• 제목/요약/키워드: 1C2M

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Generation of Carbon Monoxide from Saccharides (당류 중에서 일산화탄소의 발생에 관한 연구)

  • Kim, Nam Yee;Seo, Joong Seok;Park, Sung Woo
    • Analytical Science and Technology
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    • 제14권6호
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    • pp.522-529
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    • 2001
  • Carbon monoxide was generated when the saccharides which contained aldehyde group were added to alkali solution (NaOH solution) at $25^{\circ}C$ or $40^{\circ}C$. When the milk was added to 1.0 M NaOH solution at $25^{\circ}C$ and to 0.01 M NaOH solution at $40^{\circ}C$, carbon monoxide was generated. The carbon monoxide gas which was generated by 20 mL of 0.1 M lactose or 0.1 M xylose and 2 mL of 1.0 M NaOH solution at $50^{\circ}C$ for 2days was bubbled through 2 mL of fresh blood. The carboxyhemoglobin concentrations of both conditions were 31%. However, when the carbon monoxide gas which was generated by 30 mL of milk and 2 mL of 1.0 M NaOH at $50^{\circ}C$ for 2days or 3days was bubbled through 2 mL of fresh blood, the carboxyhemoglobin concentration was 32% or 42% respectively.

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Deposition of Alkali Metal Ions at Polypyrrole Film Electrodes Modified with Fullerene (플러렌으로 수식된 피를 고분자 피막전극에 알카리 금속이온의 포집)

  • Cha Seong-Keuck;Lee Sangchun
    • Journal of the Korean Electrochemical Society
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    • 제7권1호
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    • pp.16-20
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    • 2004
  • To electropolymerize Polypyrrole(ppy) film modified with fullerene $ions(full^-)$ the cell, Au/5 mM pyrrole, 1mM fullerene, 0.1M $TBABF_4,\;CH_2Cl_2/Pt$, was employed to Prepare the wafer-like type of $electrode/ppy(full^-)ppy(full^-){\ldots}$ electrodes. They were applied to deposit alkali metal ions with the cell of Au(quartz crystal analyzer; QCA)/ppy$(full^-)$, 0.01M metal ion(aq.)/Pt. The depositing rate constant of each ion for $Li^+,\;Na^+,\;K^+,\;Rb^+\;and\;Cs^+$, determined from the first order equation was $1.60\times10^{-8},\;3.13\times10^{-11},\;1.38\times10^{-9},\;2.71\times10^{-11}\;and\;2.98\times10^{-12}mo1.s^{-1}$ respectively. The calculated stoichiometry of the ions determined by quartz crystal microbalance(QCM) at the electrodes was $Li_7C_{60},\;Na_4C_{60},\;K_3C_{60},\;Rb_1C_{60}\;and\;Cs_1C_{60}$ respectively.

$H_{2}$ production of photosynthetic bacteria transferred TOL plasmid from flavobacterium odoratum (Flavobacterium odoratum의 TOL 플라스미드를 전달받은 광합성세균으로부터의 수소 생성)

  • 오순옥;조인성;이희경;민경희
    • Korean Journal of Microbiology
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    • 제29권6호
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    • pp.408-415
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    • 1991
  • TOL plsmid size of Flavobacterium odoratum SUB53 was estimated as 83 Md and the optimum concentration of m-toluate degradation by TOL plasmid was 5 mM. $H_{2}$ production by Rhodopseudomonas sphaeroides KCTC1425 was largely dependent on nitrogenase activity and showed the highest at 30 mM malate with 7 mM glutamate as nitrogen source. Nitrogenase activities were inhibited by 0.3 mM $NH_{4}^{+}$ions, to be appeared the decrease of $H_{2}$ production. Conjugation of TOL plasmids from F. odoratum SUB53 and Pseudomonas putida mt-2 to R. sphaeroides showed the optimum at the exponential stage of recipient cells in presence of helper plasmid pRK2013. According to the investigation of catechol-1,2-oxygenase (C-1, 2-O) and catechol-2,3-oxygenase (C-2,3-O) activities of R. sphaeroides C1 (TOL SUB53) and C2 (TOL mt-2), the gene for C-2,3-O is located on TOL plasmid and gene for C-1, 2-O on the chromosome of R. sphaeroides. m-Toluate was biodegraded by TOL plasmid in R. sphaeroides C1 and C2, presumably to be produced $H_{2}$ gas from the secondary metabolites of m-toluate.e.

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Impedance Parameters of Electrical Double Layer I. A Determination Method of Electrolytic Cell Impedance Parameter on the Platinum Electrode (전기이중층의 임피던스 파라미터 I. 백금전극을 사용한 전해쎌 임피던스 파라미터의 결정방법)

  • Kum-Sho Hwang;Un-Sik Kim
    • Journal of the Korean Chemical Society
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    • 제30권3호
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    • pp.273-281
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    • 1986
  • This study is focused on the correct measurement of the equations for the determination of the impedance parameters-the differential capacity of the double layer $C_d$, solution resistance $R_Q$, transfer resitance $R_i$, and adsorption pseudcapacity $C_{\phi}$/ The application of only an imaginary part of complex function of ${\omega}$ at the sinusoidal steady state indicates the following equations of total impedance: at low frequency $|Z_{LF}|=1/{\omega}_1\;C_{\phi}\;{\sqrt{1+{{\omega}_1}^2/{\omega}^2}$, at high frequency $|Z_{HF}|={\omega}_2/({\omega}_1{\omega}_3C{\phi})({\omega}^2+{{\omega}_2}^2)\;{\sqrt{{({\omega}^2+{\omega}_2{\omega}_3)}^2+{({\omega}_2{\omega}-{\omega_3{\omega})^2}}$. The values of the total impedance of cell, phase angle, and cell current that are necessary for the calculations of impedance parameters were experimentally measured from 200 to 6000Hz for the following supporting electrolytes, 0.5M $Na_2SO_4$, 1M NaCl, 19.373% sea water, 1M HCl, 1M $KNO_3$ and for $10^{-2}M$ KI and 60mM DBNA (Di-iso-Butylnitrosoamine) in these supporting electrolytes. The derived equations in this study shows that the values of impedance parameters of $C_d,\;C_{\phi},\;R_i\;and\;R_Q\;are\;15{\sim}40\;{\mu}F/cm^2,\;162{\sim}758\;{\mu}F/cm^2\;11.5{\sim}57.6\;ohm{\cdot}cm^2\;and\;0.5{\times}10^{-2}{\sim}4.1{\times}10^{-2}\;ohm{\cdot}cm^2$ respectively.

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Structural Analysis of Multi-Functional Fishway in Seomoon Weir (서문보의 다기능 어도의 구조해석)

  • Lee, Young Jae;Lee, Jung Shin;Jang, Hyung Kyu
    • Ecology and Resilient Infrastructure
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    • 제7권4호
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    • pp.308-319
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    • 2020
  • In this study, the field applicability of the recently constructed multifunctional fishway in Seomunbo, Yeongcheon-si, and Gyeongsangbuk-do were examined. The analysis variables were R/C slab (S1) and R/C+S/C slab (S2), the underground passage standard areas (width × length) were 1.4 m × 0.2 m, 1.4 m × 0.3 m, and 1.4 m × 0.6 m, and the flow velocities were 0.8, 1.2, and 1.6 m/s. As a result of the analysis, the safety of the design of Seomunbo was evaluated. The analysis showed compared to the Seomoon Weir fishway, the maximum stress of S2 decreased by 24 - 32%, the bending moment of the underground passage decreased by 16 - 33%, the maximum stress of the sidewall decreased by 20 - 36%. In addition, the bending moment of the upper slab decreased by 17 - 33%, the maximum stress of the upper slab decreased by 9 - 28%, and the bending moment decreased by 19 - 33%. Complementation was required in the following percentages: 18% and 14% for the maximum stress and bending moment of the underground passage, respectively, 15% and 17% for the maximum sidewall stress and bending moment, respectively, and 11% and 16% for the upper slab maximum stress and bending moment, respectively. The results showed that S2 was superior to that of the Seomoon Weir fishway, and the underground passage size of 1.4 m × 0.3 m was superior to those of 1.4 m × 0.2 m and 1.4 m × 0.6 m, and R/C+S/C slab was superior to that of R/C slab. The findings are expected to be useful for constructing and designing the multifunctional fishway.

Evaluation of Lethality by Chemical Marker (Chemical Marker를 이용한 살균도 예측)

  • Choi, Yang-Mun;Kim, Hie-Joon
    • Korean Journal of Food Science and Technology
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    • 제29권1호
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    • pp.32-37
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    • 1997
  • The rate constants and activation energies for formation of two chemical markers, M-1 and M-2 at sterilization temperatures were determined in a meatball system. Destruction rates for bacterial spores were also determined. The rate constants for M-1 and M-2 formation at $121^{\circ}C$ were 0.03 and 0.28 Abs/min, respectively. The activation energies for M-1 and M-2 were 27.9 and 24.6 Cal/mol. M-2 was formed faster than M-1 and reached a maximum and decreased. M-1 formation continued up to 30 min at $121^{\circ}C$ and 10 min at $131^{\circ}C$, which makes M-1 a more useful chemical marker for high $F_0$ values. The D-values for spores (B. stearothermophilus ATCC 12980) at 111, 114.4, 117.7 and $121^{\circ}C$ were 7.5, 4.5, 1.9 and 0.58 respectively. At temperatures between 111 and $121^{\circ}C$, there was a liner correlation between destruction of the spores and the M-1 formation. It was difficult to get accurate D-value at $126^{\circ}C\;and\;131^{\circ}C$, because almost all spores were dead before temperature at the center of the meatball reached $126^{\circ}C$. These data suggest that the chemical marker should be used to evaluate overprocessing as well as microbial lethality in aseptic processing.

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TENSOR PRODUCTS OF C*-ALGEBRAS WITH FIBRES GENERALIZED NONCOMMUTATIVE TORI AND CUNTZ ALGEBRAS

  • Boo, Deok-Hoon;Park, Chun-Gil
    • Journal of the Chungcheong Mathematical Society
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    • 제13권1호
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    • pp.139-144
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    • 2000
  • The generalized noncommutative torus $T_{\rho}^d$ of rank m was defined in [2]. Assume that for the completely irrational noncommutative subtorus $A_{\rho}$ of rank m of $T_{\rho}^d$ there is no integer q > 1 such that $tr(K_0(A_{\rho}))=\frac{1}{q}{\cdot}tr(K_0(A_{\rho^{\prime}}))$ for $A_{\rho^{\prime}}$ a completely irrational noncommutative torus of rank m. All $C^*$-algebras ${\Gamma}({\eta})$ of sections of locally trivial $C^*$-algebra bundles ${\eta}$ over $M=\prod_{i=1}^{e}S^{2k_i}{\times}\prod_{i=1}^{s}S^{2n_i+1}$, $\prod_{i=1}^{s}\mathbb{PR}_{2n_i}$, or $\prod_{i=1}^{s}L_{k_i}(n_i)$ with fibres $T_{\rho}^d{\otimes}M_c(\mathbb{C})$ were constructed in [6, 7, 8]. We prove that ${\Gamma}({\eta}){\otimes}M_{p^{\infty}}$ is isomorphic to $C(M){\otimes}A_{\rho}{\otimes}M_{cd}(\mathbb{C}){\otimes}M_{p^{\infty}}$ if and only if the set of prime factors of cd is a subset of the set of prime factors of p, that $\mathcal{O}_{2u}{\otimes}{\Gamma}({\eta})$ is isomorphic to $\mathcal{O}_{2u}{\otimes}C(M){\otimes}A_{\rho}{\otimes}M_{cd}(\mathbb{C})$ if and only if cd and 2u - 1 are relatively prime, and that $\mathcal{O}_{\infty}{\otimes}{\Gamma}({\eta})$ is not isomorphic to $\mathcal{O}_{\infty}{\otimes}C(M){\otimes}A_{\rho}{\otimes}M_{cd}(\mathbb{C})$ if cd > 1 when no non-trivial matrix algebra can be ${\Gamma}({\eta})$.

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Effect of Monosodium Glutamate and Temperature Change on the Content of Free Amino Acids in Kimchi (Monosodium Glutamate와 숙성온도 변화가 김치의 유리아미노산 함량에 미치는 영향)

  • 이예경;이명예;김순동
    • Journal of the Korean Society of Food Science and Nutrition
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    • 제33권2호
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    • pp.399-404
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    • 2004
  • This study was conducted to investigate the effect of monosodium glutamate (MSG) and fermentation methods (C-I; fermented for 5 days at 1$0^{\circ}C$ after 2$0^{\circ}C$ fermentation for 2 days, C-II; fermented for 7 days at 1$0^{\circ}C$, M-I; kimchi with MSG fermented for 5 days at 1$0^{\circ}C$ after 2$0^{\circ}C$ fermentation for 2 days, M-II; kimchi with MSG fermented for 7 days at 1$0^{\circ}C$ on fermentation and free amino acid content. Fermentation of M-I and M-II was slightly delayed compared to C-I and C-II. Total microbe of C-I and C-IIwere lower than those of M-I and M-II, and lactic acid bacteria of C-I and C-II were lower than those of M-I and M-II respectively. The major free amino acids were alanine, asparagine, homocystine and valine in C-I, especially, glutamic acid and ornithine were high in C-II. Homocystine, alanine, asparagine and valine in M-I, glutamic acid, alanine, hydroxyproline, asparagine, homocystine, ornithine and valine were the major free amino acid in M-II, respectively. The sour taste of M-I and M-II was lower than those of C-I and C-II, respectively, and the effect of delaying fermentation at 1$0^{\circ}C$ did not showed in the C-I and M-I. The crispy taste of the M-I and M-II was higher than those of C-I and C-II, which was the opposite results of sour taste. Palatable and overall taste of M-I and M-II were higher than those of C-I and C-II, respectively These results suggest that the MSG in kimchi affect not only increment of free amino acid content but also shelf-life and taste improvement, and continuous fermentation at 1$0^{\circ}C$ also enhance the content of free amino acid and shelf-life of kimchi.

Characteristics of Carbon Circulation for Ascidian Farm in Jindong Bay in Summer and Winter (진동만 미더덕 양식장의 하계 및 동계 탄소 순환 특성)

  • Park, Jihye;Cho, Yoonsik;Lee, Won-Chan;Hong, Sokjin;Kim, Hyung-Chul;Kim, Jeong-Bae;Park, Junghyun
    • Journal of Wetlands Research
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    • 제14권2호
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    • pp.211-221
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    • 2012
  • The ascidian Styela clava has been one of the favorite seafood in Korea. Suspended culture of Styela clava was initiated in 2001 and the annual production reached 15,084 M/T, but declined to 2,655 M/T in 2011. In order to solve this problem, it is necessary to estimate the material balance according to the farm-environment. Vertical particulate fluxes and release fluxes were estimated at 2 stations, an ascidian farm (AF) and a non-cultivated area (control) in Jindong Bay. An in-situ benthic chamber(BelcI) was used in summer and winter season. The sedimentation fluxes of organic carbon were 72 mmol C $m^{-2}\;d^{-1}$, 93 mmol C $m^{-2}\;d^{-1}$, 34 mmol C $m^{-2}\;d^{-1}$ in Jul. AF, Feb. AF, Feb. control. The organic carbon oxidation rates were 13 mmol C $m^{-2}\;d^{-1}$, 81 mmol C $m^{-2}\;d^{-1}$, 31 mmol C $m^{-2}\;d^{-1}$, in each. The release fluxes of nutrients followed the general pattern, well. Consequently, the ratio of the organic carbon burial fluxes were 20:4:1, in each. By the estimation of the carbon circulation, it could be a scientific basis to analyze the reason of production decline for cultivated organism.

The Study on the Freezing Methods and the Cryoprotectants for Rat Embryo Preservation (Rat 수정란의 동결보존에 있어 동결속도 및 동해방지제에 관한 연구)

  • 유준희;이재근
    • Korean Journal of Animal Reproduction
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    • 제8권1호
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    • pp.22-28
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    • 1984
  • This experiment was carried out to investigate effects of DMSO or ethylene glycol as a cryopotectant and of freezing methods on survival rate of forozen-thawed rat 2-cell embryos by morphological observation. 2-cell embryos were recovered from oviducts of Sprague Dawley females mated with males of same strain on day 2 of pregnancy after inducing superovulation by intrapertioneal injection of PMSG and HCG. In slow freezing and thawing groups, embryos were frozen to -79$^{\circ}C$ or -196$^{\circ}C$ in a glass test tube containing 0.2ml PBI with 1.5M DMSO or 1.2M ethylene glycol at a rate of 0.3-1.0C/min. and thawed slowly. When samples were frozen to -79$^{\circ}C$, higher survival rate was obtained in the medium containing DMSO (43.9%) than ethylene glycol (41%). And similar result was obtained (32.5% in DMSO vs. 31.4% in ethylene glycol) when samples were frozen. In rapid freezing and thawing groups, embryos were frozen to -79 or -196$^{\circ}C$ in a glass test tube containing 0.2ml of PBI with 1.5M DMSO or 1.2M ethylene glycol by rapid cooling, and thawed rapidly. When samples were frozen to -79$^{\circ}C$, 1.5M DMSO (13.2%) was more effective than 1.2M ethylene glycol (6.1%). When the storage temperature was -196$^{\circ}C$, survival rates were 9.8% in 1.5M and 5.4% in 1.2M ethylene glycol.

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