temperature($30/50^{\circ}C$) over period of 22 weeks. At early stage of storage free-furctose content increased by zero-order reaction, whereas at later stage, it decreased by first-order reaction. The reaction rates were positively related to water activity and/or temperature during storage. Activation energies calculated at range of aw 0.44~0.75 were found to be 10.76~19.56kcal/mole and 4.53~8.40kcal/mole, for the period of increase and decrease in the free-fructose contents, respectively. The shelf-life assessed at $25^{\circ}C$ was found to be 252(aw 0.44), 212 (aw 0.52), 193(aw 0.65) and 162(aw 0.75) days.

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Distribution of Liquid Components in Various Tissues of Cat Fish, Parasilurus asotus (메기(Parasilurus asotus)의 부위별(部位別) 지방질성분(脂肪質成分)의 분포(分布))

  • Choi, Jin-Ho;Park, Si-Hyang;Ro, Jae-Il;Pyeun, Jae-Hyeung;Choe, Sun-Nam
    • Korean Journal of Food Science and Technology
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    • v.17 no.1
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    • pp.15-21
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    • 1985
  • This study was designed to elucidate the lipid and its fatty acid composition in various tissues of cat fish, Parasilurus asotus. The free lipid contents in meat, skin and viscera were 5.62%, 26.34% and 19.27%, whereas the bound lipid contents in those tissues were 2.34%, 2.30% and 19.27%, respectively. The neutral lipid contents in free lipid were 5 times higher than those in bound lipid, while the phospholipid contents in bound lipid were 4 times higher than those in free lipid. The neutral lipid was mainly composed of triglyceride (79.84%-99.86%) in free lipid, and esterified sterol & hydrocarbon (55.12-64.33%) in bound lipid. The phospholipid was mainly composed of phosphatidyl choline (52.38-69.98%) and phosphatidyl ethanolamine (24.09-40.48%) in free lipid, and phosphatidyl choline (53.03-58.54%) and phosphatidyl ethamolamine (13.80-19.23%) in bound lipid. The major fatty acids of polar lipid in free and bound lipids were C16:0 (28.37%, 21.99%), C18:1 (12.01%, 11.52%), C18:2 (17.93%, 14.12%) and C22:6 (17.22%, 20.63%), and those of nonpolar lipid in free and bound lipids were C16:0 (14.81%, 18.94%), C18: 1 (25.93%, 10.89%) and C22:6 (9.95%,23.44%), respectively. The total essential fatty acid (TEFA) content in skin was slightly higher than that in meat. In both polar and nonpolar lipids in meat ${\omega}3-HUFA$ contents of polar lipid were 1.5-2.0 times higher than nonpolar lipid and also ${\omega}3-HUFA$ content of bound lipid was slightly higher than that of free lipid. There were significant differences in the lipid classification and its fatty acid composition between free and bound lipids and/or in various tissues.

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Browning and Sorption Characteristics of Garlic Powder with Relative Humidity and Storage Temperature (상대습도와 저장온도에 따른 마늘가루의 갈변 및 흡습특성)

  • Kim, Hyun-Ku;Jo, Kil-Suk;S.Hawer, Woo-Derck;Shin, Dong-Hwa
    • Korean Journal of Food Science and Technology
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    • v.20 no.3
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    • pp.399-404
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    • 1988
  • The sorption characteristics of garlic powder stored at various relative humidities and storage temperatures were studied. At lower relative humidity below RH 51%, the sorption equilibrium was easily attained, whereas at higher relative humidity above RH 67%, the powders were browned by higher equilibrium moisture content. The powders were browned at relative humidity above 67% at $20^{\circ}C\;and\;35^{\circ}C,\;above\;84%\;at\;5^{\circ}C$, respectively. The moisture contents of monolayer value for the powder were ranged from 5.53%(DB) to 5.92% (DB) with varying temperatures. And the necessity of moistureproof packaging material suggested for the long term storage of the powder because the lower moisture content and storage temperature, the higher driving force of wetting.

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Changes in Quality of Fried Rice with Red Snow Crab Meat Depending on the Storage Period and Temperature (저장기간 및 저장온도에 따른 붉은대게풍미 볶음밥의 품질변화)

  • Jung, Ji Hee;Lim, Ji Hoon;Jeong, Min Jeong;Jeong, In Hack;Kim, Byoung Mok
    • Korean journal of food and cookery science
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    • v.31 no.4
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    • pp.387-394
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    • 2015
  • The red snow crab lives at a depth 200-2,000 m in the east coast. It has a smooth taste with a rich texture. However mostly red snow crab are only utilized materials. For seafood development, research is needed on using red snow crab in various products. In this study, quality changes in fried rice prepared with red snow crab meat, red snow crab emulsion sauce and red snow crab effluent were investigated. Physicochemical, microbiological and sensory characteristics were determined during storage at -20, 4 and $25^{\circ}C$ for 5 weeks to assess changes in the quality of the fried rice. The pH and acidity values did not show any significant differences at $-20^{\circ}C$. The VBN and TBA values of fried rice stored at 4 and $25^{\circ}C$ were significantly higher than those of fried rice stored at $-20^{\circ}C$ during the same storage period. The viable cell count of the fried rice stored at $-20^{\circ}C$ changed little during the storage period. During storage at $25^{\circ}C$, the overall quality was initially 8.0, but rapidly decreased to 1.0 after 5 weeks. In conclusion, the best storage temperature for both quality and safety was $-20^{\circ}C$. The storage condition for instant rice containing red snow crab affects the quality and we confirmed the applicability of using materials from red snow crab.

Minimization of Recombination Losses in 3D Nanostructured TiO2 Coated with Few Layered g-C3N4 for Extended Photo-response

  • Kang, Suhee;Pawar, Rajendra C.;Park, Tae Joon;Kim, Jin Geum;Ahn, Sung-Hoon;Lee, Caroline Sunyong
    • Journal of the Korean Ceramic Society
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    • v.53 no.4
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    • pp.393-399
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    • 2016
  • We have successfully fabricated 3D (3-dimensional) nanostructures of $TiO_2$ coated with a $g-C_3N_4$ layer via hydrothermal and sintering methods to enhance photoelectrochemical (PEC) performance. Due to the coupling of $TiO_2$ and $g-C_3N_4$, the nanostructures exhibited good performance as the higher conduction band of $g-C_3N_4$, which can be combined with $TiO_2$. To fabricate 3D nanostructures of $g-C_3N_4/TiO_2$, $TiO_2$ was first grown as a double layer structure on FTO (Fluorine-doped tin oxide) substrate at $150^{\circ}C$ for 3 h. After this, the $g-C_3N_4$ layer was coated on the $TiO_2$ film at $520^{\circ}C$ for 4 h. As-prepared samples were varied according to loading of melamine powder, with values of loading of 0.25 g, 0.5 g, 0.75 g, and 1 g. From SEM and TEM analysis, it was possible to clearly observe the 3D sample morphologies. From the PEC measurement, 0.5 g of $g-C_3N_4/TiO_2$ film was found to exhibit the highest current density of $0.12mA/cm^2$, along with a long-term stability of 5 h. Compared to the pristine $TiO_2$, and to the 0.25 g, 0.75 g, and 1 g $g-C_3N_4/TiO_2$ films, the 0.5 g of $g-C_3N_4/TiO_2$ sample was coated with a thin $g-C_3N_4$ layer that caused separation of the electrons and the holes; this led to a decreasing recombination. This unique structure can be used in photoelectrochemical applications.