• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.191.2-191.2
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• 2014

Cu/ZnO/$Al_2O_3$ is widely used methanol synthesis catalyst at elevated pressures P (50 to 100 bar) and temperatures T (473 to 573 K) using $CO_2$, CO, $H_2$ syngas mixture. Although Cu step and planar defects have been regarded as active sites in this catalyst, detailed $CO_2$ hydrogenation procedure has been still unknown and debated as well as initial intermediate. In this study, we investigated the mechanism of $CO_2$ hydrogenation on Cu(111) model surface at P (1 bar) and T (298 to 450 K) using reflection absorption infrared spectroscopy (RAIRS). Two distinct formates by hydrogenation of $CO_2$, on step and on terrace, show different behavior with elevating temperature. The peak intensity of on step formate was continuously decreased above 360 K up to 450K in contrast to the increase of on terrace formate. These phenomena are strong possibilities that the formate is initial intermediate and is desorbed by hydrogenation reaction because thermal desorption temperature of formate (~470 K) is much higher than desorption of on step formate. And the formate production peak of on step site was weakly correlated with CO formation.

• The Mathematical Education
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• v.40 no.2
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• pp.179-194
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• 2001

The seventh curriculum put into operation gradually from first-year student in 2000 academic years of elementary school is subject to form and apply a step-wise level curriculum. Mathematics(correspond to junior high school course from 7th school year to 9th school year) should apply a step-wise level curriculum from 7th school year in 2001 academic years. Accordingly, mathematics teachers must diagnose actual conditions of educations, distribution tables of test results, step-wise teaching-studying programs etc. They also make proper plans suitable for actual situations of each school, prepare appropriate teaching materials and aids. I investigated preceding studies planned for preparation of putting into operation of a step-wise level curriculum. It showed that most of the studies were conducted at schools of medium or large scale and studies conducted at schools of small scale was rare. There were 113 small scale middle schools out of total 297 middle schools in Kyongsangbuk-do area in 2000. In this situation, I felt necessities of modeling of a step-wise level curriculum suitable for small scale schools. In this study, I modeled a step-wise level curriculum suitable for small scale middle schools, applied this model to 44 students in M middle school. I modeled two types of curriculum. One is a step-wise level curriculum that execute special supplementation process to students who do not complete 7-가 step successfully. The other is a step-wise level curriculum which is a regular model for a step-wise level of 7-나 step. I carried out an academic achievement test and intimacy test about mathematics before and after the application of the model. In this study, I found out that this model was very effective in academic achievement of students and helpful to declined students in scholarship. In the intimacy test, It was found out that most of the students gained confidence in mathematics, felt less anxiety, formed positive self consciousness. Therefore, I think that this model will be helpful to the application of the seventh step-wise level curriculum.

• Nuclear Engineering and Technology
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• v.28 no.3
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• pp.299-310
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• 1996

A two-step approach has been used to obtain a new criterion for the onset of slug formation : (1) In the first step, a more general expression than the existing models for the onset of slug flow criterion has been derived from the analysis of singular points and neutral stability conditions of the transient one-dimensional two-phase flow equations of two-fluid model. (2) In the second step, introducing simplifications and incorporating a parameter into the general expression obtained in the first step to satisfy a number of physical conditions a priori specified, a new simple criterion for the onset of slug flow has been derived. Comparisons of the present model with existing models and experimental data show that the present model agrees very closely with Taitel & Dukler's model and experimental data in horizontal pipes. In an inclined pipe ($\theta$ =50$^{\circ}$), however, the difference between the predictions of the present model and those of existing models is appreciably large and the present model gives the best agreement with Ohnuki et al.'s data.

• Nuclear Engineering and Technology
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• v.41 no.8
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• pp.1109-1114
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• 2009

The evolution of a high burnup structure (HBS) in a light water reactor (LWR) $UO_2$ fuel was simulated using the Potts model. A simulation system for the Potts model was defined as a two-dimensional triangular lattice, for which the stored energy was calculated from both the irradiation damage of the $UO_2$ matrix and the formation of a grain boundary in the newly recrystallized small HBS grains. In the simulation, the evolution probability of the HBS is calculated by the system energy difference between before and after the Monte Carlo simulation step. The simulated local threshold burnup for the HBS formation was 62 MWd/kgU, consistent with the observed threshold burnup range of 60-80 MWd/kgU. The simulation revealed that the HBS was heterogeneously nucleated on the intergranular bubbles in the proximity of the threshold burnup and then additionally on the intragranular bubbles for a burnup above 86 MWd/kgU. In addition, the simulation carried out under a condition of no bubbles indicated that the bubbles played an important role in lowering the threshold burnup for the HBS formation, thereby enabling the HBS to be observed in the burnup range of conventional high burnup fuels.

• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.5
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• pp.962-978
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• 1989

A new model of the combustion rates of soot particle in turbulent flames has been suggested. This model applies the combustion rate of soot particles in laminar flames and uses local time-averaged quantities in order to consider the effect of the chemical reaction on the soot combustion in turbulent flames. The proposed rate equation has been tested for two propane-air turbulent round-jet diffusion flames and gives better predictions for the soot concentration field of two flames than the model previously used, especially in low temperature regions. A modified Monte carlo Method for analyzing radiative heat transfer of a flame also has been suggested and tested, which reveals good results.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.11
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• pp.1594-1605
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• 2001

In this study, a numerical simulation was developed which was capable of predicting the characteristics of NO formation in pilot scale combustor adopting the air-staged burner flame. The numerical calculation was constructed by means of establishing the mathematical models fur turbulence, turbulent combustion, radiation and turbulent nitric oxide chemistry. Turbulence was solved with standard k-$\xi$ model and the turbulent combustion model was incorporated using a two step reaction scheme together with an eddy dissipation model. The radiative transfer equation was calculated by means of the discrete ordinates method with the weighted sum of gray gases model for CO$_2$and H$_2$O. In the NO chemistry model, the chemical reaction rates for thermal and prompt NO were statistically averaged using the $\beta$ probability density function. The results were validated by comparison with measurements. For the experiment, a 0.2 MW pilot multi-air staged burner has been designed and fabricated. Only when the radiation was taken into account, the predicted gas temperature was in good agreement with the experimental one, which meant that the inclusion of radiation was indispensable for modeling multi-air staged gas flame. This was also true of the prediction of the NO formation, since it heavily depended on temperature. Subsequently, it was found that the multi-air staged combustion technique might be used as a practical tool in reducing the NO formation by controlling the peak flame temperature.

• Bulletin of the Korean Chemical Society
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• v.10 no.1
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• pp.96-101
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• 1989

The infrared multiphoton decomposition of trichloroethylene-H(TCE-H) and trichloroehtylene-D(TCE-D) was studied by using the high power $CO_2$ laser. The pressure dependence of TCE-H decomposition showed that the HCl elimination channel to form ClC ≡ CCl was the major step at high pressures, while the HC ≡ CCl formation step became important at low pressures. $Cl_2C$ = CHCl ${\rightarrow}$ (high pressure) ClC ${\equiv}$ CCl + HCl ${\rightarrow}$ (low pressure) HC ${\equiv}$ CCl + 2Cl${\cdot}$($Cl_2$) The IRMPD of TCE-H and TCE-D mixtures with 10P(20) laser line showed that optimum conditions of large isotope selectivity were the low system pressures and high laser powers. The experimentally observed dependence of the branching ratios on the pressure and laser fluence, and the isotope selectivity coefficients were quantitatively explained by using the modified energy grained master equations (EGME) model.

• 대한공업교육학회지
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• v.33 no.1
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• pp.249-264
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• 2008

In this dissertation, shallow $p^+-n$ junctions were formed by ion implantation and dual-step annealing processes and a new simulator is designed to model boron diffusion in silicon. This simulator predicts the boron distribution after ion implantation and annealing. The dopant implantation was performed into the crystalline substrates using $BF_2$ ions. The annealing was performed with a RTA(Rapid Thermal Annealing) and a FA(Furnace Annealing) process. The model which is used in this simulator takes into account nonequilibrium diffusion, reactions of point defects, and defect-dopant pairs considering their charge states, and the dopant inactivation by introducing a boron clustering reaction. FA+RTA annealing sequence exhibited better junction characteristics than RTA+FA thermal cycle from the viewpoint of sheet resistance and the simulator reproduced experimental data successfully. Therefore, proposed diffusion simulator and FA+RTA annealing method was able to applied to shallow junction formation for thermal budget. process.

• The Bulletin of The Korean Astronomical Society
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• v.39 no.2
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• pp.77.2-77.2
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• 2014

Questions of how our Milky Way evolves through the interaction with its environment have been constantly raised. One particularly interesting question is how the metallicity would change as our Milky Way goes through collision with HVCs. Because of the possibility of HVCs providing fuel for star formation in the Galactic disk, we simulate the collision between HVCs and the Galactic disk. More specifically, we trace how the Galactic metallicity changes throughout the process of HVCs colliding with our Milky Way based upon a specific scenario that HVCs are primordial gas left-overs from an ancient galaxy formation. Such mixing between metal-rich gas (disk) and metal-poor HVC can be traced by running numerical simulations with the FLASH code due to its capability of tracking down the abundance change of a specific element such as carbon at each time step of the hydrodynamic evolution. As for now, we give how this mixing depends on model parameters that we choose such as collision speed, initial metallicities, temperature and so on.

• Journal of Korean Society for Quality Management
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• v.20 no.2
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• pp.129-136
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• 1992

This paper aims to develope an algorithm to minimize the total production time, sum of group formation times and processing times, under the balanced workload among the machines by grouping parts with machine loading in FMS. The algorithm of this study is composed of four step procedures ; (1) Parts grouping by Group Technology(GT) (2) Minimizing total processing time in loading problem (3) Machine workload balancing, including above(2) (4) Group formation time, including above(3) For parts grouping, Rank Order Clustering(ROC) algorithm developed by King(1980) is used and this algorithm is programmed by using the MACRO functions of QUATTRO Pro, one of the spreadsheet packages. The structure for loading model is solved by using the Hyper-LINDO. As a case study, numerical examples are demonstrated to show the effectiveness of the proposed machine loading procedure.