• 제목/요약/키워드: 2D porosity

Search Result 245, Processing Time 0.052 seconds

Enhancement of Soil Physicochemical Properties by Blending Sand with Super Absorbent Polymers of Different Swelling Capacities (팽윤 능력이 다른 고흡수성수지(Super Absorbent Polymers)의 혼합 비율별 모래 토양의 물리화학성 변화)

  • Young-Sun Kim;Tae-Wooung Kim;Yun-Seob Kim;Yang-Ho Na;Geung-Joo Lee
    • Korean Journal of Environmental Agriculture
    • /
    • v.42 no.1
    • /
    • pp.1-7
    • /
    • 2023
  • Super absorbent polymers (SAPs) are hydrophilic molecules that can absorb large amounts of water. This study was conducted to investigate the enhancement of the physicochemical properties of sand soil blended with three SAPs imbibed with 100, 150, and 200-fold water. Three treatments were applied, namely, 100SAP, 150SAP, and 200SAP. The three SAPs were blended at concentrations of 0% (control), 3%, 5%, 7%, and 10% with sand. The pH, electrical conductivity, and cation exchangeable capacity (CEC) of soil blended with the three SAPs were pH 6.35-6.46, 0.09-0.65 dS/m, and 1.42-1.92 cmolc/kg, respectively, and their capillary porosity, total porosity, and saturated hydraulic conductivity were 21.0-29.3%, 39.2-48.7%, and 272-470 mm/hr. CEC, capillary porosity, total porosity, and saturated hydraulic conductivity of soil were positively correlated with the ratio of the SAPs (p<0.01). These results indicate that blending sand soil with SAPs increased CEC, capillary porosity, and saturated hydraulic conductivity, thus improving the nutrient-retention capacity, water-retention capacity, and permeability of the soil.

Pharmaceutical Potential of Gelatin as a pH-responsive Porogen for Manufacturing Porous Poly(d,l-lactic-co-glycolic acid) Microspheres

  • Kim, Hyun-Uk;Park, Hong-Il;Lee, Ju-Ho;Lee, Eun-Seong;Oh, Kyung-Taek;Yoon, Jeong-Hyun;Park, Eun-Seok;Lee, Kang-Choon;Youn, Yu-Seok
    • Journal of Pharmaceutical Investigation
    • /
    • v.40 no.4
    • /
    • pp.245-250
    • /
    • 2010
  • Porous poly(lactic-co-glycolic acid) microspheres (PLGA MS) have been utilized as an inhalation delivery system and a matrix scaffold system for tissue engineering. Here, gelatin (type A) is introduced as an extractable pH-responsive porogen, which is capable of controlling the porosity and pore size of PLGA microspheres. Porous PLGA microspheres were prepared by a water-in-oil-in-water ($w_1/o/w_2$) double emulsification/solvent evaporation method. The surface morphology of these microspheres was examined by varying pH (2.0~11.0) of water phases, using scanning electron microscopy (SEM). Also, their porosity and pore size were monitored by altering acidification time (1~5 h) using a phosphoric acid solution. Results showed that the pore-forming capability of gelatin was optimized at pH 5.0, and that the surface pore-formation was not significantly observed at pHs of < 4.0 or > 8.0. This was attributable to the balance between gel-formation by electrostatic repulsion and dissolution of gelatin. The appropriate time-selection between PLGA hardening and gelatin-washing out was considered as a second significant factor to control the porosity. Delaying the acidification time to ~5 h after emulsification was clearly effective to make pores in the microspheres. This finding suggests that the porosity and pore size of porous microspheres using gelatin can be significantly controlled depending on water phase pH and gelatin-removal time. The results obtained in this study would provide valuable pharmaceutical information to prepare porous PLGA MS, which is required to control the porosity.

The Study on the Electrical Resistivity for Mo Back Contacts Film of CIGS Solar Cell (태양전지 CIGS용 Mo 후면전극의 전기 저항에 관한 연구)

  • Kim, Gang-Sam;Cho, Yong-Ki
    • Journal of the Korean institute of surface engineering
    • /
    • v.44 no.6
    • /
    • pp.264-268
    • /
    • 2011
  • The Molybedenium thin film is generally used on back contact material of CIGS solar cell due to low electrical resistivity and stable thermal expansion coefficient. The Mo thin films deposited on si wafer by the magnetron sputtering method. The research focused on the variation of electrical resistivity of films which deposited with various working pressure at the target power of 2.0 kW(8.4 W/). The lowest resistivity of Mo thin film showed $9.0{\mu}O$-cm at pressure of 1.5 mTorr. However, working pressure increasing up to 50 mTorr, resistivities were highly increased. The results showed that the conductivity of Mo films depended on growing structures and defects in deposition process. Surface morphology, porosity, grain size, oxidation, and bonding structures were analysed by SEM, AFM, spectroscopic ellipsometry (SE), XRD, and XPS.

Fabrication and Mechanical Properties of STS316L Porous Metal for Vacuum Injection Mold (진공사출금형용 STS316L 금속 다공체 제조 및 기계적 특성)

  • Kim, Se Hoon;Kim, Sang Min;Noh, Sang Ho;Kim, Jin Pyeong;Shin, Jae Hyuck;Sung, Si-Young;Jin, Jin Kwang;Kim, Taean
    • Journal of Powder Materials
    • /
    • v.22 no.3
    • /
    • pp.197-202
    • /
    • 2015
  • In this study, porous stainless steel (STS316L) sintered body was fabricated by powder metallurgy method and its properties such as porosity, compressive yield strength, hardness, and permeability were evaluated. 67.5Fe-17Cr- 13Ni-2.5Mo (wt%) powder was produced by a water atomization. The atomized powder was classified into size with under $45{\mu}m$ and over $180{\mu}m$, and then they were compacted with various pressures and sintered at $1210^{\circ}C$ for 1 h in a vacuum atmosphere. The porosities of sintered bodies could be obtained in range of 20~53% by controlling the compaction pressure. Compressive yield strength and hardness were achieved up to 268 MPa and 94 Shore D, respectively. Air permeability was obtained up to $79l/min{\cdot}cm^2$. As a result, mechanical properties and air permeability of the optimized porous body having a porosity of 25~40% were very superior to that of Al alloy.

The Sound Velocity and Attenuation Coefficient of the Marine Surface Seciments in the nearshore area, Korea (韓半島 沿近海底 表層堆積物에서의 音波傳達速度와 減衰係數)

  • 김성;석봉출
    • 한국해양학회지
    • /
    • v.20 no.2
    • /
    • pp.10-21
    • /
    • 1985
  • The sound velocity (compressional wave) and attenuation coefficient in the marine surface sediments in the nearshore areas off the Pohang, Pusan, Yeosu and Kunsan were investigated in terms of the geotechnical properties of the marine surface sediments in the water depth range of 10-50 meters. The marine surface sediments in the study areas are variable, that is, sand to clay. Due to the various four different study area, the sound velocities and attenuation coefficients in the surface sediment facies vary 1,44m/sec to 1,510m/sec in velocity and 0.82dB/m to 3.70dB/m in coefficient respectively. In fact, the sound velocity increases with increasing of density and mean grain sizes of the sediments, and however, with decreasing of porosith. The correlation equations between the sound velocith and geotechnical properties of mean grain size, density, and porosity were expressed as the following: Vp=1512.28406-9.16083(Mz)+0.20795(Mz)$\^$2/, Vp=1876.15527-597.50397(d)+210.48375(d)$\^$2/, Vp=1559.47217-2.09266(n)$\^$2/. where Vp is sound velocity, Mz is mean grain size, d is density, and m is porosity, respectively. However, the relationship between the attenuation and geotechnical properties were different from that of sound velocity and geotchnical properties. Furthermore, the correlation equations between attenuation coefficient and geotechnical properties were expressed as the following: a=1.85217+0.67197(Mz)-0.09035 (Mz)$\^$2/, a=48.87859+58.21721(d)-16.3.143(d)$\^$2/, a=2.06765+0.07215(n)-0.00111(n)$\^$2/, where a is attenuation coefficient. The high attenuation appeared in the silty sand through fine sand facies in sediment and k values in these facies were in the range of 0.86 to 0.89 dB/m/KHz.

The Relationship Between Smoke-Yields and Tipping Materials of the Cigarette (담배 연기발생과 Tipping 재료와의 상관성 연구)

  • Kim, Young-Hoh;Lee, Young-Taek;Kim, Sung-Han;Kim, Chung-Ryul;Kim, Jong-Yeol;Shin, Chang-Ho;Lee, Keun-Hoi
    • Journal of the Korean Society of Tobacco Science
    • /
    • v.20 no.1
    • /
    • pp.131-138
    • /
    • 1998
  • In order to minimize the trial frequency in the new filter cigarette design, we studied the relationship between smoke yield and tipping materials of cigarette. A three levels full factorial design involving filament denier (X1,2.5-3.3d), Porosity of the acetate filter plug wrap (X2, 3,500-16,000CU) and porosity of the tip paper (X3, 400-1,200CU) was used. Three independent factors (Xl, X2, X3) were chosen for their effects on the various responses and the function was expressed in terms of a quadratic polynomial equation, Y : $\beta$o + $\beta$1Xl + $\beta$2X2 + $\beta$3X3 + $\beta$11Xl2 + $\beta$22X22+ $\beta$33X32 + $\beta$12X1X2 + $\beta$13XIX3 $\beta$23X2X3 which measures the linear, quadratic, and interaction effects. Twenty-nine trial numbers were obtained as a results of using a three levels full factorial design and it was analyzed by the multiple regression analysis with backward stepwise in STATISTICA/pc under restricted conditions. Tar yields of the cigarette was affected by porosity of tip paper (0.66), filament denier (0.47) and porosity of plug wrap (0.28) in the decreasing order, and linear effect of tip paper porosity (B3) and filament denier (91) were significant at a level of 0.01($\alpha$). The filament denier and tipping paper porosity interaction F ratio among three factors had a P-value of 0,000041, indicating higher interaction between these factors. Based on the analysis of variance, the model fitted for Tar (Y1) was significant at 5% confidence level and the coefficient of determination (0.96) was the proportion of variability in the data fitted for by the model.

  • PDF

Comparison of capsule type resin modified glass ionomer porosity according to mixing methods (혼합방법에 따른 캡슐형 광중합글라스아이노머의 공극률 비교)

  • Kim, Jung-min;Kim, Jin-Woo;Cho, Kyung-Mo;Lee, Yoon;Kim, Eung-Hyun;Park, Se-Hee
    • Journal of Dental Rehabilitation and Applied Science
    • /
    • v.37 no.4
    • /
    • pp.217-224
    • /
    • 2021
  • Purpose: The purpose of this study was to evaluate the porosity of resin modified glass ionomer (RMGI) by different mixing methods. Materials and Methods: Five specimens were prepared for each groups according to capsules and mixing methods. Two RMGI capsule and two mixing machines were used for this study. One resin-modified glass ionomer cement is Fuji II LC (F2LC) and the other is Photac Fil Quick Aplicap (PFQ). For Mixing of RMGI capsule, Rotomix using rotating motion and CM-II using shaking motion were used. After measuring height, radius and mass of specimens, Density was calculated. And porosity was measured using micro-computed tomography (micro-CT). All data were statistically analyzed using T-test, two-way ANOVA to compare between groups at 95% significance level to evaluate the affect of capsule and mixing method on the porosity. Results: The porosity was observed in all specimens generally. And there is significant differece between porosities according to RMGI capsule and Mixing method. The porosity of PFQ was lower than that of F2LC and the porosity of Rotomix was lower than that of CM-II. Conclusion: There was a difference of porosity according to kind of capsules and mixing methods. When using same capsule, less porosity was observed on PFQ than F2LC. When using same mixing mehod, less porosity was observed on Rotomix than CM-II. Using mixing machine of same coporation as that of RMGI capsule did not lead to lower porosity. Therefore, Selecting optimal mixing machine is important.

Fabrication of Fe-Cr-Al Porous Metal with Sintering Temperature and Times (소결 온도와 유지 시간에 따른 Fe-Cr-Al 다공성 금속의 제조)

  • Koo, Bon-Uk;Lee, Su-In;Park, Dahee;Yun, Jung-Yeul;Kim, Byoung-Kee
    • Journal of Powder Materials
    • /
    • v.22 no.2
    • /
    • pp.100-104
    • /
    • 2015
  • The porous metals are known as relatively excellent characteristic such as large surface area, light, lower heat capacity, high toughness and permeability. The Fe-Cr-Al alloys have high corrosion resistance, heat resistance and chemical stability for high temperature applications. And then many researches are developed the Fe-Cr-Al porous metals for exhaust gas filter, hydrogen reformer catalyst support and chemical filter. In this study, the Fe-Cr-Al porous metals are developed with Fe-22Cr-6Al(wt) powder using powder compaction method. The mean size of Fe-22Cr-6Al(wt) powders is about $42.69{\mu}m$. In order to control pore size and porosity, Fe-Cr-Al powders are sintered at $1200{\sim}1450^{\circ}C$ and different sintering maintenance as 1~4 hours. The powders are pressed on disk shapes of 3 mm thickness using uniaxial press machine and sintered in high vacuum condition. The pore properties are evaluated using capillary flow porometer. As sintering temperature increased, relative density is increased from 73% to 96% and porosity, pore size are decreased from 27 to 3.3%, from 3.1 to $1.8{\mu}m$ respectively. When the sintering time is increased, the relative density is also increased from 76.5% to 84.7% and porosity, pore size are decreased from 23.5% to 15.3%, from 2.7 to $2.08{\mu}m$ respectively.

Tribological Behavior of Multilayered WC-Ti1-xAlxN Coatings Deposited by Cathodic Arc Deposition Process on High Speed Steel

  • Kim, Jung Gu;Hwang, Woon Suk
    • Corrosion Science and Technology
    • /
    • v.5 no.2
    • /
    • pp.52-61
    • /
    • 2006
  • Recently, much of the current development in surface modification engineering are focused on multilayered coatings. Multilayered coatings have the potential to improve the tribological properties. Four different multilayered coatings were deposited on AISI D2 steel. The prepared samples are designed as $WC-Ti_{0.6}Al_{0.4}N$, $WC-Ti_{0.53}Al_{0.47}N$, $WC-Ti_{0.5}Al_{0.5}N$ and $WC-Ti_{0.43}Al_{0.57}N$. The multilayered coatings were investigated with respect to coating surface and cross-sectional morphology, roughness, adhesion, hardness, porosity and tribological behavior. Especially, wear tests of four multilayered coatings were performed by using a ball-on-disc configuration with a linear sliding speed of 0.017 m/sec, 5.38 N load. The tests were carried out at room temperature in air by employing AISI 52100 steel ball ($H_R=66$) having a diameter of 10 mm. The surface morphology, and topography of the wear scars of samples and balls have been determined by using scanning electron spectroscopy (SEM). Results have showed an improved wear resistance of the $WC-Ti_{1-x}Al_xN$ coatings with increasing of Al concentration. $WC-Ti_{0.43}Al_{0.57}N$ coating with the lower surface roughness and porosity with good adhesion enhanced wear resistance.

Elastic stability of functionally graded graphene reinforced porous nanocomposite beams using two variables shear deformation

  • Fortas, Lahcene;Messai, Abderraouf;Merzouki, Tarek;Houari, Mohammed Sid Ahmed
    • Steel and Composite Structures
    • /
    • v.43 no.1
    • /
    • pp.31-54
    • /
    • 2022
  • This paper is concerned with the buckling behavior of functionally graded graphene reinforced porous nanocomposite beams based on the finite element method (FEM) using two variables trigonometric shear deformation theory. Both Young's modulus and material density of the FGP beam element are simultaneously considered as grading through the thickness of the beam. The finite element approach is developed using a nonlocal strain gradient theory. The governing equations derived here are solved introducing a 3-nodes beam element, and then the critical buckling load is calculated with different porosity distributions and GPL dispersion patterns. After a convergence and validation study to verify the accuracy of the present model, a comprehensive parametric study is carried out, with a particular focus on the effects of weight fraction, distribution pattern of GPL reinforcements on the Buckling behavior of the nanocomposite beam. The effects of various structural parameters such as the dispersion patterns for the graphene and porosity, thickness ratio, boundary conditions, and nonlocal and strain gradient parameters are brought out. The results indicate that porosity distribution and GPL pattern have significant effects on the response of the nanocomposite beams, and the results allows to identify the most effective way to achieve improved buckling behavior of the porous nanocomposite beam.