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Template Synthesis of New Nickel(Ⅱ) Comlexes of 14-Membered Pentaaza Macrocyclic Ligands: Effects of C-Alkyl and N-Hydroxyalkyl Pendant Arms on the Solution Behaviors of the Complexes

  • 강신걸;최장식;김성진
    • Bulletin of the Korean Chemical Society
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    • v.16 no.6
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    • pp.518-523
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    • 1995
  • New square planar nickel(Ⅱ) complexes with various 1-alkyl (4a-4c) and 1-hydroxyalkyl (4d-4f) derivatives of the 14-membered pentaaza macrocycle 8-ethyl-8-nitro-1,3,6,10,13-pentaazacyclotetradecane have been synthesized by two-step metal template condensation reactions of ethylenediamine, nitroethane, formaldehyde, and appropriate primary amines. The nitro group and/or hydroxyl group of 4a-4f are not directly involved in the coordination. The nickel(Ⅱ) complexes exist in coordinating solvents such as MeCN, Me2SO, and H2O as equilibrium mixtures of the square planar [Ni(L)]2+(L=4a-4f) and octahedral species [Ni(L)S2]2+(S=solvent molecule). Although the ligand field strength and redox potentials of the complexes are not affected by the nature of the substituents, the formation of octahedral species for 4d-4f in MeCN is strongly restricted by the hydroxyl group. Synthesis, characterization, and solution behaviors of the nickel(Ⅱ) complexes are described.

A Study on the Analysis for the Stability of Bailey Panel Bridge by FEM (유한요소해석을 통한 장간조립교 주요 부재의 안정성 분석 연구)

  • Lee, Jong-Woo;Lee, Jae-Young;Cho, Seong-Sik;Yoo, Sam-Hyun;Choi, Hyun-Ho;Yun, Woo-Seob;Kim, Tae-Yang
    • Journal of the Korea Institute of Military Science and Technology
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    • v.14 no.3
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    • pp.335-344
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    • 2011
  • In this paper, the results of computational analysis for the stability and F.S.(Factor of Safety) of Bailey Panel Bridge have been presented by FEM(Finite Element Method). The computational analysis was conducted by using LUSAS V14.0 that is a program applicated in the field of Civil Engineering. 6-free beam elements and 3-free truss elements were considered and F.S. against Yield Stress of main sections(considered self-weight and Live-Load) was investigated through the linear-elastic analysis method. The results showed that currently used sections of bailey bridge satisfied for the standard F.S. unit and could be operated in drill of troops and battle fields.

Internet Use Time and Health Risk Behavior in Adolescents (청소년의 인터넷 사용시간과 건강위험행위)

  • Kim, Young-Sook
    • The Journal of Korean Society for School & Community Health Education
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    • v.14 no.2
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    • pp.1-14
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    • 2013
  • Objectives: The purpose of this study was to identify the relationship of internet use time and health risk behaviors among adolescents and provide data to set up a strategy for preventing internet addiction. Methods: The data of the 2011 Youth Health Risk Behavior web-based Survey Collected by Korean Center for Disease Control was analyzed using t-test, ANOVA, Chi-square test for this study. Results: There were significant differences between boys and girls in internet use time. Boy's internet use time was different according to city size(F=13.20, p<.001), grade(F=35.85, p<.001), school record(F=298.95, p<.001), economic state(F=326.75, p<.001), living with parents(t=11.60, p<.001), father's education level(F=147.92, p<.001), and mother's education level(F=110.93, p<.001). Girls' internet use time was also different according to school grade(t=-8.68, p<.001), grade(F=61.03, p<.001), school record(F=233.32, p<.001), economic state(F=185.78, p<.001), living with parents(t=10.81, p<.001), father's education level(F=86.54, p<.001), and mother's education level(F=92.64, p<.001). Regarding the health risk behaviors, present smoking, present alcohol drink, drug use skipping breakfast, eating fast food, drinking soda, sexual behavior, suicidal attempt, engagement time in physical education classes, severe exercise, and sleeping satisfaction made differences in the internet use time. Conclusions: The results suggest that health risk behaviors are influenced by internet use time of adolescents. Thus, these results may be contribute to development of programs to prevent internet addiction.

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Effects of $C_2F_{6}$ Gas on Via Etching Characteristics ($C_2F_{6}$ 가스가 Via Etching 특성에 미치는 영향)

  • Ryu, Ji-Hyeong;Park, Jae-Don;Yun, Gi-Wan
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.39 no.1
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    • pp.31-38
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    • 2002
  • In order to improve the 0.35 $mutextrm{m}$-via hole etching process the etching characteristic of the gas $C_2F_{6}$ has been analyzed. The samples were triple-layer films(TEOS/SOG/TEOS) on 8-inch wafers and the orthogonal array matrix technique was used for the process. The equipment for etching was the transformer coupled plasma (TCP) source which is a type of high density plasma(HDP). This experiment showed the etching rate for $C_2F_{6}$ was 0.8 $mutextrm{m}$/min-1.1 $mutextrm{m}$/min and the measured uniformity was under $pm$6.9% in the matrix window. The CD skew comparison between pre and post-etching was under 10% which is an outstanding results in the window of profile in anisotropic etching. There was no problem in C2F6 with the flow rate of 20sccm, but when 14sccm of $C_2F_{6}$ was supplied there was a recess problem on the inner wall of SOG film. Consequently the etching characteristic of $C_2F_{6}$ shows a fast etching rate and a very wide process window in HDP TCP.

Characteristics of TiO2 Thin Films Fabricated by R.E, Magnetron Sputtering (R.F Magnetron Sputtering법으로 제조한 TiO2 박막의 특성)

  • Chu Y. H.;Choi D. K.
    • Korean Journal of Materials Research
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    • v.14 no.11
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    • pp.821-827
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    • 2004
  • Titanium oxide thin films were prepared on Si(100) substrates by R.F. magnetron reactive sputtering at $30\sim200watt$ R.F power range, and annealed at $600^{\circ}C\sim800^{\circ}C$ for 1 hour. The properties of $TiO_2$ thin films were analyzed using x-ray, ${\alpha}-step$, ellipsometer, scanning electron microscopy, and FT-IR spectrometer. Upon in-situ depositions, the initial phase of $TiO_2$ thin film showed non-crystalline phase at R.F. power $30\sim100$ watt. The crosssection of $TiO_2$ thin films were sbserved to be the columnar structure. With the increasing R.F power and annealing temperature, the grain size, crystallinity, refractive index, and void size of titanium oxides showed a tended to increase. The FT-IR transmittance spectra of titanium oxide thin films have the obsorption band of Ti-O bond, Si-O bond, Si-O-Ti bond and O-H bond. With the increase of R.F. power and annealing temperature, these films have the stronger bond structures. It is considered that such a phenomena is due to phase transition and good crystallinity

Effect of Overshooting on Final Masses of Type Ibc Supernova Progenitors

  • Chun, Wonseok;Yoon, Sung-Chul
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.2
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    • pp.88.1-88.1
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    • 2014
  • Helium mass in the envelope is one of the most important properties in progenitors of type Ib/c supernovae (SNe Ib/c), since SN Ib/c progenitors are distinguished by the presence of He I lines. However, previous progenitor models do not reproduce the required He mass limit($M_{He}$ < $0.14M_{\odot}$) suggested by a spectroscopic analysis of SN Ib/c. In this work, we investigated the effect of overshooting on the evolution of pure helium stars, focusing on the final He mass in the envelope, $M_{He,f}$. We used the MESA code to calculate single helium star models with the initial masses of $M_{init}=5{\sim}30M_{\odot}$, Z=0.02, 0.04 and overshooting parameters of $f_{ov}=0{\sim}0.4$. The final He mass $M_{He,f}$ decreases as $f_{ov}$ increases, due to larger burning core compared to weak overshooting models. Dependence of the final mass $M_{He,f}$ on overshooting is strongest for models with $M_{init}=7{\sim}10M_{\odot}$, and this effect originates from accelerated mass loss during transition between WNE and WC/O phase. However, $M_{He,f}$ exceeds $0.27M_{\odot}$ for all models, which still doesn't meet the criteria of $M_{He}$ < $0.14M_{\odot}$. This implies that mass loss during the post helium burning phase must be enhanced dramatically compared to what the standard models predict.

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Preparation and Structure of $Re(NC_6F_5)(PPh_3)_2Cl_3 $ ($Re(NC_6F_5)(PPh_3)_2Cl_3 $화합물의 합성 및 구조)

  • 박병규;김영웅
    • Korean Journal of Crystallography
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    • v.7 no.2
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    • pp.113-119
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    • 1996
  • Reaction of Re(O)(PPh3)2Cl3,I, with 2,3,4,5,6-pentafluoroaniline (C6F5NH2), produced Re(NC6F5)(PPh3)2Cl3, II. The product has been characterized by 1H-NMR, elemental analysis, and X-ray diffraction. II crystallizes in the orthorhombic system, space group Pna21 with cell parameters a=18.763Å, b=14.737(2)Å, c=16.707(3)Å, Z=4. Least-square refinement of the structure led to an R(wR2)factor of 0.0455(0.1148) for 3319 unique reflections of I > 2σ(I) and for 174 variables.

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Effect of PEL Exopolysaccharide on the wspF Mutant Phenotypes in Pseudomonas aeruginosa PA14

  • Chung, In-Young;Choi, Kelly B.;Heo, Yun-Jeong;Cho, You-Hee
    • Journal of Microbiology and Biotechnology
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    • v.18 no.7
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    • pp.1227-1234
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    • 2008
  • Pseudomonas aeruginosa is an opportunistic human pathogen that produces and secretes exopolysaccharides (EPS), in which cells are embedded to form a highly organized community structure called biofilm. Here, we characterized the role of cyclic diguanylate (c-di-GMP) and EPS (PEL) overproduction in the wspF mutant phenotypes of P. aeruginosa PA14 (wrinkly appearance, hyperadherence, impaired motilities, and reduced virulence in acute infections). We confirmed that the elevated c-di-GMP level plays a key role in all the wspF mutant phenotypes listed above, as assessed by ectopic expression of a c-di-GMP-degrading phophodiesterase (PvrR) in the wspF mutant. In contrast, PEL EPS, which is overproduced in the wspF mutant, was necessary for wrinkly appearance and hyperadherence, but not for the impaired flagellar motilities and the attenuated virulence of the wspF mutant. These results suggest that c-di-GMP affects flagellar motility and virulence, independently of EPS production and surface adherence of this bacterium.

Intrared-to-visible upconversion in $Er^{3+}:LaF_3와\;Er^{3+}:YAlO_3$ crystals ($Er^{3+}:LaF_3와\;Er^{3+}:YAlO_3$에서의 적외선으로부터 가시광선으로의 상방전환)

  • ;;;W.M.Yen
    • Korean Journal of Optics and Photonics
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    • v.7 no.2
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    • pp.120-128
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    • 1996
  • We studied the red, green and blue upconverted emission in 1 at.% $Er^{3+}: LaF_3$ and 1 at.% $Er^{3+}:YAlO_3$ crystals y pumping in 780~820 nm range at 14 K and 295 K. A cw titanium-sapphire laser was used to pump the $^4I_{9/2}$ level in two materials. The spectral analysis of the emission from $^4F_{9/2},\;^4S_{3/2}$ and $^2P_{3/2}$ levels allowed to reveal the upconversion process with multi-step absorption and cross-relaxation energy transfer.

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Coreference Resolution for Korean using Mention Pair with SVM (SVM 기반의 멘션 페어 모델을 이용한 한국어 상호참조해결)

  • Choi, Kyoung-Ho;Park, Cheon-Eum;Lee, Changki
    • KIISE Transactions on Computing Practices
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    • v.21 no.4
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    • pp.333-337
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    • 2015
  • In this paper, we suggest a Coreference Resolution system for Korean using Mention Pair with SVM. The system introduced in this paper, also be able to extract Mention from document which is including automatically tagged name entity information, dependency trees and POS tags. We also built a corpus, including 214 documents with Coreference tags, referencing online news and Wikipedia for training the system and testing the system's performance. The corpus had 14 documents from online news, along with 200 question-and-answer documents from Wikipedia. When we tested the system by corpus, the performance of the system was extracted by MUC-F1 55.68%, B-cube-F1 57.19%, and CEAFE-F1 61.75%.