• Title/Summary/Keyword: 3 Elements of Combustion

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Characterization of PM10 and Air-borne Metallic Elements Produced in Asan and Seoul

  • Son, Bu-Soon;Choi, Kyung-Ho;Yang, Won-Ho
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2004.06a
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    • pp.142-145
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    • 2004
  • The purpose of this study was to characterize background mass concentration of fine particle PM10 and metallic composition from September 2001 to August 2002 in comparison with a medium-sized city, Asan and a metropolitan city, Seoul. Annual mean PM10 concentrations in Asan and Seoul were 47.98 and $75.33\;{\mu}g\;/\;m^3$, respectively. The concentrations of PM10 were highest in spring season in both cities. The concentrations of measured metals except As and Pb in Asan were higher than those in Seoul. Yellow dust could affect the mass and metals concentrations of measured PM10 in Asan and Seoul. Relationship between measured metals concentrations showed that Si and Fe were associated with natural sources such as soil. Pb, Cu and Zn were closely related to urban anthropogenic sources such as fuel combustion. Especially, relationship between metals showed different association during yellow dust. Proper management for fine particles is warranted in Asan, considering the concentrations of metallic elements in fine particles in Asan were relatively higher than those in Seoul.

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Size-resolved Source Apportionment of Ambient Particles by Positive Matrix Factorization at Gosan, Jeju Island during ACE-Asia (PMF 분석을 이용한 ACE-Asia 측정기간 중 제주 고산지역 입자상 물질의 입경별 발생원 추정)

  • Moon K.J.;Han, J.S.;Kong, B.J.;Jung, I.R.;Cliff Steven S.;Cahill Thomas A.;Perry Kelvin D.
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.5
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    • pp.590-603
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    • 2006
  • Size-and time-resolved aerosol samples were collected using an eight-stage Davis rotating unit for monitoring (DRUM) sampler from 23 March to 29 April 2001 at Gosan, Jeju Island, Korea, which is one of the super sites of Asia-Pacific Regional Aerosol Characterization Experiment(ACE-Asia). These samples were analyzed using synchrotron X-ray fluorescence for 3-hr average concentrations of 19 elements including Al, Si, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, As, Se, Br, Rb, and Pb. The size-resolved data sets were then analyzed using the positive matrix factorization(PMF) technique to identify possible sources and estimate their contributions to particulate matter mass. PMF analysis uses the uncertainty of the measured data to provide an optimal weighting. Twelve sources were resolved in eight size ranges($0.09{\sim}12{\mu}m$) and included continental soil, local soil, sea salt, biomass/biofuel burning, coal combustion, oil combustion, municipal incineration, nonferrous metal source, ferrous metal source, gasoline vehicle, diesel vehicle, and volcanic emission. The PMF result of size-resolved source contributions showed that natural sources represented by local soil, sea salt, continental soil, and volcanic emission contributed about 79% to the predicted primary particulate matter(PM) mass in the coarse size range ($1.15{\sim}12{\mu}m$) while anthropogenic sources such as coal combustion and biomass/biofuel burning contributed about 58% in the fine size range($0.56{\sim}2.5{\mu}m$). The diesel vehicle source contributed mostly in ultra-fine size range($0.09{\sim}0.56{\mu}m$) and was responsible for about 56% of the primary PM mass.

A Thermal Study of the Harmful Chemical Species of Charcoal and Their Transformation during Combustion (숯의 유해물질과 이들의 연소 중 상변화에 대한 열분석 연구)

  • Yoon, Hye-On;Kim, Ki-Hyun
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.2
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    • pp.101-110
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    • 2011
  • Charcoal burning in the process of manufacture and ordinary use often release many constituent chemical species. As a result of open burning, the chemical composition as well as the physical properties of original material changes through the modification of surface properties of charcoal. Surface modification could be more responsible toward the outside elements for surface adsorption, it becomes easy to adsorb more toxic elements through surface adsorption. In this study, four kinds of commercially available charcoal were studied against the chemical and thermal stability along with the heavy metals and organic hazardous substances. Thermo gravimetric analysis (TGA) and differential scanning calorimetry, from room temperature to $400^{\circ}C$, were performed to study the weight loss and the changes in the behavior of those substances. According to TGA analysis, about 10% of weight loss was happened before $200^{\circ}C$. It was found that related weight loss of this temperature region may responsible to the gas phase organic matter. Natural charcoal, K1 and C1 show 15% of loss during the reaction heated to $400^{\circ}C$, while the artificial charcoal K2, C2 show the weight loss of about 20% was found. This is consistent with the main organic matter and VOC analysis results shown. Chemical composition based on the x-ray diffraction analysis was carried out. X-ray diffraction analysis reveals the existence of chemical additive in the forms of $Ba(NO_3)_2$, $BaCO_3$, and $NaNO_3$.

A Study on the Stability Improvement of Oxygen Handling Equipment to Prevent Fire and Explosion Accidents in High-Pressure Oxygen Transport Piping (고압산소 이송배관시 화재·폭발 사고 방지를 위한 산소 취급 설비 안정성 향상에 관한 연구)

  • Sang Kyu Oh;Sang Ryung Kim
    • Journal of the Korean Institute of Gas
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    • v.27 no.3
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    • pp.84-90
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    • 2023
  • Oxygen, which is always present in the atmosphere among the three elements of combustion, can cause fires and explosions with only a very small amount of combustibles under high-pressure oxygen conditions. The burning rate is also significant, and can rise to temperatures that can have a direct impact, such as melting process equipment and piping in an instant. Therefore, accidents that occur under high pressure oxygen often cause more damage than other accidents. Recently, while operating a valve installed in an oxygen supply pipe, rapid combustion and rupture occurred inside, resulting in human casualties due to an explosion. In the case of an old carbon steel pipe, particles generated during operation become combustible and can cause accidents. . In particular, since oxygen facilities are facilities licensed under the High Pressure Gas Safety Management Actand there are no restrictions under the Occupational Safety and Health Act, accumulating these standards is of utmost importance. Therefore, in this study, based on accident cases and overseas standards, methods for improving safety when handling hyperbaric oxygen are reviewed.

A Model of Collision Point to Estimate Impact Force Related to Piston Slap (피스톤 슬랩 충격력 예측을 위한 충돌점 모델)

  • 조성호;안상태
    • Journal of KSNVE
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    • v.10 no.3
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    • pp.474-479
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    • 2000
  • Piston slap is not only one of the major sources of noise and vibration in internal combustion engines but also a cause of the deterioration of engine performance. The basic mechanism associated with the piston slap seems to be quite simple but the phenomenon is in fact complicated with regard to many mechanical elements associated, First of all the impact force of piston slap must be identified to estimate engine block surface vibration, In this paper model of collision point is proposed to calculate the impact force when slap surface vibration. In this paper model of collision point is proposed to calculate the impact force when slap occurs. The parameters of the model are estimated by employing the concept of point mobility, . The predicted and experimentally observed vibration results confirm that the proposed method is practically useful.

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Chemical Characteristics and Source Apportionment ofPM2.5 in Seoul Metropolitan Area in 2010 (2010년도 서울시 대기 중 PM2.5의 성분특성 및 발생원 추정에 관한 연구)

  • Moon, Kwang-Joo;Park, Seung-Myung;Park, Jong-Sung;Song, In-Ho;Jang, Sung-Ki;Kim, Jong-Chun;Lee, Seok-Jo
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.6
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    • pp.711-722
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    • 2011
  • This study is aimed to estimate the $PM_{2.5}$ source apportionment at Seoul intensive monitoring site located in Seoul metropolitan area. Time-resolved chemical compositions of $PM_{2.5}$ are measured in real time using ambient ion monitor, semi-continuous carbon monitor, and on-line XRF at Seoul intensive monitoring site in 2010. The mass concentration of $PM_{2.5}$ was simultaneously monitored with eight ionic species (${SO_4}^{2-}$, $NO_3{^-}$, $Cl^-$, $NH_4{^+}$, $Na^+$, $K^+$, $Mg^{2+}$, $Ca^{2+}$), two carbonaceous species (OC and EC), and fourteen elements (Si, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Zn, As, Se, Pb) in 1-hr interval. The data sets were then analyzed using EPA PMF version 3 to identify sources and contributions to $PM_{2.5}$ mass. EPA PMF modeling identified eight PM2.5 sources, including soil dust, secondary sulfate, secondary nitrate, motor vehicle, coal combustion, oil combustion, biomass burning, and municipal incineration. This study found that the average $PM_{2.5}$ mass was apportioned to anthropogenic sources such as motor vehicle, fuel combustion, and biomass burning (61%) and secondary aerosols, including sulfate and nitrate (38%).

A Study on Waveform Analysis of Oxygen Sensor, Injector and Secondary Waveform through Emission Characteristics by a Decrepit Vehicle (노후 차량의 배기가스 측정을 이용한 산소센서, 인젝터, 점화2차파형의 파형분석 연구)

  • Yoo, Jongsik;Kim, Chulsoo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.5
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    • pp.151-156
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    • 2013
  • The experiment was done on cars travelling at the speeds of 20km/h, 60km/h and 100km/h using the performance testing mode for chassis dynamometer. In this experiment, the relativity between the secondary waveform coming from ignition coil and exhaust emissions were measured in case of cars with failures, in oxygen sensor, spark plugs. The following results obtained by analysis of the relativity between the secondary waveform and exhaust emissions. 1) When the oxygen sensor is failure, the average value of CO emission measured was 6.8 times higher than the standard CO emission value and the average value of HC emission measured was 2.3 times higher than the standard emission level. 2) When engine parts are in failure, more fuel enters the cylinder due to longer opening duration of injector, and it tended to make CO and HC emission values increase. 3) Combustion duration, the shape of flame propagation during spark line, and the size of the discharge-induced energy were the three main elements that directly cause variations in CO and HC emission values.

The Study of Heat Resistant Aluminum Alloy with CrW Homogeneous Solid Solution (CrW 전율고용체 첨가 내열 알루미늄 합금에 관한 연구)

  • Kim, Jin-Pyeong;Sung, Si-Young;Han, Beom-Suck;Kim, Sang-Ho
    • Journal of Korea Foundry Society
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    • v.33 no.3
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    • pp.122-126
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    • 2013
  • Recently, heat-resistant aluminum alloy has been re-focused as a downsizing materials for the internal combustion engines. Heat-resistant Al alloy development and many researches are still ongoing for the purpose of improving thermal stability, high-temperature mechanical strength and fatigue properties. The conventional principle of heat-resistant Al alloy is the precipitation of intermetallic compounds by adding a variety of elements is generally used to improve the mechanical properties of Al alloys. Heat resistant aluminum alloys have been produced by CrW homogeneous solid solution to overcome the limit of conventional heat resistant aluminum alloy. From EPMA, it is found that CrW homogeneous soild solution phases with the size of $50-100{\mu}m$ have been dispersed uniformly, and there is no reaction between aluminum and CrW alloy. In addition, after maintaining at high temperature of 573 K, there is no growth of hardening phase, nor desolved, but CrW still exists as a homogeneous solid solution.

A Experimental Study on Nitrous Oxide Formation in Direct Injection Diesel Engine (직접분사식 디젤엔진에서 아산화질소의 생성에 관한 실험적 연구)

  • Yoo, Dong-Hoon
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.21 no.2
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    • pp.188-193
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    • 2015
  • It has been generally recognized that $N_2O$(Nitrous Oxide) emission from marine diesel engines has a close correlation with $SO_2$(Sulfur Dioxide) emission, and diversity of fuel elements using ships affects characteristics of the $N_2O$ emission. According to recent reports, in case of existence of an enough large NO(Nitric Oxide) generated as fuel combustion, effect of the $SO_2$ emission in exhaust gas on the $N_2O$ formation is more vast than effect of the NO. Therefore, $N_2O$ formation due to the $SO_2$ element operates on a important factor in EGR(Exhaust Gas Recirculation) systems for NOx reduction. An aim of this experimental study is to investigate that intake gas of the diesel engine with increasing of $SO_2$ flow rate affects $N_2O$ emission in exhaust gas. A test engine using this experiment was a 4-stroke direct injection diesel engine with maximum output of 12 kW at 2600rpm, and operating condition was set up at a 75% load. A standard $SO_2$ gas with 0.499%($m^3/m^3$) was used for changing of $SO_2$ concentration in intake gas. In conclusion, the diesel fuel included out sulfur elements did mot emit the $SO_2$ emission, and the $SO_2$ emission in exhaust gas according as increment of the $SO_2$ standard gas had almost the same ratio compared with $SO_2$ rate in mixture inlet gas. Furthermore, the $N_2O$ element in exhaust gas was formed as $SO_2$ mixture in intake gas because increment of $SO_2$ flow rate in intake gas increased $N_2O$ emission. Hence, diesel fuels included sulfur compounds were combined into $SO_2$ in combustion, and $N_2O$ in exhaust gas should be generated to react with NO and $SO_2$ which exist in a combustion chamber.

A Study on the Recognition of Cooks about the Kitchen Ventilation (주방 환기에 대한 조리사들의 인식도 연구 - 서울 지역을 대상으로 -)

  • Van, Ju-Won;Heo, Jun
    • Culinary science and hospitality research
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    • v.11 no.4 s.27
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    • pp.228-244
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    • 2005
  • The objective of the study is to observe cooks first from the kitchen and those who care health and to grasp the impression regarding the kitchen environment. Also, it grasped the recognition degree of cooks against the elements of kitchen ventilation and kitchen ventilation equipments. We surveyed against 385 cooks who work in the kitchen of special grade hotels and family restaurants, used 5 scales for the object, and executed the analysis. The results of this study are as follows: (1) Health condition of the cooks appeared most highly pain in the shoulder and the neck. (2) for the impression regarding the kitchen environment, temperature was high and the insufficiency of ventilation is answered highly. (3) The importance of kitchen ventilation of cooks was recognized very high. (4) The combustion gas was recognized as very high percentage and the most effective element of the kitchen on the human body to remove first inside the kitchen. (5) Most cooks were recognized that the improvement of ventilation equipments is necessary. (6) The object of ventilation equipments is appeared to maintain comfortable kitchen environment. (7) The optimum operation method of ventilation equipment uses the automatic system of ventilation equipment from the kitchen and it is necessary to maintain the optimum. This research is based on preceding studies, investigating special grade hotels and family restaurants in Seoul. The ventilation plan of the kitchen should be accomplished to improve the health of cooks and productivity.

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