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Long-Term Shelf Lifetime of Polymer:Nonfullerene Solar Cells Stored under Dark and Indoor Light Environment

  • Lee, Sooyong;Kim, Hwajeong;Kim, Youngkyoo
    • Current Photovoltaic Research
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    • v.8 no.4
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    • pp.107-113
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    • 2020
  • Here we report the long-term stability of polymer:nonfullerene solar cells which were stored under dark and indoor light condition. The polymer:nonfullerene solar cells were fabricated using bulk heterojunction (BHJ) layers of poly[(2,6-(4,8-bis(5-(2-ethylhexyl) thiophen-2-yl)-benzo[1,2-b:4,5-b']dithiophene))-alt-(5,5-(1',3'-di-2-thienyl-5',7-bis(2-ethylhexyl)benzo[1',2'-c:4',5'-c']dithiophene-4,8-dione))] (PBDB-T) and 3,9-bis(6-methyl-2-methylene-(3-(1,1-dicyanomethylene)-indanone))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2',3-d']-s-indaceno[1,2-b:5,6-b']dithiophene (IT-M). To investigate their long-term stability, the PBDB-T:IT-M solar cells were stored in an argon-filled glove box. One set of the fabricated solar cells was completely covered with an aluminum foil to prevent any effect of light, whereas another set was exposed to indoor light. The solar cells were subjected to a regular performance measurement for 40 weeks. Results revealed that the PBDB-T:IT-M solar cells underwent a gradual decay in performance irrespective of the storage condition. However, the PBDB-T:IT-M solar cells stored under indoor light condition exhibited relatively lower power conversion efficiency (PCE) than those stored under the dark. The inferior stability of the solar cells under indoor light was explained by the noticeably changed optical absorption spectra and dark spot generation, indicative of degradations in the BHJ layers.

Efect of Mixed-Culture Soil on Growth Characteristics and Nutrient Silage Corn (혼파재배 토양이 옥수수 생육특성 및 영양수량에 미치는 영향)

  • 이상무;문상호;전병태
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.16 no.4
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    • pp.283-290
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    • 1996
  • This experiment was carried out to determine the effects of soil condition that previous crop cultivated after [TO: Soil of corn cultivated, T1 : Soil of rye monoculture cultivated(l50kg/ha), T2 : Soil of mixedculture cultivated(Rye : Red clover = 120 : 3koa). T3 : Soil of mixed-culture cultivated(Rye : Red clover = 90 : 6kg/ ha), T4 : Soil of mixedculture cultivated(Rye : Red clover = 60 : 9kg/ha), T5 : Soil of mixedculture cultivated (Rye: Red clover = 30 : 12kg/ha), T6 : Soil of red clover monoculture cultivated(l5kgha)) on the growth characteristics and nutrient yield of silage corn. The results are summarized as follows. 1. The plant length of silage corn was high in order of T6>T5>T4 treatment. In the leaf length, T5 and T6 treatment showed short compared to the other treatments, but they were wider than the other treatments in leaf width. In the number of leaf, T6 treatment was the highest as 14 leaves per plant, while T1 treatment showed lower than the other treatments as 12.6 leaves per plant. 2. In the stem hardness, ear length, ear width and ear full degree, soil treatment of red clover mono-culture cultivation(T6) showed higher than the other treatment as 5.1 1kg/$cm^2$, 20.8~~1, 7.7cm and 97%. respectively (P<0.01, 0.05). Ihe leaf of summer depression did not many occurrence, but T6 treatment was lower than the other treatment as 0.8 leaf per plant. 3. ADF and NDF composition were not affected by soil condition. Crude protein composition of T6 treatment was the highest as 7.8%. while TI treatment was the lowest as 6.9%. Fresh weight yield(59,083kg/ha), dry matter yield(21,743kg/ha), crude protein yield(l,369kg/ha) and TDN yield(15,800kg/ha) at T6 treatment were much more increased by 41.9, 47.5, 57.4 and 49% than TI treatment(39,410, 14,259, 827 and 10,056kg/ha).

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Effect of Scoria, Quartz Porphyry and Oak Charcoal Powder Feeding on the Meat Quantity and Quality of Fattening Cross Bred Hanwoo Bulls (점토광물 급여가 한우교잡우의 산육능력 및 육질에 미치는 영향)

  • 강수원;손용석;박남건;진신흠;고서봉
    • Journal of Animal Environmental Science
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    • v.5 no.3
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    • pp.157-170
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    • 1999
  • This study was conducted to investigate the effects of Scoria, Quartz porphyry and Oak charcoal powder feeding by 1% level of concentrate on the fattening cross bred bulls(5/8 Korean Native Cattle, 2/8 Charolais, 1/8 Brahman germ plasma) Feeding trial was conducted with 4 treatment groups which were T1(Full feeding of concentrate and roughage for 12 months), T2(T1 and Scoria addition), T3(T1 and Quartz porphyry addition) and T4(Oak charcoal addition) for 360 days, consisting of 32 heads whose initially weights were about 299.7kg. The results obtained are summarized as follows; 1. During the over-all period, average daily gains by T3, T4, T2 and T1 were 1.024, 0.987, 0.977kg and 0.964, respectively, without a significant difference by treatments. 2. Concentrate intakes per body weight and TDN intakes required per unit of kilogram gain were lower in addition agent groups than in control, and in all the treatments feed efficiency was higher at early stage for 360 fattening day than at end stage. 3. Carcass weight, dressing percent, back-fat thickness and loin eye muscle area by treatments were 330.9 to 348.4kg(average 340.3kg), 55.2~56.2(average 55.8%), 0.41~0.55(average 0.46cm)and 76.0~80.9$\textrm{cm}^2$(average 77.6$\textrm{cm}^2$), respectively, and were improved in addition agent groups than in control. 4. Meat quality grade is higher in addition agent groups than in control, and heads of 1st grade by treatments was 3, 2, 1 and none in T4, T2, T3 and T1, respectively. 5. Incidence heads of diseases by treatment were not apparently different, but diseases of digestive system was decreased in addition agent groups than in control. 6. The nitrate nitrogen content of fattening bull dung which collected in rectum were 0.082~0.089% (average 0.084%), and the content in addition agent groups was smaller than in controll. 7. Income was higher in order of T4, T3, T2, and T1 and incomes of treatment groups were grater than that of control group by 21.4 to 33.5 percent. According to the above results it may be concluded that fattening bulls may be required to feed no more than 1% of Scoria, Quartz porphyry and Oak charcoal powder based on the concentrate feeding level during the fattening period(12 to 24 month of age) to produce high quality meat and increase income.

Synthesis of 6-Hydroxyalkylidenepenicillanates (6-히드록시알킬리덴페니실란산 염의 합성)

  • Lee, Jung Hwan;Ko, Jae Young;Seo, Kyung Jae;Goo, Yang Mo;Lee, Youn Young
    • Journal of the Korean Chemical Society
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    • v.43 no.4
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    • pp.447-455
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    • 1999
  • Allyl (5R)-(Z)- and (5R)-(E)-6-[(2S)-2,3-isopropylidenedioxypropylidene]Penicillanate(10a and 10b) were prepared from allyl (5R)-dibromopenicillanate(6) via a sequence of reactions involving condensation with 2,3-O-isopropylidene-D-glyceraldehyde, reduction with $Zn-NH_4OAc$, and Mitsunobu elimination. Deprotection of isopropylidene and allyl groups of 10a gave potassium (5R)-(Z)-6-[(2S)-2,3-dihydroxypropylidene]penicillanate(4). However, deprotection of isopropylidene group of 10b afforded ${\alpha},\;{\beta}$-unsaturated-lactone(12). Allyl (5R)-(Z)- and (5R)-(E)-6-[(2S)-2-(t-butyldimethlsilyloxy)propylidene]penicillanate(18a and 18b) were prepared from ally (5R)-dibromopenicillanate(6) via a sequence of reactions involving condensation with (2S)-2-(t-butyldimethylsilyloxy)propanal(15), reduction with $Zn-NH_4OAc$ and Mitsunobu elimination or mesylation-elimination. Deprotection of t-butyldimethylsilyl and allyl groups of 18a and 18b gave potassium (5R)-(Z)- and (5R)-(E)-6-[(2S)-2-hydroxypropylidene]penicillanate(5a and 5b), respectively.

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Effects of Planting Density on Growth Characteristics, Dry Matter Yield and Feed Value of Teosinte New Variety, "Geukdong 6" [Zea mays L. subsp. mexicana (Schrad.) H. H. lltis]

  • Lee, Se Ho;Kim, Eun Joong;Lee, Sang Moo
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.42 no.3
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    • pp.162-168
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    • 2022
  • This study was carried out to investigate the effects of planting densities on the growth characteristics, dry matter yield, and feed value of "Geukdong 6" (a new variety of corn for feed). The experimental design was arranged in a randomized block design with three replications. Treatments consisted of six planting densities, 60 cm × 25 cm (T1), 60 cm × 30 cm (T2), 70 cm × 25 cm (T3), 70 cm × 30 cm (T4), 80 cm × 25 cm (T5) and 80 cm × 30 cm (T6). All treatments were sown on May 14, 2021, and the harvest was on October 3 (late flowering). Plant length and the number of tillers were the highest in T5 (p<0.05), but the number of leaves and stem diameter were the highest in T6 than in the other treatments (p<0.05). Leaf length, leaf width, and dead leaf were not significantly different among the treatments. Organic matter was highest in T6, and crude protein was highest in T5 (p<0.05). The ether extract was not significantly different among the treatments. Crude fiber, NDF, and ADF were highest in T2 with relatively higher planting density (p<0.05). Calcium and phosphorus were not significantly different among the treatments. TDN content was the highest in T3 (p<0.05). Sugar degree (Brix), fructose, glucose, dextran, isomerose, and inverted sugar were not significantly different among the treatment. Fresh yield, dry matter yield and TDN yield were higher in order of T6 > T5 > T4 > T3 > T2 > T1 (p<0.05). Relatively feed value was higher in order of T3 > T6 > T5 > T1 > T4 > T2 (p<0.05). Based on the above results, planting density could be recommended from 80 cm × 30 cm for efficient production of "Geukdong 6".

Effect of Thermal Diffusion on Autumn Traffic in Street Space (가을철 교통조건에 따른 가로공간 열확산 분포 영향)

  • Yoon, Yong-Han;Kim, Jeong-Ho
    • Journal of Environmental Science International
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    • v.26 no.4
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    • pp.467-481
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    • 2017
  • This study sought to determine the changes in weather conditions in urban streets, along with conditions of traffic and roads in urban areas. The variations in weather conditions depending on traffic differed according to distance. First, the temperature difference measured by traffic results is as follows: T1 point $1.03^{\circ}C$, T2 point $1.04^{\circ}C$, T3 point $0.9^{\circ}C$, T4 point $1.01^{\circ}C$, and T5 point $0.31^{\circ}C$. The average difference between the measured temperatures by the point of measurement was $0.86^{\circ}C$. The changes in wind velocity according to traffic volume results of the measurements is T1 point 1.32 m/s, T2 point 0.80 m/s, T3 point 0.29 m/s, T4 point 0.04 m/s, and T5 point 0.09 m/s. The difference between the average wind speeds was 0.51 m/s and traffic jams caused substantial differences in distance. The relative humidity tended to be inversely proportional to temperature. The measurements results ares T1 point 2.29%, T2 point 2.67%, T3 point 2.47%, T4 point 2.16%, and T5 point 0.91% The difference between the average relative humidity was 7.3%. In case of independent sampling T test according to traffic volume, changes in wind velocity and temperature were directly proportional to the level of statistical significance(p<0.01). On the other hand, relative humidity tended to be inversely proportional; however, there was no statistical significance.

THE SEQUENCE OF P-T CURVES AROUND A QUATERNARY INVARIANT POINT IN THE SYSTEM NaAlSiO4-KAlSiO4-SiO2-H2O (NaAlSiO4-KAlSiO4-SiO2-H2O 4성분계(成分系)의 불변점부근(不變點附近)의 P-T 곡선(曲線)의 변이(變移))

  • Kim, Ki-Tae
    • Economic and Environmental Geology
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    • v.5 no.2
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    • pp.77-86
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    • 1972
  • The system NaAlSiO_4-KAlSiO_4-SiO_2-H_2O, Bowen's "Petrogeny's Residua System" of course is extremely important in understanding the phase relationships of igneous and metamorphic rock in the continental crust. The phase relationships in this system, however, have not been completely established in the P-T range above the Mohorovicic discontinuity. They need to be established. In this study, the most probable sequence of P-T curves around a quaternary invariant point(~5Kb/${\sim}635^{\circ}C$) in the system using Schreinemakers' rule, is deduced, essentially on the basis of Morse's(1969a and b) experimental data. Possible modifications of the sequence of the P-T curves considering likely changes of the invariant chemogram are also considered. It is concluded that the sequence of P-T curves around the invariant point (~5Kb/${\sim}635^{\circ}C$) is (L), (Anl), (Or), (V), (Ne) and (Ab) on the P-T projection, where the P-T curve (L) is extended towards lower P-T regions, and the (Anl) curve is extended towards a region of higher temperature and lower pressure from the invariant point respectively.

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Radiotherapy of Early Stage Glottic Cancer (조기성문암의 방사선치료)

  • Kim, Yong-Ho;Chai, Gyu-Young
    • Radiation Oncology Journal
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    • v.15 no.4
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    • pp.315-319
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    • 1997
  • Purpose : To evaluate the role of curative radiotherapy and salvage surgery in Patients with T1 T2 glottic canter. Materials and Method : Between June 1989 and December 1994, 23 patients with early glottic cancer, 18 with T1N0M0 and 5 with T2N0M0, were treated with radiotherapy at Gyeongsang National University Hospital All Patients were male. Median follow-up period was 46 months, and $100\%$ were observed for at least 3 years. Results : Actuarial survival rates at 5 years were $84.3\%$ for 23 patients. The 5-year actuarial survival rates were $94.4\%$ for T1 and $53.3\%$ for 72(P=0.05) The 5-rear local control rates was $70.0\%$ for T1 and $60.0\%$ for T2 (P=0.44). Of 8 Patients with treatment failure, 6 patients $(75.0\%)$ were salvaged with surgery. After surgical salvage, the 5-year local control rates were $87.2\%$ for T1 and $80.0\%$ for T2(p=0.55). Conclusion : In early stage (Stage I and II) glottic cancer, curative radiotherapy can be a treatment of choice and surgery reserved for salvage of radiotherapy failure.

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Effects of Ammonium Sulfate and Potassium Sulfate Fertilizer on Dry Matter Yield and Forge Quality of Sorghum X Sudangrsss Hybrid in Reclaimed Tidal Land (간척지에서 수수 X 수단그라스에 대한 유안 및 황산칼리비료 시용효과)

  • Shin Jae Soon;Lee Seung Heon;Kim Won Ho;Kim Jong Geun;Yoon Sei Hyung;Lim Keun Bal
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.25 no.4
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    • pp.245-250
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    • 2005
  • This experiment was conducted to compare the frech and dry matter yields and feed values of Sorghum$\times$Sudangrsss Hybrid in accordance with different nitrogen and potassium fertilizer sources at the Dae-Ho reclaimed tidal land, Korea from 2003 to 2004. Soil salt contents of ammonium sulfate plots(T3, T4, T5) were higher than that of the urea plot(T2), but that of potassium sulfate plot(T6) was the lowest. The fresh yields of ammonium sulfate plots(T3, T4, T5) and potassium sulfate plot(T6) were higher than that of the urea plot(T2) as $173\%,\;173\%,\;144\%\;and\;90\%$. respectively. The dry matter and total digestible nutrient(TBN) yields were similar tendency like the results of the fresh matter yields. The crude protein(CP), neutral detergent fiber(NDF) and acid detergent fiber(ADF) contents of ammonium sulfate plots(T3, T4, T5) were higher than those of urea plot(T2), but those of potassium sulfate plot(T6) were the lowest. On the other hand, TDN content in potassium sulfate plot(T6) was the highest. It was desirable to use ammonium sulfate$(20\~30kg\;N/10a)$ and potassium sulfate fertilizer$(15kg\;K_2O/10a)$ than those of urea and potassium chloride fertilizer on reclaimed tidal land in view of forage production and its feed value.

우모를 이용한 taurine 강화 계란 생산

  • 이승민;임희석;백인기
    • Proceedings of the Korea Society of Poultry Science Conference
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    • 2003.11a
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    • pp.119-120
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    • 2003
  • The experiments were conducted to investigate the effects of supplementary feather meal(FM) and its digest on the taurine content and performance of laying hens. Feeding trial was conducted with 810 78-wk-old ISA-Brown layers for 5wk. The experiment consisted of nine dietary treatments ; T1 ; control(basal diet), T2;Tl + feather meal(FM) 6 % diet, T3;T2 + pyridoxin(21 mg/kg) supplemented diet, T4; T1 + H$_2$O$_2$treated FM 6%, T5; T4 + pyridoxin(21 mg/kg) supplemented diet, T6; T1 + cystine(0.25 %) supplemented diet, T7; T6 + pyridoxin(21 mg/kg) supplemented diet, T8; T1 + synthetic taurine supplemented(0.25%) diet, T9; T1 + synthetic taurine supplemented(0.5 %) diet. Diets were formulated to be iso-caloric and to meet NRC(1994) requirements of essential nutriente. Birds in treatments T3 showed significantly higher(P<0.01) egg production, feed intake, feed conversion ratio, egg weight, haugh unit and eggshell strength than those fed other treatments. Supplementation of FM. H$_2$O$_2$treated FM and cystine with or without pyridoxin did not significantly affected taurine content of egg yolk. Only synthetic taurine supplemented diets(T8 and T9) linearly increased(P<0.01) taurine content of egg yolk.

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