• Title/Summary/Keyword: 2-AB

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Electrochemical properties of $AB_5$-type Hydrogen alloys upon addition of Zr, Ti and V ($AB_5$계 수소저장합금의 Zr, Ti 및 V 첨가에 따른 전기화학적특성)

  • Kim, D.H.;Cho, S.W.;Jung, S.R.;Park, C.N.;Choi, J.
    • Journal of Hydrogen and New Energy
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    • v.17 no.1
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    • pp.31-38
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    • 2006
  • There are two types of metal hydride electrodes as a negative electrode in a Ni-MH battery, $AB_2$ Zr-based Laves phases and $AB_5$ LM(La-rich mischmetal)-based alloys. The $AB_5$ alloy electrodes have characteristic properties such as a large discharge capacity per volume, easiness in activation, long cycle life and a low cost of alloy. However they have a relatively small discharge capacity per weight. The $AB_2$alloy electrodes have a much higher discharge capacity per weight than $AB_5$ alloy electrodes, however they have some disadvantages of poor activation behavior and cycle life. Therefore, in order to improve the discharge capacity of the $AB_5$ alloy electrode the Zr, Ti and V which are the alloying elements of the $AB_2$ alloys were added to the $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}$ alloy which was chosen as a $AB_5$ alloy with a high capacity. The addition of Zr, Ti and V to $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}$ alloy improved the activation to be completed in two cycles. The discharge capacities of Zr 0.02, Ti 0.02 and V 0.1 alloys in $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}M_y$ (M = Zr, Ti, V) were respectively 346, 348 and 366 mAh/g alloy. The alloy electrodes, Zr 0.02, Ti 0.05 and V 0.1 in $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}M_y$ (M = Zr, Ti, V), have shown good cycle property after 200 cycles. The rate capability of the $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}M_y$ (M = Zr, Ti, V) alloy electrodes were very good until 0.6 C rate and the alloys, Zr 0.02, Ti 0.05 and V 0.1, have shown the best result as 92 % at 2.4 C rate. The charge retention property of the $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}M_y$ (M = Zr, Ti, V) alloys was not good and the alloys with M content from 0.02 to 0.05 showed better charge retention properties.

Ab Initio Study of the Conformations of Tetramethoxycalix[4]arenes

  • Choe, Jong-In;Lee, Sang-Hyun;Oh, Dong-Suk
    • Bulletin of the Korean Chemical Society
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    • v.25 no.1
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    • pp.55-58
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    • 2004
  • In this study we have performed ab initio computer simulations to investigate the conformational characteristics of the tetramethoxycalix[4]arenes (1 and 2). The structures of four types (cone, partial cone, 1,2-alternate, and 1,3-alternate) of conformers for each compound have been optimized using ab initio RHF/6-31G and 6-31$G^{**}$ methods. General trends in relative stabilities of tetramethyl ether derivatives of calix[4]arene 1 and p-tert-butylcalix[4]arene 2 are similar and decrease in following order: partial cone (most stable) > cone > 1,3-alternate > 1,2-alternate. The calculated results of the most stable conformation of partial cone structure agree with the reported NMR experimental observations.

Design of a 4kb/s ACELP Codec Using the Generalized AbS Principle (Generalized AbS 구조를 이용한 4kb/s ACELP 음성 부호화기의 설계)

  • 성호상;강상원
    • The Journal of the Acoustical Society of Korea
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    • v.18 no.7
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    • pp.33-38
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    • 1999
  • In this paper, we combine a generalized analysis-by-synthesis (AbS) structure and an algebraic excitation scheme to propose a new 4kb/s speech codec. This codec partly uses the structure of G.729. We design a line spectrum pair (LSP) quantizer, an adaptive codebook, and an excitation codebook to fit the 4 kb/s bit rate. The codec has a 25㎳ algorithmic delay, which corresponds to a 20㎳ frame size and a 5㎳ lookahead. At the bit rates below 4kb/s, most CELP speech codecs using the AbS principle have a drawback that results a rapid degradation of speech quality. To overcome this drawback we use the generalized AbS structure which is efficient for the low bit rate speech codec. LP coefficients are converted to LSP and quantized using a predictive 2-stage VQ. A low complexity algebraic codebook which uses shifting method is used for the fixed codebook excitation, and gains of the adaptive codebook and the fixed codebook are quantized using the VQ. To evaluate the performance of the proposed codec A-B preference tests are done with the fixed rate 8kb/s QCELP. As the result of the test, the performance of the codec is similar to that of the fixed rate 8kb/s QCELP.

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AB3217-A and B, herbicidal compounds related to anisomycin from Streptomyces sp. ME-13 (Streptomyces sp. ME-13 균주가 생산하는 anisomycin계 AB3217 화합물의 제초활성)

  • Kim, Won-Kon;Kim, Jong-Pyung;Park, Dong-Jin;Kim, Chang-Jin;Kwak, Sang-Soo;Yoo, Ick-Dong
    • Applied Biological Chemistry
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    • v.39 no.2
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    • pp.153-158
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    • 1996
  • During the screening of herbicidal substances from microbial secondary metabolites using photoautotrophic cells, a strain of ME-13 with strong herbicidal activity was isolated from soil. Based on the taxonomic studies, the strain was identified as Streptomyces. Two active compounds were purified from the culture broth through the column chromatographies using active charcoal, silica gel, MCI gel, and ODS HPLC. The compounds were identified as AB3217-A and B, respectively, related to anisomycin by spectroscopic methods. AB3217-A and B completely suppressed the germination of radish and barnyard grass at 25 ppm. In comparison to anisomycin, they showed the 6 times higher inhibitory activities against the growth of shoot and root of radish and barnyard grass with EC5O of around 6 ppm.

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The effect of co-contraction exercises of abdominal bracing combined with ankle dorsiflexion on abdominal muscle thickness and strength in patients with chronic low back pain

  • Chai, Wenlan;Lee, So Hee;Park, Yu Hyung
    • Physical Therapy Rehabilitation Science
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    • v.3 no.2
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    • pp.93-100
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    • 2014
  • Objective: The purpose of this study was to determine the effect of the abdominal bracing (AB) and abdominal bracing combined with ankle dorsiflexion (ABDF) on abdominal muscle thickness and strength in patients with chronic low back pain (LBP). Design: Two group pretest posttest design. Methods: Sixteen subjects were divided randomly into two group: ABDF group (n=8), and alone AB group (n=8). The ABDF group practiced AB exercise with additional ankle dorsiflexion. AB group practiced only AB exercises. Subjects in both groups received ABDF exercise and AB exercise for 40 min per day, three days per week during a period of three weeks, respectively. All the subjects were evaluated for abdominal muscle thickness and strength before and after intervention using ultrasonography and MedX machine. Results: The external oblique (EO), internal oblique, transverse abdominis (TrA) muscle thickness and the strength produced at $48^{\circ}$, $60^{\circ}$, $72^{\circ}$ showed a significant increase in the ABDF group after intervention, with a more significant improvement in EO and TrA muscle thickness in the ABDF group compared with the AB group (p<0.05). Also, the strength at $48^{\circ}$ strength showed a significant improvement in the ABDF group than the AB group (p<0.05). Conclusions: The study results showed that abdominal muscle contraction exercises with AD in patients with LBP had an influence on abdominal muscle thickness and strength. Therefore, these findings suggest that ABDF may be useful approach for enhancement of abdominal muscle thickness and strength in patients with chronic low back pain.

Design of -60dB THD, 32ohm Load, 0.7Vrms Output Low Power CMOS class AB Stereo Audio Amplifier (-60dB THD, 32ohm load, 0.7Vrms 출력의 저전력 CMOS class AB Stereo Audio Amplifier 설계)

  • Kim, Ji-Hoon;Park, Sang-Hune;Park, Hong-June;Kim, Tae-Ho;Jung, Sun-Yeop
    • Proceedings of the IEEK Conference
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    • 2005.11a
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    • pp.905-908
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    • 2005
  • 본 논문에서는 class AB opamp 를 채용한 384kHz differential PWM 신호를 입력으로 하는 2-channel stereo audio amplifier 블록을 공급전압 3.3V 조건에서 SMIC 0.18um thick oxide 기술을 이용하여 설계한다. 여기서 class AB opamp 는 공정 변화에 따른 quiescent current가 변하는 것을 최소화하기 위하여 adaptive load 를 사용하며, 전체적으로는 3 차 Butterworth lowpass filter 와 differential-to-single converter 로 구성된 2 개의 audio amplifier 와 출력전압이 ${\frac{1}{2}}Vdd$ 인 common output 블록으로 구성된다. 이러한 설계를 통하여 32ohm 의 저항 load 를 구동할 수 있는 -60dB THD, 전체 quiescent current 2mA 대인 CMOS class AB stereo audio amplifier 를 구현하였다.

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Production of Monoclonal Antibodies to Phytohormones and Its Application (식물홀몬에 대한 단클론성 항체 생산과 이용)

  • 황태익
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.34 no.s01
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    • pp.48-54
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    • 1989
  • An immunoassay techniques using monoclonal antibodies have been developed of the quantitative analysis of endogenous hormones in plants. In order to be useful for immunoassay, both a high degree of specificity and a high affinity are required. A system is described for production of hybridomas which secrete antibodies against the plant hormone. Using the system we were able to produce hybridmas with the desired antibody specificity by cell fusion and culture method. For a number of obvious reasons, monoclonal antibodies(mAb) were superior to polyclonal antibodies.

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Influence of different universal adhesives on the repair performance of hybrid CAD-CAM materials

  • Demirel, Gulbike;Baltacioglu, Ismail Hakki
    • Restorative Dentistry and Endodontics
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    • v.44 no.3
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    • pp.23.1-23.9
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    • 2019
  • Objectives: The aim of this study was to investigate the microshear bond strength (${\mu}SBS$) of different universal adhesive systems applied to hybrid computer-aided design/computer-aided manufacturing (CAD-CAM) restorative materials repaired with a composite resin. Materials and Methods: Four types of CAD-CAM hybrid block materials-Lava Ultimate (LA), Vita Enamic (VE), CeraSmart (CS), and Shofu Block HC (SH)-were used in this study, in combination with the following four adhesive protocols: 1) control: porcelain primer + total etch adhesive (CO), 2) Single Bond Universal (SB), 3) All Bond Universal (AB), and 4) Clearfil Universal Bond (CU). The ${\mu}SBS$ of the composite resin (Clearfil Majesty Esthetic) was measured and the data were analyzed using two-way analysis of variance and the Tukey test, with the level of significance set at p < 0.05. Results: The CAD-CAM block type and block-adhesive combination had significant effects on the bond strength values (p < 0.05). Significant differences were found between the following pairs of groups: VE/CO and VE/AB, CS/CO and CS/AB, VE/CU and CS/CU, and VE/AB and CS/AB (p < 0.05). Conclusions: The ${\mu}SBS$ values were affected by hybrid block type. All tested universal adhesive treatments can be used as an alternative to the control treatment for repair, except the AB system on VE blocks (the VE/AB group). The ${\mu}SBS$ values showed variation across different adhesive treatments on different hybrid CAD-CAM block types.

Effects of Pd Addition on Electrode properties of Metal Hydride (Pd 첨가가 금속수소화물 전극 특성에 미치는 영향)

  • Choi, Jeon;Lee, Kyung-Ku
    • Journal of Hydrogen and New Energy
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    • v.10 no.2
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    • pp.141-149
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    • 1999
  • Recently the Ni/MH secondary battery has been studied extensively to achieve higher energy density, longer cycle life and faster charging-discharging rate etc. In this work, the electrode properties of $(LM)Ni_{4.49}Co_{0.1}Mn_{0.205}Al_{0.205}$ alloy and $Ti_{0.6}Zr_{0.4}V_{0.6}Ni_{1.4}$ alloy with addition of Pd were investigated. These alloys did not show any change in XRD pattern by Pd addition. As Pd was added as alloy element, the activation behavior was not affected significantly in both $AB_2$ type and $AB_5$ type electrodes and, On charging and discharging in high current density, Discharge capacity with increasing of Pd content was more decreased. But cycle life was showed increasing. Especially the electrode of $Ti_{0.6}Zr_{0.4}V_{0.6}Ni_{1.4}+0.5wt%$ Pd alloy was not almost decreased discharge capacity for 400cycles.

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