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Cis-Trans Isomerization of Dimeric $[Me_2Al(μ-NH^tBu)]_2$

  • Park, Joon T.;오원태;김윤수
    • Bulletin of the Korean Chemical Society
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    • v.17 no.12
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    • pp.1147-1149
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    • 1996
  • The trans (2a)-cis (2b) isomerization of [Me2Al(μ-NHtBu)]2 (2) has been studied by 1H NMR spectroscopy. The equilibrium has been observed to follow reversible first order kinetics with ΔH0=2.22±0.07 kJmol-1 and ΔS0=2.85±0.07 JK-1mol-1. The activation parameters for the conversion 2a→2b are ΔH1=49.7±2.3 kJmol-1 and ΔS1=-126.3±0.2 JK-1mo1-1 and for the reverse reaction 2b→2a are ΔH-1=47.5±2.3 kJmol-1 and ΔS-1=-129.1±0.5 JK-1mol-1. The isomerization is markedly accelerated in the presence of Lewis bases. A crossover experiment indicates that the isomer interconversion is a unimolecular process. The large negative entropies of activation suggest either the existence of a sterically congested intermediate or the participation of solvent in the isomerization process.

A preliminary study of the anti-inflammatory activities of the Japanese oak silk moth, Antheraea yamamai

  • Park, Seung-Won
    • International Journal of Industrial Entomology and Biomaterials
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    • v.45 no.1
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    • pp.17-21
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    • 2022
  • The present study aimed to determine whether a hemolymph prepared from Antheraea yamamai larvae had the same biological activities using a Bombyx mori hemolymph prior to exposure to lipopolysaccharide (LPS) in order to induce an inflammatory response. The effects of the hemolymph were determined using a reverse transcription-quantitative polymerase chain reaction to assess the expression of pro-inflammatory molecules. The A. yamamai hemolymph exerted anti-inflammatory effects on LPS-activated human monocytic leukemia cells via Toll-like receptor (TLR) 4-mediated suppression, similar to the B. mori hemocyte extract. Treatment with the A. yamamai hemolymph significantly suppressed LPS-induced upregulated inducible nitric oxide synthase (iNOS) and cyclooxygenase-2 (COX-2) mRNA expression at all tested concentrations compared with the control, similar to the B. mori immune-challenged hemolymph. Finally, the A. yamamai hemolymph, like the B. mori immune-challenged hemolymph, suppressed all of these concentrations in a dose-independent manner. These results demonstrate that the hemolymph of A. yamamai exhibited important biologically active substances. Further in-depth functional studies are required to fully understand the mechanisms underlying the biological activities of wild-type silkworm hemolymphs.

A Design of XAS4B for Adding Function in BPEL using Aspect-Oriented Programming (관점지향 프로그래밍 기법을 이용한 BPEL 기능 추가를 위한 XAS4B 엔진 설계)

  • Kwak, Donggyu;Choi, Jaeyoung
    • Journal of IKEEE
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    • v.17 no.4
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    • pp.525-530
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    • 2013
  • The BPEL is standard of workflow. A domain experts not familiar with programming languages and he can write workflow. But he need new function without BPEL. We must develop or modify a BPEL engine for new functions. This method is expensive. In this paper, We propose the XAS4B documents that extend the XML schema. And We describe method that can process new function in BPEL using Aspect-Oriented Programming. AOP can cross-cut concern adding to core concern using weaving without modification. We use an existing B2J (BPEL to JAVA) engine that is transfer a BPEL's document to a JAVA program and B2J execute a JAVA program. This system adding new functions to BPEL's flow using AOP. In this system, A JAVA program is core concern and a program of new function is cross-cut concern. And this system weave a JAVA program made in B2J and a program of new function. This method provide abstract grammar for new functions. And domain experts can easily write new function is a BPEL Document and reuse new function using abstract grammar.

Effect of Magnesium, Boron and Zinc on Several Characteristics of Sesame in Reclaimed Upland (개간지에 있어서 마그네슘, 붕소 및 아연 시용이 참깨 제형질변화에 미치는 영향)

  • 오병석;김진호;정병관;김용재
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.39 no.4
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    • pp.317-322
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    • 1994
  • This study was conducted to increase the seed yield and to find the interaction of several characters of sesame on the reclaimed upland by application of minor nutrient which were boron, magnesium and zinc. A result of testing of boron and magnesium were effective relatively. Application of boron and magnesium were increased the dry stem wt. of upper capsule setting position, Specially dual application of boron and magnesium were remarkable. Dry stem wt. affected on seed increasing of lower and middle capsule setting part. Capsule no. per plant was showed higher degree in dual B+Mg than each application. Capsule no. affected on increasing of dry stem wt. as well as seed yield also. Capsule no. of lower and upper capsule setting part indicated relation with seed yield, 1000 grains weight. This result showed increasing tendency of upper capsule setting part in B+Mg+Zn application. The products of seed yield indicated the increasing of estimate production at the highest 21% in dual Mg+B, 17% of dual B+Zn+Mg secondly, 12% of single boron application thirdly.

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A Comparative Study on Medical Care Services in Two Community Health Sub-centers(Seo San-Gun, Choong Chung Nam-Do) (일선 2개 보건지소의 진료실적 비교 분석 (충남 서산군))

  • Chang, Il-Young
    • Journal of Preventive Medicine and Public Health
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    • v.17 no.1
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    • pp.121-126
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    • 1984
  • Several detailed aspects of medical care services during one year (Aug 1, $1982{\sim}$July 31, 1983) were compared between two community health sub-centers; one (A) was served by a local clinician, the other (B) by a trainee of preventive medicine. The results were analysed as follows: 1. Total spells of medical services during the same period in 'A' sub-center was 4,087 and that in 'B' 2,347. Medicaid visitors in 'A' was 1,051 (25.7% of the total), that in 'B' was 250 (10.7%). Significant difference was observed. 2. Average number of visits for the same case in 'A' was 2.0, that in 'B' was 1.4. Average duration of service by day for the same case in 'A' was 3.9, that in 'B' 3.0. 3. Average cost of service for a case in 'A' was 6,770 won, that in 'B' 4,230 won. 4. Difference in age distribution of visitors in the two sub-centers was insignificant. $0{\sim}9$ year group was 38.5% of the total. Difference in distribution by sex (between two sub-centers) was minimal. Male utilisers more than female by ca. 10%. 5. Concerning distribution of visitors by month, utilisation in July, August and September was the highest; the sum of them was 32.7% of the total in 'A' and 32.9% in 'B'. 6. Distribution by diagnoses in 'A' in decreasing order of frequency was Respiratory system diseases (26.1%), Digestive system diseases (23.0%), Diseases of skin and subcutaneous tissue (17.4%), Accidents and poisoning (11.5%) and Diseases of musculoskeletal system and connective tissue (5.4%). That in 'B' was Respiratory system diseases (39.0%), Digestive system diseases (23.0%), Diseases of skin and subcutaneous tissue (14.2%), Accidents and poisoning (10.9%) and Infection and parasitic diseases (9.1%). 7. The 10 most frequent diagnoses comprised 68.5% of the total in 'A' and 65.5% in 'B' 8. Utilisation by accessibility to each sub-center was studied. It is shown that the nearer the distance or the easier the accessibility, the more visits to services. The distinct pattern is manifested in the utilisation in 'A'-Myun.

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The Hyperfine Interaction for the FeIn2S4 by Mössbauer Spectroscopy (뫼스바우어 효과를 통한 FeIn2S4에서의 Fe2+ 초미세 상호 작용 연구)

  • Son, Bae-Soon;Kim, Sam-Jin;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.17 no.1
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    • pp.30-33
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    • 2007
  • The $FeIn_2S_4$ exhibits an inverse spinel which Fe ions are occupied to the octahedral(B) site, while In ions are occupied to both the tetrahedral(A) and the octahedral(B) site. The $N\'{e}el$ temperature($T_N$) is determined to be 13 K. The effective moment of $FeIn_2S_4$ found to be $5.094{\mu}_B$ from the fit of Curie-Weiss inverse susceptibility for the temperature range over $T_N$, implying angular momentum contribution. The angular momentum contribution is shown in $M\"{o}ssbauer$ spectra for the antiferromagnetic ordering region($T{\leq}\;13K$), too. A weak $Fe^{2+}(B)-S^2-Fe^{2+}(B)$ interaction is responsible for a low $N\'{e}el$ temperature($T_N$) in $FeIn_2S_4$ system. The temperature dependence of electric quadrupole interaction is explained by z-axial crystalline field energy.

Design and Experiment of Ku_band Linear Active Phased Array Antenna System (Ku 대역 선형 능동 위상 배열 안테나 시스템 설계 및 실험)

  • Ryu Sung-Wook;Eom Soon-Young;Yun Jae-Hoon;Jeon Soon-Ick;Kim Nam
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.17 no.7 s.110
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    • pp.694-705
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    • 2006
  • In this paper, the linear active phased array antenna system operated in Ku DBS band was designed and experimented. The antenna system was composed of sixteen radiating active channels and Wilkinson power combiners with 16-channel inputs, a stabilizing DC bias and phase control board. Electrical beams of the antenna system can be formed by controling the phase-states of 3-bit digital phase shifter inside each active channel by virtue of the phase control board. The amplitude and phase deviations measured between active channels were less than ${\pm}0.8dB$ and ${\pm}15^{\circ}$, respectively, and the noise figure of each active channel was measured less than 1.2 dB in the operating band. The measured performances of the overall antenna system showed the antenna gain of more than 23.07 dBi and the sidelobe level of less than -11.17 dBc, and the bore-sight cross-polarization level of less than -12.75 dBc in the operating band. Also, by phase-controlling active channels, the beam scan patterns at $10^{\circ},\;20^{\circ},\;30^{\circ}$ were measured, and the losses caused by the corresponding beam scanning were 1.1 dB, 2.5 dB and 3.6 dB from the measurements, respectively.

The study on the abdominal temperature difference according to primary dysmenorrhea severity (원발성(原發性) 월경통(月經痛) 정도에 따른 하복부(下腹部) 온도차이(溫度差異) 연구(硏究))

  • Yoon, Young-Jin;Choi, Yun-Hui;Cho, Jung-Hoon;Jang, Jun-Bock;Lee, Kyung-Sub
    • Journal of Oriental Medical Thermology
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    • v.3 no.1
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    • pp.6-14
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    • 2004
  • Purpose: We intended to research the relations between abdominal temperature and primary dysmenorrhea severity. Methods: We selected the 95 primary dysmenorrhea patients by means of screening test (first screening test-inquiry, second screening test-clinical test, additionally Waist-to-Hip ratio (WHR) by Inbody 2.0). We measured 4 points abdominal temperature (Chon-jung(CV17), Chung-wan(CV12), Kwan-won(CV4), Chung-guk(CV3)) by DITI (DOREX Inc., USA). And then we checked the difference of temperature $({\Delta}T)$ between CV17 and CV4 / CV17 and CV3 / CV12 and CV4 / CV12 and CV3. After that, we compared ${\Delta}T$ with primary dysmenorrhea severity evaluated by multidimensional scales (verbal rating scale modified from the one devised by Bibe roglu & Berhrman(VRS; B&B), multidimensional verbal rating scale by Andersch & Milsom(MVRS)). In dysmenorrhea severity, we standardized scale score and 3-group-severity by score (mild, moderate, severe). For statistics, we used Pearson correlations and Spearman's rho correlations, SPSS 11.0 for windows. Results: In case of MVRS, MVRS score and 3-group-severity were not correlated to ${\Delta}T$. In case of VRS; B&B, VRS; B&B score was correlated to ${\Delta}T$ (CV12 and CV4 / CV12 and CV3) and 3-group-severity was correlated to ${\Delta}T$ (CV12 and CV3). Statistically they showed significant result (p<0.05). So we can consider that ${\Delta}T$ (CV12 and CV3) and the primary dysmenorrhea severity by VRS; B&B are most correlated. Conclusion: The primary dysmenorrhea patients showed that severity by VRS; B&B was connected with ${\Delta}T$ (CV12 and CV3). So we can consider DITI as primary dysmenorrhea evaluation instrument and must further research measurement points for the exact primary dysmenorrhea evaluation by DITI.

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Phytosociological Study of Weed Vegetation around the Climbing Paths on Mt. Chungyeong (경기도 축령산 등산로 주변 잡초 식생의 식물사회학적 연구)

  • 안영희;송종석
    • Korean Journal of Environment and Ecology
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    • v.17 no.3
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    • pp.232-241
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    • 2003
  • Mountain Chungyeong, 879m in altitude, is located in the northeast of the middle area in Korea. Around Mt. Chungyeong, many Korean endemic and rare plants are populated, so it is considered a very important biogeographical area where the temperature zones of northern and southern plants are crossed. Because it is close to Seoul, a capital of Korea, it is a common mountain where many tourists visit frequently. Continuous tourist's visit may cause a bad influence on vegetation around the climbing paths. Therefor, weed community around the climbing paths on Mt. Chungyeong, where visitors exert a bad influence directly on its community by coming in and out, was surveyed phytosocialogically. Our surveys have been accomplished from August, 2001 to September, 2002. weed communities formed around the climbing paths on Mt. Chungyeong were divided into several patterns and analysed. They have been divided into 5 communities and 5 subcommunities. Community A: Plantago asiatica community, A-a: Erigeron annuus subcommunity, A-b: Carex. lanceolata subcommunity, B: Pseudostellaria palibiniana community, B-a: Carex siderosticta subcommunity, B-b: Galium trachyspermum subcommunity, C: Pueraria thunbergiana community, D: Lespedeza maximowiczii community, E: Rubus crataegifolius community, F: Oplismenus undulatifolius community, The flora surveyed in these communities was constituted of 47 families, 101 genera, 17 varieties, and 149 species. Wild plants such as Plantago asiatica, Erigeron annuus, Erigeron strigosus, Pueraria thunbergiana, Lespedeza maximowiezii, Rubus crataegifolius, Artemisia princeps var. orientalis, Artemisia japonica and Lysimachia clethroides were mostly light loving plants and higher resistant plants against the stamping pressure. Our result from the ranking all surveyed areas by the Bray-Curtis ordination method was very similar to the results from phytosocialogical table analysis.

Physicochemical Properties of Germinated Brown Rice (발아시킨 현미의 품질특성)

  • 금준석;최봉규;이현유;박종대;박현준
    • Food Science and Preservation
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    • v.11 no.2
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    • pp.182-188
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    • 2004
  • This study was carried out to investigate nutritional composition and physicochemical properties of waxy(WGR) and nonwaxy(NWGR) germinated brown rice. Amylose contents of WGR(moisture content 15.45 %) and NWGR (moisture content 15.02%) were 4.9% and 17.9%. Reducing sugar of those were 4.91% and 2.28%. The free sugar contents of WGR were glucose 0.42%, sucrose 0.15%, maltose 0.27% and that of NWGR were glucose 0.59%, sucrose 0.50%, maltose 0.24%, respectively. Color value of WGR and NWGR were L=60.30, a=2.12, b=23.52 and L=59.51, a=3.15, b=23.04, respectively. Degree of gelatinization of WGR and NWGR were 7.67%, 5.21% and hardness of WGR and NWGR were 7.53 kg$\_$f//$\textrm{cm}^2$, 8.93 kg$\_$f//$\textrm{cm}^2$. Vitamin E contents of those were 271.8 $\mu\textrm{g}$/kg, 310.6 $\mu\textrm{g}$/kg and total dietary fiber contents of those were 4.21%, 3.17%. Total amino acids of brown rice, nonwaxy germinated brown rice and cooked germinated brown rice were 126.8 mg/l00 g, 90.8 mg/l00 g and 106.5 mg/l00 g, respectively. Among amylogram characteristics of WGR and NWGR, initial gelatinization temperature, peak viscosity, breakdown, setback were 42$^{\circ}C$, 498 B.U., 94 B.U., -48 B.D. and 70$^{\circ}C$, 212 B.D., 0 B.D., 123 B.D., respectively. Sensory properties of germinated brown rices were affected by color and flavor. Palatability score of WGR that intensity score of color and flavor were lower than that of NWGR showed high.