• Journal of the Korea Organic Resources Recycling Association
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• v.30 no.1
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• pp.33-39
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• 2022

Batch experiments were conducted to find out the effects of various types of magnesium compounds on phosphorus recovery by magnesium ammonium phosphate (MAP) crystallization. The phosphorus recovery from the centrate of anaerobic digested sludge was performed using magnesium chloride, magnesium hydroxide and magnesium oxide under different pH (7.5, 8.0 and 8.5) and Mg/P molar ratio (1.0, 1.5, 2.0, 2.5) conditions. The phosphorus recovery rate increased with increasing pH and Mg/P molar ratio in all magnesium compounds. At pH 7.5, magnesium oxide showed the highest phosphorus recovery rate, followed by magnesium hydroxide and magnesium chloride. However, at pH 8.5, more than 90% of phosphorus recovery rate was obtained in all Mg/p molar ratios. Thus, it is expected that magnesium hydroxide and magnesium oxide are able to replace magnesium chloride as a magnesium source in terms of phosphorus recovery efficiency and cost.

• Korean Chemical Engineering Research
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• v.51 no.6
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• pp.666-670
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• 2013

Recovery method of silicon wafer from defective products generated from manufacturing process of silicon solar cells was studied. The removal effect of the N layer and antireflection coating (ARC) of the waste solar cell were investigated at room temperature ($25^{\circ}C$) by variation of concentration of $H_3PO_4$, $NH_4HF_2$, and concentration and types of chelating agent. Removal efficiency was the best in the conditions; 10 wt% $H_3PO_4$ 2.0 wt% $NH_4HF_2$, 1.5 wt% Hydantoin. Increasing the concentration of $H_3PO_4$, the surface contamination degree was increased and the thickness of the silicon wafe became thicker than the thickness before surface treatment because of re-adsorption on the silicon wafer surface by electrostatic attraction of the fine particles changed to (+). The etching method by mixed solution of $H_3PO_4$-$NH_4HF_2$-chelating agents was expected to be great as an alternative to conventional RCA cleaning methods and as the recycle method of waste solar cells, because all processes are performed at room temperature, the process is simple, and less wastewater, the removal efficiency of the surface of the solar cell was excellent.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.11a
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• pp.105-106
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• 2017

Previous studies have confirmed the performance of pH reduction agents using liquid sodium phosphate based ammonium chloride as a pH reduction agent. In this study, the pH reduction performance considering economical and applicability as a practical stage and the property change analysis for the identification of the reaction mechanism of the pH reduction agent were carried out. As a result, the pH reduction performance at a low rate of the pH reducing agent was confirmed. The specific gravity of CaO decreased significantly after XRF analysis. It is also believed that this reduces the amount of Ca(OH)₂ produced and contributes to pH reduction.

• Korean Journal of Food Science and Technology
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• v.29 no.6
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• pp.1131-1137
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• 1997

The production rates of leavening gases and textures of cookies were investigated with various chemical leavening agents(baking powders). The chemical leavening agents could be divided into three group of a fast-acting group such as potassium bicarbonate, tartaric acid, aluminium ammonium sulfate, and fumaric acid, a slow-acting group such as ammonium bicarbonate, sodium bicarbonate, $glucono-{\delta}-lactone$, and ammonium chloride. and a double-acting group such as anhydro monocalcium phosphate, disodium dihydrogenpyrophosphate, and aluminium potassium sulfate according to the different production rate of gases. The leavening rate of ammonium bicarbonate, which was the highest of all leavening agents used in this experiment, was 131.25%. But its after-taste in a cookie was not good due to the residual ammonia. $Glucono-{\delta}-lactone$ only had no after-taste. The higher leavening rate, the more peaks in texture profile graph. Ammonium bicarbonate showed the most peaks in this experiment. It was found that the number of peak had correlation with brittleness of cookies $(r^2=0.8176)$ and brittleness of cookies was different as to various chemical leavening agents.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.322-325
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• 2003

본 연구에서는 경유와 윤활유로 오염된 토양에서 유류분해능이 우수한 분해균주 5종을 분리하여 동정하였고. 분리된 미생물을 이용하여 실험실 및 현장 Pilot Test 수행으로 현장 복원에 필요한 설계인자를 도출하여 실제 현장 토양복원에 적용하였다. 미생물의 투입량은 2.0 $\times$ $10^{6}$ CFU/g 이상으로 투입하고, 투입 영양분의 조성은 오염된 탄소원의 몰비 농도와 비교하여 질소원으로는 황산암모늄, 요소, 질산암모늄 등을 질소 몰수로 첨가하구 인산원으로는 인산칼륨, 이인산칼륨 등을 인산 몰수로 공급하여 토양의 C/N/P 비율이 100:10:1~ 100:1:0.5 범위 이내로 조절되도록 오염 토양에 영양분을 공급하였으며, 경작 횟수는 3회/주 이상으로 수행하여 오염토양 TPH 5,000ppm을 40일 동안 2,000ppm 이하로 복원하였으며, 이때 생분해상수 k는 0.0229/day로 확인되었다.

• Korean Chemical Engineering Research
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• v.53 no.6
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• pp.824-830
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• 2015

The influence of phosphorous precursors, $NH_4H_2PO_4$, $(NH_4)_2HPO_4$, $H_3PO_4$, $(C_2H_5)_3PO_4$, and $P_2O_5$, on the catalytic performance of the $BiFe_{0.65}MoP_{0.1}$ catalysts in the oxidative dehydrogenation of 1-butene to 1,3-butadiene was studied. The catalysts were characterized by XRD, $N_2$-sorption, ICP, SEM and TPRO analyses. It was not observed big difference on the physical properties of catalysts in accordance with used different phosphorous precursors, however, the catalytic performance was largely depended on the nature of the phosphorous precursors. Of various precursors, the $BiFe_{0.65}MoP_{0.1}$ oxide catalyst, which was prepared from a phosphoric acid precursor, showed the best catalytic performance. Conversion and yield to butadiene of the catalyst showed 79.5% and 67.7%, respectively, after 14 h on stream. The cation of phosphorous precursors was speculated to affect the lattice structure of the catalysts during catalyst preparation and this difference was influenced on the re-oxidation ability of the catalysts. Based on the results of TPRO, it was proposed that the catalytic performance could be correlated with re-oxidation ability of the catalysts.

• Journal of the Korean Wood Science and Technology
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• v.12 no.4
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• pp.12-18
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• 1984

Soaking treated in 20% aqueous solutions of $(NH_4)_2SO_4$, $NH_4H_2PO_4$, $(NH_4)_2HPO_4$, $Na_2B_4O_7-H_3BO_3$(60:40) and Minalith, the mixed salts for 9 hrs. the wet 3.5mm meranti (Parashorea spp.) plywoods were press-dried at 90, 120 and $150^{\circ}C$ and put to static bending test to examine the influence of redrying temperature on the strength of fire-retardant treated plywoods ill flexure. While water-soaking treatment (control) showed serious reduction in Stress at proportional limit, MOE, MOR, Work per unit volume at $150^{\circ}C$, all the fire-retardant treatments maintained bending strength even at $150^{\circ}C$ and showed rather increased values in case of some chemicals. In view of drying rate and maintenance of strength, the most pertinent platen temperature was $150^{\circ}C$ and Borax-Boric acid was the predominant fire-retardant in this study.

• Fire Science and Engineering
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• v.29 no.6
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• pp.1-5
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• 2015

In this study, the combustion characteristics of Hinoki Cypress Louver were measured after performing pressure impregnation with aqueous solution of boric acid, borax, and ammonium phosphate. The characteristics measured include ignition time, critical heat flux, and mass loss rate by incident hear flux (25, 30 and $50kW/m^2$). The samples used for the test were $100{\times}100{\times}10mm$, and the 5 min variation for each incident heat flux was measured 3 times. The results show that the ignition time for incident heat flux of $25kW/m^2$ showed a delay effect of 17.4 to 21.3% except for Type C-H. There was no significant difference at 35 and $50kW/m^2$ in the average mass loss rate in Types A-H and D-H, which had lower rates than Type N-H, which was predicted to be higher than that of Type N-H ($10.7kW/m^2$) by 38.22 to 60.46%. It is thus expected that at the time of initial primary fire, there would be a delay effect against fire spread.

• Applied Biological Chemistry
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• v.43 no.3
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• pp.163-168
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• 2000

To remove phosphate accumulated in the soil and water, Acinetobacter lwoffi PO8 possessing a high ability to accumulate phosphate was isolated from a active sludge. Bacterium was cultured in the liquid medium containing $150\;{\mu}g/mL$ of phosphate at $30^{\circ}C$ in different culture conditions to examine intracellular phosphate uptake. The initial pH in the range of $7.5{\sim}8.5$ was effective on the growth and phosphate uptake of the strain. Glycerol and arabinose used as a carbon sources showed 93 and 91% the phsphate uptake, respectively. Among the nitrogen sources, ammonium salt such as $NH_4NO_3$ and $(NH_4)_2SO_4$ was effectively utilized on the phosphate uptake compared with amino compounds. The rate of phosphate uptake of $NH_4NO_3$, and $(NH_4)_2SO_4$, was 95 and 96%, respectively The growth and Phosphate uptake ability in the strain were significantly promoted when metal ions were added in the medium; $Co^{2+}$, however, was not utilized by the strain. The capacity of phosphate uptake was enhanced to $10{\sim}20%$ when arginine, methionine, or lysine was added. Using $^{32}P$ to examine the uptake Pattern of intracellular phosphate, experiment result showed that polyphosphate was largely found in the fraction of intracellular inorganic phosphate of Acinetobacter lwoffi PO8.

• Korean Journal of Soil Science and Fertilizer
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• v.10 no.1
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• pp.1-6
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• 1977

Fifteen soils including volcanic ash, acid sulfate and degraded saline soils were investigated for Languir adsorption isotherm of ammonium using $NH_4H_2PO_4$. The results are as follows. Languir adsorption maxima of ammonium (LAMA) ranged from 2.4me/100g soil to 12.3 and the average was 5.3. Initial concentration of 30 to 60 or 40 to 80 ppm(as N) appears to be suitable for LAMA measurement. There were two LAMA in some soils. Difference between adsorption constants (bonding energy) was mostly greater than that between LAMA. LAMA ranged from 9.4% to 72% of cation exchange capacity and average was 47%. It did not show any clear tendency with CEC, pH, organic matter content, base saturation percent, P, K, Ca, Mg, Na and Si. Except volcanic ash soils which were grouped into two groups according to ammonium adsorption LAMA was significantly (r=0.951 at 1%) correlated with adsorption at 200ppm. This single concentration seems suitable for LAMA measurement. Probable mechanism of ammonium adsorption was discussed, in which the associated anions were combined with iron and aluminum and then ammonium was bound to phosphorus. Applicability of Langmuir adsorption isotherm model to the soils under field condition was also discussed.