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Kinetics of Seed Growth of α-Ferric Oxyhydroxide (α-Ferric oxyhydroxide 입자의 핵성장 반응에 관한 연구)

  • Seul, Soo-Duk;Shin, Dong-Ock
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.602-609
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    • 1997
  • The seed formation and growth of $\alpha$-ferric oxyhydroxide with aerial oxidative precipitation from aqueous solution of ferrous sulfate with KOH, NaOH, $Na_2CO_3$ and $K_2CO_3$ as precipitants have been studied by free pH drift experiment. It has been shown that all precipitants give same particle formation and growth path, and average particle length from KOH and NaOH as precipitants was about 1.5 times shorter than that of $K_2CO_3$ and $Na_2CO_3$. When initial mole ratio, $R_o=[Fe^{2+}]_o/[OH^-]_o$ of KOH was decreased the particle was grown oxyhydroxide seed growth from aqueous solution of ferrous sulfate with KOH has been studied. The influence of the air flow rate, reaction temperature and initial mole ratio, $R_o=[Fe^{2+}]_o/[OH^-]_o$, on the kinetics of seed growth are investigated by static pH experiment. The oxidation rate of seed growth increased with increase in the air low rate, reaction temperature and initial mole patio. The activation energy of seed growth is 16.16 KJ/mol and the rate equation of seed growth can be written as follows: $-\frac{d[Fe^{2+}]}{dt}=1.46{\times}10^4[P_{o2}]^{0.66}[OH^-]^{2.19}exp(-\frac{16.16}{dt})$.

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Flexural strength of various kinds of the resin bridges fabricated with 3D printing (3D 프린팅으로 제작된 여러 종류의 레진브릿지의 굴곡강도에 대한 연구)

  • Park, Sang-Mo;Kim, Seong-Kyun;Park, Ji-Man;Kim, Jang-Hyun;Jeon, Yoon-Tae;Koak, Jai-Young
    • Journal of Dental Rehabilitation and Applied Science
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    • v.33 no.4
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    • pp.260-268
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    • 2017
  • Purpose: Manufacturing with AM (Additive manufacturing) technique has many advantages; but, due to insufficient study in the area, it is not being widely used in the general clinic. In this study, differences of flexural strength among various materials of 3 unit fixed dental prosthesis were analyzed. Materials and Methods: A metal jig for specimens that had a 3-unit-fixed dental prosthesis figure were fabricated. The jigs were made appropriately to the specifications of the specimens. Three different kinds of materials of specimens which were NC (mathacrylic esther based), DP-1 (Bisphenol A epoxy acrylate type oligomer based), and DT-1 (urethane acrylate based) were printed with DLP machine. Five specimens for each kind of material were printed with an angle of $30^{\circ}$ from the horizontal surface. The specimens were placed on the jig and the flexural strength was measured and recorded using Universal testing machine. The recorded data was analyzed in SPSS using One-way ANOVA and Tukey HSD to determine the significance of the differences of flexural strength among the groups. Results: The flexural strengths of each group were the followings: NC, $1119{\pm}305$ N; DP-1, $619{\pm}150$ N; DT-1, $413{\pm}65N$. Using One-way ANOVA and Tukey Honestly Significant Difference test, significant difference was found between NC and the other groups (P < 0.05), but there was no significant difference between DP-1 and DT-1 (P > 0.05). Conclusion: Higher flexural strength was shown in 3-unit-fixed dental prosthesis that were 3D printed using a DLP machine with NC material.

Kinetics and Mechanism of Ruthenium(III) Catalyzed Oxidation of Butanone and Uncatalyzed Oxidation of Cychlohexanone by Cerium(IV) in Acid Sulphate Medium

  • Sharma, Priyamvada;Hemkar, Shalini;Khandelwal, C.L.;Sharma, P.D.
    • Journal of the Korean Chemical Society
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    • v.56 no.1
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    • pp.28-33
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    • 2012
  • The kinetics of ruthenium(III) chloride catalyzed oxidation of butanone and uncatalyzed oxidation of cyclohexanone by cerium(IV) in sulphuric acid medium have been studied. The kinetic rate law(I) in case of butanone conforms to the proposed mechanism. $$-\frac{1}{2}\frac{d[Ce^{IV}]}{dt}=\frac{kK[Ru^{III}][butanone]}{1+K[butanone]}$$ (1). However, oxidation of cyclohexanone in absence of catalyst accounts for the rate eqn. (2). $$-\frac{1}{2}\frac{[Ce^{IV}]}{dt}=\frac{(k_1+k_1K^'[H^+])[Ce^{IV}][Cyclohexanone]}{1+K_3[HSO_4^-]}$$ (2) Kinetics and activation parameters have been evaluated conventionally. Kinetically preferred mode of reaction is via ketonic and not the enolic forms.

Measuring of Rotational Accuracy of Lathe Spindle (선반 주축의 회전운동 정도 측정)

  • Kim, Young-Seuk
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.6
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    • pp.43-48
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    • 2007
  • It is important to measure the rotational accuracy of lathe spindle as it affects to the qualities of all machines machined by the lathe using in industries. The bad rotational accuracy of lathe spindle are caused mainly by wearness of the spindle in using and quality of spindle when machining and using low level bearings. It occurs especially in case of lathes because the cutting force acting to work-piece act on one side to the spindle not to both sides symmetrically. Therefore in this study, constructing experimental apparatus for measuring of rotational accuracy by using eddy current type gap sensors AEC5706PS and sensors, s-06LN, data acquisition board DT9834(USB type) and software for data acquisition, DT Measure Foundry ver. 4.0.7 etc., error data acquired in the rotational accuracy test of lathe spindle are analysed in plots and statistical treatments.

Fracture Toughness Testing in Alumina (알루미나에서의 파괴인성 측정)

  • 윤경진;박성길;김종집;조성재
    • Journal of the Korean Ceramic Society
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    • v.29 no.8
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    • pp.651-659
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    • 1992
  • Fracture toughness of alumina was determined by IF, IS, DT, SEPB methods, and the data were inter-compared. Round robin test on IF and IS methods was also conducted under the participitation of 4∼5 domestic institutes. Fracture toughness data determined by IF, IS, DT methods were similar, while those by SEPB method were smaller. Variation of toughness data determined by IS method using 98N of indentation load was significantly small compared to those determined by any other methods. Round robin test results showed that toughness data determined by IF method at various institutes do not coincide each other, while those by IS method do well coincide. Thus, it was concluded that inter-confidence on fracture toughness data, if determined by IS method at all institute, can be established between institutes.

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SURVEY ON THE ORAL HEALTH STATUS IN CHANG-GYUNG PRIMARY SCHOOL CHILDREN (창경국민학교 학생의 구강보건실태 조사연구 - 시범학교 계속구강건강관리사업을 위한 예비조사 -)

  • Paik, Dai-Il
    • The Journal of the Korean dental association
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    • v.19 no.6 s.145
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    • pp.535-540
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    • 1981
  • In order to collect the basic data for planning school dental health programmes, the author had examined dental health conditions of 120 males and 120 females of Changgyung Primary School children in the first grade. The percentages of persons with conditions requiring immediate attention, toothbrushing times and daily frequency, df rate, df index, dt index, ft index, it index, DMF rate, DT index, MT index, FT index, IT index, DMFT index, percentages of persons with periodontal status in every of the four categories with soft deposits, calculus, intense gingivitis, and advanced periodontal involvement were calculated and evaluated. The obtained results were as follows: 1. Persons with requiring immediate attention was 7.1% of all the examined children. 2. The df rate was 88.3%, and df index was 3.4 teeth per person. And then the DMF rate was 17.1%, while DMFT index was 0.3 teeth per person. 3. As the periodontal status, the persons with soft deposits was 90.0% of children, calculus 26.3%, intense gingivitis 0.4%, and no advanced periodontal involvement. 4. Average toothbrushing frquency was 1.2 times in a day per person. But 71.5% of toothbrushing was performed before meals, while the others after meals.

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Denigration Kinetics by Formic Acid in the Simulated Radwaste Solution (모의 방사성폐액에서의 개미산 탈질속도 연구)

  • Lee, E.H.;Whang, D.S.;Kim, K.W.;Kwon, S.G.;Yoo, J.H.
    • Applied Chemistry for Engineering
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    • v.8 no.1
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    • pp.132-139
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    • 1997
  • This study was carried out to examine the kinetics and reaction mechanism of denitration with formic acid in the simulated radwaste solution containing 6 components such as Nd, Pd, Ru, Zr, Mo and Fe. All experiments were performed with the changes of initial nitric acid concentration, molar ratio of formic acid to nitric acid, and denitration time at $90^{\circ}C$ and a batch system. As results, destruction rate of nitric acid and formic acid was obtained as follows, respectively. $\frac{d[HNO_3]}{dt}=-4.842{\times}10^{-2}[HNO_3][HCOOH],\;\frac{d[HCOOH]}{dt}=-8.911{\times}10^{-2}[HNO_3][HCOOH]$ It was confirmed that denitration with formic acid was controlled by reaction mechanism suggested this study in the range of the initial nitric acid of 2~5M and $[HCOOH]/[HNO_3]$ of 1.5~2.0. In the 1M initial nitric acid, however, it was found that the nitric acid and the formic acid were decomposed by a different reaction mechanism.

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Oropharyngeal Carriage and Antimicrobial Resistance of S. pneumoniae in Children of Seoul (서울 지역 소아의 구인강에서 폐구균 보균율과 항균제 내성)

  • Kim, Young Kee;Lee, Chang Kyu
    • Pediatric Infection and Vaccine
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    • v.4 no.2
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    • pp.218-224
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    • 1997
  • Purpose: The antimicrobial resistance of S. pneumoniae has encountered with increasing frequency from around the world. In our country, penicillin resistant strains of S. penumococci are rapidly increasing. It has been known that colonized pneumococci in upper respiratory tract cause sinisitis, otitis media, meningitis and pneumonia. We tried to reveal the colonization rate of pneumonocci in upper respiratory tract, their antimicrobial resistance and DNA fingerprinting pattern in normal children. Methods: We got specimens from 117 children of day-care center in Seoul through oropharyngeal swab. After incubation on BAP, optochin test and slide latex agglutination test were used for identification. Antimicobial susceptibility test to penicillin, vancomycin, erythromycin and TMP-SMZ was done with disk diffusion method. Penicillin MIC was gotten through the broth microdilution method. Genotyping of 45 pneumococci was done by rep-PCR using REP1R-Dt and REP2-Dt primer. Results: The carriage rate of pneumococci in the day-care center children was 38%(45/117). The resistance of penicillin, erhthromycin, TMP/SMZ, vancomycin by the disk diffusion method are 89%, 91%, 64% and 0%, respectively. 64% of the isolates showed multiple resistance. 7 types of DNA fingerprinting were gotten and 78% of isolates belonged to three types. Conclusion: We found that the antimicrobial resistance of children attending the day-care center in Seoul was much higher than expected. We assumed that this might be due to their easy and frequent exposure to antimicrobial agents and crowded day-care center environment.

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Anchorage Strength of High Strength Headed Bar Embedded Vertically on SFRC Members (SFRC 부재에 수직 배근된 고강도 확대머리철근의 정착강도)

  • Lee, Chang-Yong;Kim, Seung-Hun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.1
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    • pp.148-156
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    • 2020
  • The paper is a summary of the results of the basic pullout test which is conducted to evaluate the anchorage capacity of high strength headed bars that is mechanical anchored vertically on steel fiber reinforced concrete members. The main experimental parameters are volume fraction of steel fiber, concrete strength, anchorage length, yield strength of headed bars, and shear reinforcement bar. Both sides of covering depth of the specimen are planned to double the diameter of the headed bars. The hinged point is placed at the position of each 1.5𝑙dt and 0.7𝑙dt around the headed bars, and the headed bars are drawn directly. As a result of pullout test experiment, concrete fracture and steel tensile rupture appear by experimental parameters. The compressive strength of concrete is 2.7~5.4% higher than that of steel fiber with the same parameters, while the pullout strength is 20.9~63.1% higher than that of steel fiber without the same parameters, which is evaluated to contribute greatly to the improvement of the anchorage capacity. The reinforcements of shear reinforcements parallel to the headed bars increased 1.7~7.7% pullout strength for steel fiber reinforced concrete, but the effect on the improvement of the anchorage capacity was not significant considering the increase in concrete strength. As with the details of this experiment, it is believed that the design formula for the anchorage length of KCI2017and KCI2012 are suitable for the mechanical development design of SD600 head bar that is perpendicular to the steel fiber reinforced concrete members.

Influence of Sugar Cane Diets and a High Fibre Commercial Diet on Growth and Carcass Performance in Local Caribbean Pigs

  • Xande, X.;Despois, E.;Giorgi, M.;Gourdinegi, J.L.;Archimedee, H.;Renaudeau, D.
    • Asian-Australasian Journal of Animal Sciences
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    • v.22 no.1
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    • pp.90-98
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    • 2009
  • The aim of this study was to evaluate the effect of a milling by-product diet and two sugar cane diets on the local Creole pig breed (CR). A total of 48 CR pigs (24 females and 24 castrated males) were randomly assigned to four different groups of 12 animals. Pigs were allotted to one of 4 dietary treatments: fed with a control soya-bean meal-corn diet containing 19.1% crude protein (CP) and 15.4 MJ DE/kg (diet 1), with an experimental milling by-product diet (soya-bean meal and wheat by-products) containing 19.4% CP and 13.0 MJ DE/kg (diet 2), with ground cane stalks (GCS) or with fresh sugar cane juice (SCJ). Both GCS and SCJ were supplemented with soya-bean meal complement (400 g/d of a 48.7% CP and 16.1 MJ DE/kg diet) in order to obtain diets 3 and 4, respectively. Pigs were fed close to ad libitum level and had free access to water. All the pigs were slaughtered at 65 kg BW. Between 30 and 65 kg BW, growth performance was significantly (p<0.001) affected by dietary treatments: average daily BW gain was 657, 530, 546 and 200 g/d for diets 1, 2, 4, and 3, respectively. Average daily DM intake was 1.8, 1.9, 2.5 and 1.4 kg/d for diets 1, 2, 4, and 3, respectively. Fat cuts (backfat+leaf fat) and backfat thickness were significantly lower on diet 3 than for other treatments (127 vs. 192, 166 g/kg of left half-carcass weight and 24.6 vs. 39.0, 35.3 mm for diet 3 vs. diets 1 and 4, and diet 2, respectively; p<0.001). The dressing weight was significantly lower on diets 2 (82.7 vs. 84.0%; p<0.001). The entire empty digestive tract (DT) weight was higher on diet 2 (73.1 vs. 66.7 g/kg empty BW). However, stomach and large intestine were more developed on diet 3: 12.8 vs. 9.3 g/100 g empty DT (p<0.001) and 26.4 vs. 23.8 g/100 g empty DT (p<0.05), respectively. In conclusion, this study suggests the CR pig has the ability to reach rather good growth and carcass performance with a well-formulated sugar cane meal and/or with a milling by-product diet refined according to its low requirements.