• Korean Journal of Food Science and Technology
• /
• v.29 no.6
• /
• pp.1304-1308
• /
• 1997

In the course of studies for anti-plaque agents, novel procyanidin structure isolated from Artocarpus heterophyllus folium was established by thiolysis and spectroscopic analysis. The chemical structure was identified for $(-)-epiafzelecin-(4{\beta}{\rightarrow}8)-afzelecin-(4{\alpha}-8)-catechin$ containing the trimeric flavan-3-ols and molecular weight was 833[M-H] by FAB-MS negative ion method. The inhibitory effect on the glucosyltransferase activity was investigated, novel compound showed complete inhibition at 1.0 mM and inhibited on the glucosyltransferase noncompetitively.

• Analytical Science and Technology
• /
• v.34 no.4
• /
• pp.180-190
• /
• 2021

This study compared the efficacy of chiral GC and chiral HPLC for the analysis of nicotine. To develop a suitable dispersive liquid-liquid microextraction (DLLME) method, the following parameters were optimized: pH, extraction solvent, dispersive solvent, type and quantity of salt, and laboratory temperature. The validation of the method was carried out by the established HPLC method. The LODs were 0.11 ㎍/mL and 0.17 ㎍/mL for the (S)- and (R)- enantiomers, respectively. The LOQs were 0.30 ㎍/mL and 0.44 ㎍/mL, respectively. The optimal calibration range was between 0.30-18 ㎍/mL and 0.44-4.40 ㎍/mL, respectively, and the correlation coefficient (r²) was 0.9978-0.9996. The intra-day accuracy was 79.9-110.6 %, and the intra-day precision was 1.3-12.0 %. The inter-day accuracy was 87.8-108.0 %, and the inter-day precision was 4.0-12.8 %. E-liquid and biological fluids (urine and saliva) were analyzed using the established method.

• The Journal of Engineering Geology
• /
• v.25 no.2
• /
• pp.299-304
• /
• 2015

Slope stability analysis of unsaturated soil slopes due to rainfall infiltration is an important issue in evaluating landslide analysis and stability assessment. The purpose of this study is to establish the critical depth considering weathered soil of parent rock and rainfall intensity at main scarp in national landslide. Based on the analytical results, it is found that as rainfall duration and Slope angle increased, the critical depth of gneiss-weathered soil increased from 3.00 m to 3.77 m, the critical depth of granite weathered-soil increased from 1.75 m to 2.40 m, and the critical depth of mudstone-weathered soil increased from 3.00 m to 4.15 m, respectively. The critical depth of granite-weathered soil with low cohesion and high internal friction angle is much lower than those of other soils. It is interestingly shown that a decrease in the safety factor is highly significant, much affected by the slope increase rather than the rainfall intensity.

• Journal of Magnetics
• /
• v.19 no.4
• /
• pp.323-326
• /
• 2014

Superparamagnetic maghemite nanoparticles were prepared by chemical co-precipitation, followed by a temperate oxidation stage, and investigated using FE-SEM, XRD, TGA, VSM, and M$\ddot{o}$ssbauer spectroscopy. Through SEM image and XRD analysis, its average particle size was found to be 13.9 nm. While VSM magnetic measurement showed typical superparamagnetic behavior at room temperature, M$\ddot{o}$ssbauer spectroscopic investigation revealed that non-vanishing magnetic hyperfine structure were retained. Cation distribution estimated from M$\ddot{o}$ssbauer spectroscopy confirmed the formation of maghemite nanophase in the sample.

• Journal of the Korean Chemical Society
• /
• v.57 no.4
• /
• pp.476-482
• /
• 2013

Cyanopyridone was prepared by the condensation of cyanoacetamide, substituted arylaldehydes and malononitrile in presence of pipyridine. The structure of the synthesized compound CP 1-20 was assigned on the basis of elemental analysis, IR, $^1H$-NMR and mass spectroscopy. These compounds were also screened for antimicrobial activity. The Minimum Inhibitory Concentration (MIC) of all the synthesized compounds was compared with standard drugs.

• Journal of the Korea Institute of Information Security & Cryptology
• /
• v.7 no.4
• /
• pp.24-36
• /
• 1997

본 논문에서는 기밀 통신 시스템에서의 지연 분석을 위해 대기 이론ㅇ르 이용하여 시큐리티와 성능사이의 tradeoff를 정량화하고, 시큐리티 메커니즘과 프로토콜에 의해 야기된 지연을 줄이기 위한 최적화기법으로 전처리, 메시지의 분할과 압축, 압축과 암호의 통합, 사용자 인증과 접근 제어의 통합을 고려한다. 그리고, 시큐리티 서비스를 제공하기 위한 시큐리티 메커니즘으로 DES를 이용한 경우, RAS 의 디지털 서명, IDEA와 RSA의 결합을 고려하고, 각각에 대해 대개 이론의 M/M/1모델, M/E/1모델, M/H/1 모델을 적용하여 컴퓨터 시뮬레이션을 통해 평균 지연을 분석한다.

• Bulletin of the Korean Chemical Society
• /
• v.23 no.8
• /
• pp.1097-1102
• /
• 2002

The mass spectrometry using an ion trap tandem mass spectrometer has been investigated to find optimum conditions for the analysis of benzo(a)pyrene (3,4-benzpyrene). The applicability to a real soil sample was also investigated to verify the usef ulness of the MS/MS (or collision induced dissociation, CID) analysis. The optimum CID condition was 1.5 and 0.45 for the RF excitation voltage and the q value, respectively. For comparison, CID and EI were applied to the analysis of a soil sample. CID analysis was more sensitive than EI analysis of the soil sample. The limit of detection (LOD) of benzo(a)pyrene was 3.18 ng mL-1 and 0.85 ng mL,-1 for EI and MS/MS analysis, respectively. The precision at the soil sample for EI and CID showed relative standard deviations of 6.1% and 4.1%, respectively, and the concentrations were 168 ㎍ kg-1 and 162 ㎍ kg-1 , respectively.

• Journal of the Korean Institute of Gas
• /
• v.17 no.5
• /
• pp.15-21
• /
• 2013

This study evaluated comparison of the risk according to the type of fuel by three-dimensional simulation tool(FLACS). The consequence analysis of fire explosion and jet-fire was carried out in the layout of a typical high-pressure gas filling stations using CNG, hydrogen and 30%HCNG. Under the same conditions, hydrogen had a 30kPa maximum overpressure, CNG had a 0.4kPa and HCNG had a 3.5kPa. HCNG overpressure was 7.75 times higher than the CNG measurement, but HCNG overpressure was only 11.7% compared to hydrogen. In case of flame propagation, hydrogen had a very fast propagation characteristics. On the other hand, CNG and HCNG flame propagation velocity and distance tended to be relatively safe in comparison to hydrogen. The estimated flame boundary distance by jet-fire of hydrogen was a 5.5m, CNG was a 3.4m and HCNG was a 3.9m.

• Journal of the Korean Applied Science and Technology
• /
• v.35 no.4
• /
• pp.1393-1406
• /
• 2018

In this study, three parameters (Pressure ($X_1$), Airflow rate ($X_2$), Operation time ($X_3$)) were experimentally designed and the predicted model and optimal conditions were established by using the terminal rise velocity of the microbubbles as the response value. The polynomial regression analysis showed that the optimum value for the terminal rise velocity at the Pressure ($X_1$) of 4.5 bar, Airflow rate ($X_2$) of 3.3 L/min and Operation time ($X_3$) of 2.2 min was 5.14 cm/min ($85.7{\mu}m/sec$). Also, the highest microbubble diameter size distribution in the range of 2 to $5{\mu}m$ and 25 to $50{\mu}m$ was confirmed by using a laser particle counting apparatus.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2000.04b
• /
• pp.117-120
• /
• 2000

The relation of crystal phase and charge/discharge capacity of $Li[Li_yMn_{2-y}]O_4$ were studied for different degrees of Li substitution (y). All cathode material showed spinel phase based on cubic phase in X-ray diffraction. Other peaks didn't show in spite of the increase of y value in $Li[Li_yMn_{2-y}]O_4$. Ununiform of $Li[Li_yMn_{2-y}]O_4$ which calcinated by (111) face and (222) face was more stable than that of pure $LiMn_2O_4$. In addition, At TG analysis, calcined $Li[Li_{0.1}Mn_{1.9}]O_4$ exhibited much mass loss at $800{\mu}m$. The cycle performance of the $Li(Li_yMn_{2-y}]O_4$ was improved by the substitution of $Li^{1+}$ for $Mn^{3+}$ in the octahedral sites. Specially, $Li[Li_{0.08}Mn_{1.92}]O_4$ and $Li[Li_{0.1}Mn_{1.9}]O_4$ cathode materials showed the charge and discharge capacity of about 125mAh/g at first cycle, and about 95mAh/g after 70th cycle. It is excellent than that of pure $LiMn_2O_4$, which 125mAh/g at first cycle, 65mAh/g at 70th.