Browse > Article
http://dx.doi.org/10.9713/kcer.2015.53.6.824

Oxidative Dehydrogenation of 1-butene over BiFe0.65MoP0.1 Catalyst: Effect of Phosphorous Precursors  

Park, Jung-Hyun (Department of Chemical Engineering, Chungbuk National University)
Youn, Hyun Ki (Industry-University Cooperation Foundation, Chungbuk National University)
Shin, Chae-Ho (Department of Chemical Engineering, Chungbuk National University)
Publication Information
Korean Chemical Engineering Research / v.53, no.6, 2015 , pp. 824-830 More about this Journal
Abstract
The influence of phosphorous precursors, $NH_4H_2PO_4$, $(NH_4)_2HPO_4$, $H_3PO_4$, $(C_2H_5)_3PO_4$, and $P_2O_5$, on the catalytic performance of the $BiFe_{0.65}MoP_{0.1}$ catalysts in the oxidative dehydrogenation of 1-butene to 1,3-butadiene was studied. The catalysts were characterized by XRD, $N_2$-sorption, ICP, SEM and TPRO analyses. It was not observed big difference on the physical properties of catalysts in accordance with used different phosphorous precursors, however, the catalytic performance was largely depended on the nature of the phosphorous precursors. Of various precursors, the $BiFe_{0.65}MoP_{0.1}$ oxide catalyst, which was prepared from a phosphoric acid precursor, showed the best catalytic performance. Conversion and yield to butadiene of the catalyst showed 79.5% and 67.7%, respectively, after 14 h on stream. The cation of phosphorous precursors was speculated to affect the lattice structure of the catalysts during catalyst preparation and this difference was influenced on the re-oxidation ability of the catalysts. Based on the results of TPRO, it was proposed that the catalytic performance could be correlated with re-oxidation ability of the catalysts.
Keywords
Oxidative Dehydrogenation; Phosphorous Precursors; 1,3-Butadiene; $BiFe_{0.65}MoP_{0.1}$ Oxide Catalyst; Temperature Programmed re-Oxidation;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 Bhasin, M. M., McCain, J. H., Vora, B. V., Imai, T. and Pujado, P. R., "Dehydrogenation and Oxydehydrogenation of Paraffins to Olefins," Appl. Catal. A: Gen,, 221, 397-419(2001).   DOI
2 Brazdil, J. F., Suresh, D. D. and Crasselli, R. K., "Redox Kinetics of Bismuth Molybdate Ammoxidation Catalysts," J. Catal., 66, 347-367(1980).   DOI
3 Chung, Y.-M., Kwon, Y.-T., Kim, T. J., Lee, S. J. and Oh, S.-H., "Prevention of Catalyst Deactivation in the Oxidative Dehydrogenation of n-butene to 1,3-butadiene over Zn-Ferrite Catalysts," Catal. Lett., 131, 579-586(2009).   DOI
4 Miura, H., Morikawa, Y. and Shirasaki, T., "Studies on the Reduction-reoxidation of Bismuth Molybate Catalysts by Temperature Programmed Reoxidation Method," J. Catal., 39, 22-28(1975).   DOI
5 Park, J.-H. and Shin, C.-H., "Oxidative Dehydrogenation of n-Butenes over $BiFe_{0.65}MoP_{0.1}$ Oxide Catalysts Prepared with Various Synthesis Method," Korean Chem. Eng. Res., 53(3), 391-396(2015).   DOI
6 Park, J.-H., Row, K. H. and Shin, C.-H., "Oxidative Dehydrogenation of 1-butene to 1,3-butadiene over $BiFe_{0.65}Ni_xMo$ Oxide Catalysts: Effect of Nickel Content," Catal. Commun., 31, 76-80 (2013).   DOI
7 White, W. C., "Butadiene Production Process Overview," Chem.-Biol. Interact., 166, 10-14(2007).   DOI
8 Lee, H. W., Jung, J. C., Kim, H. S., Chung, Y. M., Kim, T. J., Lee, S. J., Oh, S.-H., Kim, Y. S. and Song, I. K., "Effect of $Cs_xH_{3-x}PW_{12}O_{40}$ Addition oh the Catalytic Performance of $ZnFe_2O_4$ in the Oxidative Dehydrogenation of n-butene to 1,3-butadiene," Korean J. Chem. Eng., 26, 994-998 (2009).   DOI
9 Soares, A. P. V., Dimitrov, L. D., Oliveira, M. C.-R. A., Hilaire, L., Portela, M. F. and Grasselli, R. K., "Synergy Effects Between $\beta$ and $\gamma$ Phases of Bismuth Molybdates in the Selective Catalytic Oxidation of 1-butene," Appl. Catal. A: Gen., 253, 191-200(2003).   DOI
10 Park, J.-H., Noh, H. R., Park, J. W., Row, K. H. Jung, K. D. and Shin, C.-H., "Effect of Iron Content on Bismuth Molybdate for the Oxidative Dehydrogenation of n-butenes to 1,3-butadiene," Appl. Catal. A: Gen., 431-432, 137-143(2012).   DOI
11 Park, T.-J., "Oxidative Dehydrogenation of Butenes over Zinc Ferrite Catalysts," Ph. D. Thesis, University of Rice, Texas(1987).
12 Weng, L.-T. and Delmon, B., "Phase Cooperation and Remote Control Effects in Selective Oxidation Catalysts," Appl. Catal. A: Gen., 81, 141-213(1992).   DOI
13 H. F. Christmann, "Production of Unsaturated Compounds," US 3,270,080(1966).
14 Takita, Y., Qing, X., Takami, A., Nishiguchi, H. and Nagaoka, K., "Oxidative Dehydrogenation of Isobutane to Isobutene III: Reaction Mechanism over $CePO_4$ Catalyst," Appl. Catal. A: Gen., 296, 63-69(2005).   DOI
15 Park, J.-H., Noh, H. R., Park, J. W., Row, K. H., Jung, K. D. and Shin, C.-H., "Oxidative Dehydrogenation of n-butenes to 1,3-butadiene over $BiMoFe_{0.65}Px$ Catalysts: Effect of Phosphorous Contents, Res. Chem. Interm., 37, 1125-1134(2011).   DOI
16 Jung, J. C., Lee, H. W., Kim, H. S., Chung, Y.-M., Kim, T. J., Lee, S. J., Oh, S.-H. and Song, I. K., "Effect of pH in the Preparation of $Ni_9Fe_3Bi_1Mo_{12}O_{51}$ for Oxidative Dehydrogenation of n-butene to 1,3-butadiene: Correlation Between Catalytic Performance and Oxygen Mobility of $Ni_9Fe_3Bi_1Mo_{12}O_{51}$," Catal. Commun., 9, 943-949(2008).   DOI
17 Iordanova, R., Dimitriev, Y., Dimitrov, V., Kassabov, S. and Klissurski, D., "Glass Formation and Structure in the $V_2O_5-Bi_2O_3-Fe_2O_3$ Glasses," J. Non-Cryst. Solids, 204, 141-150(1996).   DOI
18 Bautista, F. M., Campelo, J. M., Garcia, A., Luna, D., Marinas, J. M., Romero, A. A., Colon, G., Navio, J. A. and Macias, M., "Structure, Texture, Surface Acidity, and Catalytic Activity of $AlPO_4-ZrO_2(5-50wt%\;ZrO_2)$ Catalysts Prepared by a Sol-gel Procedure," J. Catal., 179, 483-494(1998).   DOI
19 Chen, Y. and Wang, Q., "Preparation, Properties and Characterizations of Halogen-free Nitrogen-phosphorous Flame-retarded Glass Fiber Reinforced Polyamide Composite," Polym. Degrad. Stab., 91, 2003-2013(2006).   DOI
20 Gabor, T., Cozar, O., Daraban, L. and Ardelean, I., "FT-IR, Raman and Thermoluminescence Investigation of $P_2O_5-BaO-Li_2O$ Glass System," J. Mol. Struct., 993, 249-253(2011).   DOI
21 Iordanova, R., Dimitriev, Y., Dimitrov, V., Kassabov, S. and Klissurski, D., "Glass Formation and Structure in the System $MoO_3-Bi_2O_3-Fe_2O_3$," J. Non-Cryst. Solids, 231, 227-233(1998).   DOI
22 Carrazfin, S.R.G., Martin, C., Rives, V. and Vidal, R., "An FT-IR Spectroscopy Study of the Adsorption and Oxidation of Propene on Multiphase Bi, Mo and Co catalysts," Acta. Part A., 52 1107-1118(1996).   DOI
23 Woo, S. I., Kim, J. S. and Jun, H. K., "Characterization of Ca-Bi-Mo Oxide Catalyst for Selective Propane Ammoxidation, Using XRD, XPS, TPRX/TPRO, and IR/Raman," J. Phys. Chem. B, 108, 8941-8946 (2004).
24 Vasilev, A. N. and Galicia, P. N., "Catalysts for the Oxidative Dehydrogenation of Butenes and Butane to Butadiene," Chem. Technol. Fuels Oils, 33, 185-192(1997).   DOI
25 Jung, J. C., Kim, H.S., Choi, A. S., Chung, Y.-M., Kim, T. J., Lee, S. J., Oh, S.-H. and Song, I. K., "Effect of pH in the Preparation of ${\gamma}-Bi_2MoO_6$ for Oxidative Dehydrogenation of n-butene to 1,3-butadiene: Correlation Between Catalytic Performance and Oxygen Mobility of ${\gamma}-Bi_2MoO_6$," Catal. Commun., 8, 625-628 (2007).   DOI
26 Park, J.-H. and Shin, C.-H., "Oxidative Dehydrogenation of Butenes to Butadiene over Bi-Fe-Me (Me=Ni, Co, Zn, Mn and Cu)-Mo Oxide Catalysts," J. Ind. Eng. Chem., 21, 683-688(2015).   DOI