• 한국세라믹학회지
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• 제54권1호
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• pp.1-8
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• 2017

Electrochemical water splitting to produce hydrogen energy is regarded as a promising energy conversion process for its environmentally friendly nature. To improve cell efficiency, the development of efficient water oxidation catalysts is essentially demanded. For several decades, 3d transition metal oxides have been intensively investigated for their high activity, good durability and low-cost. This review covers i) recent progress on 3d transition metal oxide electrocatalysts and ii) the reaction mechanism of oxygen evolving catalysis, specifically focused on the proposed pathways for the O-O bond formation step.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회A
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• pp.1301-1302
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• 2008

In this study, the fracture strength for fracture mechanism porous calcium phosphate made from sintered with ${\beta}$-tricalcium phosphate obtained by wet precipitation procedure is analyzed using finite element method and experiment measurement. First, three $3{\times}3{\times}3mm^3$ and $5{\times}5{\times}5mm^3$ specimens are prepared and tomographic images of one $5{\times}5{\times}5mm^3$ specimen are obtained by micro focus X-ray CT. The compression tests using the specimens are carried out to measure the elastic modulus and fracture strength to analyze the fracture mechanism of porous calcium phosphate specimen. The tomographic images are reconstructed by 3D reconstruction program. The finite elements are directly built up in the reconstructed specimen. The numerical simulation for the compression tests is performed using the element. The mechanism of calcium phosphate of simulation are obtained by the compression tests using there cylindric specimen of height 19.5 mm and diameter 10 mm. From the results, the applicability of porous calcium phosphate is evaluated to care fracture and vacant bone of a patient as the reinforcement material.

• 디지털융복합연구
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• 제19권6호
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• pp.285-292
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• 2021

최근 코로나19 사태로 캠핑 문화가 급속하게 많은 사람들에게 관심을 받고 있다. 많은 캠퍼들이 겨울철 사용하는 대류난방기구는 온도 성층화 문제를 가지고 있다. 이를 해결하기 위해 다양한 동력 서큘레이터가 활용되고 있다. 몇 가지 무동력 서큘레이터도 판매가 되고 있으나, 서큘레이터의 방향이 대류난방기구와 직각으로 디자인되어 있어 실제 공기 순환의 역할을 제대로 하지 못하고 있다. 이러한 문제점을 해결하고자 3D 프린터를 이용하여 대류난방기구의 방향과 같은 무동력 서큘레이터를 디자인하였다. 펠티어소자와, 세라믹페이퍼 등을 이용하여 무동력으로 전기를 만들어 냈으며, HTPLA-CF 필라멘트를 이용하여 열에 강하게 제작하였다. 3D 프린터를 이용하여 원가를 절감할 수 있었으며, 다양한 대류난방기구의 크기에 맞게 제작 할 수 있는 장점이 있다. 본 연구는 효율적인 대류순환을 통해 온도 성층화 문제를 해결할 수 있는 하나의 방법을 제시한다. 또한 3D 프린터를 이용하여 보다 저렴하게 제품을 제작하는 것이 본 연구의 목적이다.

• 한국정밀공학회지
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• 제25권5호
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• pp.82-88
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• 2008

This paper proposes a novel method of 2 dimensional shape display. Shape displays allow us to feel tile actual volume of the object, unlike conventional 2D visual displays of 3D objects. The proposed method employs a wireframe structure to present 2D or 3D objects. The wireframe is composed of small units driven by shape memory alloy (SMA) actuators. The drive unit is analogous to the agonist-antagonist system of animal musculoskeletal systems, where the SMA actuators serve as agonist and antagonist muscles. The force in the SMA actuator is controlled by electrical current. The drive unit is equipped with the locking mechanism so that it can sustain the external force exerted by the user as well as the own weight of the wireframe structure. By controlling the current into the SMA actuator and locking mechanism, we can control the angle of the drive unit. A chain of drive units enables presentation of 2 dimensional objects. 3 dimensional presentations are possible by collecting the chains of drive units.

• 과학교육연구지
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• 제42권2호
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• pp.95-105
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• 2018

이 연구의 목적은 생체 모방 기반 융합 학습 모델을 이용하여 골격근의 구조 및 수축 메커니즘에 대한 디지털 교과서를 개발하는 것이다. 골격근의 구조 및 수축 메커니즘 단원은 고등학교 생명과학I에 포함된 내용이다. 융합 학습 모델은 3D 모델링 및 프린팅을 포함하는 3단계의 생체 모방 기반 융합 학습(Exploration-Design-Implementation)으로 설계되었다. 개발된 디지털 교재는 8차시로 구성되어 있는데, 골격근 탐색, 스케치 앱과 3D 모델링을 이용한 골격근 모방 창의적 설계 2개 차시, 3D 프린팅을 이용하여 설계안의 융합적 구현, 근수축의 탐색, 스케치 앱과 3D 모델링을 이용한 근수축 모방 창의적 설계 2개 차시, 3D 프린팅을 이용하여 설계안의 융합적 구현 등으로 구성되었다. 각 차시는 대화 형 및 모바일 학습을 위해 갤러리 위젯, 미디어 위젯, 프레젠테이션 위젯, 스케치 위젯, 클라우드, 설문 위젯 및 평가 위젯의 컨텐츠를 포함하고 있다. 개발 된 디지털 교과서를 고등학생 20 명에게 투입한 결과 학생들의 생명과학 학습에 효과가 긍정적인 것으로 나타났다. 또한 이 연구에서 개발된 생체 모방 기반 융합 학습 디지털 교재는 학생들의 창의적 설계 및 구현 능력의 향상에서 효과적인 학습자료로 평가되었다. 이러한 결과를 볼 때 디지털 교재는 학생들의 흥미와 생명과학에 대한 자기주도적 학습에 유용한 자료임을 보여주었다.

• Journal of Photoscience
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• 제12권1호
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• pp.51-54
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• 2005

The electronic excitationenergy quenching of 2, 5-diphenyl-1, 3, 4-oxadiazole (PPD) by Carbon tetrachloride ($CCl_4$) in different solvents viz, n-hexane, n-heptane, toluene, benzene, cyclohexane, 1, 4- dioxane has been carried out at room temperature to understand the role of quenching mechanism. The Stern-Volmer plots have been found to be linear. As probability of quenching per encounter 'p' is less than unity, and the activation energy for quenching '$E_a$' is greater than the activation energy of diffusion '$E_d$', it is inferred that the fluorescence quenching mechanism is not due to material diffusion alone.

• 한국세라믹학회지
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• 제31권3호
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• pp.249-256
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• 1994

By surface structure and X-ray topographic observation, growth mechanism of NAB single crystal grown by TSSG technique using a BaB4O7 flux was studied. Surface structure of grown crystals were investigated by optical microscope. Growth history and crystal defects included within grown crystal were investigated using X-ray topography. The {001} faces were grown by 2-D nucleation growth. As decreasing cooling rate, growth mechanism of {111} and {11} was changed from 2-D nucleation growth to the growth by screw dislocation. Only surface striations developed parallel to a-axis were observed on {010} faces. Growth sector of NAB crystals were divided into {001}, {111}, {010}, {021}, {11}. The inclusion which was usually trapped between {001} faces was investigated.

• Bulletin of the Korean Chemical Society
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• 제33권2호
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• pp.663-669
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• 2012

The nucleophilic substitution reactions of dibutyl chlorophosphate (3) with substituted anilines ($XC_6H_4NH_2$) and deuterated anilines ($XC_6H_4ND_2$) are investigated kinetically in acetonitrile at $55.0^{\circ}C$. The obtained deuterium kinetic isotope effects (DKIEs; kH/kD) are secondary inverse ($k_H/k_D$ = 0.86-0.97) with the strongly basic anilines while primary normal ($k_H/k_D$ = 1.04-1.10) with the weakly basic anilines. The DKIEs, steric effects of the two ligands, activation parameters, cross-interaction constants, variation trends of the kH/kD values with X, and mechanism are discussed for the anilinolyses of the nine ($R_1O$)($R_2O$)P(=O)Cl-type chlorophosphates. A concerted mechanism is proposed with a backside nucleophilic attack transition state for the strongly basic anilines and with a frontside attack involving a hydrogen-bonded four-center-type transition state for the weakly basic anilines on the basis of the magnitudes, secondary inverse and primary normal, and variation trends of the $k_H/k_D$ values with X.

• BMB Reports
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• 제33권3호
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• pp.228-233
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• 2000

The steady-state investigation of the mechanism of Dhydroxyisovalerate dehydrogenase was performed in order to understand this type of kinetic patterns. The initial velocity was measured with various amounts of both substrates, NADPH and 2-ketoisovalerate. Double reciprocal plots gave patterns that conversed on or near the abscissa. Binding studies indicated that NADPH bound first to the enzyme. The product $NADP^+$ was found to be a competitive inhibitor with respect to NADPH at a constant concentration of 2-ketoisovalerate. However, it showed noncompetitive inhibition against 2-ketoisovalerate at a fixed amount of NADPH. Another product, D-hydroxyisovalerate, was a non-competitive inhibitor versus NADPH and 2-ketoisovalerate at constant levels of 2-ketoisovalerate and NADPH, respectively. These results were comparable with an ordered bi-bi mechanism, in which NADPH bound first to the enzyme, followed by the binding of 2- ketoisovalerate. $NADP^+$ is the last product to be released. The ordered reaction manner of D-hydroxyisovalerate dehydrogenase from 2-ketoisovalerate to D-hydroxyisovalerate allows the accurate regulation of valine metabolism and it may lead to the regulation of total biosynthesis of enniatins in the Fusarium species.

• 대한약학회:학술대회논문집
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• 대한약학회 2002년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2
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• pp.259.2-259.2
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• 2002

The purpose of the present study was to determine the effects of platycodin D and D3 on the contractile force of the isolated rat aorta and blood pressure of the anesthetized rat. and also to establish the mechanism of action. The phenylephrine (10 $\mu$M)-induced contractile responses were greatly inhibited in the presence of platycodin D (4 ∼ 24 $\mu$g/$m\ell$) in a dose-dependent fashion. (omitted)