• Title/Summary/Keyword: 1L-5

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Studies on the Chemical Structure of the New Polysaccharide C - (The New Polysaccharides of Gum Tragacanth. II) - (Tragacanth gum 의 신다당류(新多糖類) C 의 화학구조(化學構造) - Tragacanth gum의 신다당류(新多糖類)에 관(關)한 연구(硏究) 제2보(第二報) -)

  • Lee, Sung-Hwan
    • Applied Biological Chemistry
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    • v.3
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    • pp.25-48
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    • 1962
  • The polysaccharide C prepared from gum tragacanth powder (U. S. P. grade) by the precipitation method with 85% ethanol was a neutral polysaccharide, $[{\alpha}]^{30}_D-72.2$. The polysaccharide C consisted of L-rhamnose, D-xylose, L-arabinose and D-galactose in the molar ratio 2:1:17:9 (Table 1, 2, 3, ). The polysaccharide C was methylated with dimethylsulphate and 40% NaOH, and Purdies regent. The hydrolyzate of fully methlated product ($[{\alpha}]^{22}_D-102$ in chloroform, the methoxy content 40.6%) was composed of 2, 3, 5-tri-O-methyl-L-arabofuranose (I), 3,4-di-O-methyl-L-rhamnopyranose (II), 2,3-di-O-methyl-D-xylose (III), 2,3,4-tri-O-methyl-D-galactopyranose (IV), 2,4-di-O-methyl-L-arabopyranose (?), 2,4-di-O-methyl-D-galactose(VI), 2-O-methyl-D-arabinose (VII), and L-arabopyranose(VIII) (Table 4, 5, and Fig. 4). The first partial hydrolysis (A) of the polysaccharide C with 0.05N-HCl for 4.5 hours at $80-85^{\circ}C$ released only L-arabinose: the second hydrolysis (B) with 0.1N-HCl for 5 hours at $80-85^{\circ}C$, L-arabinose and D-galactose; and the third hydrolysis (C) with 0.3N-HCl at $90-95^{\circ}C$ in sealed tube, L-rhamnose, D-xylose, L-arabinose and D-galactose. From the unhydrolyzate A' were found L-rhamnose, D-xylose, L-arabinose, and D-galactose; from B' L-rhamnose, d-xylose, L-arabinose and D-galactose; and from C' D-xylose and D-galactose respectively (Table 6). The periodate consumption and formic acid production of the polysaccharide C were measured at various time intervals. After 120 hours periodat was consumed by 1.23 mole per $C_5H_8O_4$ and formic acid was produced 0.78 mole per $C_5H_8O_4$ (Table 7). Although a definite chemical structure for this polysaccharide C may not be formulated, experimental data, especially, from methylation, partial hydrolysie and determination of its molar ratio, and periodate analysis showed that the polysaccharide C is a highly branched polysaccharide and would be constructed of galactoaraban as a main chain residue and L-arabofuranose, D-galactopyranosyl $(1{\rightarrow}1)$-L-arabofuranose, D-xylopyranosyl $(1{\rightarrow}2)$-L-rhamnopyranosyl $(1{\rightarrow}1)$-L-arabofuranose, and L-rhamnopyranosyl $(1{\rightarrow}1)$-arabofuranose, and D-galactopyranosyl-$(1{\rightarrow}2)$-L-arabopyranosyl-$(1{\rightarrow}1)$-I-arabofuranose as a branch chain or end group (page 21).

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Fatty Acid Composition and Antioxidative Activity in Waxy Corn (Zea mays L.) $F_1's$ (찰옥수수 $F_1$의 지방산 조성과 항산화 활성)

  • Seo, Young-Ho;Kim, In-Jong;Min, Hwang-Kee;Rhee, Hae-Ik;Park, Seung-Ue
    • Korean Journal of Food Science and Technology
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    • v.31 no.6
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    • pp.1415-1420
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    • 1999
  • This study was carried out to obtain basic information for breeding materials on the improvement of waxy corn (Zea mays L.). The percents of palmitic, stearic, oleic, linoleic and unsaturated fatty acids in 310 $F_1's$ analyzed were $14.6\;{\pm}\;2.5%,\;2.5\;{\pm}\;1.0%,\;24.8\;{\pm}\;4.2%,\;55.6\;{\pm}\;5.4%\;and\;81.8\;{\pm}\;3.1%$, respectively. The mean value of antioxidative ability was $22.8\;{\pm}\;5.9%$. The average contents of tocopherols, phenolic compounds and carotenoids were $36.2\;{\pm}\;11.5\;{\mu}g/mL,\;120.3\;{\pm}\;27.7\;{\mu}g/mL\;and\;0.4\;{\pm}\;0.6\;{\mu}g/mL$, respectively. The level of oleic acid was significantly correlated with the level of linoleic acid. The electron donating ability was significantly correlated with the level of phenolic compounds and tocopherols but not with the content of carotenoids

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Nuclear LS-Energy Matrix Elements with the Harmonic Oscillator Shell Model Wave Functions for the Configurations ($I_1$$I_{1+1}$$I_1$$I_{1+1}$) and Sum Rules (조화 단진동자 파동함수를 쓴 원자핵의 LS에너지 행열요소 합법칙)

  • Chung-hum Kim;Soon-Kwon Nam
    • Nuclear Engineering and Technology
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    • v.14 no.1
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    • pp.22-40
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    • 1982
  • The nuclear LS-energy matrix elements have been calculated with the harmonic oscillator shell model wave functions for the configurations ( $l_{i}$ $l_{i+1}$$l_{i}$ $l_{i+1}$) where 1$_1$= $l_{s}$ , $l_2$=lp, $l_3$=ld, 2s, $l_4$=1f, 2p, $l_{5}$ =1g, 2d, 3s. The resulting matrix elements are expressed in terms of both Talmi integrals $I_1$ and Slater integrals $F^{k}$ . In addition to this various sum rules are derived and applied to check the results of the calculations.ons.

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In vitro micropropagation of Philodendron cannifolium (기내배양에 의한 Philodendron cannifolium의 대량번식)

  • Han, Bong-Hee;Park, Byoung-Mo
    • Journal of Plant Biotechnology
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    • v.35 no.3
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    • pp.203-208
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    • 2008
  • In order to micropropagate uniform plantlets of Philodendron cannifolium in vitro, the shoot tips were cultured on MS media supplemented with $0.5{\sim}10.0$ mg/L BA or $0.05{\sim}0.1$ mg/L thidiazuron(TDZ). The adventitious multi-bud clusters from basal part of shoots were formed on MS media containing $2.0{\sim}5.0$ mg/L BA or $0.05{\sim}0.1$ mg/L TDZ. But the shoots grown on MS media with TDZ showed necrosis by the lack of chlorophyll. The adventitious multi-bus clusters were cut into $5{\sim}7$ mm sections and cultured on MS media containing BA and TDZ for shoot proliferation. Shoots were proliferated vigorously on MS medium supplemented with $1.0{\sim}3.0$ mg/L BA with up to 30 shoots. But abnormally swollen hard calli were formed from basal parts of shoots on MS media with TDZ and high concentration of BA(10.0 mg/L). The proliferated shoots on same media also showed necrosis by the lack of chlorophyll. The shoot growth and rooting were favorable on MS media containing $0.5{\sim}2.0$ mg/L IBA. The rooted plantlets were acclimatizated effectively in soil mixed with perlite 1:vermiculite 1 or vermiculite alone. Fifteen mL of liquid medium containing 10 g/L activated charcoal and 30 g/L sucrose were added in same vessels after small shoots were proliferated to stimulate shoot growth and rooting. After 8 weeks in culture, the shoots were dipped into high concentration of IBA solution. and planted in soil mexed with perlite 1:vermiculite 1. The shoot growth and rooting were favorable in dipping treatments of $500{\sim}2,000$ ppm IBA solutions for 10 sec.

In Vitro Propagation of Lilium Asiatic Hybrid 'Hae Hwa' via the Formation of Shoot Clusters (신초 Cluster 형성에 의한 Lilium Asiatic Hybrid 'Hae Hwa'의 기내번식)

  • Han, Bong-Hee;Yu, Hee-Ju;Yae, Byeoung-Woo;Goo, Dae-Hoe
    • Journal of Plant Biotechnology
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    • v.29 no.1
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    • pp.19-23
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    • 2002
  • This experiment was conducted to micropropagate bulblets via shoot cluster formation and massproduce normal bulblets from the sections of proliferated shoot clusters in Lilium asiatic hybrid 'Hae Hwa'. The induction of shoot clusters from the culture of bulblet sections was more effective than that of bulb scales on MS medium with 1.0 mg/L BA and 0.5 mg/L IAA. Proliferation of shoot clusters from the formed shoot cluster sections was the most favorable on medium containing 5.0 mg/L BA and 0.5 mg/L IAA. The formation and the growth of bulblets from shoot cluster sections were achieved effectively on medium with 60∼90 g/L sucrose. The leaves derived from shoot clusters grew vigorously but the bulblets from shoot clusters grew very poor in 5L air-lift bioreactor culture. By the addition of 30 mL fresh liquid medium containing doulble strength MS salts, 250 g/L sucrose and 5 g/L activated charcoal after 8 weeks in the shoot cluster culture on MS medium with 5.0 mg/L BA and 0.5 mg/L IAA, the number of bulblets was increased in light condition, but the growth of bulblets was not affected by light. Bulblet production was possible with the bulblet product at 53 to 68 mg in fresh weight by liquid medium addition after the proliferation of shoot cluster.

Characteristics of Stormwater Runoff from Urban areas with Industrial Complex (산업단지의 도시 강우유출수 배출 특성)

  • Jung, Yong-Jun;Kim, Si-Won
    • Journal of Wetlands Research
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    • v.14 no.1
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    • pp.131-137
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    • 2012
  • This study was investigated to characterize the stormwater runoff pollutant materials from the urban area mixed with industrial area. Almost the similar rainfall pattern is shown during the 5 years, and the yearly precipitation was 5.2~6.6 mm. The first flushing effect during the early-stage rainfall-run off was observed in some events. EMC ranges are 19.3~39.9 mg/L for BOD, 45.2~190 mg/L for CODcr, 67.2~351 mg/L for TSS, 3.6~10.3 mg/L for TN, 1.2~2.5 mg/L for TP. Heavy metal are not detected except Zn which is observed at only one event. The particle size was distributed to 10 ${\mu}m$ at the 3% weight volume and the 50% cumulative weight percent was shown at 12 ${\mu}m$.

Investigation of Selenium Distribution in Highland Province of Gangwon and Effect of Sodium Selenate Treatment on the Selenium Content and Growth of Some Western Vegetables Grown by Ferigation (고랭지 지역의 셀레늄 분포 조사 및 양채류 관비재배시 Sodium Selenate 처리가 생육과 셀레늄 함량 미치는 영향)

  • Lee, Sung-Jin;Kang, Ho-Min;Kim, Il-Seop
    • Journal of Bio-Environment Control
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    • v.17 no.1
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    • pp.38-42
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    • 2008
  • This study was conducted to investigate distribution of selenium in Gangwon highland Province and to confirm the effect of sodium selenate added nutrient solution on the selenium content of some western vegetables; beet, broccoli, cabbage lettuce, celery, and parsley. The contents of selenium were distributed from 0.024 to $0.038\;mg{\cdot}kg^{-1}$ in soil of Gangwon highland province. As the selenium content in soil increased, the selenium content in broccoli was increased in highland of Gangwon province. The selenium content of broccoli showed $10.5{\sim}17.9\;mg{\cdot}kg^{-1}DW$ 1311owe4 by celery ($6.02\;mg{\cdot}kg^{-1}DW$). Beet, cabbage lettuce, and parsley contained just about $1\;mg{\cdot}kg^{-1}DW$ in highland of Gangwon province. Some western vegetables grown by fertigation supplied $2\;mg{\cdot}L^{-1}$ sodium selenate were shown better growth and higher selenium content than those of $0\;mg{\cdot}L^{-1}$ sodium selenate supplied treatment(control). The selenium contents of western vegetables supplied $2\;mg{\cdot}L^{-1}$ sodium selenate in fertigation culture for 60 days were $76.2\;mg{\cdot}L^{-1}$ in broccoli, $69.1\;mg{\cdot}L^{-1}$ in parsley, $63.2\;mg{\cdot}L^{-1}$ in celery, $54.2\;mg{\cdot}L^{-1}$ in beet, $8.3\;mg{\cdot}L^{-1}$ in cabbage lettuce. Those selenium content of broccoli, celery, and parsley treated $2\;mg{\cdot}L^{-1}$ sodium selenate were followed the order 4.2 times, 10.5 times and 62.5 times higher in compared to control.

Occurrence of UV Filters in Nakdong River Basin : Mainstreams, Tributaries and STP Effluents (낙동강 수계에서의 자외선 차단제류 검출 특성 : 본류, 지류 및 하수처리장 방류수)

  • Seo, Chang-Dong;Son, Hee-Jong;Choi, Jin-Taek;Yoo, Pyung-Jong;Jang, Seong-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.8
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    • pp.472-479
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    • 2015
  • This study was investigated occurrence and distribution patterns of UV filters in Nakdong River basin (mainstream, tributaries and sewage treatment plant (STP) effluents). 5 (EHS, BP-3, 4-MBC, BZC and EHMC) out of 7 UV filters were detected in 5 out of 20 sampling sites (mainstream and tributaries), 7 UV filters were not detected in mainstream samples, and the EHS, BP-3, 4-MBC, BZC and EHMC concentration levels in tributary samples were ND~60.8 ng/L, ND~72.1 ng/L, ND~57.2 ng/L, ND~60.1 ng/L and ND~85.2 ng/L, respectively. 5 (EHS, BP-3, 4-MBC, BZC and EHMC) out of 7 UV filters were detected in effluents of 11 STPs around the Nakdong River basin. The EHS, BP-3, 4-MBC, BZC and EHMC concentration levels in 11 STP effluents were ND~89.3 ng/L, ND~90.8 ng/L, ND~88.1 ng/L, ND~118.5 ng/L and ND~104.4 ng/L, respectively. According to the sampling season, distribution patterns and detected concentrations of 5 UV filters were similar in June and September 2014, but change ranges of distribution patterns and detected concentrations of 5 UV filters were highly variable in April and November 2014.

Synthesis of Nuclophilic Adducts of Thiols (Ⅵ). Addition of L-Cystein to $\beta,\;\beta$-Diethoxycarbonylstyrene Derivatives

  • kim, Tae-Rin;Cho, Bong-Rae;Choi, Sung-Yong;Choi, Won-Sik
    • Bulletin of the Korean Chemical Society
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    • v.5 no.6
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    • pp.215-218
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    • 1984
  • A series of S-(2,2-diethoxycarbonyl-1-phenylethyl)-L-cysteine derivatives (10a-e) were synthesized from the reaction of $\beta$$\beta$-diethoxycarbonylstyrene with L-cysteine in 1:1 aqueous methanol. Thus, S-(2,2-diethoxycarbonyl-1-phenylethyl)-L-cysteine( 10a), S-[2,2-diethoxycarbonyl-1-(3',4'-methylendioxy)ph enylethyl]-L-cysteine (10b), S-[2,2-diethoxycarbonyl-1-(3',4',5'-trimethoxy)phe nylethyl]-L-cyseine (10c), S-[2,2-diethoxycarbonyl-1-(p-hydroxy)phenylethyl] -L-cysteine (10d), S-[2,2-diethoxycarbonyl-1-(p-methoxy)phenylethyl] -L-cysteine (10e) were obtained in moderate to excellent yields. The structure of the adducts was characterized by analytical and spectral data. The effects of pH upon the product yields were also briefly examined.

Plant Regeneration from Leaf Segments Culture of Several Jeju Native Lilies (잎절편 배양에 의한 제주 자생나리의 재분화)

  • Kim Jeong-Seon;Song Seung-Woon;Kim Yong Chol;Kim Kwang-Ho;Park Young-Chul
    • Korean Journal of Plant Resources
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    • v.18 no.3
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    • pp.450-455
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    • 2005
  • This study was conducted to examine the effects of plant growth regulators on the plant regeneration from leaf segments of Lilium callosum, L. concolor var. partheneion, and L. formosanum. Leaf segments were sectioned about 5 mm long and cultured on the basal medium (MS medium with $3\%$ sucrose and $0.8\%$ agar) under dark condition, The most effective plant regulators on harvesting more shoots from leaf culture of L. callosum were $0.2\;mg{\cdot}L^{-1}\;BA$ and $0.5\;mg{\cdot}L^{-1}\;NAA$. Culturing in the basal medium with $0.2\;mg{\cdot}L^{-1}\;BA$ and $2.0\;mg{\cdot}L^{-1}\;NAA$ was effective for leaf culture of L. concolor var. partheneion. The treatment of $1.0\;mg{\cdot}L^{-1}\;BA$ and $1.0\;mg{\cdot}L^{-1}\;NAA$ was the most effective condition for shoot harvest at the leaf culture of L. formosanum.