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Influence of Ga-Addition on the Manetic Properties of $\alpha-Fe$ Based Nd-Fe-B Alloy (Ga 첨가가 $\alpha$-Fe기 Nd-Fe-B 합금의 자기특성에 미치는 영향)

  • 조덕호;이병엽;조용수
    • Journal of the Korean Magnetics Society
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    • v.7 no.1
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    • pp.44-48
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    • 1997
  • The nanocrystalline Nd-Fe-B alloys with low Nd content were prepared by rapid solidification technique. The alloys consist of both$\alpha$-Fe as the main phase and $Nd_2Fe_{14}B_1$ as a secondary phase and have an ultrafine grain structure of about 30 nm. The addition of Ga in $Nd_4Fe_{82}B_{10}Mo_3Cu_1$ alloy increases remanence up to 1.29 T and improves squareness. The nanocrystalline $Nd_5Fe_{81}B_9Mo_3Cu_1Ga_1$ alloy has a volume fraction of $Nd_2Fe_{14}B_1$ phase of around 35% due to the increase of Nd content and shows an improved coercivity. The remanence, coercivity and energy product of optimally annealed nanocrystalline $Nd_5Fe_{81}B_9Mo_3Cu_1Ga_1$ alloy are 1.24 T, 257.4 kA/m (3.23 kOe), and 100.3 kJ/ ㎥ (12.6 MGOe), respectively.

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DDC문학류의 조합식 분류시스템 분석 - 20판을 중심으로

  • 윤희윤
    • Journal of Korean Library and Information Science Society
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    • v.20
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    • pp.351-381
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    • 1993
  • The purpose of this study is to analyze the various processes and patterns to build or synthesize class numbers in the 800 class of the Dewey Decimal Classification, Edition 20(1989). The results of the analysis are as follows: 1. The 800(Literature and rhetoric) class in the DDC system is the main class added analytico-synthetic principle positively to an enumerative scheme. 2. The facets to be a n.0, pplied in literature are language literary form literary period ; kind, scope, or medium ; notation 08(collection) or 09(criticism) literary feature, subject, author, etc. 3. In the 800 class, there are the five tables of precedence for literary forms aspects ; specific kinds of persons ; literary, period in relation to the aspects for works treating more than one literary form subforms, aspects and literary periods in the works treating a specific literary form. 4. The basic number synthesis of literary works proceeds through the various facets in the following sequence, as far as necessary for the item : base no. + literary form + literary time or period + kind, scope, or medium + notation 08 or 09 + subform + additional notation from T3C and other tables. 5. In view of the multiplicity of facets, their synthesis formulas take the following order : (1) Works about the literature : base no.(schedule) + language(T6) or form(T3B) (2) Works by or about individual author : base no.(schedule) + form (T3A) + period(schedule) + subform(T3A) (3) Works by or about more than one author, not restricted by language facet : base no.(schedule) + period(T1) ; base no.(schedule) + kind, scope, medium(T3B), or feature(T3C), or person(T5). (4) Works by or about more than one author, restricted by language facet : base no.(schedule) + form (T3B) + period(schedule) + subform(T3B) + notation 08 or 09(T3B) ; base no.(schedule) + notation 08 or 09(T3B) + 9(T3C) + area notation(T2) : base no.(schedule) + form (T3B) + notation 008 or 009(T3B) : base no.(schedule) + form (T3B) + kind, scope, medium(T3B) + notation 08 or 09(T3B) + period(schedule). (5) Affiliated literatures for which period numbers are not us base no.(schedule) + form (T3A or T3B), or notation 08 or 09(T3B) : base no.(schedule) + kind, scope, medium(T3B), feature(T3C), or person(T5) 6. The problems in the number building of the 800 class are the complexity and difficulty of number synthesis, the intrinsic weakness of from distinction and the inconvenience of retrieval inherent in the form class. In order to solve these problems, therefore, the citation orders and methods of DDC should be improved and synthesis patterns simplified from the point of view of its applicability and its usefulness in the "literature class".

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TMA Study on Phase Evolution During Hydrogen-assisted Disproportionation of Nd-Fe-B Alloy

  • Kwon, H.W.;Yu, J.H.
    • Journal of Magnetics
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    • v.16 no.3
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    • pp.229-233
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    • 2011
  • Phase evolution during the hydrogen-assisted disproportionation of $Nd_{12.5}Fe_{80.6}B_{6.4}Ga_{0.3}Nb_{0.2}$ alloy was investigated mainly by using a magnetic balance-type thermomagnetic analyser (TMA). In order to avoid any undesirable phase change in the course of heating for TMA, a swift TMA technique with very high heating rate (around 2 min to reach $800^{\circ}C$ from room temperature) was adopted. The hydrided $Nd_{12.5}Fe_{80.6}B_{6.4}Ga_{0.3}Nb_{0.2}$ alloy started to be disproportionated in hydrogen from around $600^{\circ}C$, and the alloy after the early disproportionation (from 600 to $660^{\circ}C$) has been partially disproportionated. The partially disproportionated alloy consisted of a mixture of $NdH_x$, $Fe_3B$, ${\alpha}$-Fe, and the remaining undisproportionated $Nd_2Fe_{14}BH_x$-phase. During the subsequent heating to $800^{\circ}C$ in hydrogen, two additional phases of $Fe_{23}B_6$ and $Fe_2B$ were formed, and the material consisted of a mixture of $NdH_x$, $Fe_{23}B_6$, $Fe_3B$, $Fe_2B$, and ${\alpha}$-Fe phases. During the subsequent isothermal holding at $800^{\circ}C$ for 1 hour, the phase constitution was further changed, and one additional unknown magnetic phase was formed. Eventually, the fully disproportionated $Nd_{12.5}Fe_{80.6}B_{6.4}Ga_{0.3}Nb_{0.2}$ alloy consisted of $NdH_x$, $Fe_{23}B_6$, $Fe_3B$, $Fe_2B$, ${\alpha}$-Fe, and one additional unknown magnetic phase.

Crystal Structure of Lithium Heptaborate, $Li_3B_7O_12$ ($Li_3B_7O_12$의 결정구조)

  • 박현민;조양구
    • Korean Journal of Crystallography
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    • v.9 no.1
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    • pp.15-20
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    • 1998
  • Single crystals of lithium heptaborate, Li3B7O12(M=288.49), have been grown and their structure was determined by the x-ray powder diffraction and the single crystal diffraction technique. It is found that the borate anion consists of two(B3O7)3- and (B3O8)5- groups a unit cell. The space group was determined to be P-1(Ci1) with a=6.500(3) Å, b=7.839(2) Å, c=8.512(1) Å, α=92.07(2)˚, β=104.97(2)˚, γ=99.35(3)˚, V=412.0(2) Å3, Z=2 Dx=2.32 g cm-3, MoKα, λ=0.71069 Å, μ=2.15cm-1, T=293K. The structure was refined to R=0.0339 and wR=0.0882 for 2296 unique reflections by the single crystal diffraction. By the x-ray powder diffraction, we could obtain the similar results.

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Magnetic Propertes of $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}(x=\;3,\;4,\;5)$ Nanocrystalline Alloys ($Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}(x=\;3,\;4,\;5)$ 초미세결정립합금의 자기특성)

  • 조용수;김만중;천정남;김택기;박우식;김윤배
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.880-894
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    • 1995
  • Magnetic properties of $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}(x=\;3,\;4,\;5)$ rrelt-spun alloys with 6 at% B content were studied aiming for finding out a new $\alpha$-Fe based Nd-Fe-B nanocrystalline alloy with good hard magnetic properties. $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}$ melt-spun alloys prepared by RSP crystallized to nanocrystalline phase. An optimally annealed $Nd_{3}{(Fe_{0.9}Co_{0.1})}_{87}B_{6}Nb_{3}Cu_{1}$ melt-spun alloys had larger volume ratio of $\alpha$-Fe(Co) than that of higher Nd content alloy and showed high remanence of about 1.6 T. On the contrary, the increase of Nd content in $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}$ alloys gave rise to gradual increase of an amount of $Nd_{2}{(Fe,\;Co)}_{14}B$ phase and improved coercivity. An optimally annealed $Nd_{5}{(Fe_{0.9}Co_{0.1})}_{85}B_{6}Nb_{3}Cu_{1}$ alloy showed the most improved hard mag¬netic properties. The remanence, coercivityand energy product of the alloy were 1.35 T, 219 kA/m (2.75 kOe), and $129\;kJ/m^{3}$ (16.2 MGOe), respectively.

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Viability of Bifidobacterial Strains against Acid, Bile Acid, and Oxygen Exposure (산, 담즙산, 산소 노출에 대한 비피도박테리아의 생존에 관한 연구)

  • Lim, Kwang-Sei;Huh, Chul-Sung
    • Food Science of Animal Resources
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    • v.26 no.4
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    • pp.503-510
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    • 2006
  • Survival and stability of 19 bifidobacterial strains included 13 isolates from Korean infants against acid, bile acid and oxygen exposure were examined. Acid resistance of selected strains at pH values of 4.0, 3.0 and 2.0 was tested. Among the bifidobacterial strains tested, B. bifidum B3, B. longum D6, and B. adolescentis F1 exhibited higher viable cell counts exposed to acid whereas other strains had various results. The abilities of the strains to grow in the MRS broth containing 0.2% thioglycolic acid and 0.2% oxgall were tested and the tolerance of B. bifidum B3 and B. longum D6 to bile acid were higher than that of others. Even though in same species, the tolerance of tested strains to bile acid were variable. Stabilities of tested strains to oxygen exposure were variable and B. bifidum and B. longum strains showed relatively higher viable cell counts after 48 hours exposure to aerobic incubation. These results demonstrated that the survival and stability of bifidobacterial strains to acid, bile acid, and oxygen exposure were variable and strain-dependent. Due to their tolerant ability to environmental factors like acid, bile acid, and oxygen, B. bifidum B3 and B. longum D6 had good potential properties as probiotic cultures and may be useful for industrial application.

Addition Compounds of Alkali Metal Hydrides. 32. A Comparison Study of Chiral Trialkylborohydrides and Chiral Dialkylmonoalkoxyborohydrides for the Asymmetric Reduction of Prochiral Ketones: The Effect of Comparable Chiral Alkyl and Alkoxy Groups on Asymmetric Industion$^\dag$

  • Brow, Hervert C.;Park, Won-Suh;Cho, Byung-Tae
    • Bulletin of the Korean Chemical Society
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    • v.8 no.4
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    • pp.276-280
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    • 1987
  • Several chiral potassium B-alkyl-9-boratabicyclo[3.3.1]nonanes $(K\; B-R^*-9-BBNH)$ and potassium B-alkoxy-9-boratabicyclo[3.3.1]nonanes $(K \;B-OR^*-9-BBNH)$ were synthesized by treatment of the corresponding trialkylboranes and dialkylmonoalkoxyboranes with a small excess of potassium hydride. The chiral B-alkoxy derivatives generally reduce representative ketones, such as acetophenone and 3-methyl-2-butanone, with greater optical induction than the corresponding B-alkyl derivatives, suggesting the involvement of the oxygen atom in the control process for asymmetric synthesis.

Investigation of $xV_2O_5-B_2O_3$ and $xV_2O_5-B_2O_3-yNa_3O$ Glasses by $^{11}B MAS$ NMR

  • Kim, Sun-ha;Han, Oc-Hee;Kang, Jae-Pil
    • Journal of the Korean Magnetic Resonance Society
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    • v.9 no.1
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    • pp.61-66
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    • 2005
  • $^{11}B MAS NMR$ spectra of binary glass system $xV_2O5-B_2O_3$ and ternary glass system $xV_2O5-B_2O_3-yNa_2O$ (x = $V_2O_5 mol%/$B_2O_3$ mol%, y = $Na_2O$ mol$/$B_2O_3$ mol%) were acquired. $BO_3$ units are dominant components in the spectra of $xV_2O_5-B_2O_3$glass systems while both $BO_3$ and $BO_4$ unit appear in comparable amounts in the spectra of $xV_2O_5-B_2O_3-yNa_2O$ glass systems. More $BO_3$ units were monitored for higher $V_2O_5$ contents while more $BO_4$ unit for higher $Na_2O$ contents. Quadrupole parameters such as $e^2qQ$ and $\eta$ obtained form spectral simulation indicate that $e^2qQ$ has a maximum value at x = y 1 and $\eta$ decreases and increases as x or y grows, respectively. Our results suggest that $V_2O_5$ and $Na_2O$ play opposite roles in the ternary glasses.

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Design and Implementation of UWB BPFs (UWB BPF의 설계 및 구현)

  • Kang, Sang-Gee;Lee, Jae-Myung;Hong, Sung-Yong
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.12 no.5
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    • pp.815-820
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    • 2008
  • Recently the frequency assignment and the technical specifications of UWB systems for communications are completed. Therefore many UWB systems have been developed. In our country $3.1{\sim}4.8GHz$ and $7.2{\sim}10.2GHz$ are assigned for UWB systems for communications. When we consider RF technologies and the easy implementation of UWB systems, UWB systems used in the low band are more developed than high band systems. In this paper we design and implement a BPF for low band UWB systems by means of considering the easy implementation of UWB systems. The designed and implemented BPFs are low band filter and low band channel filters. The measured results of the low band filter show that the filter has 21.85dB and 17.91dB attenuation at 3.1GHz and 4.8GHz, 1.53GHz of -10dB bandwidth and 2dB of insertion loss. Low band can be divided into 3 channels with 500MHz of the channel bandwidth. The channel filter for channel number 1 has the characteristics of 24.85dB attenuation at 3.1GHz, 0.61GHz of -10dB bandwidth and 1.87dB of insertion loss. The filter for channel 3 in low band has 19.2dB of attenuation at 4.8GHz, 0.49GHz of -10dB bandwidth and 2.49dB of insertion loss.

Copolymerization of Ethylene and 1-Hexene via Polymethylene Bridged Cationic Dinuclear Constrained Geometry Catalysts (폴리메틸렌 다리로 연결된 양이온 이핵 CGC를 이용한 에틸렌과 1-헥센의 공중합)

  • Bian, Feng Ling;Que, Dang Hoang Dan;Lyoo, Won-Seok;Lee, Dong-Ho;Noh, Seok-Kyun;Kim, Yong-Man
    • Polymer(Korea)
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    • v.31 no.6
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    • pp.497-504
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    • 2007
  • We have prepared the dinuclear half-sandwich CGC(constrained geometry catalyst) with polymethylene bridge $[Zr(({\eta}^5\;:\;{\eta}^1-C_9H_5SiMe_2NCMe_3)Me_2)_2\;[(CH_2)_n]$ [n=6(4), 9(5), 12(6)] by treating 2 equivalents of MeLi with the corresponding dichlorides compounds. To study the catalytic behavior of the dinuclear catalysts we conducted copolymerization of ethylene and 1-hexene in the presence of three kinds of boron cocatalysts, $Ph_3C^+[B(C_6F_5)_4]^-\;(B_1),\;B(C_6F_5)_3\;(B_3)$, and $Ph_3C^+[(C_6F_5)_3B-C_6F_4-B(C_6F_5)_3]^{2-}\;(B_2)$. It turned out that all active species formed by the combination of three dinuclear CGCs with three cocatalyst were very efficient catalysts for the polymerization of olefins. The activities increase as the bridge length of the dinuclear CGCs increases. At the same time the dinuclear cocatalyst exhibited the lowest activity among three cocatalysts. The prime observation is that the dinuclear cocatalyst gave rise to the formation of the copolymers with the least branches on the polyethylene backbone.