• Korean Journal of Materials Research
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• v.13 no.1
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• pp.36-42
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• 2003

The oxidation behaviors of Y-Cr bilayer deposited on ferritic steel by magnetron-sputtering for application of the Fe-Cr alloys as interconnectors of planar-type solid oxide fuel cells (SOFCs) were studied. After oxidation at $800^{\circ}C$ for 40 hours, the major phase of $Y_2$$O_3$and the minor phase of $YCrO_3$, $Mn_{1.5}$ $Cr_{1.5}$ $O_4$and Cr$_2$SiO$_4$were formed in the Y/Cr bilayered samples, while the major phase of Cr$_2$O$_3$and the minor phase of $Y_2$$O_3$were formed as the major phase in the Cr/Y bilayered samples. The Log(ASR/T) that expresses electric resistance of the Y/Cr coated specimen with nonconducting $_Y2$$O_3$oxide showed high value of -2.80 Ω$\textrm{cm}^2$$K^{-1}$ / and that of the Cr/Y coated specimen with conducting $Cr_2$$O_3$oxide appeared to be -4.11 Ω$\textrm{cm}^2$$^{K}$ . The electric resistance of the Y/Cr coated specimen was largely increased due to the formation of high resistance oxide scales. However, the Cr/Y coated specimen did not show any increase in the electric resistance and had the long-term stability of oxidation because there was no formation of the secondary phases with low conductivity.

• Korean Journal of Materials Research
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• v.6 no.12
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• pp.1257-1262
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• 1996

1.0Cr-1.0Mo-0.25V강 용접부의 크립 파단 시험시 파단 발생 원인에 관한 연구가 시행되었다. 파괴는 Intercritical Heat Affected Zone에서 발생하였으며 파단면에서 구상의조대한 M6C탄화물이 발견되었다. 모재는 molybdenum 주성분의 M2C, vanadium 주성분의 M4C3 및 chromium 주성분의 M23C6와 M7C3 탄화물이 존재하였다. 모의 실험 결과 준안정 상태인 M2C 탄화물은 85$0^{\circ}C$, 10oh에서 안정한 M6C탄화물로 변태하였다. M6C 탄화물은 주변의 molybdenum 농도를 떨어뜨려 강도의 저하를 가져오며 크립 기공의 발생 원인을 제공하였다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2013.05a
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• pp.112-113
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• 2013

Thin CrAlMgSiN films, whose composition were 30.6Cr-11.1Al-7.3Mg-1.2Si-49.8N (at.%), were deposited on steel substrates in a cathodic arc plasma deposition system. They consisted of alternating crystalline Cr-N and AlMgSiN nanolayers. After oxidation at $800^{\circ}C$ for 200 h in air, a thin oxide layer formed by outward diffusion of Cr, Mg, Al, Fe, and N, and inward diffusion of O ions. Silicon ions were relatively immobile at $800^{\circ}C$. After oxidation at $900^{\circ}C$ for 10 h in air, a thin $Cr_2O_3$ layer containing dissolved ions of Al, Mg, Si, and Fe formed. Silicon ions became mobile at $900^{\circ}C$. After oxidation at $900^{\circ}C$ for 50 h in air, a thin $SiO_2-rich$ layer formed underneath the thin $Cr_2O_3$ layer. The film displayed good oxidation resistance. The main factor that decreased the oxidation resistance of the film was the outward diffusion and subsequent oxidation of Fe at the sample surface, particularly along the coated sample edge.

• Journal of the Korean Society for Heat Treatment
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• v.22 no.6
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• pp.361-367
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• 2009

The two-step gas nitriding was adopted to increase the depth of surface hardening in 3%Cr-Mo-V steel. The two-step gas nitriding consisted of Step I; $520^{\circ}C{\times}20\;hrs$ and Step II; $550^{\circ}{\times}70\;hrs$. The layer of two-step gas nitriding showed better uniformity and deeper nitriding layer than one-step gas-nitriding layer. The maximum surface hardness showed the value of 850 Hv. The maximum depth of nitrogen permeation showed $750\;{\mu}m$ (350 Hv). X-ray diffraction analysis showed that compound layer was mainly consisted of CrN and $\varepsilon-Fe_3N$ phases. These phases were presumed contributing to surface hardening and wear resistance. However, the corrosion resistance of gas-nitrided Cr-Mo-V steel were not improved in the solution of 1 N HCl and NaOH. Therefore, it is necessary that the continuous study for improvement of corrosion resistance hereafter.

• Journal of Welding and Joining
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• v.18 no.2
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• pp.49-56
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• 2000

Recently developed Austenite stainless steel, 309L was used to overlay on 3Cr-1Mo-V-Ti-B steels, using Electroslag welding process, which wide electrodes were adopted. Transition region in welding interlayer relating to disbonding crack was investigated. Also, the effect of welding condition on the width of transition region and coarsening grains of the austenite were studied. 1) With increasing welding speed the width of martensite at transient region was increased, but the amount of delta ferrite in weld metal was reduced, being fine grained. 2) The form of martensite at the transition region was occurred by reversible transformation during cooling since the interdiffusion of Cr and Ni from weld metal and Fe and C from base metals at the transition region, causes to lowering the concentration of Cr and Ni at the transition region, leading to increasing Ms point. 3) With increasing welding speed, the grain of austenite formed at the welding interface was finer. With increasing welding current under the same welding speed, the grain size of the austenite was finer. At high current, original grain size of the austenite is coarse, but the austenite has fine grains because the austenite was transformed to martensite during cooling. 4) In the case of high welding speed, the width of martensite at the welding interface was increased, but the grain size of austenite at the welding interface was finer. This indicates that the inhibition of disbonding crack may be achieved through dispersening fine carbides in the gain boundary.

• Journal of Powder Materials
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• v.25 no.5
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• pp.408-414
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• 2018

This study investigates the microstructure and wear properties of cermet (ceramic + metal) coating materials manufactured using high velocity oxygen fuel (HVOF) process. Three types of HVOF coating layers are formed by depositing WC-12Co, WC-20Cr-7Ni, and Cr3C2-20NiCr (wt.%) powders on S45C steel substrate. The porosities of the coating layers are $1{\pm}0.5%$ for all three specimens. Microstructural analysis confirms the formation of second carbide phases of $W_2C$, $Co_6W_6C$, and $Cr_7C_3$ owing to decarburizing of WC phases on WC-based coating layers. In the case of WC-12Co coating, which has a high ratio of $W_2C$ phase with high brittleness, the interface property between the carbide and the metal binder slightly decreases. In the $Cr_3C_2-20CrNi$ coating layer, decarburizing almost does not occur, but fine cavities exist between the splats. The wear loss occurs in the descending order of $Cr_3C_2-20NiCr$, WC-12Co, and WC-20Cr-7Ni, where WC-20Cr-7Ni achieves the highest wear resistance property. It can be inferred that the ratio of the carbide and the binding properties between carbide-binder and binder-binder in a cermet coating material manufactured with HVOF as the primary factors determine the wear properties of the cermet coating material.

• Journal of the Korean Society for Nondestructive Testing
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• v.22 no.3
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• pp.284-291
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• 2002

An attempt was made to evaluate the degree of aging degradation in thermally aged 2.25Cr-1Mo steel by electrical resistivity measurement. Artificial aging was performed to simulate the microstructural degradation in 2.25Cr-1Mo steel arising from long time exposure at $540^{\circ}C$. Microstructural parameter (amount of solid solution element), mechanical property (ductile-brittle transition temperature) and electrical resistivity were measured to investigate the mutual relationship among these parameters. Depletion of solid solution element(Mo and Cr) in matrix was detected after aging. The ductile-brittle transition temperature(DBTT) increased rapidly in the initial stage of aging and then saturated afterward. On the other hand, the electrical resistivity decreased rapidly in the beginning and then saturated in the later stage of aging.

• Corrosion Science and Technology
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• v.15 no.3
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• pp.125-128
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• 2016

The ASTM T92 steel was corroded at $600^{\circ}C$ and $800^{\circ}C$ at 1 atm of $N_2/3.1%H_2O/2.42%H_2S-mixed$ gas. The formed scales were thick and fragile. They consisted primarily of the outer FeS scale and the inner (FeS, $FeCr_2S_4$)-mixed scale containing a small amount of the $Cr_2O_3$ scale. This indicated that corrosion occurred mainly via sulfidation rather than oxidation due to the $H_2S$ gas. Since FeS was present throughout the whole scale, T92 steel was non-protective, displaying high corrosion rates.

• Journal of the Korean Vacuum Society
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• v.7 no.s1
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• pp.171-178
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• 1998

The microstructure and properties of plasma-sprayed coatings depend on a great number of spraying parameters, random factors, which lead to vibration in these spraying parameters, may in some degree influence the microstructure and properties of the coatings. Therefore, the property values appear certain distributions, and the description and comparison of the properties of plasma-sprayed coatings should be performed employing statistical analysis. In this paper, $Cr_3C_2$-Nicr coatings of different thickness were sprayed onto stainless steel using atmosphere plasma system and adopting three kinds of gun translation speeds. Then the microhardness measurements were performed on polished surface of the coatings. Forty readings were taken and statistically analyzed by calculating the characteristic values, estimating and comparing the means, and assessing whether they belonged to the Normal or Weibull Distribution. This study has found that statistical analysis could discriminate influence of spraying parameters and coating design on microhardness of the $Cr_3C_2$-Nicr coatings from random vibration, which showed that the microharness of the $Cr_3C_2$-Nicr coatings were related to gun translation speed coating thickness.

• Journal of the Korean institute of surface engineering
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• v.40 no.5
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• pp.219-224
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• 2007

The corrosion characteristics of Fe-18Cr-10Ni steels were studied between $600^{\circ}C$ and $1000^{\circ}C$ in Ar+(0.2, 1)%$SG_2$ gas for up to 300 hr in order to employ Fe-18Cr-10Ni steels in the coal-fired power plants. The corrosion resistance of Fe-18Cr-10Ni steels was good due mainly to the high amount of Cr, which formed $Cr_2O_3$ from the initial corrosion stage. Fe in the steels corroded to mainly $Fe_2O_3$ and $Fe_3O_4$. Ni was not susceptible to corrosion under the current corrosion condition. Relatively thin, single-layered scales formed.